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1.
Previous studies of diamonds from Finsch have shown that eclogitic inclusions are rare at Finsch and that the eclogitic garnet and clinopyroxenes are iron and manganese-rich. In order to expand the current database of information, 93 eclogitic diamonds were selected for this study. Eight diamonds were polished into plates for cathodoluminescence studies and infrared examination of diamond growth and 31 diamonds were cracked to retrieve inclusions. The eclogitic garnets analysed in this study are enriched in Fe and are relatively depleted in Ca and Mg relative to worldwide data. FeO contents for garnet range from 15 to 27 wt.% and MnO contents reach a maximum value of 1.6 wt.%. The eclogitic clinopyroxenes have relatively high FeO contents, up to 14.8 wt.% and K 2O contents are low (<0.4 wt.%). Three non-touching garnet–clinopyroxene mineral pairs produce equilibration temperatures of 1138–1179 °C at an assumed pressure of 50 kb. No Type II diamonds were found during this study, all diamonds are of Type IaAB. Total nitrogen contents of Type IaAB diamonds range from 11 to 1520 ppm, with variable aggregation states (up to 84% nitrogen aggregated as B-defects). Distinct infrared characteristics suggest that the Finsch kimberlite sampled either more than one mantle source region of similar age but differing temperature, or two different populations of diamonds with different ages. The diamonds provide evidence of changing mantle conditions during crystallisation. Continuous diamond growth is illustrated by the presence of regular octahedral growth zones, although in some diamonds cubic growth is noted. One diamond shows evidence of platelet degradation, suggesting exposure to high temperatures and/or shearing stresses. 相似文献
2.
A mineral inclusion, carbon isotope, nitrogen content, nitrogen aggregation state and morphological study of 576 microdiamonds from the DO27, A154, A21, A418, DO18, DD17 and Ranch Lake kimberlites at Lac de Gras, Slave Craton, was conducted. Mineral inclusion data show the diamonds are largely eclogitic (64%), followed by peridotitic (25%) and ultradeep (11%). The paragenetic abundances are similar to macrodiamonds from the DO27 kimberlite (Davies, R.M., Griffin, W.L., O'Reilly, S.Y., 1999. Diamonds from the deep: pipe DO27, Slave craton, Canada. In: Gurney, J.J., Gurney, J.L., Pascoe, M.D., Richardson, S.H. (Eds.), The J. B. Dawson Vol., Proc. 7th Internat. Kimberlite Conf., Red Roof Designs, Cape Town, pp. 148–155) but differ to diamonds from nearby kimberlites at Ekati (e.g., Lithos (2004); Tappert, R., Stachel, T., Harris, J.W., Brey, G.P., 2004. Mineral Inclusions in Diamonds from the Panda Kimberlite, S. P., Canada. 8th International Kimberlite Conference, extended abstracts) and Snap Lake to the south (Dokl. Earth Sci. 380 (7) (2001) 806), that are dominated by peridotitic stones. Eclogitic diamonds with variable inclusion compositions and temperatures of formation (1040–1300 °C) crystallised at variable lithospheric depths sometimes in changing chemical environments. A large range to very 13C-depleted C-isotope compositions (δ13C=−35.8‰ to −2.2‰) and an NMORB bulk composition, calculated from trace elements in garnet and clinopyroxene inclusions, are consistent with an origin from subducted oceanic crust and sediments. Carbon isotopes in the peridotitic diamonds have mantle compositions (δ13C mode −4.0‰). Mineral inclusion compositions are largely harzburgitic. Variable temperatures of formation (garnet TNi=800–1300 °C) suggest the peridotitic diamonds originate from the shallow ultra-depleted and deeper less depleted layers of the central Slave lithosphere. Carbon isotopes (δ13C av.=−5.1‰) and mineral inclusions in the ultradeep diamonds suggest they formed in peridotitic mantle (670 km). The diamonds may have been entrained in a plume and subcreted to the base of the central Slave lithosphere. Poorly aggregated nitrogen (IaA without platelets) in a large number of eclogitic (67%) and peridotitic (32%) diamonds, with similar nitrogen contents, indicates the diamonds were stored in the mantle at low temperatures (1060–<1100 °C) following crystallisation in the Archean. Type IaA diamonds have largely cubo-octahedral growth forms, and Type II and Type IaAB diamonds, with higher nitrogen aggregation states, mostly have octahedral morphologies. However, no correlation between these groups and their mineral inclusion compositions, C-isotopes, and N-contents rules out the possibility of unique source origins and suggests eclogitic and peridotitic diamonds experienced variable mantle thermal states. Variation in mineral inclusion chemistries in single diamonds, possible overgrowths of 13C-depleted eclogitic diamond on diamonds with peridotitic and ultradeep inclusions, and Type I ultradeep diamond with low N-aggregation is consistent with diamond growth over time in changing chemical environments. 相似文献
3.
Kimberlite pipes K11, K91 and K252 in the Buffalo Head Hills, northern Alberta show an unusually large abundance (20%) of Type II (no detectable nitrogen) diamonds. Type I diamonds range in nitrogen content from 6 ppm to 3300 ppm and in aggregation states from low (IaA) to complete (IaB). The Type IaB diamonds extend to the lowest nitrogen concentrations yet observed at such high aggregation states, implying that mantle residence occurred at temperatures well above normal lithospheric conditions. Syngenetic mineral inclusions indicate lherzolitic, harzburgitic, wehrlitic and eclogitic sources. Pyropic garnet and forsteritic olivine characterize the peridotitic paragenesis from these pipes. One lherzolitic garnet inclusion has a moderately majoritic composition indicating a formation depth of ∼ 400 km. A wehrlitic paragenesis is documented by a Ca-rich, high-chromium garnet and very CaO-rich (0.11–0.14 wt.%) olivine. Omphacitic pyroxene and almandine-rich garnet are characteristic of the eclogitic paragenesis. A bimodal δ13C distribution with peaks at − 5‰ and − 17‰ is observed for diamonds from all three kimberlite pipes. A large proportion (∼ 40%) of isotopically light diamonds ( δ13C < −10‰) indicates a predominantly eclogitic paragenesis.The Buffalo Head Terrane is of Lower Proterozoic metamorphic age (2.3–2.0 Ga) and hence an unconventional setting for diamond exploration. Buffalo Hills diamonds formed during multiple events in an atypical mantle setting. The presence of majorite and abundance of Type II and Type IaB diamonds suggests formation under sublithospheric conditions, possibly in a subducting slab and resulting megalith. Type IaA to IaAB diamonds indicate formation and storage under lower temperature in normal lithospheric conditions. 相似文献
4.
Mineral inclusions recovered from 100 diamonds from the A154 South kimberlite (Diavik Diamond Mines, Central Slave Craton, Canada) indicate largely peridotitic diamond sources (83%), with a minor (12%) eclogitic component. Inclusions of ferropericlase (4%) and diamond in diamond (1%) represent “undetermined” parageneses. Compared to inclusions in diamonds from the Kaapvaal Craton, overall higher CaO contents (2.6 to 6.0 wt.%) of harzburgitic garnets and lower Mg-numbers (90.6 to 93.6) of olivines indicate diamond formation in a chemically less depleted environment. Peridotitic diamonds at A154 South formed in an exceptionally Zn-rich environment, with olivine inclusions containing more than twice the value (of 52 ppm) established for normal mantle olivine. Harzburgitic garnet inclusions generally have sinusoidal rare earth element (REEN) patterns, enriched in LREE and depleted in HREE. A single analyzed lherzolitic garnet is re-enriched in middle to heavy REE resulting in a “normal” REEN pattern. Two of the harzburgitic garnets have “transitional” REEN patterns, broadly similar to that of the lherzolitic garnet. Eclogitic garnet inclusions have normal REEN patterns similar to eclogitic garnets worldwide but at lower REE concentrations. Carbon isotopic values (δ13C) range from − 10.5‰ to + 0.7‰, with 94% of diamonds falling between − 6.3‰ and − 4.0‰. Nitrogen concentrations range from below detection (< 10 ppm) to 3800 ppm and aggregation states cover the entire spectrum from poorly aggregated (Type IaA) to fully aggregated (Type IaB). Diamonds without evidence of previous plastic deformation (which may have accelerated nitrogen aggregation) typically have < 25% of their nitrogen in the fully aggregated B-centres. Assuming diamond formation beneath the Central Slave to have occurred in the Archean [Westerlund, K.J., Shirey, S.B., Richardson, S.H., Gurney, J.J., Harris, J.W., 2003b. Re–Os systematics of diamond inclusion sulfides from the Panda kimberlite, Slave craton. VIIIth International Kimberlite Conference, Victoria, Canada, Extended Abstracts, 5p.], such low aggregation states indicate mantle residence at fairly low temperatures (< 1100 °C). Geothermometry based on non-touching inclusion pairs, however, indicates diamond formation at temperatures around 1200 °C. To reconcile inclusion and nitrogen based temperature estimates, cooling by about 100–200 °C shortly after diamond formation is required. 相似文献
5.
In a diamond from New South Wales (Australia), cubic and octahedral growth sectors, as identified by cathodoluminescence (CL), show slight differences in N-contents of 29 and 42 ppm respectively but no significant differences in either δ 13C, δ 15N and nitrogen aggregation state with values at +1.96‰, +19.4‰, and 25% Type IaAB aggregation, respectively.Two gem cubes from the Orapa kimberlite (Botswana) were studied by CL revealing a nonfaceted cubic growth. Accordingly, nine other gem cubes were combusted and yielded δ 13C-values from -5.33‰ to -6.63‰, δ 15N from -1.0‰ to -5.5‰, and nitrogen contents from 914 to 1168 ppm, with nitrogen aggregation state being only Type IaA (zero % B). The gem cubes show striking similarities to fibrous/coated diamonds, not only in both δ 13C ranges (less than 3‰ from -5 to -8‰), but also in the high levels of nitrogen (≈ 1000 ppm), suggesting that the two diamond types are related. Additionally, no δ 15N variation was detected between the cube and octahedral growth sectors of the Australian diamond, in the cube sectors of the nine gem cubes from Botswana, nor in fibrous/coated diamonds previously studied. These analyses contrast with an earlier study on a synthetic diamond, which reported a strong kinetic fractionation of N-isotopes of about 40‰ between cube and octahedral growth. The present evidence, therefore, suggests that kinetic fractionation of N-isotopes does not operate during natural diamond formation. 相似文献
6.
Analyses of mineral inclusions, carbon isotopes, nitrogen contents and nitrogen aggregation states in 29 diamonds from two Buffalo Hills kimberlites in northern Alberta, Canada were conducted. From 25 inclusion bearing diamonds, the following paragenetic abundances were found: peridotitic (48%), eclogitic (32%), eclogitic/websteritic (8%), websteritic (4%), ultradeep? (4%) and unknown (4%). Diamonds containing mineral inclusions of ferropericlase, and mixed eclogitic-asthenospheric-websteritic and eclogitic-websteritic mineral associations suggests the possibility of diamond growth over a range of depths and in a variety of mantle environments (lithosphere, asthenosphere and possibly lower mantle). Eclogitic diamonds have a broad range of C-isotopic composition (δ13C=−21‰ to −5‰). Peridotitic, websteritic and ultradeep diamonds have typical mantle C-isotope values (δ13C=−4.9‰ av.), except for two 13C-depleted peridotitic (δ13C=−11.8‰, −14.6‰) and one 13C-depleted websteritic diamond (δ13C=−11.9‰). Infrared spectra from 29 diamonds identified two diamond groups: 75% are nitrogen-free (Type II) or have fully aggregated nitrogen defects (Type IaB) with platelet degradation and low to moderate nitrogen contents (av. 330 ppm-N); 25% have lower nitrogen aggregation states and higher nitrogen contents (30% IaB; <1600 ppm-N). The combined evidence suggests two generations of diamond growth. Type II and Type IaB diamonds with ultradeep, peridotitic, eclogitic and websteritic inclusions crystallised from eclogitic and peridotitic rocks while moving in a dynamic environment from the asthenosphere and possibly the lower mantle to the base of the lithosphere. Mechanisms for diamond movement through the mantle could be by mantle convection, or an ascending plume. The interaction of partial melts with eclogitic and peridotitic lithologies may have produced the intermediate websteritic inclusion compositions, and can explain diamonds of mixed parageneses, and the overlap in C-isotope values between parageneses. Strong deformation and extremely high nitrogen aggregation states in some diamonds may indicate high mantle storage temperatures and strain in the diamond growth environment. A second diamond group, with Type IaA–IaB nitrogen aggregation and peridotitic inclusions, crystallised at the base of the cratonic lithosphere. All diamonds were subsequently sampled by kimberlites and transported to the Earth's surface. 相似文献
7.
Diamonds from the Kankan area in Guinea formed over a large depth profile beginning within the cratonic mantle lithosphere and extending through the asthenosphere and transition zone into the lower mantle. The carbon isotopic composition, the concentration of nitrogen impurities and the nitrogen aggregation level of diamonds representing this entire depth range have been determined. Peridotitic and eclogitic diamonds of lithospheric origin from Kankan have carbon isotopic compositions (' 13C: peridotitic -5.4 to -2.2; eclogitic -19.7 to -0.7) and nitrogen characteristics (N: peridotitic 17-648 atomic ppm; eclogitic 0-1,313 atomic ppm; aggregation from IaA to IaB) which are generally typical for diamonds of these two suites worldwide. Geothermobarometry of peridotitic and eclogitic inclusion parageneses (worldwide sources) indicates that both suites formed under very similar conditions within the cratonic lithosphere, which is not consistent with a derivation of diamonds with light carbon isotopic composition from subducted organic matter within subducting oceanic slabs. Diamonds containing majorite garnet inclusions fall to the isotopically heavy side (' 13C: -3.1 to +0.9) of the worldwide diamond population. Nitrogen contents are low (0-126 atomic ppm) and one of the two nitrogen-bearing diamonds shows such a low level of nitrogen aggregation (30% B-centre) that it cannot have been exposed to ambient temperatures of the transition zone (̿,400 °C) for more than 0.2 Ma. This suggests rapid upward transport and formation of some Kankan diamonds pene-contemporaneous to Cretaceous kimberlite activity. Similar to these diamonds from the asthenosphere and the transition zone, lower mantle diamonds show a small shift towards isotopic heavy compositions (-6.6 to -0.5, mode at -3.5). As already observed for other mines, the nitrogen contents of lower mantle diamonds were below detection (using FTIRS). The mutual shift of sublithospheric diamonds towards isotopic heavier compositions suggests a common carbon source, which may have inherited an isotopic heavy composition from a component consisting of subducted carbonates. 相似文献
8.
Major element and Re–Os isotope analysis of single sulfide inclusions in diamonds from the 240 Ma Jwaneng kimberlite has revealed the presence of at least two generations of eclogitic diamonds at this locality, one Proterozoic (ca. 1.5 Ga) and the other late Archean (ca. 2.9 Ga). The former generation is considered to be the same as that of eclogitic garnet and clinopyroxene inclusion bearing diamonds from Jwaneng with a Sm–Nd isochron age of 1.54 Ga. The latter is coeval with the 2.89 Ga subduction-related generation of eclogitic sulfide inclusion bearing diamonds from Kimberley formed during amalgamation of the western and eastern Kaapvaal craton near the Colesberg magnetic lineament. The Kimberley, Jwaneng, and Premier kimberlites are key localities for characterizing the relationship between episodic diamond genesis and Kaapvaal craton evolution. Kimberley has 3.2 Ga harzburgitic diamonds associated with creation of the western Kaapvaal cratonic nucleus, and 2.9 Ga eclogitic diamonds resulting from its accretion to the eastern Kaapvaal. Jwaneng has two main eclogitic diamond generations (2.9 and 1.5 Ga) reflecting both stabilization and subsequent modification of the craton. Premier has 1.9 Ga lherzolitic diamonds that postdate Bushveld–Molopo magmatism (but whose precursors have Archean Sm–Nd model ages), as well as 1.2 Ga eclogitic diamonds. Thus, Jwaneng provides the overlap between the dominantly Archean vs. Proterozoic diamond formation evident in the Kimberley and Premier diamond suites, respectively. In addition, the 1.5 Ga Jwaneng eclogitic diamond generation is represented by both sulfide and silicate inclusions, allowing for characterization of secular trends in diamond type and composition. Results for Jwaneng and Kimberley eclogitic sulfides indicate that Ni- and Os-rich end members are more common in Archean diamonds compared to Proterozoic diamonds. Similarly, published data for Kimberley and Premier peridotitic silicates show that Ca-rich (lherzolitic) end members are more likely to be found in Proterozoic diamonds than Archean diamonds. Thus, the available diamond distribution, composition, and age data support a multistage process to create, stabilize, and modify Archean craton keels on a billion-year time scale and global basis. 相似文献
9.
The Venetia kimberlites in the Northern Province of South Africa sampled diamonds from the lithosphere underlying the Central Zone of the Limpopo Belt. Given the general correlation of diamond-bearing kimberlites with old stable cratons, this tectonic setting is somewhat anomalous and, therefore, it is desirable to characterise the diamonds in terms of their infrared characteristics. A suite of diamonds of known paragenesis from the Venetia mine spans a large range of nitrogen concentrations from less than the detection limit to 1,355 ppm. Diamond nitrogen contents are, on average, higher in the eclogitic diamond population relative to the websteritic and peridotitic diamonds. Nitrogen aggregation states are variable, ranging from almost pure type IaA diamond (poorly aggregated nitrogen) to pure type IaB diamond (highly aggregated nitrogen). On a nitrogen aggregation diagram two distinct groups can be identified based on nitrogen content and nitrogen aggregation state. These are a minor population of diamonds with nitrogen contents generally higher than 500 ppm and nitrogen aggregation states of less than 40% IaB, and another, dominant population that is characterised by higher and more variable nitrogen aggregation. The unusually aggregated nature of the majority of the diamonds analysed is unique to Venetia relative to other intrusives on the Kaapvaal-Kalahari craton, but is similar to aggregation states observed for diamonds from other craton margin or adjacent mobile belt settings such as the Argyle lamproite and the George Creek kimberlite. This could be a consequence of diamond mantle residence at mantle temperatures higher than the norm for other kimberlites from the interior of cratons. Deformation of the mantle, associated with dynamic processes such as orogenesis or subduction, might also be responsible for accelerating the rate of nitrogen aggregation in these diamonds. Low numbers of diamonds with degradation of platelets at the Venetia kimberlite, relative to diamonds from the Argyle lamproite, indicate that deformation was at a significantly lower level. The comparatively low value of diamonds from Argyle (at approximately US8/ carat) as opposed to Venetia ( US8/carat) as opposed to Venetia (US90/carat) is in large part because of the very high abundance of brown diamonds at Argyle. Therefore, it is apparent that deformational history of the mantle in which the diamonds were resident prior to or during sampling by the host may have an important role to play in the profitability of a primary diamond deposit. The apparently consistent association of diamonds with unusually aggregated nitrogen with kimberlites, or lamproites intruded into craton margin or mobile belt settings suggests that it may be possible to recognise such contributory sources in alluvial diamond deposits, through the study of the infrared characteristics of the diamonds. Electronic supplementary material to this paper can be obtained by using the Springer Link server located at http://dx.doi.org/10.1007/s00410-002-0385-2 相似文献
10.
Two decades of diamond research in southern Africa allow the age, average N content and carbon composition of diamonds, and the dominant paragenesis of their syngenetic silicate and sulfide inclusions to be integrated on a cratonwide scale with a model of craton formation. Individual eclogitic sulfide inclusions in diamonds from the Kimberley area kimberlites, Koffiefontein, Orapa and Jwaneng have Re–Os isotopic ages that range from circa 2.9 Ga to the mid-Proterozoic and display little correspondence with the prominent variations in the P-wave velocity (±1%) that the mantle lithosphere shows at depths within the diamond stability field (150–225 km). Silicate inclusions in diamonds and their host diamond compositions for the above kimberlites, Finsch, Jagersfontein, Roberts Victor, Premier, Venetia, and Letlhakane show a regional relationship to the seismic velocity of the lithosphere. Mantle lithosphere with slower P-wave velocity relative to the craton average correlates with a greater proportion of eclogitic vs. peridotitic silicate inclusions in diamond, a greater incidence of younger Sm–Nd ages of silicate inclusions, a greater proportion of diamonds with lighter C isotopic composition, and a lower percentage of low-N diamonds. The oldest formation ages of diamonds support a model whereby mantle that became part of the continental keel of cratonic nuclei first was created by middle Archean (3.2–3.3 Ga or older) mantle depletion events with high degrees of melting and early harzburgite formation. The predominance of eclogitic sulfide inclusions in the 2.9 Ga age population links late Archean (2.9 Ga) subduction–accretion events to craton stabilization. These events resulted in a widely distributed, late Archean generation of eclogitic diamonds in an amalgamated craton. Subsequent Proterozoic tectonic and magmatic events altered the composition of the continental lithosphere and added new lherzolitic and eclogitic diamonds to the already extensive Archean diamond suite. Similar age/paragenesis systematics are seen for the more limited data sets from the Slave and Siberian cratons. 相似文献
11.
The Archean lithospheric mantle beneath the Kaapvaal–Zimbabwe craton of Southern Africa shows ±1% variations in seismic P-wave velocity at depths within the diamond stability field (150–250 km) that correlate regionally with differences in the composition of diamonds and their syngenetic inclusions. Seismically slower mantle trends from the mantle below Swaziland to that below southeastern Botswana, roughly following the surface outcrop pattern of the Bushveld-Molopo Farms Complex. Seismically slower mantle also is evident under the southwestern side of the Zimbabwe craton below crust metamorphosed around 2 Ga. Individual eclogitic sulfide inclusions in diamonds from the Kimberley area kimberlites, Koffiefontein, Orapa, and Jwaneng have Re–Os isotopic ages that range from circa 2.9 Ga to the Proterozoic and show little correspondence with these lithospheric variations. However, silicate inclusions in diamonds and their host diamond compositions for the above kimberlites, Finsch, Jagersfontein, Roberts Victor, Premier, Venetia, and Letlhakane do show some regional relationship to the seismic velocity of the lithosphere. Mantle lithosphere with slower P-wave velocity correlates with a greater proportion of eclogitic versus peridotitic silicate inclusions in diamond, a greater incidence of younger Sm–Nd ages of silicate inclusions, a greater proportion of diamonds with lighter C isotopic composition, and a lower percentage of low-N diamonds whereas the converse is true for diamonds from higher velocity mantle. The oldest formation ages of diamonds indicate that the mantle keels which became continental nuclei were created by middle Archean (3.2–3.3 Ga) mantle depletion events with high degrees of melting and early harzburgite formation. The predominance of sulfide inclusions that are eclogitic in the 2.9 Ga age population links late Archean (2.9 Ga) subduction-accretion events involving an oceanic lithosphere component to craton stabilization. These events resulted in a widely distributed younger Archean generation of eclogitic diamonds in the lithospheric mantle. Subsequent Proterozoic tectonic and magmatic events altered the composition of the continental lithosphere and added new lherzolitic and eclogitic diamonds to the already extensive Archean diamond suite. 相似文献
12.
The first studies of diamonds in eclogitic xenoliths from the Komsomolskaya kimberlite pipe are described. Among round and oval-shaped xenoliths with diamond ingrowths, samples with a garnet content of 40–90% of the xenolith volume dominate. Two eclogite samples contain grains of accessory rutile; a kyanite sample is also revealed. Certain samples contain two or more crystals of diamonds. Diamonds with an octahedral habit and crystals with transitional habits, which belong to an octahedral-rhombic dodecahedral row, dominate in eclogites; there are many variety VIII aggregates. A high concentration of structural nitrogen, commonly in the A form, was registered in most of the crystals. Diamonds with a small content of nitrogen impurities, 40–67% in the B1 form, are present in a number of xenoliths. The calculated temperatures of the formation of eclogitic xenoliths is 1100–1300°C. Diversity in the impurity compositions of diamonds in the same xenolith shows that these diamonds were formed at various times and in different settings. The diamond position in xenoliths, the various level of nitrogen aggregation in the diamonds, and a number of other factors point to the later formation of the diamonds, as compared to minerals of eclogites, from fluid or fluid-melts in the process of metasomatosis. 相似文献
13.
The diamond population from the Jagersfontein kimberlite is characterized by a high abundance of eclogitic, besides peridotitic
and a small group of websteritic diamonds. The majority of inclusions indicate that the diamonds are formed in the subcratonic
lithospheric mantle. Inclusions of the eclogitic paragenesis, which generally have a wide compositional range, include two
groups of eclogitic garnets (high and low Ca) which are also distinct in their rare earth element composition. Within the
eclogitic and websteritic suite, diamonds with inclusions of majoritic garnets were found, which provide evidence for their
formation within the asthenosphere and transition zone. Unlike the lithospheric garnets all majoritic garnet inclusions show
negative Eu-anomalies. A narrow range of isotopically light carbon compositions (δ 13C −17 to −24 ‰) of the host diamonds suggests that diamond formation in the sublithospheric mantle is principally different
to that in the lithosphere. Direct conversion from graphite in a subducting slab appears to be the main mechanism responsible
for diamond formation in this part of the Earth’s mantle beneath the Kaapvaal Craton. The peridotitic inclusion suite at Jagersfontein
is similar to other diamond deposits on the Kaapvaal Craton and characterized by harzburgitic to low-Ca harzburgitic compositions. 相似文献
14.
博茨瓦纳是世界上金刚石资源最为丰富的国家之一。奥拉帕金刚石矿床是该国最大的金刚石矿,矿床的金伯利岩为Ⅰ型,其中的包体可以分为2种:橄榄岩型和榴辉岩型;金刚石可以分为3类:橄榄岩型、榴辉岩型及两者的过渡类型-二辉岩型。其中,橄榄岩型和部分榴辉岩型金刚石来自于地幔结晶堆晶体,而榴辉岩型则与板块俯冲的构造-热事件有关。金伯利岩的形成时代主要为白垩纪,而金刚石则主要形成于元古宙和太古宙,金伯利岩和金刚石为不同时期的产物,金刚石为金伯利岩侵位期间捕获的上地幔物理破碎产物。其中年龄为900~1000Ma的金刚石为板块构造-热事件的产物,并对早期金刚石进行了改造破坏。 相似文献
15.
Ar–Ar age measurements are reported for selected eclogitic clinopyroxene and garnet inclusions in Orapa diamonds and clinopyroxene inclusions in Venetia diamonds. Laser drilling of encapsulated clinopyroxene inclusions within Venetia diamonds released a maximum of 3% of the total 40Ar, indicating little diffusive transfer and storage of radiogenic 40Ar at the diamond–inclusion boundary. Apparent ages obtained during stepped heating of three diamonds are consistent with diamond crystallisation occurring just prior to the kimberlite eruption 520 Ma ago. Stepped heating of three clinopyroxene-bearing Orapa diamonds gave ages of 906–1032 Ma, significantly above the eruption age, but consistent with previously determined isotopic ages. A few higher apparent ages hint at the presence an older generation of Orapa diamonds that formed >2500 Ma ago. Orapa garnets also contain measurable K contents, and record a range of ages between 1000 and 2500 Ma. The old apparent ages and lack of significant interface 40Ar released by the laser probe, suggests that pre-eruption radiogenic 40Ar and mantle-derived 40Ar components are trapped in microinclusions within the pyroxene and garnet inclusions. 相似文献
16.
The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/ Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO 2 content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P- T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m 2 conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle. 相似文献
17.
FTIR microspectroscopic data were used to construct two-dimension maps showing the distribution of structural impurities and mineral microinclusions in cubic and coated octahedral diamond crystals from the Udachnaya kimberlite pipe in Yakutia. Elevated concentrations of hydrogen and total nitrogen are detected in parts corresponding to the early growth of single-episode growth regions of diamond crystals. These concentrations decrease toward the peripheral portions of these regions. The microinclusions contain water and polyphase mineral associations that preserve a high residual pressure. Microinclusions in the coats of octahedral diamond crystals are dominated by silicates, in which the intensity of IR spectral bands increases toward the peripheries, whereas the cubes posses irregularly distributed domains rich in these phases. The carbonate phases of the microinclusions are distributed according to growth zones of the crystals, and their distribution is often not correlated with the concentrations of structural impurities. The facts that microinclusions in the diamond cuboids are dominated by carbonates and that the rims of the octahedra are dominated by silicates suggest that the diamonds crystallized from dominantly carbonate and silicate fluids/ melts, respectively. The chemical composition of the microinclusions point to an eclogitic paragenesis of the crystals. Facts are obtained that provide support for the earlier hypothesis that cubic diamond crystals and coated octahedral crystals grow at metasomatic interaction between deep fluids and eclogitic rocks in the lithospheric mantle. 相似文献
18.
Three-dimensional neutron and X-ray tomography reveals the textural and spatial relationship of diamonds and associated minerals in situ, in a unique suite of 17 diamondiferous eclogites. We emphasize the reporting of X-ray imaging on mantle xenoliths, which in combination with neutron imaging enables the clear identification of diamonds and interstitial metasomatic secondary minerals. In particular, neutrons are highly sensitive to hydrogen (H), allowing for the identification of OH- and H 2O-bearing metasomatic minerals. The identification of metasomatic minerals allows for the delineation of distinct metasomatic pathways through the eclogite xenoliths. Diamonds are readily identified as the darkest greyscales due to their low attenuation, and are typically surrounded by secondary minerals, never in contact with primary minerals, and always confined within metasomatic pathways. The ubiquitous occurrence of diamonds in association with pathways suggests a potential genetic link. Both octahedral and dodecahedral diamonds are observed within individual xenoliths, suggesting multiple heterogeneous growth and dissolution processes at small scales. The distinct age dichotomy between eclogite xenoliths and metasomatic mineral assemblages implies that the observed textural relationship of diamonds and late-stage metasomatic pathways for this suite of 17 eclogites casts doubt on the theory that eclogitic diamonds formed billions of years ago. Diamonds are interpreted to have formed from multiple growth episodes, with the last of these episodes represented by the metasomatic assemblages observed in this study. This further indicates that eclogitic diamond inclusions may span large time scales from ancient ages (>2 Ga) all the way to the last growth event, perhaps even close to the time of kimberlite emplacement (~360 Ma), which has significant implications for age-dating of diamonds and the study of diamonds as a whole. 相似文献
19.
Based on a compilation of more than 100 kimberlite age determinations, four broad kimberlite emplacement patterns can be recognized in North America: (1) a northeast Eocambrian/Cambrian Labrador Sea province (Labrador, Québec), (2) an eastern Jurassic province (Ontario, Québec, New York, Pennsylvania), (3) a Cretaceous central corridor (Nunavut, Saskatchewan, central USA), and (4) a western mixed (Cambrian-Eocene) Type 3 kimberlite province (Alberta, Nunavut, Northwest Territories, Colorado/Wyoming). Ten new U–Pb perovskite/mantle zircon and Rb–Sr phlogopite age determinations are reported here for kimberlites from the Slave and Wyoming cratons of western North America. Within the Type 3 Slave craton, at least four kimberlite age domains exist: I-a southwestern Siluro-Ordovician domain (450 Ma), II-a SE Cambrian domain (540 Ma), III-a central Tertiary/Cretaceous domain (48–74 Ma) and IV-a northern mixed domain consisting of Jurassic and Permian kimberlite fields. New U–Pb perovskite results for the 614.5±2.1 Ma Chicken Park and 408.4±2.6 Ma Iron Mountain kimberlites in the State Line field in Colorado and Wyoming confirm the existence of at least two periods of pre-Mesozoic kimberlite magmatism in the Wyoming craton. A compilation of robust kimberlite emplacement ages from North America, southern Africa and Russia indicates that a high proportion of known kimberlites are Cenozoic/Mesozoic. We conclude that a majority of these kimberlites were generated during enhanced mantle plume activity associated with the rifting and eventual breakup of the supercontinent Gondwanaland. Within this prolific period of kimberlite activity, there is a good correlation between North America and Yakutia for three distinct short-duration (10 my) periods of kimberlite magmatism at 48–60, 95–105 and 150–160 Ma. In contrast, Cenozoic/Mesozoic kimberlite magmatism in southern Africa is dominated by a continuum of activity between 70–95 and 105–120 Ma with additional less-prolific periods of magmatism in the Eocene (50–53 Ma), Jurassic (150–190) and Triassic (235 Ma). Several discrete episodes of pre-Mesozoic kimberlite magmatism variably occur in North America, southern Africa and Yakutia at 590–615, 520–540, 435–450, 400–410 and 345–360 Ma. One of the surprises in the timing of kimberlite magmatism worldwide is the common absence of activity between about 250 and 360 Ma; this period is even longer in southern Africa. This >110 my period of quiescence in kimberlite magmatism is likely linked to relative crustal and mantle stability during the lifetime of the supercontinent Gondwanaland. Economic diamond deposits in kimberlite occur throughout the Phanerozoic from the Cambrian (Venetia, South Africa; Snap Lake and Kennady Lake, Canada) to the Tertiary (Mwadui, Tanzania; Ekati and Diavik in Lac de Gras, Canada). There are clearly some discrete periods when economic kimberlite-hosted diamond deposits formed globally. In contrast, the Devonian event, which is such an important source of diamonds in Yakutia, is notably absent in the kimberlite record from both southern Africa and North America. 相似文献
20.
Following the discovery of diamonds in river deposits in central South Africa in the mid nineteenth century, it was at Kimberley where the volcanic origin of diamonds was first recognized. These volcanic rocks, that were named “kimberlite”, were to become the corner stone of the economic and industrial development of southern Africa. Following the discoveries at Kimberley, even more valuable deposits were discovered in South Africa and Botswana in particular, but also in Lesotho, Swaziland and Zimbabwe.A century of study of kimberlites, and the diamonds and other mantle-derived rocks they contain, has furthered the understanding of the processes that occurred within the sub-continental lithosphere and in particular the formation of diamonds. The formation of kimberlite-hosted diamond deposits is a long-lived and complex series of processes that first involved the growth of diamonds in the mantle, and later their removal and transport to the earth's surface by kimberlite magmas. Dating of inclusions in diamonds showed that diamond growth occurred several times over geological time. Many diamonds are of Archaean age and many of these are peridotitic in character, but suites of younger Proterozoic diamonds have also been recognized in various southern African mines. These younger ages correspond with ages of major tectono-thermal events that are recognized in crustal rocks of the sub-continent. Most of these diamonds had eclogitic, websteritic or lherzolitic protoliths.In southern Africa, kimberlite eruptions occurred as discrete events several times during the geological record, including the Early and Middle Proterozoic, the Cambrian, the Permian, the Jurassic and the Cretaceous. Apart from the Early Proterozoic (Kuruman) kimberlites, all of the other events have produced deposits that have been mined. It should however be noted that only about 1% of the kimberlites that have been discovered have been successfully exploited.In this paper, 34 kimberlite mines are reviewed with regard to their geology, mantle xenolith, xenocryst and diamond characteristics and production statistics. These mines vary greatly in size, grade and diamond-value, as well as in the proportions and types of mantle mineral suites that they contain. They include some of the world's richest mines, such as Jwaneng in Botswana, to mines that are both small and marginal, such as the Frank Smith Mine in South Africa. They include large diatremes such as Orapa and small dykes such as those mined at Bellsbank, Swartruggens and near Theunissen. These mines are all located on the Archaean Kalahari Craton, and it is apparent that the craton and its associated sub-continental lithosphere played an important role in providing the right environment for diamond growth and for the formation of the kimberlite magmas that were to transport them to the surface. 相似文献
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