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1.
A detailed Rb‐Sr total‐rock and mineral and U‐Pb zircon study has been made on suites of Proterozoic silicic volcanic rocks and granitic intrusions, from near Mt Isa, northwest Queensland. Stratigraphically consistent U‐Pb zircon ages within the basement igneous succession show that the oldest recognized crustal development was the outpouring of acid volcanics (Leichhardt Metamorphics) 1865 ± 3 m.y. ago, which are intruded by coeval, epizonal granites and granodiorites (Kalkadoon Granite) whose pooled U‐Pb age is 1862 +27 ‐21 m.y. A younger rhyolitic suite (Argylla Formation) within the basement succession has an age of 1777 ± 7 m.y., and a third acid volcanic unit (Carters Bore Rhyolite), much higher again in the sequence, crystallized 1678 ± 1 m.y. ago.

All of these rocks are altered in various degrees by low‐grade metamorphic events, and in at least one area, these events were accompanied by, and can be partly related to, emplacement of a syntectonic, foliated granitic batholith (Wonga Granite) between 1670 and 1625 m.y. ago. Rocks that significantly predate this earliest recognized metamorphism, have had their primary Rb‐Sr total‐rock systematics profoundly disturbed, as evidenced by 10 to 15% lowering of most Rb‐Sr isochron ages, and a general grouping of many of the lowered ages (some of which are in conflict with unequivocal geological relationships) within the 1600–1700 m.y. interval. Such isochrons possess anomalously high initial 87Sr/86Sr ratios, and some have a slightly curved array of isotopic data points. Disturbance of the Rb‐Sr total‐rock ages is attributed primarily to mild hydrothermal leaching, which resulted in the loss of Sr (relatively enriched in 87Sr in the Sr‐poor (high Rb/Sr) rocks as compared with the Sr‐rich rocks).  相似文献   

2.
Sm‐Nd and Rb‐Sr isotopic data for Archaean gneisses from three localities within the eastern Yilgarn Block of Western Australia indicate that the gneisses define a precise Rb‐Sr whole rock isochron age of 2780 ± 60 Ma and an initial 87Sr/86Sr of 0.7007 ± 5. The Sm‐Nd isotopic data do not correspond to a single linear array, but form two coherent groups that are consistent with a c. 2800 Ma age of crust formation, with variable initial Nd. These results indicate that the gneiss protoliths existed as continental crust for a maximum period of only c. 100 Ma, and probably for a much shorter time, prior to the formation of the 2790 ±30 Ma greenstones.  相似文献   

3.
Investigations described from three Victorian damsites indicate that weathering of Ordovician bedrock is increased where it is overlain by basalt, even though the basalt is little weathered. Sub‐basaltic weathering may account for the fact that weathered rock beneath a Jurassic lava flow gives a weathering remagnetization age of Mid‐Cainozoic, consistent with palaeomagnetically determined ages of lateritization from elsewhere in Australia.  相似文献   

4.
Hydrogen‐ and oxygen‐isotope analyses of biotite (19), sericite (8), chlorite (2), quartz (27), and total rocks (37) from the Panguna porphyry‐copper deposit on Bougainville Island, place important constraints on the origin of the hydrothermal fluids responsible for mineralization and alteration in the mine region. Early high‐temperature amphibole‐magnetite alteration resulted from magmatic‐hydrothermal fluids. Several lines of evidence indicate 500°C as a realistic average temperature for mineralization, development of quartz veins, and biotitization processes. On the basis of mineral isotope data, responsible fluids could represent either 18O‐shifted ground‐waters or magmatic‐hydrothermal fluids at submagmatic temperatures. Independent evidence, as well as total‐rock 18O data, support the magmatic‐hydrothermal model.

Late‐stage sericitization processes probably resulted from fluids produced by 18O shifting of groundwaters during the evolution of the propylitic zone. Outermost quartz veins and biotitization conceivably resulted from fluids similar to those that caused sericitization, indicating that some interaction between relatively cool, 18O‐poor meteoric waters and the ore fluids occurred near the margins of the deposit. The origin of the chlorite‐sericite alteration cannot be resolved solely by isotope studies.  相似文献   

5.
Woodlark Island, the largest above‐sea portion of the Woodlark Rise, has an exposed basement of pre‐Miocene (?Cretaceous‐Eocene) low‐K tholeiitic basalt and dolerite, and minor sediments. The basement is unconformably overlain by Early Miocene limestone and volcaniclastic sediments and later Miocene high‐K volcanics and comagmatic intrusives. Pleistocene to Recent sediments partly blanket the Tertiary sequence. Basement low‐K tholeiites vary only slightly in composition and are interpreted as ocean floor or possible marginal basin material. The high‐K suite appears to be chemically similar to late Tertiary to Recent high‐K igneous rocks of mainland Papua New Guinea. It includes porphyritic hornblende‐, clinopyroxene‐, biotite‐ and magnetite‐bearing shoshonite, latite and toscanite, and intrusive equivalents that range from olivine normative to strongly quartz normative compositions (S1Q2 46% to 75%). Computer mixing models indicate that separation of the pheno‐crysts in the shoshonites, particularly pargasitic hornblende, is a feasible mechanism for producing the more silica‐rich monzonites and latites.

The low‐K tholeiitic basement rocks of Woodlark Island are inferred to be part of an ophiolitic slab en echelon with the Papuan Ultramafic Belt, thrust over equivalents of the Cretaceous Owen Stanley Metamorphics or, in part, onto existing oceanic crust. High‐K igneous rocks on Woodlark Island appear to form an eastward extension of a province of calcalkaline to shoshonitic volcanic and intrusive rocks, which stretches from Mount Lamington to the Louisiade Archipelago. Late‐middle Miocene high‐K magmatism at Woodlark Island is consistent with the observation that activity commenced earlier in the E and became progressively younger westwards towards mainland Papua New Guinea. Periodicity in the magmatism was apparently synchronous with major rifting episodes that formed the Woodlark Basin. The data on the Woodlark Island high‐K suite support the currently accepted. concept of delayed partial melting of a mantle source previously modified by the introduction of water and LILE from an earlier subduction zone (Johnson et al., 1978b).  相似文献   

6.
The volcanogenic Woodlawn Cu‐Pb‐Zn sulphide mineralization occurs within a low‐grade metamorphosed sequence of Middle to Upper Silurian felsic volcanics and fine‐grained sedimentary rocks. Studies on a total of 234 rock samples from diamond drill holes have delineated zones of hydrothermally altered rocks extending more than ～500 m laterally from the main ore lens, at least ～100 m into the foot wall and up to ～200 m into the hanging wall. These altered rocks contain virtually no remnants of primary feldspars and ferromagnesian minerals, and they are variably chloritized, sericitized and silicified. Chlorite and disseminated sulphide minerals are most abundant in zone I, a restricted zone of intense alteration immediately around the main ore lens, whereas sericitic muscovite is most abundant in the relatively extensive zone II, further from the ore. Silicification is also a feature of volcanics well beyond the limits of observed phyllosilicate‐rich alteration zones. Chemical changes within the hydrothermally altered rocks include major enrichment of Fe, Mg, S, Si and H2O, more sporadic enrichment of Ag, Ba, Bi, Cd, Cu, Mn, Pb, Sn and Zn, and major depletion of Ca, Na and Sr. K is depleted in zone I and shows considerable variation, but no overall depletion or enrichment, in zone II.

Lithological, mineralogical and geochemical features around the Woodlawn orebody are basically similar to those associated with the younger, unmetamorphosed Kuroko deposits.  相似文献   

7.
In ternary feldspars of essentially one phase, calcium content has a dominant influence on the optic axial angle. In such feldspars and also in binary feldspars from solvsbergite rocks, variations of cooling histories do not significantly affect the optic axial angle. In ternary feldspars which are unmixed into two or three prominent phases, Al/Si ordering has an important effect on the 2V value. A recent suggestion of several writers that in feldspars the alkali structural site may be partially occupied by (H3O)+ ions is applied as a possible way to explain a correlation observed between petrographical features of the rocks and the optic axial angles of their feldspar phenocrysts.  相似文献   

8.
Sequence‐stratigraphic interpretations of the 4200 m‐thick Palaeoproterozoic (1700–1650 Ma) Mt Isa Group and underlying Surprise Creek Formation identify three unconformity‐bounded packages termed the Prize, Gun and Loretta Supersequences. Siliciclastic rocks of the Surprise Creek Formation and Warrina Park Quartzite comprise the Prize Supersequence. Rapid facies changes from proximal, conglomeratic fluvial packages to distal, fine‐grained and deep‐water, rhythmites characterise this supersequence. Conglomeratic intervals in the Mt Isa area reflect syndepositional movement along basin‐margin faults during the period of supersequence initiation. A major unconformity, which extends over a period of about 25 million years, separates the Gun and Prize Supersequences. In the Leichhardt River Fault Trough uplift and incision of Prize sedimentary rocks coincided with emplacement of the Sybella Granite (1671±8 Ma) and Carters Bore Rhyolite (1678±2 Ma) and the removal of an unknown thickness of Prize Supersequence section. Deep‐water, turbiditic rhythmites of the Mt Isa Group dominated the Gun and Loretta Supersequences. Tempestites are present over discrete intervals and represent times of relative shallowing. High accommodation and sedimentation rates at the base of the Gun Supersequence resulted in the deposition of transgressive nearshore facies (uppermost Warrina Park Quartzite) overlain by a thick interval of deep‐water, siltstone‐mudstone rhythmites of the Moondarra Siltstone and Breakaway Shale. With declining rates of siliciclastic sedimentation and shallowing of the succession, calcareous sediments of the Native Bee Siltstone prograded over the deeper water deposits. Two third‐order sequences, Gun 1 and 2, characterise these lower parts of the Gun Supersequence. An increase in accommodation rates near the top of the Native Bee Siltstone in Gun 3 time, resulted in a return to deep‐water sedimentation with deposition of dolomitic rhythmites of the Urquhart Shale and Spear Siltstone. The Pb–Zn–Ag ore‐hosting interval of the Urquhart Shale is interpreted to occur in progradational highstand deposits of the Gun 3 Sequence. In the Leichhardt River Fault Trough the Loretta Supersequence boundary forms a correlative conformity. Coarser grained and thicker bedded sediments of the Kennedy Siltstone comprise lowstand deposits at the base of this cycle. These sediments fine up into the transgressive, deep‐water, siliciclastic facies of the Magazine Shale, which in turn are truncated against the Mt Isa Fault.  相似文献   

9.

40Ar‐39Ar age spectra on minerals from granitic, metamorphic and hydrothermal rocks confirm that the Early Proterozoic Tennant Creek Block was affected by two thermal events during its evolution. Although extensive alteration of biotite and feldspar within the granites precludes the direct determination of their cooling history, 40Ar‐39Ar analyses for hydrothermal muscovite from several nearby gold‐copper deposits indicate that regional cooling to below ～ 300°C was not prolonged. Flat, uniform muscovite age spectra were obtained from gold deposits east of the Tennant Creek town site and indicate a minimum age of 1825–1830 Ma for their formation. These ages are within error of those for the felsic volcanism of the Flynn Subgroup, and a genetic relationship between the two may exist. Samples from gold deposits elsewhere in the area indicate disturbance of the K‐Ar isotope system. The second thermal event to affect the region occurred at around 1700 Ma, and is confirmed by the 40Ar‐39Ar muscovite ages for the ‘Warrego’ granite (1677 ± 4 Ma) and for the metamorphism of the Wundirgi Formation (1696 ± 4 Ma).  相似文献   

10.
The oxide mineralogy and rock magnetic properties of unmineralised banded iron‐formations in selected portions of four drillholes in the Hamersley Basin, Western Australia are reviewed. In all four drillholes, petrographic studies indicate that primary euhedral to subhedral hematite is partially replaced by magnetite as a result of subsolidus reduction. All drillholes show partial recrystallisation of the secondary magnetite, suggesting that early subsolidus reduction was probably a regional event occurring during prograde metamorphism. Incomplete replacement of primary hematite by magnetite within and between sedimentary band structures indicates that equilibration in the magnetite stability field was not reached even at the mesoband scale. Subsequent subsolidus oxidation of magnetite and the formation of a second‐generation hematite are documented in only two of the drillholes. Goethite‐filled veins and thick selvages of goethite around some veins reflect movement of circulating oxidising fluids. The absence of goethite and second‐generation hematite in two of the drillholes indicates that subsolidus oxidation is not a regional event, but very much localised. Rapid changes in down‐hole susceptibility measurements correlate directly with detailed petrographic results as susceptibility readings change with the hematite/magnetite ratio on a mesoband scale. Acquisition of the main remanence correlates with the formation of hematite as the primary oxide phase followed by partial replacement by magnetite as a result of subsolidus reduction, supporting regional models requiring pre‐folding remanence. The strong orientation of the primary hematite parent parallel to band structures in the banded iron‐formations has influenced the direction of crystallisation remanent magnetisation during subsolidus reduction to the magnetite daughter. The strong planar alignment has also produced a planar magnetic fabric and marked anisotropy of magnetic susceptibility. A natural remanent magnetisation overprint and reduction in anisotropy of magnetic susceptibility are only recorded in samples that have undergone subsolidus oxidation and the recognition of localised post‐metamorphic oxidation overprinting can also explain ore deposit models requiring post‐folding remanence. The relative timing of and between oxidising fluid events is not known, but both petrographic and rock magnetic evidence to date suggests that there was at least one and probably two post‐folding oxidising events in the area of study.  相似文献   

11.
The geochemistry of two deerite‐bearing meta‐ironstones from the Emo Metamorphics of Papua New Guinea suggests that they were deposited as metalliferous cherts enriched in manganese and iron by hydrothermal exhalative activity in an ocean ridge system. Subsequent blueschist facies metamorphism resulted in the formation of the assemblage deerite‐quartz‐albite‐iron oxides‐alkali amphiboles‐spessar‐tine‐stilpnomelane‐apatite, with calcium‐manganese carbonates in one specimen. Assemblages in associated metabasites suggest P‐T conditions of 7 kb at 320°C, which overlap with the P‐T field defined by one of the meta‐ironstones. Oxygen fugacity was probably an important control in determining variations in mineralogy and mineral chemistry. Preliminary data on the trace element geochemistry of associated metabasites are consistent with an ocean ridge environment for the formation of the meta‐ironstones.  相似文献   

12.
Biotite igneous ages and well‐defined isochron ages of plutons from the composite Blue Tier Batholith and the Coles Bay area in northeastern Tasmania range from 395 to 370 Ma. The older limit of this range, for the George River granodiorite, is considerably older than any age previously recorded for NE Tasmania. The ages of the youngest plutons (Mt Paris and Anchor granites), which host cassiterite ores, record pervasive hydrothermal alteration events. The initial 87Sr/80Sr ratios of the granitoids range from 0.7061 to 0.7136 and suggest different protolith compositions, consistent with mineralogical and geochemical characteristics of each pluton. The S‐type garnetbiotite granites (Ansons Bay and Booby alia granites) have initial ratios greater than 0.7119, indicative of enriched, high Rb/Sr ratio, crustal source‐rocks of Proterozoic age (1700–800 Ma). The S‐type biotite granites (Poimena and Pearson granites) have relatively high initial 87Sr/86Sr ratios (0.7070, 0.7105) but overlap with those of the I‐type granodiorites (George River, Scamander Tier, Pyengana and Coles Bay granodiorites) which are in the range of 0.7061 to 0.7073. The initial ratios of the enriched altered plutons are poorly constrained, and on both hand‐specimen and thin‐section scales, reveal open‐system Sr isotopic patterns.

Isochron ages for the arenite‐lutite and lutite sedimentary associations of the Mathinna Beds, which are intruded by the granitoids, reflect an approach to Sr isotopic equilibrium during regional metamorphism. The metamorphic age (401 ± 7 Ma) of the early Pragian arenite‐lutite association indicates a relatively small time interval between deposition, regional metamorphism and granitoid intrusion. The isotopic age for the lutite sedimentary association (423 ± 22 Ma) is tentatively correlated with a Benambran‐age burial metamorphic event that has not previously been recorded in Tasmania.  相似文献   

13.
The development of a thin peat layer over metamorphic rock during the last cold stage in the Louisa and Melaleuca Plains and at Birch's Inlet, Tasmania, has recently been reported. This paper presents results of a numerical model on permafrost growth and decay, which explores the possibility of the development of a thin layer of permafrost for this particular depositional setting at the end of the last cold stage in Tasmania. The increase in thermal conductivity of peat sediments under frozen conditions results in a preferred penetration of the cold winter wave (in comparison to the summer wave) into the subsurface. The results of the model calculations suggest the development of a several metres‐thick permafrost layer, even under slightly positive mean annual temperatures in the region.  相似文献   

14.
The Alagoinhas pluton is a member of the widespread high‐K calc‐alkaline association of northeastern Brazil. Some authors suggest that this region represents an amalgamation of distinct tectonic terranes assembled during the Brasiliano (Pan‐African) orogeny. Our work compares geochemical data (major, trace and REE) of the Alagoinhas with other plutons of same petrotectonic association (Caruaru‐Arcoverde batholith). These plutons apparently intrude several distinct tectonic terranes, separated by a major E‐W dextral transcurrent system, the East Pernambuco shear zone (EPSZ). Anisotropy of magnetic susceptibility and structural data for the Alagoinhas pluton are used to compare tectonic regimes across the EPSZ. The results indicate that the Caruaru‐Arcoverde batholith and the Alagoinhas pluton evolved from similar sources and were subjected to the same tectonic regime during emplacement, placing severe restrictions on use of the EPSZ as a suture zone between distinct tectonic terranes.  相似文献   

15.
The Hongcheon area in the central Gyeonggi massif is a unique carbonatite locality in South Korea. The age and petrogenesis of this uncommon rock type and associated rare earth element (REE) mineralization still remain uncertain. The NNE trending, 20–50 m wide and ~ 2 km long Fe-REE ore bodies are hosted within a swarm of carbonatite dykes intruding Precambrian basement gneisses. The intrusive nature of the dykes, fenite alteration halos, exsolution intergrowths of constituent minerals and stable isotope data in the literature collectively attest to the ore formation by crystallization of carbonatite magma. The carbonatites are composed primarily of dolomite, ankerite, siderite, magnetite, monazite, apatite, strontianite and pyrite with subordinate quartz, barite, columbite, fergusonite and calcite. The principal carrier phase of REEs is monazite. The REE contents of monazite vary narrowly (TREO = 66.1–69.4 wt.%) irrespective of the textural occurrence. Although the monazite shows a sample-to-sample variation in La/Nd ratio, the textural varieties from each rock sample are similar with respect to this ratio. Thorium contents in monazite are consistently low (average = ca. 2500 ppm) with unusually high (average = ca. 2200) Th/U ratios. Sensitive high-resolution ion microprobe (SHRIMP) dating of monazite yielded a weighted mean 208Pb/232Th age of 232.9 ± 1.6 Ma, which agrees with a weighted mean 206Pb/238U age of 227.2 ± 8.3 Ma within uncertainties. This age, coupled with comparable intrusion ages documented for kimberlites and monzonite-syenite-gabbro-mangerite suite from central Korea, demonstrates the occurrence of mantle-derived alkaline igneous activities and associated REE mineralization following the North and South China collision. The intrusion of the Hongcheon carbonatite and potassic or ultrapotassic suite in central Korea may have resulted from the post-collisional detachment of the subducted slab and consequent upwelling of hot asthenosphere and melting of the overriding lithospheric mantle. Initial Nd‐Sr isotopic ranges of the Hongcheon carbonatite (εNd = ca. − 26, 87Sr/86Sr = 0.703–0.706) and previous trace element data deny a petrogenetic linkage with the coeval silicate magmas. The metasomatism in the lithospheric mantle source of the Hongcheon carbonatite must have occurred in the distant past (> 1.7 Ga) to generate significantly negative εNd values.  相似文献   

16.
The presence of base‐metal mineralization at Woodlawn was first recognised early in 1968 when a roadside reconnaissance geochemical sampling survey, conducted over felsic volcanic rocks in the Goulburn‐Tarago area, encountered anomalous B horizon soils containing up to 200 ppm Cu, 800 ppm Pb and 300 ppm Zn. Regional soil thresholds have been determined at 50 ppm Cu, 90 ppm Pb and 50 ppm Zn. Chip samples from the subsequently located gossan revealed up to 2000 ppm Cu, 8000 ppm Pb and 2000 ppm Zn, 500 ppm Sn, 25 ppm Ag and 3000 ppm As.

The first grid B horizon soil geochemical survey was conducted in 1968 over the gossan and surrounding area, and repeated with closer spaced sampling in the first half of 1970. The first survey delineated strong Cu (to 1000 ppm) and Pb (to 2500 ppm) anomalies coincident with the gossan zone, and intense hydromorphic zinc anomalies (to 3000 ppm) located down slope from the gossan in residual clay‐soils derived from dolerite bedrock. Threshold values have been determined at 140 ppm Cu, 700 ppm Pb and 580 ppm Zn. Ag and Sn in B horizon soils show pronounced anomalies coincident with the gossan and are suitable metals for geochemical target definition. Of fourteen trace elements determined in 1974 from B and C horizon soils on two lines across the ore zone Cu, Pb, Zn, Se, Ba, Sn and Ag show direct correlation with the mineralization, whereas Cd and Mn show moderate hydromorphic dispersion, having accumulated principally in clay soils derived from dolerite weathering. As, Sb and Bi, whilst responding over the ore zone, show elevated values in soils over hanging‐wall units; Ni and Co show maximum levels in soils over dolerite bedrock.

Bark and leaves of Acacia mearnsii, collected from a line across the gossan, contain anomalous levels of Cu, Pb, Zn, Sn and Ti near the ore zone, and weaker, but clearly anomalous Mn and Ni levels over dolerite bedrock. Both bark and leaves of Acacia mearnsii reflect the presence of concealed mineralization. The shrub Solanum linearifolium grows preferentially over and close to the Woodlawn ore zone, where it contains up to 840 ppm Cu, 250 ppm Pb, 7300 ppm Zn, 6 ppm Sn and 250 ppm Ti in leaf ash compared with levels of 200 ppm Cu, 2 ppm Pb, 400 ppm Zn, 0.8 ppm Sn and 60 ppm Ti in plants growing 1.5 km from the ore zone. This shrub has potential as an indicator of base‐metal mineralization.  相似文献   

17.

The Murray Basin in southeastern Australia is a large, shallow, intracratonic basin filled with laterally extensive, undeformed, Cenozoic carbonate and terrigenous clastic sedimentary rocks that constitute regional and locally important groundwater aquifers. The marine Oligo‐Miocene strata distributed throughout the southwestern portion of the basin are here encompassed within the Murray Supergroup. The Murray Supergroup (formerly Murray Group) incorporates the marginal marine marl and clay of the Ettrick Formation, Winnambool Formation and Geera Clay in the western and northern portions of the Murray Basin in South Australia, in addition to the limestone that outcrops along the banks of the River Murray in nearly continuous section for 175 km. The stratigraphic nomenclature of these rocks is revised as follows. The boundary between the lower and upper members of the Mannum Formation is redefined and a new Swan Reach Dolomite Member is erected. The Finniss Clay is revised to Finniss Formation possessing three new members: the Cowirra Clay Member, Portee Carbonate Member and Woolpunda Marl Member. The ‘Morgan Limestone’ is raised to Morgan Group and contains three new formations: the Glenforslan Formation, Cadell Formation (with Murbko Marl Member and Overland Corner Clay Member) and Bryant Creek Formation. The Pata Formation is redefined and described. Type and reference sections are erected for each new and revised unit, and are lithostratigraphically correlated to illustrate their stratigraphic architecture.  相似文献   

18.
The Newer Volcanics Province of Victoria and South Australia consists of a major region of mainly alkaline basalts within which are two restricted areas containing strongly differentiated flow‐rocks. Typical alkalic basalts from this widespread province have K‐Ar ages from 4.5 to 0.5 m.y. and initial 87Sr/86Sr ratios from 0.7038 to 0.7045. Contrastingly, in the Macedon area of differentiated lavas, flow compositions range from limburgite to soda trachyte, with K‐Ar ages from 6.8 to 4.6 m.y. and initial 87Sr/86Sr ratios from 0.7052 to 0.7127. These differentiated rocks therefore are older, and some of them may have been contaminated by reaction with more radiogenic basement rocks during differentiation. Alternatively, the variation in initial Sr‐isotope composition may have resulted from varying isotopic composition of partial melts from the immediate source rocks. The most felsic of the differentiated rocks, soda trachyte, is extremely enriched with Rb relative to Sr; one of the three restricted outcrops of this rock (Camel's Hump) yields a total‐rock Rb‐Sr isochron age of 6.3 ± 0.6 m.y. with an initial 87Sr/86Sr ratio of 0.7127. K‐Ar sanidine ages reported for the three outcrops of trachyte are identical to each other and to the Rb‐Sr isochron result.  相似文献   

19.
Fractionation of tholeiitic magma in the Red Hill intrusion produced a gradational series of rocks ranging from dolerite to granophyre (McDougall, 1962). Granophyres are enriched in Fe, Si and alkalies, and impoverished in Mg, Ca and Al. With fractionation the magma was depleted rapidly in Cr and Ni owing to their removal in early crystallizing pyroxene and iron oxides. Cobalt decreases gradually from chilled dolerite to silicic dolerite, followed by a significant maximum in the most Fe‐enriched rocks, and finally decreases markedly in the granophyres. Cobalt follows Fe2+ closely and shows no obvious relationship with Mg. Copper was progressively enriched in the magma during the main stages of fractionation until precipitation of sulphide occurred, which caused impoverishment of Cu in the final liquid. Copper also is present in the silicates, it substitutes for Na in the feldspars and Fe2+ in pyroxenes and iron oxides.  相似文献   

20.
A precise baddeleyite U‐Pb age of 2418 ± 3 Ma is reported for the westerly extension of the Binneringie Dyke in the south‐western Yilgarn Craton of Western Australia. The Binneringie Dyke is a member of the large and extensive Widgiemooltha dyke swarm that trends east‐west across the craton. This age is similar to ages of major dyke swarms In other Archaean Cratons and supports the hypothesis that dykes of the Widgiemooltha swarm are part of a worldwide Palaeoproterozoic mafic magmatic event at ca 2420 Ma.  相似文献   

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