共查询到18条相似文献，搜索用时 125 毫秒
1.
利用稳定同位素大气水平衡模式（iAWBM）,在一个水平衡和水稳定同位素平衡的框架下以及在相同的气象驱动下,模拟在不同的下垫面蒸发和不同的云中凝结分馏条件下降水中稳定同位素效应的空间分布特征,并通过与GNIP实测数据的比较以及模拟试验结果之间的相互比较,揭示云中的稳定同位素分馏和从下垫面蒸发的水汽同位素δe对降水中稳定同位素变化的可能影响,增进对全球水循环中稳定同位素效应的理解和认识。结果显示：iAWBM的4个模拟试验均很好地再现了全球降水中平均δ18O和平均δ18O季节差的空间分布特征;很好地模拟了降水同位素的温度效应、降水量效应的分布特点以及全球的大气水线MWL;比较而言,平衡分馏假设下模拟的全球降水中平均δ18O的空间分布与根据GNIP数据得到的实际空间分布以及模拟的全球MWL与实际MWL最接近,且模拟效果亦最好;动力分馏假设下模拟的降水中δ18O平均季节差的空间分布与根据GNIP数据得到的实际分布之间的相关程度较好,且拟合水平明显提高;在动力分馏和δe季节性的假设下,iAWBM再现全球δ18O-T和δ18O-P相关关系空间分布的能力较强。 相似文献
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利用稳定同位素大气水平衡模式,模拟了2012年全球大气水汽和降水中δ18O的空间分布和时间变化以及降水中δ18O与降水量、温度之间的关系.其目的在于检验稳定同位素大气水平衡模式模拟水稳定同位素循环的能力,揭示稳定同位素效应产生的主要原因,改善对水循环中稳定同位素效应的理解和认识.模拟结果很好地再现了全球降水中δ18O的纬度效应、大陆效应和季节差异.在水循环过程中,引起降水中稳定同位素空间变化和时间变化的原因与蒸发对水汽同位素的富集作用、降水对水汽同位素的贫化作用、凝结温度对水汽同位素贫化程度的影响有关.模拟的降水量效应主要出现在中低纬度海洋和季风区,这种分布形势与δ18O季节差和降水量季节差的分布相对应;模拟的温度效应主要出现在中高纬度陆地,这种分布形势与降水中δ18O季节差的分布形势相对应.在一些低纬度地区,伴随强降水量效应的出现,温度效应也同时出现. 相似文献
3.
全球降水中氢氧稳定同位素GCM模拟空间分布的比较 总被引：1，自引：0，他引：1
《地球科学进展》2017,(9)
利用大气环流模式模拟降水中氢氧稳定同位素可以深入了解水循环过程中水稳定同位素的迁移变化规律并弥补实测数据在空间和时间方面的不连续性。利用10个引入水稳定同位素循环的GCM(General Circulation Models)模拟数据,分析了全球降水中稳定同位素效应的空间分布特征,对不同模式的模拟结果之间以及模拟结果与全球降水同位素监测网络(GNIP)的实际监测结果之间进行了比较,旨在对稳定同位素大气环流模式模拟结果的有效性进行评价,改善对水循环中水稳定同位素效应的理解和认识。结果显示,在δ~(18)O的全球空间分布模拟方面,iso GSM,ECHAM4,LMDZ4和Had AM3模拟效果较佳;在δ~(18)O的季节差的空间分布模拟方面各模式模拟效果总体较好,仅Had AM3模拟效果稍差;在δ~(18)O与气温相关关系的空间分布模拟方面,iso GSM,GISS E-F,ECHAM4,GISS E-N和LMDZ4模拟结果与实测较匹配;在δ~(18)O与降水量相关关系的空间分布模拟方面LMDZ4,iso GSM,GISS E-F,ECHAM4和MUGCM模拟能力较强;在全球大气降水线模拟方面GISS E-F,iso GSM和GISS E-N优势明显。 相似文献
4.
降水中氢氧稳定同位素的空间分布是同位素水文学和同位素生态学研究的基础资料， 近年来高空间分辨率的氢氧稳定同位素分布数据产品获得了越来越多的重视。利用新疆天山地区实测降水同位素数据， 评估两套常用的全球降水同位素分布模拟数据（OIPC和RCWIP）的适用性。结果表明： 从时间尺度来看， 两套产品在夏半年（4 - 10月）的模拟效果明显优于冬半年（11月 - 次年3月）； 在各自然区中， 准噶尔盆地荒漠自然区的模拟效果相对较好， 而吐鲁番盆地-哈密（戈壁）荒漠自然区模拟效果相对较差。通过均方根误差、 线性判定系数、 平均偏置误差、 平均绝对误差等指标的比较， 在本研究区内RCWIP数据产品对降水同位素值的模拟效果比OIPC的效果好。结合乌鲁木齐多年降水氢氧稳定同位素数据， 发现降水同位素年际变化差异并未明显影响到代表性， 在缺乏长期监测的情况下这两套数据仍有重要的使用价值。 相似文献
5.
利用稳定同位素大气水平衡模式（iAWBM）的模拟数据,分析了在不同的下垫面蒸发和不同的凝结分馏条件下降水中δ18O的时间变化、降水量效应、负温度效应和大气水线。并通过与长沙站5年实测数据的比较以及模拟试验结果之间的相互比较,揭示下垫面蒸发水汽中稳定同位素的季节性变化和云中稳定同位素分馏对降水中稳定同位素变化的可能影响,增进对季风区水稳定同位素效应的理解和认识。iAWBM给出的4个模拟试验均很好地再现了监测站降水中δ18O的时间变化,模拟出季风区降水中稳定同位素在暖半年被贫化、在冷半年被富集的基本特点。与平衡分馏相比,动力分馏下降水中稳定同位素被贫化的程度加强、季节差和离散程度减小;由下垫面蒸发水汽中稳定同位素δe季节性变化所引起的降水中稳定同位素的变化在不同季节完全相反：在长沙,暖半年降水中δ18O更低,冷半年降水中δ18O更高,使得降水中稳定同位素季节差和离散程度增大。4个模拟试验均很好地再现了季风区的降水量效应和负温度效应。与平衡分馏相比,动力分馏下模拟的降水量效应和负温度效应的斜率相对较小;δe季节性变化导致模拟的降水量效应和负温度效应的斜率增大。利用iAWBM,模拟出季风区湿热气候条件下的MWL。动力分馏以及δe季节变化均使模拟得到的MWL的斜率和截距减小。 相似文献
6.
湿度效应及其对降水中δ18O季节分布的影响 总被引：6，自引：3，他引：3
提出了湿度效应的概念,即降水中稳定同位素比率与大气的温度露点差ΔTd存在显著的正相关关系.对两个气候特征完全不同的取样站乌鲁木齐和昆明降水中δ18O与温度露点差之间的关系进行了分析,尽管两站的δ18O与ΔTd的季节变化存在差异,但它们的湿度效应是显著的.利用稳定同位素动力分馏模型并根据500hPa月平均温度的季节分布对昆明站云中凝结物中δ18O进行了模拟,模拟的月平均δ18O与月平均温度的变化具有非常好的一致性,说明昆明站云中凝结物中的氧稳定同位素具有温度效应.这个结果与地面降水中氧稳定同位素的降水量效应截然不同.昆明站降水中δ18O一定程度上指示大气的干湿状况,同时也间接地指示降水量的多寡或季风的强弱.湿度效应的存在,影响降落雨滴中稳定同位素蒸发富集的强度以及雨滴与大气之间稳定同位素物质迁移的方向.它不仅改变降水中稳定同位素比率的大小,也改变其季节分布的特点. 相似文献
7.
利用不同插值方法对青藏高原降水稳定同位素空间分布分析 总被引：1，自引：0，他引：1
利用稳定同位素大气环流模型模拟结果, 借鉴数据同化的思想, 运用Cressman插值法和最优插值法两种空间插值方法对青藏高原多年平均降水δ18O模拟结果进行客观订正, 并运用交叉验证方法检验空间插值的效果. 结果表明: 最优插值法订正的结果稍优于Cressman插值法; 对比订正结果与运用经验回归模型BW模拟结果表明, 最优插值所建立的降水稳定同位素的空间分布结果要优于BW模型模拟结果, 而Cressman插值方法订正的降水稳定同位素的空间分布结果与BW模型模拟的结果相当. 两种空间插值所得结果经过高程订正后, 对青藏高原南部的预测结果得到了明显改善. 相似文献
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10.
以GNIP为数据源,选取研究了黄土高原区7个站点(兰州、银川、靖边、西安、平凉、包头、太原)降水中稳定同位素的时空变化特征,分析了除靖边站之外的其他站点降水同位素与温度和降水量的关系,揭示了该地区降水中稳定同位素的变化规律。结果表明:(1)黄土高原大气降水稳定同位素在不同的区域有着相似的时间变化特征和不同的空间变化特征;(2)建立了黄土高原区域大气降水线方程δD=7.0δ18O+0.36‰;(3)黄土高原各站点降水同位素的温度效应和雨量效应表现出较为显著的空间特性;(4)黄土高原区在冬季风期间较夏季风期间风速大、湿度低且蒸发强烈。 相似文献
11.
水体蒸发过程中稳定同位素分馏的模拟 总被引：16，自引：3，他引：13
通过对非平衡条件下水体蒸发中稳定同位素分馏机制的分析, 模拟了蒸发水体中稳定同位素比率的变化及与温度、大气湿度的关系. 在瑞利模式中, 剩余水中的稳定同位素随剩余水比例f的减小不断富集, 富集的速率与温度呈反比. 在动力蒸发条件下, 稳定同位素的分馏不仅与相变温度有关, 而且受大气湿度和液-气相之间物质交换的影响. 在动力蒸发过程中, 相对湿度越小, 剩余水中稳定同位素比率随 f的变化越快. 当相对湿度较大时, 在经历了一段时间蒸发后的剩余水中的δ将不随 f变化. 蒸发水体达到稳定状态的速率主要取决于大气的相对湿度. 当温度约20℃时, 在瑞利平衡条件下模拟的蒸发线与全球大气水线较接近. 在非平衡蒸发条件下, 蒸发线的梯度项和常数项与温度和相对湿度呈正比. 相似文献
12.
Naoyuki Kurita Kimpei Ichiyanagi Jun Matsumoto Manabu D. Yamanaka Tetsuo Ohata 《Journal of Geochemical Exploration》2009,102(3):113
General circulation models (GCMs) fitted with stable isotope schemes are widely used to interpret the isotope–climate relationship. However, previous studies have found that the spatiotemporal isotope/precipitation correlation simulated by GCMs is stronger and more widespread than the observed value. To understand the reason for this failure, we investigated the factors influencing the empirically well-known isotope/precipitation relationship, or precipitation amount effect, in the tropics using newly obtained daily precipitation isotope monitoring data over Asia. As in previous studies, we found an apparent correlation between the long-term monthly mean isotopic content and the corresponding precipitation amount (local precipitation) observed at sub-tropical island stations. Furthermore, on a monthly timescale, the isotopic variability of precipitation for these stations was more clearly related to the regional precipitation amount than to local precipitation. This correlation of isotopic content with the regional precipitation amount was observed at the equatorial (Maritime Continent) stations. For these stations, isotope/local precipitation relationships only appeared over longer timescales, with different regression line slopes at each station. However, at the coastal stations, there was a strong linear relationship between the monthly mean isotopic content and corresponding regional precipitation, and regression line slopes were spatially uniform. For the two sub-tropical terrestrial (Indochina Peninsula) stations, the isotopic minimum appeared without any relationship to rainfall amount but usually occurred at the leeward station during the rainy season. These results suggest that the isotopic variations of precipitation did not depend on the ’local’ rain-out history but on the rain-out process in the surrounding region. However, local rainfall events were associated not only with large-scale disturbances but also with regional circulation. Thus, the scale difference of controlling factors between local rainfall amount and isotopic value results in the weakening of the rainfall amount effect at the observation site and in the discrepancy between GCM simulations and observations. This finding suggests that regional precipitation–isotope relationships should be compared with GCM results. Additionally, because the isotope signal reflects the rain-out history at a regional scale, evaluation of the isotopic field using isotopic GCMs will be useful not only to reconstruct paleoclimate conditions but also to examine how GCMs can reproduce real atmospheric circulation over the tropics. 相似文献
13.
Yanjun Che Mingjun Zhang Shengjie Wang Jie Wang Yangmin Liu Fuxian Zhang 《Arabian Journal of Geosciences》2016,9(19):732
The stable water isotope ratio in precipitation is a useful tracer of atmospheric circulation. Such observations, however, are very limited in space and time. To solve this problem, many isotope-enabled general circulation models (GCMs) are used to help the interpretation of isotope proxies. In this paper, several isotope-enabled GCMs released by the second Stable Water Isotope Intercomparison Group (SWING2) were selected to assess the spatial pattern of deuterium (δD) and the deuterium excess (d) of precipitation in China. The isotopic data of the Global Network of Isotopes in Precipitation (GNIP) and the Chinese Network of Isotopes in Precipitation (CHNIP) were also applied to verify the simulations. The results indicate that these models accurately simulate the spatial characteristics of δD and d of precipitation in China. The correlation between the observations and simulations for LMDZ is the highest among these models, while the root-mean-square (RMS) and standard deviation are not perfect. In addition, LMDZ is worse than other models in capturing the low signal in certain regions, such as CAM, GISS_E, and MIROC. For the monthly variation, most SWING2 models underestimate δD of the precipitation but overestimate the value of d, except for isoGSM. The simulated monthly variation of the water isotopes from SWING2 models is in general similar to the observations, and the trend corresponds to the monthly variation in the Northern Hemisphere. Moreover, all models are good at illustrating the temperature and precipitation amount effects, while they exhibit varying skills in interpreting the altitude and continental effects. 相似文献
14.
Yunyan Ni Geoffrey S. Ellis Barry Katz Yongchun Tang 《Geochimica et cosmochimica acta》2011,75(10):2696-2707
Based on quantum chemistry calculations for normal octane homolytic cracking, a kinetic hydrogen isotope fractionation model for methane, ethane, and propane formation is proposed. The activation energy differences between D-substitute and non-substituted methane, ethane, and propane are 318.6, 281.7, and 280.2 cal/mol, respectively. In order to determine the effect of the entropy contribution for hydrogen isotopic substitution, a transition state for ethane bond rupture was determined based on density function theory (DFT) calculations. The kinetic isotope effect (KIE) associated with bond rupture in D and H substituted ethane results in a frequency factor ratio of 1.07. Based on the proposed mathematical model of hydrogen isotope fractionation, one can potentially quantify natural gas thermal maturity from measured hydrogen isotope values. Calculated gas maturity values determined by the proposed mathematical model using δD values in ethane from several basins in the world are in close agreement with similar predictions based on the δ13C composition of ethane. However, gas maturity values calculated from field data of methane and propane using both hydrogen and carbon kinetic isotopic models do not agree as closely. It is possible that δD values in methane may be affected by microbial mixing and that propane values might be more susceptible to hydrogen exchange with water or to analytical errors. Although the model used in this study is quite preliminary, the results demonstrate that kinetic isotope fractionation effects in hydrogen may be useful in quantitative models of natural gas generation, and that δD values in ethane might be more suitable for modeling than comparable values in methane and propane. 相似文献
15.
作为古气候代用指标,石笋氧同位素为亚洲季风演化研究提供了一系列可靠的证据。然而,关于石笋氧同位素指示的气候意义一直存在争论。本文选取了位于神农架地区海拔1250～2250m的黑龙洞、青天洞和三宝洞3个洞穴进行对比分析,发现不同海拔洞穴石笋δ18O在波动形式上相同,但绝对值存在约-0.1‰/100m的系统差,而大气降水的在该地的海拔效应约为-0.2‰/100m。为此,我们认为,石笋δ18O除了受季风降雨的影响外,不同海拔的温度梯度也对石笋δ18O具有较大的贡献。结合洞穴年均温度,初步估算石笋δ18O的温度效应约为-0.25‰/℃,与O’Neil的同位素平衡分馏计算结果相同。 相似文献
16.
Sizhong Yang Xianyong Cao Huijun Jin 《Boreas: An International Journal of Quaternary Research》2015,44(3):502-510
Inactive ice wedges are still present today at Yituli'he in the middle Da Xing'anling (Greater Hinggan) Mountains in northeastern China, which is the southernmost known site (50°37′N) with ice wedges in the Northern Hemisphere. However, it is uncertain whether the ice‐wedge isotope composition, characterized by low δ18O, δD and low deuterium excess values, is representative of the isotope signature of a broader region. In this paper, the ice‐wedge isotope compositions were examined in the context of the stable isotopes of precipitation from the nearby Global Network of Isotopes in Precipitation (GNIP) stations. In addition, the pollen spectra from the host sediments were analysed to provide additional information on local vegetation in order to better understand the climate conditions favouring ice‐wedge formation. The pollen spectra suggest that the Yituli'he ice wedges developed during the colder and wetter period after 6000 cal. a BP. The isotopes in the Yituli'he ice wedges are consistent with the isotope background recorded in atmospheric precipitation collected at the nearby GNIP stations. When the snow‐melt froze into ice veinlets, the isotope signals did not change substantially because of the strong, cold, continental anticyclones in winter as well as a strong temperature inversion that prevail in the Da Xing'anling Mountains. As the climate pattern did not change substantially, the neoglacial cold period is unlikely to have allowed for strong secondary fractionation of isotope records during ice‐wedge formation. Thus, the annual isotope signature can be interpreted as a valid archive of climate data. 相似文献
17.
华北地区大气降水稳定同位素特征与水汽来源 总被引：4，自引：0，他引：4
选取华北地区的包头,石家庄,天津,太原IAEA/WMO/GNIP大气降水的氢氧同位素组成的资料,分析了华北地区降水稳定同位素的时空分布特征及其影响因素.研究表明:华北地区降水中的δ18O值都表现出明显的“夏高冬低”的季风气候特征,夏季表现雨量效应,冬季温度效应明显;华北各地区降水线方程与全国及全球降水线相比,斜率和截距都偏小,揭示了华北地区降水是在非瑞利条件下进行的,并且除天津外,其他地区稳定同位素特征还受到降水过程中局地水汽循环的影响;d值总体表现出冬高夏低的季节变化特征,说明了冬季风和夏季风期间降水的水源区蒸发条件不同. 相似文献
18.
Yong-Fei Zheng 《地学学报》1991,3(5):510-516
Correlative fractionation relationships of sulphur isotope data for coexisting sulphate and sulphide pairs from hydrothermal ore deposits on δ38S versus Δ34S diagrams are deciphered theoretically. Taking into account dissolved H2S and SO42- in hydrothermal fluids during precipitation of both sulphate and sulphide minerals, a 4-species closed system is suggested for describing the conservation of mass among all sulphur-bearing species on the δ-Δ diagrams. The covariation in the δ34S values of both sulphate and sulphide is ascribed to isotopic exchange between oxidized and reduced sulphur species during mineral precipitation. The isotopic exchange could be a thermodynamic process due to simple cooling of high temperature fluids, which results in an equilibrium fractionation, or a kinetic process due to mixing of two sulphur reservoirs, which leads to a disequilibrium fractionation. The δ34S value of total sulphur in a hydrothermal system could change due to the precipitation of minerals, or due to the escape of H2S and/or SO42-. Sulphur isotope data for anhydrite and pyrite pairs from the Luohe porphyrite iron deposit in the Yangtze River Valley is used to illustrate the mixing responsible for the disequilibrium fractionation. 相似文献