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1.

This paper presents the results of thermodynamic calculations on the solubility of gold and silver in low‐temperature, moderately saline, oxygen‐saturated fluids. Based on the solubilities of gold and silver it is argued that the quantity of gold transported by the fluids depends on the concentration of silver in the primary ores. In ores where the silver/gold ratio is high (1 to > 10), the fluids become saturated in silver and can not dissolve geologically significant concentrations of gold. In ores where the silver/gold ratio is low (< 1), the fluids remain undersaturated with respect to silver and are able to dissolve geologically realistic concentrations of gold and silver. The oxidized fluids start depositing gold and silver as they move downwards and are reduced by the Fe+2‐bearing minerals of the primary ores. The occurrence of gold in lateritic profiles can be explained by a prolonged process of interaction between the fluid and primary ores, during which gold and silver precipitate and redissolve selectively at the gradually advancing oxidation‐reduction interface.  相似文献   

2.
156 samples of naturally‐occurring molybdenite from 87 localities in Australia have been examined to determine the distribution of the hexagonal (2H1) and rhombohedral (3R) polytypes. 90% of the specimens examined are 2H1 polytypes, the remainder being 3R and mixtures of 2H1 and 3R polytypes. The 3R and mixed polytypes are more abundant in porphyry copper deposits or as disseminations, in veins, and in garnet‐quartz pipes in granite. 2H1 polytypes are the sole modification observed in pegmatites, quart‐pegmatite pipes, simple quartz veins, and skarns.

The highest average concentrations of rhenium are in molybdenite from porphyry copper deposits, quartz porphyry pipes, skarn deposits, garnet‐quartz pipes, and pegmatites. Low concentrations occur in molybdenite which is disseminated or in quartz veins in granite and in quartz or pegmatitic pipes. Molybdenites in which the 2H1 polytype is dominant have a lower average rhenium content than those with dominant 3R polytype.  相似文献   

3.
Two lithofacies maps of the Lachlan Fold Belt, one for the Ordovician and one for the Silurian, are illustrated. Both maps indicate shorelines in western New South Wales, Victoria and Tasmania.

The Ordovicoan map suggests open‐sea conditions eastwards from the shoreline with one major and two minor andesitic volcanoes (or volcanic centres). The Silurian map suggests segmentation of the Lachlan Fold Belt into the Melbourne Basin, Omeo Land, Newell Basin, and Budawang Land. The Newell Basin displays a nearshore (Louth‐Mitta Mitta) coarse clastics facies and an offshore (Wellington‐Cooma) platform carbonate facies. Acid volcanism was widespread over the Newell Basin in Silurian time, but did not occur in the Melbourne Basin.

The Louth‐Mitta Mitta and Wellington‐Cooma facies boundary coincides with the position of the Coolac‐Honeybugle Serpentine Belt and the outcrop area of the Girilambone Beds, suggesting that these features were already in some way prominent during the Silurian Period: the Serpentine Belt may have been a fault, and the Girilambone Beds may have been land.

The origin of base‐metal deposits in the Silurian rocks is thought to be somehow related to the heat generated in the subsurface during Silurian time as is indicated by the volcanism and granite intrusion; and also to the fact that the deposits occur in a transgressive sequence which contains the first phase of acid volcanism in the known geological history of the Lachlan Fold Belt.  相似文献   

4.
The stable magnetizations of the Tasmanian Dolerites are shown to fall into two distinct groups depending upon their directions and the geographical region of the dolerites. It has been suggested that this could be a result of significant age differences between the dolerites of these groups. A series of K‐Ar determinations indicates that there is no detectable systematic age differences and the average of the five bodies dated is 170.5 ± 8.0 m.y. (not significantly different from previous K‐Ar dates from a single body). A re‐appraisal of the palaeomagnetic data, in the light of the distinct groupings of the directions, yields two significantly different pole positions‐ Lat 50.7°S, Long. 174.5°E (A9r, = 5.2°) and Lat. 47.7 °S, Long. 123.5° (A95 = 9.5°)’. The former of these is in excellent agreement with pole positions from other Lower to Middle Jurassic rocks of Australia but the significance of the latter remains obscure.  相似文献   

5.
Hydrogen‐ and oxygen‐isotope analyses of biotite (19), sericite (8), chlorite (2), quartz (27), and total rocks (37) from the Panguna porphyry‐copper deposit on Bougainville Island, place important constraints on the origin of the hydrothermal fluids responsible for mineralization and alteration in the mine region. Early high‐temperature amphibole‐magnetite alteration resulted from magmatic‐hydrothermal fluids. Several lines of evidence indicate 500°C as a realistic average temperature for mineralization, development of quartz veins, and biotitization processes. On the basis of mineral isotope data, responsible fluids could represent either 18O‐shifted ground‐waters or magmatic‐hydrothermal fluids at submagmatic temperatures. Independent evidence, as well as total‐rock 18O data, support the magmatic‐hydrothermal model.

Late‐stage sericitization processes probably resulted from fluids produced by 18O shifting of groundwaters during the evolution of the propylitic zone. Outermost quartz veins and biotitization conceivably resulted from fluids similar to those that caused sericitization, indicating that some interaction between relatively cool, 18O‐poor meteoric waters and the ore fluids occurred near the margins of the deposit. The origin of the chlorite‐sericite alteration cannot be resolved solely by isotope studies.  相似文献   

6.
The geochemistry of two deerite‐bearing meta‐ironstones from the Emo Metamorphics of Papua New Guinea suggests that they were deposited as metalliferous cherts enriched in manganese and iron by hydrothermal exhalative activity in an ocean ridge system. Subsequent blueschist facies metamorphism resulted in the formation of the assemblage deerite‐quartz‐albite‐iron oxides‐alkali amphiboles‐spessar‐tine‐stilpnomelane‐apatite, with calcium‐manganese carbonates in one specimen. Assemblages in associated metabasites suggest P‐T conditions of 7 kb at 320°C, which overlap with the P‐T field defined by one of the meta‐ironstones. Oxygen fugacity was probably an important control in determining variations in mineralogy and mineral chemistry. Preliminary data on the trace element geochemistry of associated metabasites are consistent with an ocean ridge environment for the formation of the meta‐ironstones.  相似文献   

7.
A detailed Rb‐Sr total‐rock and mineral and U‐Pb zircon study has been made on suites of Proterozoic silicic volcanic rocks and granitic intrusions, from near Mt Isa, northwest Queensland. Stratigraphically consistent U‐Pb zircon ages within the basement igneous succession show that the oldest recognized crustal development was the outpouring of acid volcanics (Leichhardt Metamorphics) 1865 ± 3 m.y. ago, which are intruded by coeval, epizonal granites and granodiorites (Kalkadoon Granite) whose pooled U‐Pb age is 1862 +27 ‐21 m.y. A younger rhyolitic suite (Argylla Formation) within the basement succession has an age of 1777 ± 7 m.y., and a third acid volcanic unit (Carters Bore Rhyolite), much higher again in the sequence, crystallized 1678 ± 1 m.y. ago.

All of these rocks are altered in various degrees by low‐grade metamorphic events, and in at least one area, these events were accompanied by, and can be partly related to, emplacement of a syntectonic, foliated granitic batholith (Wonga Granite) between 1670 and 1625 m.y. ago. Rocks that significantly predate this earliest recognized metamorphism, have had their primary Rb‐Sr total‐rock systematics profoundly disturbed, as evidenced by 10 to 15% lowering of most Rb‐Sr isochron ages, and a general grouping of many of the lowered ages (some of which are in conflict with unequivocal geological relationships) within the 1600–1700 m.y. interval. Such isochrons possess anomalously high initial 87Sr/86Sr ratios, and some have a slightly curved array of isotopic data points. Disturbance of the Rb‐Sr total‐rock ages is attributed primarily to mild hydrothermal leaching, which resulted in the loss of Sr (relatively enriched in 87Sr in the Sr‐poor (high Rb/Sr) rocks as compared with the Sr‐rich rocks).  相似文献   

8.
Sm‐Nd and Rb‐Sr isotopic data for Archaean gneisses from three localities within the eastern Yilgarn Block of Western Australia indicate that the gneisses define a precise Rb‐Sr whole rock isochron age of 2780 ± 60 Ma and an initial 87Sr/86Sr of 0.7007 ± 5. The Sm‐Nd isotopic data do not correspond to a single linear array, but form two coherent groups that are consistent with a c. 2800 Ma age of crust formation, with variable initial Nd. These results indicate that the gneiss protoliths existed as continental crust for a maximum period of only c. 100 Ma, and probably for a much shorter time, prior to the formation of the 2790 ±30 Ma greenstones.  相似文献   

9.
An ‘autochthon’ model for the tectonic development of Timor is suggested, based on observations of Palaeozoic‐Mesozoic relationships from a broad area of central East Timor, including:
  1. (a) ‘allochthonous’ Permian rocks unconformable on metamorphic rocks

  2. (b) ‘allochthonous’ Permian units interbedded with ‘autochthonous’ Permian units, and

  3. (c) ‘autochthonous’ Triassic sediments stratigraphically overlying ‘allochthonous’ Permian rocks.

The model is supported by recent modifications in palaeogeographic interpretations for the Permian of north Australia (e.g. Powell, 1976; Thomas, 1976). Our observations support and extend the earlier suggestions of Grady (1975), and the resulting model is in contrast with some of the hypotheses of Audley‐Charles and his associates (as, most recently, Barber et al., 1977), Fitch & Hamilton (1974), Hamilton (1973, 1976), and Crostella (1976).

Our model involves no essentially allochthonous pre‐Cainozoic material in Timor. The Permian to Cretaceous units are envisaged as developing on the continental margin which was dominantly inactive, but affected to some extent by Late Jurassic rifting activity. Following the Pliocene collision with the Inner Banda Arc, uplift along the collision zone would have caused gravity gliding towards the south. Thus, surficial olistostrome deposits, originally from the island arc, could have eventually moved to the northern slopes of the Timor Trough, while at depth, reverse faulting could have developed as a result of gravity gliding.

We maintain that previous postulates of a pervasive, strongly imbricate structure for Timor, lack adequate substantiation in the literature. Furthermore, accounts of the tectonic development of Timor, involving large scale translation on low angle faults, are even less well substantiated.  相似文献   

10.
11.
Differential earth movements occurred during Eocene, Miocene, and late Caino‐zoic times. The faulting formed basins of sedimentation, led to dissection of land‐surfaces in some localities and burial in others, and faulted the Cainozoic sediments.

Laterite and silcrete cap remnants of relict landsurfaces of two different ages. Laterite formed before the Eocene; it was faulted and dissected during the Eocene in the north but continued to develop until the Miocene in the south. Silcrete formed from Eocene to Miocene times; its dissection was promoted by late Cainozoic tectonism.

Since laterite and silcrete formed on the same strata in warm, very moist environments, lithology and climate are not important genetic factors causing laterite to form at one time and silcrete at another. Only base levels of erosion differed. The silcrete surface was largely developed by streams flowing into mid‐Cainozoic lacustrine basins, whereas there is no evidence that these drainage conditions prevailed for laterite formation.  相似文献   

12.
The Toolebuc Formation, which is a potentially important source of oil shale in the Eromanga Basin of NW Qld, exhibits a marked gamma‐ray response that has long beeen used as a stratigraphic marker. At Julia Creek, a large area of the Formation contains low‐grade oil shale that is accessible to mining. Detailed investigation, by gamma‐ray spectrometry and neutron activation analysis, of drill core samples from this deposit and from the type section of the Toolebuc Formation at Boulia (BMR Boulia 3A stratigraphic drill hole) show that the Toolebuc gamma‐ray anomaly in the northern Eromanga Basin is due to the presence of uranium. Analyses for organic carbon and phosphorus show that the uranium is associated primarily with organic matter in the oil shales and with phosphatic skeletal fish debris in the accompanying coquinites.

Drill core samples from Tibooburra, N.S.W. were also analysed (BMR Urisino‐1 stratigraphic drill hole) to investigate whether the gamma‐ray anomalies observed in the Bulloo Embayment on the southern margin of the Eromanga Basin (possibly correlative with the Toolebuc Formation) might also be indicative of oil shale. The results show that the much weaker anomaly at this locality is due principally to potassium and reflects the presence of an argillaceous siltstone within glauconitic sandstones.  相似文献   

13.
This paper is a synthesis of structural and geochronological data from eastern Mediterranean ophiolitic metamorphic rocks and surrounding units to interpret the intra‐oceanic subduction and ophiolite emplacement mechanism.

Metamorphic rocks occur as discontinuous tectonic slices at the base of the ophiolites, generally between the peridotite tectonites and volcanic‐sedimentary units, and locally in fault zones in the overlying peridotites. They consist essentially of amphibolite, and in lesser quantities, micaschist, quartzite, epidotite and marble.

Geological and geochronological data indicate that recrystallization of the metamorphic rocks occurred in the oceanic environment. The contact between the metamorphic rocks and the hanging‐wall is parallel to the foliation of the metamorphic rocks, and is interpreted as the fossil plane of intra‐oceanic subduction. Structural relationships suggest that intra‐oceanic subduction was situated between two lithospheric blocks separated by an oceanic fracture zone. Therefore the Neotethyan ophiolites with metamorphic soles represent the remnants of the overriding oceanic lithosphere's training slices of the metamorphic rocks at the base.

In the Anatolian region, radiometric dating of metamorphic rocks from the Taurus and Izmir‐Ankara‐Erzincan zone ophiolites yield nearly identical ages. Besides, palaeontological and structural data indicate coeval opening and similar oceanic ridge orientation. Consequently it is highly probable that Taurus and Izmir‐Ankara‐Erzincan zone ophiolites represent fragments of the same oceanic lithosphere derived from a single spreading zone. Palaeontological data from underlying volcanic and sedimentary units point out that the opening of the Neotethyan ocean occurred during Late Permian‐Middle Triassic time in the Iranian‐Oman region, during Middle Triassic in Dinaro‐Hellenic area, and finally during Late Triassic in the Anatolian region.

Radiometric dating of the metamorphic rocks exhibit that the intra‐oceanic thrusting occurred during late Lower‐early Late Jurassic for Dinaro‐Hellenic ophiolites, late Lower‐early Late Cretaceous for Anatolian, Iranian and Oman ophiolites well before their obduction on the Gondwanian continent. Neotethyan ophiolites were obducted onto various sections of the Gondwanian continent from late Upper Jurassic to Palaeocene time, Dinaro‐Hellenic ophiolites during late Upper Jurassic‐early Lower Cretaceous onto the Adriatic promontory, Anatolian, Iranian and Oman ophiolites from late Lower Cretaceous to Palaeocene onto the Aegean, Anatolian and Arabic promontories.  相似文献   

14.
15.
Two approaches to the time‐stratigraphic subdivision of the Australian Pre‐cambrian are possible. In one, bodies of rock are referred, by means of radio‐metric dates, to periods defined by chosen points on the absolute time‐scale. In the second, the boundaries of time‐rock units are defined at selected reference points on the ground, and these reference points are dated as accurately as possible by radiometric means. Geographically distant bodies of rock are correlated with “type” time‐rock units by radiometric dates.

The second approach is preferred since: (a) it leads to a geological time‐scale homogeneous in concept; (b) it implies that there is no difference in principle between Precambrian and Phanerozoic time‐stratigraphy; and (c) the time‐rock units so created are directly comparable with those that might be established by lithological, palaeontological, magnetometric, or climatic‐litho‐logical correlation. Criteria and procedures for the definition of time‐rock units and their boundaries are suggested.  相似文献   

16.
In ternary feldspars of essentially one phase, calcium content has a dominant influence on the optic axial angle. In such feldspars and also in binary feldspars from solvsbergite rocks, variations of cooling histories do not significantly affect the optic axial angle. In ternary feldspars which are unmixed into two or three prominent phases, Al/Si ordering has an important effect on the 2V value. A recent suggestion of several writers that in feldspars the alkali structural site may be partially occupied by (H3O)+ ions is applied as a possible way to explain a correlation observed between petrographical features of the rocks and the optic axial angles of their feldspar phenocrysts.  相似文献   

17.
Investigations described from three Victorian damsites indicate that weathering of Ordovician bedrock is increased where it is overlain by basalt, even though the basalt is little weathered. Sub‐basaltic weathering may account for the fact that weathered rock beneath a Jurassic lava flow gives a weathering remagnetization age of Mid‐Cainozoic, consistent with palaeomagnetically determined ages of lateritization from elsewhere in Australia.  相似文献   

18.
A largely convergent setting is proposed for crustal, tectonic and basin evolution of the intracratonic regions of north‐central Australia between 1800 and 1575 Ma. The new geodynamic model contrasts with previous proposals of widespread extension during the Leichhardt, Calvert and Isa intervals. Local transtensional to extensional structures exist, but these are best explained by a combination of flexural, thermal and dynamic processes related to an active southern margin. The development of thick accumulations of sediments (superbasins) is linked geodynamically to interpreted active margin processes (subduction and magmatic arcs) in central Australia. A synthesis of geochemical data from the 1870–1575 Ma igneous units from the Arnhem, McArthur and Mt Isa regions of north‐central Australia confirms the intracratonic setting of these units and suggests that a long‐lived thermal anomaly was responsible for the generation of both mafic and felsic magmas. The geochemical characteristics suggest the igneous units are derived from the lithospheric mantle and are not typical rift‐ or plume‐related melts. A review of the U–Pb SHRIMP ages for the entire region demonstrates the minimum distribution of correlative igneous rocks was widespread. Exotic populations in the 207Pb/206Pb isotopic data provide insights into the nature and evolution of the crust throughout north‐central Australia. Archaean inheritance is found to be nearly ubiquitous. The data support the temporal subdivision of north‐central Australia into the Leichhardt (1800–1750 Ma), Calvert (1750–1690 Ma) and Isa (1690–1575 Ma) intervals which are marked by superbasins and concomitant episodes of igneous activity. A highly heterogeneous pre‐superbasin crust is interpreted from regional, newly processed geophysical data. The cratonic portion of north‐central Australia is interpreted to consist of three broad northwest‐trending belts or elements that are further distinguished into western, central and eastern geophysically distinct provinces. A map of the superbasin distribution is derived and integrated with structural and stratigraphic data to assess the evolution of the basins and the crust through time. The superbasin successions of north‐central Australia are synchronous and widespread, although not necessarily interconnected. The tectonic model incorporates dynamic tilting of the craton during episodes of subduction and transmission of compressive intraplate stresses through the craton during intervening episodes of orogeny. These processes resulted in flexure, strike‐slip deformation and a complex thermal structure. These mechanisms account for the subsidence and basin evolution that results in widespread ramp and strike‐slip basins. The model also accounts for the thermal history recorded by magmatic events. The proposed geodynamical model provides a unifying crustal evolution scenario for central and northern Australia for approximately 225 million years of the Proterozoic.  相似文献   

19.
Biotite igneous ages and well‐defined isochron ages of plutons from the composite Blue Tier Batholith and the Coles Bay area in northeastern Tasmania range from 395 to 370 Ma. The older limit of this range, for the George River granodiorite, is considerably older than any age previously recorded for NE Tasmania. The ages of the youngest plutons (Mt Paris and Anchor granites), which host cassiterite ores, record pervasive hydrothermal alteration events. The initial 87Sr/80Sr ratios of the granitoids range from 0.7061 to 0.7136 and suggest different protolith compositions, consistent with mineralogical and geochemical characteristics of each pluton. The S‐type garnetbiotite granites (Ansons Bay and Booby alia granites) have initial ratios greater than 0.7119, indicative of enriched, high Rb/Sr ratio, crustal source‐rocks of Proterozoic age (1700–800 Ma). The S‐type biotite granites (Poimena and Pearson granites) have relatively high initial 87Sr/86Sr ratios (0.7070, 0.7105) but overlap with those of the I‐type granodiorites (George River, Scamander Tier, Pyengana and Coles Bay granodiorites) which are in the range of 0.7061 to 0.7073. The initial ratios of the enriched altered plutons are poorly constrained, and on both hand‐specimen and thin‐section scales, reveal open‐system Sr isotopic patterns.

Isochron ages for the arenite‐lutite and lutite sedimentary associations of the Mathinna Beds, which are intruded by the granitoids, reflect an approach to Sr isotopic equilibrium during regional metamorphism. The metamorphic age (401 ± 7 Ma) of the early Pragian arenite‐lutite association indicates a relatively small time interval between deposition, regional metamorphism and granitoid intrusion. The isotopic age for the lutite sedimentary association (423 ± 22 Ma) is tentatively correlated with a Benambran‐age burial metamorphic event that has not previously been recorded in Tasmania.  相似文献   

20.
At present, most, if not all zinc is being produced from the mineral sphalerite. With the exception of its piezoelectricity and in some cases its density, sphalerite has no salient physical properties to routinely allow its direct detection by geophysical methods. Although the mineral usually occurs with other sulfides, which do respond to various geophysical techniques, detection of zinc‐bearing deposits is often difficult. In this paper, physical property measurements from numerous, mainly Australian, deposits are presented, together with examples from various geophysical surveys. The results are used to suggest the most effective geophysical technique for the direct detection of the different types of zinc‐bearing deposits. Induced polarisation is probably the most effective technique for unmetamorphosed sediment‐hosted deposits and for carbonate‐hosted deposits, whereas electromagnetics is usually the most appropriate method to use for volcanic‐hosted deposits and for sediment‐hosted deposits that have been strongly metamorphosed. Magnetics is the best technique for skarn and ‘Cobar‐style’ deposits. However, it must be emphasised that usually more than one geophysical technique is required before a prospect can be considered to have been thoroughly explored.  相似文献   

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