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1.
温泉斑岩钼矿床位于西秦岭东段,是该区发现的一个具有大型矿前景的斑岩型钼矿床。围岩温泉复式岩体发育5个岩相单元(Ⅰ~Ⅴ),钼矿体(化)主要赋存于复式岩体Ⅱ单元富含镁铁质包体的黑云母二长花岗斑岩和Ⅲ单元富含镁铁质包体的似斑状二长花岗岩及其接触带内,其余岩相(包括单元Ⅴ似斑状正长花岗岩)很少发育矿化。该研究使用全岩地球化学数据和锆石微量元素含量数据,计算得到不同岩相单元的氧逸度。Ⅱ单元和Ⅲ单元含矿斑岩相对氧逸度ΔFMQ分别为1.35和1.38。Ⅰ单元黑云母花岗岩和Ⅳ单元二长花岗斑岩相对氧逸度ΔFMQ分别为-0.61和-0.73,明显低于含矿斑岩。富集地幔物质的加入与否可能是造成不同岩相之间氧逸度差异的主要原因。高氧逸度的熔体可以将秦岭地区古生代富钼沉积物中的钼氧化萃取出来,并使钼与高价态硫络合,不断在熔体中高度富集,最终成矿。氧逸度较低的熔体很难萃取和保存足够的钼,因而很少发育矿化。 相似文献
2.
普朗斑岩铜矿床是云南中甸地区最大的斑岩型铜矿床,其成矿作用与普朗复式岩体存在密切的成因联系。对普朗复式岩体成矿的第1期石英闪长玢岩和第2期石英二长斑岩,以及不成矿的第3期闪长玢岩开展了锆石原位微量元素和磷灰石原位主量元素成分的研究。结果表明,锆石Ce/Ce~*值、Ce~(4+)/Ce~(3+)比值和Ce/Nd比值指示,不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩的岩浆相对氧化状态大致相当,且明显高于成矿的第2期石英二长斑岩。磷灰石Cl、OH和SO3成分指示,普朗复式岩体3期斑岩具有相似的岩浆含水量,但成矿的第1期石英闪长玢岩和第2期石英二长斑岩较不成矿的第3期闪长玢岩具有更高的岩浆挥发分Cl含量和硫逸度。岩浆的高氧逸度和硫逸度、富水和富挥发分Cl均是形成斑岩铜矿床的关键因素,普朗不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩和第2期石英二长斑岩均具有富水和高氧逸度特征,但第3期闪长玢岩较成矿的第1期石英闪长玢岩和第2期石英二长斑岩具有明显更低的岩浆挥发分Cl含量和硫逸度,这很可能是导致第1期石英闪长玢岩和第2期石英二长斑岩成矿,而第3期闪长玢岩不成矿的重要原因之一。 相似文献
3.
波龙、多不杂斑岩铜金矿床是青藏高原中部发现的两个大型斑岩铜金矿床。对波龙、多不杂斑岩铜金矿床含矿花岗闪长斑岩和不含矿花岗闪长斑岩的锆石Ce~(4+)/Ce~(3+)比值以及氧逸度等特征进行研究,并且通过计算得到了3个含矿花岗闪长斑岩的锆石Ce~(4+)/Ce~(3+)比值分别为536.03,492.18,454.02;1个不含矿的花岗闪长斑岩的锆石Ce~(4+)/Ce~(3+)比值为0.67。说明波龙、多不杂斑岩矿床中与成矿相关的岩体具有相对更高的氧化状态。对比西藏冈底斯成矿带中的斑岩矿床、云南中甸岛弧成矿带中的烂泥塘斑岩铜矿床、金沙江-红河成矿带中的马厂箐、铜厂铜钼矿以及玉龙成矿带铜钼矿床岩体的锆石Ce~(4+)/Ce~(3+)比值,发现含矿岩体锆石Ce~(4+)/Ce~(3+)比值一般250。结合波龙、多不杂矿床的锆石Ce~(4+)/Ce~(3+)的计算结果发现Ce~(4+)/Ce~(3+)基本300,因此将锆石Ce~(4+)/Ce~(3+)300作为波龙、多不杂矿床斑岩成矿的一个地球化学标志。此外,通过(Ce/Ce~*)_D锆石氧逸度计和(X_(Ce~(4+))~(melt)/X_(Ce~(3+))~(melt))锆石氧逸度计计算得到的波龙、多不杂矿床含矿花岗闪长斑岩体的氧逸度(log(f_(O_2)))分别位于MH(磁铁矿-赤铁矿)缓冲带和FMQ(铁橄榄石-磁铁矿-石英)缓冲带之上,平均值为ΔMH+3.24和ΔFMQ+1.78,前人研究发现多不杂含矿石英斑岩的氧化状态较高,平均ΔNNO+2.4,含矿斑岩体的形成具有较高的氧逸度条件,说明高氧逸度更有利于多龙矿集区斑岩型铜矿成矿。 相似文献
4.
包古图斑岩铜矿位于新疆西准噶尔地区，是区内规模最大的斑岩型矿床，成矿作用与晚石炭世中酸性侵入体密切相关。III- 2岩体位于矿区南部，该岩体全岩矿化，但品位较低，是探讨成矿岩浆性质的理想对象。本文结合岩石学和角闪石、锆石等矿物成分分析，通过与典型斑岩铜矿进行对比，探讨了成矿岩浆的氧逸度。研究表明，包古图III- 2岩体以石英闪长（玢）岩和闪长岩为主，少量辉石闪长岩，主要由斜长石、角闪石、黑云母、石英和钾长石组成，含少量钛铁矿、榍石和磷灰石。石英闪长岩中早期结晶的自形角闪石属于钙质闪石，Mg#较高（0. 72~1. 00），成分分析指示成矿岩浆的氧逸度为：△NNO+1. 4~△NNO+2. 6，位于斑岩铜矿含矿岩体的分布范围。从中分选出的锆石REE含量高（338×10-6~959×10-6），具有左倾型稀土配分模式，轻稀土亏损，重稀土富集，显示强烈Ce正异常和Eu负异常。Ce4+/Ce3+比值为29. 55~89. 50，Eu/Eu*比值为0. 32~0. 47，分布于斑岩铜矿含矿岩体和未矿化岩体的叠加部位。研究结果显示，包古图斑岩铜矿III- 2岩体成矿岩浆氧逸度较高，有利于成矿元素的溶解和迁移，对斑岩铜矿的形成有促进作用。 相似文献
5.
《地质学报》2020,(8)
包古图斑岩铜矿位于新疆西准噶尔地区,是区内规模最大的斑岩型矿床,成矿作用与晚石炭世中酸性侵入体密切相关。Ⅲ-2岩体位于矿区南部,该岩体全岩矿化,但品位较低,是探讨成矿岩浆性质的理想对象。本文结合岩石学和角闪石、锆石等矿物成分分析,通过与典型斑岩铜矿进行对比,探讨了成矿岩浆的氧逸度。研究表明,包古图Ⅲ-2岩体以石英闪长(玢)岩和闪长岩为主,少量辉石闪长岩,主要由斜长石、角闪石、黑云母、石英和钾长石组成,含少量钛铁矿、榍石和磷灰石。石英闪长岩中早期结晶的自形角闪石属于钙质闪石,Mg~#较高(0.72～1.00),成分分析指示成矿岩浆的氧逸度为:△NNO+1.4～△NNO+2.6,位于斑岩铜矿含矿岩体的分布范围。从中分选出的锆石REE含量高(338×10~(-6)～959×10~(-6)),具有左倾型稀土配分模式,轻稀土亏损,重稀土富集,显示强烈Ce正异常和Eu负异常。Ce~(4+)/Ce~(3+)比值为29.55～89.50,Eu/Eu~*比值为0.32～0.47,分布于斑岩铜矿含矿岩体和未矿化岩体的叠加部位。研究结果显示,包古图斑岩铜矿Ⅲ-2岩体成矿岩浆氧逸度较高,有利于成矿元素的溶解和迁移,对斑岩铜矿的形成有促进作用。 相似文献
6.
陆内环境斑岩型矿床的成矿金属与硫等物质主要来源于富原生硫化物且呈相对还原状态的角闪岩相下地壳的部分熔融,岩浆的高氧逸度和富水是成矿的关键,但还原性下地壳的熔融产物如何变成高氧逸度岩浆尚不十分明确。为此,本文对哀牢山-红河富碱斑岩带内与陆内成矿斑岩同时代的莴莊粗面玄武岩与谷装箐云煌岩开展了成岩物理化学条件研究。结果显示,这类钾质-超钾质岩的岩浆具有较高的ΔFMQ值(+0.8～+4.3),这一特征很可能继承于经历古大洋俯冲改造的岩石圈地幔。幔源高氧逸度岩浆具备调节与改造下地壳熔融产物氧逸度的潜力。因此,源于古俯冲改造的岩石圈地幔且具有较高ΔFMQ(+2.7～+4.3)的钾质-超钾质岩浆,可能是导致陆内斑岩成矿系统中斑岩岩浆具较高氧逸度的原因,这类钾质-超钾质岩浆与富硫化物的新生的下地壳来源的熔体的混合,可能是导致陆内斑岩成矿的关键。 相似文献
7.
《矿物岩石》2016,(1)
烂泥塘斑岩铜矿床是义敦岛弧带南段(中甸岛弧)西斑岩成矿带新发现的中型铜矿床。针对烂泥塘斑岩铜矿床含矿石英二长斑岩和不含矿石英闪长玢岩、闪长玢岩的锆石Ce~(4+)/Ce~(3+)比值、δEu值以及氧逸度等特征进行研究,并通过计算得到2个含矿石英二长斑岩体Ce~(4+)/Ce~(3+)比值分别为294.85和283.31,δEu分别为0.72和0.77;不含矿的石英闪长玢岩和闪长玢岩Ce~(4+)/Ce~(3+)比值分别为105.63和87.07,δEu分别为0.73和0.36。表明与成矿有关的岩体具有相对较高的氧化状态。对比西藏冈底斯成矿带、云南金沙江-红河成矿带中段马厂箐铜钼矿和北段玉龙成矿带铜钼矿床岩体Ce~(4+)/Ce~(3+)比值,发现含矿岩体锆石的Ce~(4+)/Ce~(3+)比值通常都大于240,而不含矿岩体锆石的Ce~(4+)/Ce~(3+)比值都小于120(邦铺矿床除外)。并且可将锆石Ce~(4+)/Ce~(3+)260、δEu0.65参数作为烂泥塘斑岩型铜矿床成矿的地球化学标志。此外,烂泥塘矿区内含矿石英二长斑岩体的氧逸度(lg(fo_2))基本位于MH缓冲对之上,平均值分别为MH+2.1和MH+1.2,含矿斑岩体具有较高的氧逸度条件。锆石U-Pb年龄与锆石Ce~(4+)/Ce~(3+)比值以及氧逸度(lg(fo_2))存在负相关关系,表明复式岩体中晚阶段侵位的岩体更有利于成矿。 相似文献
8.
安徽宣城茶亭矿床位于长江中下游成矿带东南缘的南陵-宣城盆地内,是近年来该盆地内新发现的大型斑岩型Cu-Au矿床。石英闪长玢岩是茶亭矿床主要的赋矿岩石,文章从石英闪长玢岩的造岩矿物黑云母入手,利用EMPA及LA-ICP-MS等原位微区分析方法,对黑云母进行了详细的矿物化学分析,旨在查明赋矿石英闪长玢岩形成的物理化学条件,并探讨其成岩成矿意义。分析结果表明:茶亭赋矿石英闪长玢岩中黑云母具有高w(TiO_2)、低w(Al_2O_3)的特征,整体富Mg、贫Fe。黑云母温压计算结果表明,在不同深度上,石英闪长玢岩具有相似的结晶温度及压力,其结晶温度为746～773℃,压力为44～85 MPa,对应深度为1.7～3.3 km,平均为2.47 km,显示石英闪长玢岩侵位深度相对较浅。黑云母中高的氧化系数(0.613～0.864)、高Mg#(0.557～0.864),以及w(MgO)介于14.73%～15.86%,均显示石英闪长玢岩为壳幔混源,并且以幔源为主。黑云母成分显示石英闪长玢岩形成于较高氧逸度条件下。浅部岩体具有较高的X_(Mg)值,表明浅部岩体氧逸度较高,可能指示随着岩浆的不断演化,残余岩浆的氧逸度不断降低。同时,石英闪长玢岩黑云母相对一般斑岩型铜矿具有较高的w(Cu),并且高Cl、低F。这些特征均有利于茶亭Cu-Au矿床的形成。 相似文献
9.
中甸铜钼多金属矿集区位于义敦岛弧南段,区内绝大多数矿床与晚三叠世和晚白垩世岩浆活动有关,目前两期斑岩锆石氧逸度及差异性成矿研究薄弱.对4个斑岩体5类岩石的锆石开展LA-ICPMS微量元素分析,数据经筛选检验后进行了氧逸度估算.氧逸度结果由高到低为:地苏嘎铜矿晚三叠世石英闪长玢岩（Ce4+/Ce3+比值为515）、休瓦促晚三叠世贫矿黑云母花岗岩（Ce4+/Ce3+比值为443）、铜厂沟钼铜矿晚白垩世花岗闪长斑岩（Ce4+/Ce3+比值为368）、热林钼矿晚白垩世二长花岗岩（Ce4+/Ce3+比值为237）、休瓦促钨钼矿晚白垩世二长花岗岩（Ce4+/Ce3+比值为104）.综合前人资料,认为俯冲或碰撞环境的斑岩型铜矿,高氧逸度是成矿的必要非充分条件,Cu铜主要直接或间接（有幔源贡献的新生下地壳）来自地幔;碰撞型斑岩矿床钼、钨主要来自古老地壳,对氧逸度的要求相对较低,偏氧化环境有利钼矿形成,偏还原环境有利于钨矿形成.矿产评价时,斑岩型铜矿应注重幔源/壳源比例和氧逸度条件的研究,斑岩型钼、钨矿不适用斑岩型铜矿氧逸度评价标准. 相似文献
10.
二十一站岩体位于黑龙江省东北部大兴安岭地区塔河县境内,该岩体产出的岩石类型包括早白垩世二长岩和石英二长斑岩及早侏罗世花岗岩和二长岩等,在该岩体中已发现斑岩型铜金矿床,但是该岩体形成的物理化学条件和岩石成因尚不清楚,不同岩性岩浆岩的成矿潜力也不明确。鉴于此,本文以二十一站岩体中不同时代的花岗岩、二长岩、石英二长斑岩的黑云母和角闪石为研究对象,结合偏光显微镜、电子探针背散射图像和电子探针化学成分,对该岩体的岩石学、矿物学特征进行了研究,并对岩浆结晶的物理化学条件、岩石成因和成矿意义进行了探讨。结果显示:早白垩世二长岩中角闪石化学成分显示:角闪石富钙(CaO 11.21%~11.78%)、富镁(MgO 13.61%~14.85%)、贫钠(Na2O 0.80%~1.11%)和贫钾(K2O 0.40%~0.54%),属于镁角闪石,结晶温度为704.92~805.58℃,平均温度为761.82℃,压力为73.83~115.93MPa,对应岩浆侵位深度为2.8~4.4km,结晶时岩浆氧逸度为△NNO+1.63,含水量为H2O=4.92%,反映出岩浆结晶时高温、高氧逸度、富含水分、浅侵位的特征。黑云母的Fe2+/(Fe2++Mg)比值比较均一,反映黑云母未遭受后期流体改造,均为原生岩浆成因的黑云母。其中早侏罗世花岗岩和二长岩所代表的A类黑云母化学成分上富铁(TFeO 19.92%~22.42%)贫镁(MgO 7.99%~10.46%),属于铁质黑云母,早白垩世二长岩和石英二长斑岩所代表的B类黑云母相比于A类黑云母更富镁(MgO 12.38%~14.45%)和钛(TiO21.90%~2.75%),贫铁(TFeO 16.64%~17.97%)和铝(Al2O315.00%~16%.79),属于镁质黑云母。A类和B类黑云母对应岩浆结晶温度分别为720~740℃和750~780℃;压力为202.20~443.49MPa和158~231MPa,对应岩浆侵位深度为6.67~14.64km和5.24~7.24km;结晶时岩浆氧逸度分别为10-15~10-16和10-12~10-13;岩浆来源为壳源,且B类黑云母对应岩浆有地幔物质参与。因此,可以认为二十一站岩体中早白垩世二长岩和石英二长斑岩具有中高温,高氧逸度应含水量,岩浆主要来源于地壳物质的部分熔融,并有部分地幔物质参与,侵位深度较浅的特点,具有形成大型斑岩矿床的潜力。早侏罗世花岗岩和二长岩氧逸度相对较低,侵位较深,物质来源为地壳,因此不具备成矿潜力。 相似文献
11.
Geochronology and magmatic oxygen fugacity of the Tongcun molybdenum deposit, northwest Zhejiang, SE China 总被引：6，自引：0，他引：6
Jun-Ting Qiu Xin-Qi Yu M. Santosh De-Hui Zhang Shuai-Qi Chen Peng-Ju Li 《Mineralium Deposita》2013,48(5):545-556
The Tongcun Mo porphyry deposit in northwest Zhejiang is hosted in three porphyry units: Huangbaikeng, Songjiazhuang, and Tongcun, from southwest to northeast. U–Pb zircon ages of 162?±?3.0 Ma for the Huangbaikeng porphyry, 159.9?±?3.0 Ma for the Songjiazhuang porphyry, and 167.6–155.6 Ma for the Tongcun porphyry indicate that these intrusions formed during the Jurassic and are most likely associated with the northwestward subduction of the Izanagi Plate. Trace element compositions of zircons from the Tongcun deposit constrain the oxygen fugacity (fO2) of the magma using zircon Ce anomalies and Ti-in-zircon temperatures. The average magmatic fO2 for the porphyries in the Tongcun deposit is fayalite–magnetite–quartz (FMQ)?+?2.7, which is similar to the Shapinggou (FMQ?+?3.2) and Dabaoshan (FMQ?+?3.5) Mo porphyry deposits, but much higher than that of the reduced Cretaceous ore-barren Shangjieshou porphyry (FMQ-1.1) around 8 km away from the Tongcun deposit. The distinct difference in magmatic oxygen fugacity between the Jurassic and Cretaceous porphyries may help to explain the absence of Mo porphyry mineralization in northwest Zhejiang during the Cretaceous. 相似文献
12.
福建紫金山矿田罗卜岭铜钼矿化斑岩锆石LA-ICP- MS U-Pb年龄及成矿岩浆高氧化特征研究 总被引：11，自引：6，他引：5
罗卜岭斑岩铜钼矿床是紫金山Cu-Au-Mo浅成低温-斑岩矿田内新近发现的大型斑岩铜钼矿床,本文在岩芯及光薄片系统观察的基础上,分析了矿化斑岩锆石LA-ICP-MS U-Pb年龄及锆石Ce4/Ce3+比值.罗卜岭赋矿斑岩体可分为两期,早期为角闪黑云母花岗闪长斑岩及黑云母花岗闪长斑岩,晚期为黑云母花岗闪长斑岩.早期角闪黑云母花岗闪长斑岩和黑云母花岗闪长斑岩锆石LA-ICP-MS U-Pb年龄分别为103.7±1.2Ma,MSWD=0.33和103.0±0.9Ma,MSWD=1.00;晚期黑云母花岗闪长斑岩锆石LA-ICP-MS U-Pb年龄为97.6±2.1Ma,MSWD=6.00.罗卜岭成矿斑岩基质普遍发育硬石膏,两期成矿斑岩锆石都具较高的Ce4 +/Ce3平均值,在630 ～770之间,高于区内非成矿花岗岩锆石的Ce4+/Ce3+平均值(182 ～577),显示罗卜岭斑岩矿床成矿岩浆具有高氧逸度的特征.据罗卜岭斑岩矿床的形成时代、高氧逸度岩浆特征,结合华南地区中生代构造背景,我们初步认为罗卜岭斑岩矿床的形成可能和中生代古太平洋向北西西方向俯冲有关. 相似文献
13.
西藏冈底斯南缘雄村铜金矿床成矿斑岩厘定及其锆石U-Pb和黑云母Ar-Ar年龄分析 总被引：1，自引：0，他引：1
雄村特大型斑岩铜金矿床主要以细脉浸染状产于强烈蚀变岩石中,赋矿岩石原岩成因类型存在争议。本文对多个赋矿蚀变岩石作了系统光薄片显微鉴定,在多个蚀变较弱的矿化样品中发现赋矿岩石具斑状结构,其基质主要为钾长石,斑晶主要为斜长石、钾长石及少量石英,显示石英正长斑岩及二长斑岩(少量)矿物组成特征。结合前人工作,可以认为雄村铜金矿床赋矿岩石为正长斑岩、火山岩及少量二长斑岩。正长斑岩发育斑岩铜金矿床成矿早期常见的钾硅化蚀变及磁铁矿化蚀变,锆石具高的Ce4+/Ce3+比值(334~3084,平均值为1169),显示高氧逸度岩浆特征,和世界斑岩铜金矿床成矿岩体一致;这表明石英正长斑岩为雄村铜金矿床成矿岩体。石英正长斑岩锆石LA-ICP-MS U-Pb年龄为173.7±2.1Ma(MSWD=0.23),石英正长斑岩钾化阶段形成的黑云母40Ar/39Ar坪年龄为48.3±0.9Ma(MSWD=1.58),远小于锆石U-Pb年龄却与矿区东北部始新世花岗岩基的年龄一致,显示Ar-Ar年龄受后期地质事件影响而发生重置。通过上述研究,可以认为雄村铜金矿床为与石英正长斑岩有关的斑岩型矿床,形成时代约173Ma,和新特提斯洋洋壳向北俯冲诱发的岩浆事件有关,矿区内云母受后期地质事件影响重置,不能记录其形成时代。 相似文献
14.
《China Geology》2022,5(4):662-695
The porphyry copper belt in the Geza island arc in southwestern China is the only Indosinian porphyry copper metallogenic belt that has been discovered and evaluated so far. The Pulang porphyry copper deposit (also referred to as the Pulang deposit) in this area has proven copper reserves of 5.11×106 t. This deposit has been exploited on a large scale using advanced mining methods, exhibiting substantial economic benefit. Based on many research results of previous researchers and the authors’ team, this study proposed the following key insights. (1) The Geza island arc was once regarded as an immature island arc with only andesites and quartz diorite porphyrites occurring. This understanding was overturned in this study. Acidic endmember components such as quartz monzonite porphyries and quartz monzonite porphyries have been identified in the Geza island arc, and the mineralization is mainly related to the magmatism of quartz monzonite porphyries. (2) Complete porphyry orebodies and large vein orebodies have developed in the Pulang deposit. Main orebody KT1 occurs in the transition area between the potassium silicate alteration zone of quartz monzonite porphyries and the sericite-quartz alteration zone. Most of them have developed in the potassium silicate alteration zone. The main orebody occurs as large lenses at the top of the hanging wall of rock bodies, with an engineering-controlled length of 1920 m and thickness of 32.5‒630.29 m (average: 187.07 m). It has a copper grade of 0.21%‒1.56% (average: 0.42%) and proven copper resources of 5.11×106 t, which are associated with 113 t of gold, 1459 t of silver, and 170×103 t of molybdenum. (3) Many studies on diagenetic and metallogenic chronology, isotopes, and fluid inclusions have been carried out for the Pulang deposit, including K-Ar/Ar-Ar dating of monominerals (e.g., potassium feldspars, biotites, and amphiboles), zircon U-Pb dating, and molybdenite Re-Os dating. The results show that the porphyries in the Pulang deposit are composite plutons and can be classified into pre-mineralization quartz diorite porphyrites, quartz monzonite porphyries formed during the mineralization, and post-mineralization granite porphyries, which were formed at 223±3.7 Ma, 218±4 Ma, and 207±3.9 Ma, respectively. The metallogenic age of the Pulang deposit is 213‒216 Ma. (4) The petrogeochemical characteristics show that the Pulang deposit has the characteristics of volcanic arc granites. The calculation results of trace element contents in zircons show that quartz monzonite porphyries and granite porphyries have higher oxygen fugacity. The isotopic tracing results show that the diagenetic and metallogenic materials were derived from mixed crust- and mantle-derived magmas.©2022 China Geology Editorial Office. 相似文献
15.
Akira IMAI 《Resource Geology》2000,50(1):1-23
Abstract: The Mamut deposit of Sabah, East Malaysia, is a porphyry type Cu‐Au deposit genetically related to a quartz monzonite (“adamellite”) porphyry stock associated with upper Miocene Mount Kinabalu plutonism. The genesis of the Mamut deposit is discussed based on petrology of the intrusives in the Mount Kinabalu area combined with ore– and alteration–petrography, fluid inclusion and sulfur isotope studies. Groundmass of the adamellite porphyry at Mamut is rich in K which suggests vapor transport of alkaline elements during the mineralizing magmatic process, while the groundmass of the post‐ore “granodiorite” porphyry at Mamut contains small amounts of normative corundum suggesting depletion in alkaline elements at the root zone of the magma column. Sub‐dendritic tremolitic amphibole rims on hornblende phenocrysts in the Mamut adamellite porphyry suggest interaction between the mineralizing magma and the exsolved fluids. Occurrences of clinopyroxene microphenocrysts and pseudomor‐phic aggregates of shredded biotite and clinopyroxene after hornblende phenocrysts in the barren intrusives imply lower water fugacity and decreasing in water fugacity, respectively. Compositional gap between the core of hornblende phenocrysts and the tremolitic amphibole rims and those in the groundmass of the Mamut adamellite porphyry suggests a decrease in pressure. Higher XMg (=Mg/(Mg+Fe) atomic ratio) in the tremolitic amphibole rims in the Mamut adamellite porphyry compared to those of the barren intrusions suggests high oxygen fugacity. High halogen contents of igneous hydrous minerals such as amphiboles, biotite and apatite in the Mamut adamellite porphyry suggest the existence of highly saline fluids during the intrusion and solidification of the mineralizing magma. Fluid inclusions found in quartz veinlet stockworks are characterized by abundant hypersaline polyphase inclusions associated with subordinate amounts of immiscible gaseous vapor. Both Cu and Au are dispersed in disseminated and quartz stockwork ores. Chalcopyrite and pyrrhotite as well as magnetite are the principal ore minerals in the biotitized disseminated ores. Primary assemblage of intermediate solid solution (iss) and pyrrhotite converted to the present assemblage of chalcopyrite and pyrrhotite during cooling. Subsequent to biotitization, quartz veinlet stockworks formed associated with retrograde chlorite alteration. The Cu‐Fe sul–fides associated with stockwork quartz veinlet are chalcopyrite and pyrite. Overlapping Pb and Zn and subsequent Sb mineralizations were spatially controlled by NNE‐trending fractures accompanying the phyllic and advanced argillic alteration envelope. Sulfur isotopic composition of ore sulfides are homogeneous (about +2%) throughout the mineralization stages. These are identical to those of the magmatic sulfides of Mount Kinabalu adamellitic rocks. 相似文献
16.
The western Awulale metallogenic belt in northwestern China hosts a number of small‐ to medium‐sized porphyry Cu deposits that are associated with albite porphyry. The common presence of plagioclase (albite) as phenocrysts and the absence of hydrous minerals (amphibole and biotite) indicate that the water content of albite porphyry is low. Trace‐element compositions of whole rocks and zircon grains from these ore‐bearing porphyries were measured. Zircon grains from albite porphyries exhibit Ce4+/Ce3+ ratios ranging from 7.75 to 95.1, which indicate that these porphyries have a low oxygen fugacity. Trace element compositions of ore‐bearing porphyries exhibit (La/Yb)N ratios ranging from 1.09 to 11.1 and Eu/Eu* ratios ranging from 0.10 to 0.66. These ore‐bearing porphyries have Zr values ranging from 171 to 707 ppm and Hf values ranging from 8.30 to 18.9 ppm. Combining these porphyries with other ore‐bearing porphyries that formed in the Central Asian Orogenic Belt (CAOB) and the Pacific Rim metallogenic belt, we found that the (La/Yb)N and Eu/Eu* ratios of ore‐bearing porphyries in western Awulale are low, while the Zr and Hf values are high. Specifically, REEs can be used to evaluate the degree of differentiation and degree of partial melting, and Zr and Hf can be used to evaluate the redox conditions and water content of magmatic rocks. Our findings indicate that ore‐bearing porphyries in western Awulale have a lower oxygen fugacity, degree of differentiation, and water content than do others in the CAOB and the Pacific Rim metallogenic belt. Compared to those of ore‐bearing porphyries with lower zircon Ce4+/Ce3+ ratios, the (La/Yb)N ratios of ore‐bearing porphyries in our study are low, and the Zr and Hf values are high. This finding indicates that, under reducing conditions, the degree of evolution and water content may have an important influence on the metal abundance in magmas. There is also a clear relationship between (La/Yb)N, Eu/Eu*, Zr, Hf, and the size of the deposits. Large‐ (>4 Mt Cu) and intermediate (1.5–4 Mt Cu)‐sized porphyry Cu deposits are associated with granitic intrusions that have higher (La/Yb)N and Eu/Eu* ratios and lower Zr and Hf values. This finding indicates that, in addition to oxygen fugacity, the degree of evolution and water content are controlling parameters for metal abundance in magmas, especially in low oxygen fugacity porphyry Cu deposits. Such a conclusion may be useful in the exploration for other concealed porphyry Cu deposits. 相似文献
17.
湘南黄沙坪多金属矿床花岗质岩浆性质及演化对成矿差异的约束 总被引：2，自引：1，他引：1
黄沙坪矿床是湘南地区最大的铅锌矿床,除铅、锌外,可供开采利用的矿种还包括钨、锡、钼、铜、铁、硫等。矿区内岩浆作用复杂、成矿元素多样、矿化类型丰富,是研究湘南地区斑岩-矽卡岩-热液脉型Cu多金属与矽卡岩W-Sn多金属复合成矿作用的理想对象。为查明矿区Cu多金属与W多金属复合成矿机理,本文在已有研究的基础上,从岩石学、矿物学及元素地球化学等方面分别对区内石英斑岩和花岗斑岩这两类成矿岩体开展了系统研究。结果表明,两类岩体具有相似的源区特征,但在源区性质及其演化过程方面仍存在差异:石英斑岩侵位深度更浅,具有相对较高的氧逸度和较低的形成温度;而花岗斑岩则侵位相对更深,具有更高的形成温度和极高的分异演化程度、更低的氧逸度。这些地球化学特征差异可能是制约石英斑岩成铜矿而花岗斑岩成钨矿的重要原因。 相似文献
18.
山西堡子湾金矿床地质地球化学特征 总被引：3，自引：0，他引：3
山西堡子湾金矿床位于华北地台北缘，是以金为主伴生银铜多金属的中型金矿床。赋存地层为太古界集宁群。燕山期岩浆活动形成的石英二长岩及有关的隐爆角砾岩与成矿关系密切。围岩蚀变分布于角砾岩体内，主要为绢云母化、高岭石化、碳酸盐化和硅化。石英二长岩的稀土分布型式和岩石地球化学特征，说明其为重熔型岩浆侵入所形成。矿体中石英的氧同位素δ^18O值接近花岗岩类范围；矿床中硫化物的δ^34S值范围为-3．2‰～-1．2‰，接近陨石硫。堡子湾金矿的成矿物质来源于岩浆，成矿作用与燕山期岩浆期后热液活动以及隐爆作用和流体作用有关。 相似文献