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1.
We used illite and chlorite crystallinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis (EMPA), b0 geobarometer and chlorite geothermometer to quantify the diagenetic and metamorphic overprint on the Triassic flysch formations in the Songpan-Garzê orogen along profile Zoigê-Lushan, northwest Sichuan. Two anchizones, two epizones, one diagenetic zone and a transition belt in-between them are defined on the basis of the obtained data. Illite crystallinity correlates strongly with the best mean domain size of mica and moderately with chlorite crystallinity. 2M1 white mica polytype are observed within the epizone whilst 2M1 and 1M polytypes occur in the anchizone and diagenetic zone. Epizonal metamorphism reached maximum temperatures of 370oC±21oC at low-to intermediate pressure conditions. Clay minerals underwent Ostwald ripening during metamorphism. Rocks from both sides of the Longmenshan fault reveal contrasting degrees of metamorphic overprint: on the northwest side of the Longmenshan fault, epimetamorphic conditions contrast with diagenetic rocks on the southeast side.  相似文献   

2.
We used illite and chlorite crystallinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis (EMPA), b0 geobarometer and chlorite geothermometer to quantify the diagenetic and metamorphic overprint on the Triassic flysch formations in the Songpan-Garzê orogen along profile Zoigê-Lushan, northwest Sichuan. Two anchizones, two epizones, one diagenetic zone and a transition belt in-between them are defined on the basis of the obtained data. Illite crystallinity correlates strongly with the best mean domain size of mica and moderately with chlorite crystallinity. 2M1 white mica polytype are observed within the epizone whilst 2M1 and 1M polytypes occur in the anchizone and diagenetic zone. Epizonal metamorphism reached maximum temperatures of 370oC±21oC at low-to intermediate pressure conditions. Clay minerals underwent Ostwald ripening during metamorphism. Rocks from both sides of the Longmenshan fault reveal contrasting degrees of metamorphic overprint: on the northwest side of the Longmenshan fault, epimetamorphic conditions contrast with diagenetic rocks on the southeast side.  相似文献   

3.
X-ray diffraction methods for estimating the metamorphic grade of diagenetic,anchizone and epizone in metapelites are reviewed and applied to samples from a 7000 m+ borehole in western China and surfac...  相似文献   

4.
This study uses illite crystallinity,chlorite crystallinity,illite polytypes,the b_0 cell-dimension of K-white mica,clay mineral assemblages and mineral geothermo-geobarometers to investigate the overprint of diagenesis and metamorphism on the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang in northeastern Hunan Province,China.Illite crystallinity Kbler index(KI) of the 2μm fractions ranges from 0.225 to 0.485°Δ2θ while chlorite crystallinity Arkai index(AI) ranges from 0.244 to 1.500°Δ2θ.This indicates that the Meso-Neoproterozoic and the Lower Paleozoic along the profile Yueyang-Linxiang were overprinted with diagenesis and anchi- to epimetamorphism.Peak metamorphic temperature is estimated with the IV site chlorite geothermometer roughly at 360℃.The b_0 cell dimension values of illites(K-mica) range from 0.9002 to 0.9054 nm and,on average,at 0.9030 nm for the Meso-Neoproterozoic.Based on cumulative frequency curves of illite(K-mica) b_0 cell dimension,the peak metamorphic pressure of the MesoNeoproterozoic along the profile Yueyang-Linxiang is derived of an intermediate pressure type.Most illites occur in the 2M_1 polytype and some of them in a mixture of 2M1+1M types especially those in the Paleozoic.This result partly agrees with the conclusion of the lower greenschist and greenschist facies of the Lengjiaxi and Banxi Groups.However,it is not agreed with the sedimentary cover from the Sinian to the Lower Paleozoic or from the Banxi Group to the Lower Paleozoic.Crustal thickening due to "collision" between the Yangtze and Cathaysia blocks led to an increase in the thickness of the Meso-Neoproterozoic to ca.14 km and resulted in a temperature increase in those rocks due to burial.The very low grade to low grade metamorphism overprinting the Meso-Neoproterozoic implies that the so called "Chiangnania or Jiangnan orogen" was no relative with the "Grenvillian orogeney;instead,it might be a continuous amalgamation product between the Yangtze and Cathaysia blocks.  相似文献   

5.
Burial Metamorphism of the Ordos Basin in Northern Shaanxi   总被引：1，自引：0，他引：1  
Burial metamorphism has been found in the Ordos basin of northern Shaanxi. On the basis of a rather intensive study of burial metamorphism of sandstone, it has been shown that the evolution from diagenesis to metamorphism involves four stages: cementation of clay minerals, regrowth of pressolved quartz and feldspar, cementation of carbonates and formation of laumontite. On that basis it has been put forward that the laumontite is formed by burial metamorphism of clay and carbonate minerals. According to the thermodynamic data of minerals, the conditions under which laumontite is formed are T<250℃ and X_(CO_2)<0.17. High-resolution SEM and TEM studies of clay minerals in mudstone show that there occur a mixed layer assemblage of bertherine and illite/chlorite and transformation from bertherine to chlorite. On that basis coupled by the X-ray diffraction analysis the author suggests the following transformation of clay minerals during burial metamorphism: the earliest smectite-kaolinite assemblage changes into the bertherine-illite mixture with increasing depth, then into the illite/chlorite mixed layer assemblage and finally into dispersed individual illite and chlorite. The reaction of the transformation is:smectite+kaolinite+K~+=illite+chlorite+quartz According to the study of the oxygen isotope thermometry of the coexisting illitequartz pair, the temperature of the above transformation is lower than 180℃.  相似文献   

6.
The metamorphic conditions of the Upper Permian Yangjiagou Formation in eastern Changchun, China, were evaluated based on the mineral assemblage, illite crystallinity, illite polytypism,the b dimension of illite, and the chemical composition of chlorite. The pelitic rocks in the Yangjiagou Formation are characterized by illite + kaolinite + chlorite ± mixed-layer chlorite/smectite and detrital quartz + plagioclase. Illite in the formation has a crystallinity of 0.38-0.55 and comprises mixed 2 M_1 and1 M_d polytypes, indicating a metamorphic temperature of 200℃. Based on the chemical composition of chlorite and the chlorite geothermometer, we estimated diagenetic to very low-grade metamorphic conditions with temperatures of 185℃～204℃. The b dimension of illite varies from 8.992 A to 9.005 A.We used a mathematical algorithm to extend Guidotti and Sassi's(1986) diagram relating illite b dimension with temperature and pressure, and used this diagram, together with illite crystallinity and chlorite chemical composition, to semi-quantitatively estimate the formation pressure at1.2 kbar. These reveal that the Yangjiagou Formation has experienced very low-grade metamorphism.  相似文献   

7.
The map expression of "abrupt" changes in lateral stratigraphic level of a thrust fault has been traditionally interpreted to be a result of the presence of(1) a lateral(or oblique) thrust-ramp,or(2) a frontal ramp with displacement gradient、and/or(3) a combination of these geometries.These geometries have been used to interpret the structures near transverse /ones in fold-thrust belts(FTB).This contribution outlines an alternative explanation that can result in the same map pattern by lateral variations in stratigraphy along the strike of a low angle thrust fault.We describe the natural example of the Leamington transverse zone.which marks the southern margin of the Pennsy lvanian—Permian Oquirrh basin with genetically related lateral stratigraphic variations in the North American Sevier(TB.Thus.the observed map pattern at this zone is closely related to lateral stratigraphic variations along the strike of a horizontal fault.Even though the present-day erosional level shows the map pattern that could be interpreted as a lateral ramp.the observed structures along the Leamington zone most likely share the effects of the presence of a lateral(or oblique) ramp,lateral stratigraphic variations along the fault trace.and the displacement gradient.  相似文献   

8.
The Neoproterozoic and Lower Paleozoic along the profile of Yuanguping in western Hunan Province, China underwent anchimetamorphism. The illite crystallinity (IC) of the <2 μm fractions ranges from 0.23-0.34°△2θfor the Neoproterozoic to 0.23-0.35°△A2θ for the Lower Paleozoic (calibrated with the Kisch IC set, Kisch, 1991). This indicates that the metamorphic grade of the Neoproterozoic and Lower Paleozoic is the anchizone. The peak metamorphic temperature is estimated to be 290-210℃. This result does not agree with the greenschist or subgreenschist facies of the Banxi Group, nor with the lower-greenschist facies or sedimentary cover of the Sinian to Lower Paleozoic, as most previous researchers thought. The illite (K-mica) b0 values range from 0.9074 to 0.8963 (nm) for the Neoproterozoic and the Lower Paleozoic. Based on cumulative frequency curves of the illite (K-mica) b0, the peak metamorphic pressure of the Banxi Group was derived to be of a type that is slightly higher than that of the N. Ne  相似文献   

9.
K-Ar Dating of Fault Gouges from the Red River Fault Zone of Vietnam   总被引：1，自引：0，他引：1  
Constraining the timing of fault zone formation is fundamentally important in terms of geotectonics to understand structural evolution and brittle fault processes.This paper presents the first authigenic illite K-Ar age data from fault gouge samples collected from the Red River Shear Zone at Lao Cai province,Vietnam.The fault gouge samples were separated into three grain-size fractions(0.1 μm,0.1-0.4 μm and 0.4-1.0 μm).The results show that the K-Ar age values decrease from coarser to finer grain fractions(24.1 to 19.2 Ma),suggesting enrichment in finer fraction of morerecently grown authigenic illites.The timing of the fault movement are the lower intercept ages at 0%detrital illite(19.2 ± 0.92 Ma and 19.4 ± 0.49 Ma).In combination with previous geochronological data,this result indicates that the metamorphism of the Day Nui Con Voi(DNCV) metamorphic complex took place before ca.26.8 Ma.At about 26.8 Ma-25 Ma,the fault strongly acted to cause the rapid exhumation of the rocks along the Red River-Ailoa Shan Fault Zone(RR-ASFZ).During brittle deformation,the DNCV slowly uplifted,implying weak movement of the fault.This brittle deformation might have lasted for ca.5 Ma.  相似文献   

10.
The Penglai Group in the Jiaobei Belt is the only remaining cover of the Archaean to Early Proterozoic crystalline basement in eastern Shandong. The ages of deposition of the Penglai Group and of its deformation and metamorphism have long been a subject of speculation. Whole-rock Rb-Sr ages, illite-whole-rock pair Rb-Sr ages and illite K-Ar ages recently obtained from the Penglai Group slates are reported and interpreted in this paper. On the basis of structural and metamorphic studies coupled with analyses of illite crystallinity, XRD and SEM , a whole-rock age of 473±32 Ma (Ordovician) is interpreted as the time of termination of burial metamorphism experienced by the Penglai Group. Therefore, the age of the Penghai Group is older than Ordovician. The first-phase folding and syntectonic low greenschist facies metamorphism in the Penglai Group, i.e. the Penglai Movement, took place before 299±4 Ma B.P., i.e in the Late Carboniferous. The Penglai Movement that occurred in the Jiaobei Belt on the south  相似文献   

11.
周健  王河锦 《地质论评》2002,48(4):361-364
运用X射线衍射分析技术，计算了成岩带、近变质带粘土矿物C^*方向的粒度。根据阿尔卑斯造山带前陆碎屑岩粘土矿物粒度与伊利石结晶指数的关系，推导出了伊利石、绿泥石、蒙脱石、伊蒙混层、高岭石和叶蜡石的c^*方向粒度变化趋势曲线。结果表明，大多数产于成岩带和近变质带的粘矿物其c6*方向粒工为几至几十纳米。成岩带和近为质带是一维天然纳为级土帮物的产地。  相似文献   

12.
伊利石结晶度及其在低温变质研究中若干问题的讨论   总被引：4，自引：0，他引：4  
王河锦  陶晓风  M.Rahn 《地学前缘》2007,14(1):151-156
文中介绍与伊利石结晶度相关的伊利石矿物新的定名方案;讨论了伊利石结晶度的结晶学基础与Scherrer方程式的关系;讨论了三个重要的伊利石结晶度指数Weaver、K櫣bler和Weber指数的关系,并介绍推导的Weaver、K櫣bler和Weber指数的理论关系式;评价了衍射仪测量条件对结晶度数值的影响和三套伊利石结晶度标样的作用以及成岩带、变质带与葡萄石-绿纤石相、沸石相、绿纤石-阳起石亚相对比的依据。建议(1)停用绢云母一词;(2)建立可供各实验室使用的具有晶体结构和晶体化学参数和多型参数的伊利石结晶度标样;(3)建议多开展规范的可进行国际对比的低温变质研究,划分出与国际上一致的成岩带和近变质带,不仅利于低温变质作用理论的研究,而且由于成岩带到近变质转变带是重要的煤气油的生成带,也利于中国煤气油资源的勘探与开发,利于国民经济的长远持续发展。  相似文献   

13.
索书田  毕先梅 《地质科学》1998,33(4):395-405
右江盆地三叠纪槽盆相浊流沉积岩系遭受过区域极低级变质作用。依据地质观察和伊利石结晶度、绿泥石-云母堆垛集合体、标志性粘土矿物及白云母(伊利石)b0参数测定资料,阐述了泥质岩石的成岩变质作用经浅层(近)变质作用到浅变质作用的转换特征。变质温度区间为150-350℃,低压类型,具高地温梯度(40-43℃/km).变质级及亚带总体与地层时代及岩层在地层柱中的位置有耦合关系,而与区域变形强度无关。最后指出区域极低级变质作用是印支-燕山构造旋回早期及区域变形前的地质事件,属于地壳伸展构造背景下右江边缘型盆地内部的埋藏型变质作用。  相似文献   

14.
 右江盆地三叠纪槽盆相浊流沉积岩系遭受过区域极低级变质作用。依据地质观察和伊利石结晶度、绿泥石-云母堆垛集合体、标志性粘土矿物及白云母(伊利石)b0参数测定资料,阐述了泥质岩石的成岩变质作用经浅层(近)变质作用到浅变质作用的转换特征。变质温度区间为150-350℃,低压类型,具高地温梯度(40-43℃/km).变质级及亚带总体与地层时代及岩层在地层柱中的位置有耦合关系,而与区域变形强度无关。最后指出区域极低级变质作用是印支-燕山构造旋回早期及区域变形前的地质事件,属于地壳伸展构造背景下右江边缘型盆地内部的埋藏型变质作用。  相似文献   

15.
由伊利石结晶度研究桂西右江地区区域极低级变质作用   总被引：10，自引：0，他引：10  
运用伊利石结晶度Kübler指数将桂西右江地区下三叠统罗楼群和中三叠统百逢组下段划归为浅层变质带(K.I△2θ°为0.22～0.25);将中三叠统百逢组上段和河口组划归为近变质带,中三叠统百逢组上段为高级近变质带(K.I△2θ°为0.26～0.33);中三叠统上部河口组为低级近变质带(K.I△2θ°为0.38～0.40),不排除局部为成岩带的可能.地层柱自下向上,伊利石结晶度Kübler指数由小变大,变质程度由高变低,而且,变质作用级别与岩层在地层柱中位置协调以及变质带边界与地层界线趋于一致,证明为区域埋藏极低级变质作用.凌云明山金矿区剖面矿体和百逢组各层段伊利石结晶度Kübler指数为0.42～0.50,属成岩带,且没有明显时空变化规律.  相似文献   

16.
We used illite and chlorite crystallinities, index minerals, mineral assemblages, polytype and domain size of white mica, electron microprobe analysis (EMPA), b0 geobarometer and chlorite geothermometer to quantify the diagenetic and metamorphic overprint on the Triassic flysch formations in the Songpan-Garzê orogen along profile Zoigê-Lushan, northwest Sichuan. Two anchizones, two epizones, one diagenetic zone and a transition belt in-between them are defined on the basis of the obtained data. lllite crystallinity correlates strongly with the best mean domain size of mica and moderately with chlorite crystallinity. 2M1 white mica polytype are observed within the epizone whilst 2M1 and 1M polytypes occur in the anchizone and diagenetic zone. Epizonal metamorphism reached maximum temperatures of 370℃±21℃ at low-to intermediate pressure conditions. Clay minerals underwent Ostwaid ripening during metamorphism. Rocks from both sides of the Longmenshan fault reveal contrasting degrees of metamorphic overprint: on the northwest side of the Longmenshan fault, epimetamorphlc conditions contrast with diagenetic rocks on the southeast side.  相似文献   

17.
This study uses clay mineral assemblages, illite ??crystallinity?? (IC), chlorite ??crystallinity?? (CC), illite polytypes, the b cell-dimension of K-white mica, mineral geothermo-geobarometers and homogenization temperatures of fluid inclusions to investigate the transition from diagenesis to metamorphism in a 7?km thick Triassic flysch sequence in the well Hongcan 1, eastern Tibetan plateau. The 7,012.8?m deep borehole penetrated flysch of Upper to the Middle Triassic age and represents a unique chance to characterize low temperature metamorphic processes in an unusually thick sedimentary sequence developed on thickened continental crust. Mineral assemblage analysis reveals a burial metamorphic pattern with kaolinite and chlorite/smectite mix-layer phases present in the upper 1,500?m, and illite/smectite mixed-layer phases extending to a depth of 3,000?m. The metamorphic index mineral, graphite, was detected in sedimentary rock below 5,000?m using Raman spectroscopy. There exists a good correlation between IC and CC within the prograde burial sequence; with CC anchizonal boundaries of 0.242 and 0.314°2?? (upper and lower boundaries, respectively) corresponding to Kübler??s IC limits at 0.25 and 0.42°2??. Illite polytypism also shows an increase in the 2M 1 polytype with increasing depth, with ca. 60?% 2M 1 abundance compared to the 1M type at the surface, to 100?% 2M 1 at the bottom of the borehole. Fluid inclusion analysis show HHC-rich bearing fluids correspond to the diagenetic zone, CH4-rich bearing fluids appear at transitional zone from diagenetic to low anchizone and H2O-rich bearing fluids mark the high anchizone to epizone. Based on chlorite chemical geothermometer, calcite?Cdolomite geothermo-barometers as well as homogenization temperature of fluid inclusions, a paleotemperature range of 118?C348?°C is estimated for the well with a pressure facies of low to intermediate type.  相似文献   

18.
应用国际标样对伊利石结晶度测定值的校正及其意义   总被引：1，自引：0，他引：1  
伊利石的结晶度(IC),又称Kbler指数(K.I.),是指粘土矿物伊利石10×10-8cmXRD峰的半高宽。作为一个变质程度的指标,结晶度广泛用于研究高级成岩—极低级变质—低级变质作用的演变过程,随着变质程度的提高,伊利石结晶度逐渐增大。根据Kbler的建议,近变质带(极低级变质带)上、下边界的伊利石结晶度分别为0.42(°Δ2θ)和0.25(°Δ2θ)。然而,测定伊利石结晶度时,由于缺少国际标样,且各实验室间的样品制备、仪器条件、测试方法也不相同,因而导致获得的数据有较大差别,缺少可比性;因此,使用国际标样对数据进行校正,使各实验室获得的数据都能直接地进行对比,是非常必要的。利用X射线衍射方法测定了由L.N.Warr提供的5个伊利石结晶度的国际标样(其中,4个为岩石碎屑样品,采自英格兰西南部的极低级变质带;1个为单矿物样品,采自印度的花岗岩),获得了校正方程,ICCIS=0.977IC测定值+0.0336(°Δ2θ),R2=0.9835。在实验室内对213件采自国内的样品进行测定,测试条件与国际标样的测试条件相同,利用此方程对测得的伊利石结晶度数值进行校正,证实本实验室对伊利石结晶度的测定具有较高的可信度和国际可比性。  相似文献   

19.
Incipient metamorphism in the Lower Palaeozoic marginal basin of Wales   总被引：1，自引：0，他引：1  
Abstract A diagenctic through anchizone to epizone transition is demonstrated in pelitic rocks of the Lower Palaeozoic marginal basin of Wales by examination of variations in phyllo-silicate mineralogy, illite crystallinity and bo parameter of white micas. This transition represents a temperature range from ∼ 150°C to ∼ 400°C and the metamorphism is of a low-pressure facies series type, with a geothermal gradient of ∼ 40°Ckm-1. Variations in grade can be correlated largely with the original basin and shelf form, suggesting a depth-related metamorphism. However, in areas closer to the site of Caledonian plate collision an increasingly syn-tectonic metamorphic event is apparent.
Correlation of pelite data with metabasite assemblages is variable, the most consistent relationship being between epizone crystallinity values andepidote-actinolite (greenschist facies) assemblages. Diagenetic clay mineral assemblages are found associated with prehnite-pumpellyite assemblages in metabasites and it is suggested that the latter represent non-buffered, and therefore non-diagnostic, assemblages.  相似文献   

20.
Thirty-five illite and muscovite concentrates were extracted from Triassic and Permian claystones, shales, slates and phyllites along a cross-section from the diagenetic Alpine foreland (Tabular Jura and borehole samples beneath the Molasse Basin) to the anchi- and epimetamorphic Helvetic Zone of the Central Alps. Concentrates and thin sections were investigated by microscopic, X-ray, infrared, Mössbauer, thermal (DTA and TG), wet chemical, electron microprobe, K-Ar, Rb-Sr, 40Ar/39Ar and stable isotope methods.With increasing metamorphic grade based on illite crystallinity data (XRD and IR) the following continuous changes are observed: (i) the 1Md2M1 polymorph transformation is completed in the higher grade anchizone; (ii) K2O increases from 6–8 wt. % (diagenetic zone) to 8.5–10% (anchizone) to 10–11.5% (epizone), reflecting an increase in the total negative layer charge from 1.2 to 2.0; (iii) a decrease of the chemical variation of the mica population with detrital muscovite surviving up to the anchizone/ epizone boundary; iv) a shift of an endothermic peak in differential thermal curves from 500 to 750° C; (v) K-Ar and Rb-Sr apparent ages of the fraction <2 m decrease from the diagenetic zone to the epizone, K-Ar ages being generally lower than Rb-Sr ages. The critical temperature for total Ar resetting is estimated to be 260±30° C. K-Ar and Rb-Sr ages become concordant when the anchizone/ epizone boundary is approached. The stable isotope data, on the other hand, show no change with metamorphic grade but are dependent on stratigraphic age.These results suggest that the prograde evolution from 1 Md illite to 2M1 muscovite involves a continuous lattice restructuration without rupture of the tetrahedral and octahedral bonds and change of the hydroxyl radicals, however this is not a recrystallization process. This restructuration is completed approximately at the anchizone/epizone boundary. The isotopic data indicate significant diffusive loss of 40Ar and 87Sr prior to any observable lattice reorganization. The restructuration progressively introduces a consistent repartition of Ar and K in the mineral lattices and is outlined by the 40Ar/39Ar age spectra.Concordant K-Ar and Rb-Sr ages of around 35-30 Ma. with concomitant concordant 40Ar/39Ar release spectra are representative for the main phase of Alpine metamorphism (Calanda phase) in the Glarus Alps. A second age group between 25 and 20 Ma. can probably be attributed to movements along the Glarus thrust (Ruchi phase), while values down to 9 Ma., in regions with higher metamorphic conditions, suggest thermal conditions persisting at least until the middle Tortonian.  相似文献   

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