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1.
《矿物学报》2016,(3)
对位于雅鲁藏布江缝合带西段北亚带错不扎地幔橄榄岩铂族元素地球化学特征进行研究,旨在对其岩石成因和构造环境进行限定。错不扎地幔橄榄岩以方辉橄榄岩和含单辉方辉橄榄岩为主。含单辉方辉橄榄岩具有较高的铂族元素(PGEs)含量,w(PGEs)=22.31×10~(-9)~36.12×10~(-9),平均值为29.60×10~(-9),高于原始地幔含量;而方辉橄榄岩的w(PGEs)处于17.34×10~(-9)~25.18×10~(-9)之间,平均值为21.08×10~(-9),略低于原始地幔值。相对岩浆成因超基性岩,两岩类皆强烈富Os和Ir,为部分熔融后残余的地幔体。含单辉-方辉橄榄岩及部分方辉橄榄岩含较高的Pd,(Pd/Ir)m比值远大于1,具左倾型PGE组成模式,而且两者都具有低于原始地幔的Cu/Pd比值。综合研究表明错不扎方辉橄榄岩是熔融程度较低的含单辉-方辉橄榄岩继续部分熔融后的残余;两者在部分熔融过程中可能存在部分赋存Pd的硫化物未完全溶解进入硅酸盐熔体,此后又受到俯冲带岩浆渗滤形成的富硫化物熔体的改造。 相似文献
2.
泽当蛇绿岩位于雅鲁藏布江缝合带东段,由地幔橄榄岩、辉长辉绿岩、火山岩等组成。地幔橄榄岩主要为方辉橄榄岩和二辉橄榄岩,有少量的铬铁矿化方辉橄榄岩和透镜状纯橄岩。地幔橄榄岩中橄榄石的Fo值为89.6~91.8,属镁橄榄石。斜方辉石为顽火辉石,En端员组分变化于87.8~90.3。单斜辉石En组分变化于44.1~50.0,主要为顽透辉石和透辉石。二辉橄榄岩与方辉橄榄岩铬尖晶石的Cr#为17.0~31.8,为富铝型尖晶石。泽当地幔橄榄岩PGE总量为16.67×10-9~32.59×10-9,与原始地幔相似。矿物化学特征显示泽当二辉橄榄岩属于深海型地幔橄榄岩,方辉橄榄岩属于弧前地幔橄榄岩。尖晶石Cr#、橄榄石Mg#的变化以及高Os含量(3.50×10-9~7.75×10-9)表明泽当地幔橄榄岩经历了部分熔融过程;正斜率的PGE配分模式以及较高的Pd/Ir值(1.09~3.94)表明泽当地幔橄榄岩受到了俯冲带环境下地幔交代作用的改造。泽当地幔橄榄岩矿物学特征与铂族元素地球化学特征显示其形成于MOR环境,后受到SSZ环境的改造。 相似文献
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西藏雅鲁藏布江缝合带东段泽当地幔橄榄岩特征及其意义 总被引：1，自引：1，他引：0
泽当岩体位于雅鲁藏布江缝合带东段,主要由地幔橄榄岩、辉长辉绿岩和基性火山岩等组成。地幔橄榄岩主要为方辉橄榄岩和二辉橄榄岩,有少量透镜状纯橄岩。地幔橄榄岩经历了强烈的塑性变形作用。地幔橄榄岩中橄榄石的Fo值为89.6~91.8,属镁橄榄石;斜方辉石为顽火辉石,En 87.8~90.3;单斜辉石En 44.1~50.0,主要为顽透辉石和透辉石。铬尖晶石的Cr#值(=100×Cr/(Cr+Al))为17.0~93.6,其中,二辉橄榄岩和方辉橄榄岩中的铬尖晶石为富铝型尖晶石,纯橄岩中的铬尖晶石Cr#最高,为富铬型尖晶石。地幔橄榄岩的部分熔融程度为17%~34%,表明泽当地幔橄榄岩可能经历了多阶段的过程。亏损的主量元素组成和低于原始地幔的稀土元素含量(0.15×10-6~0.61×10-6)指示泽当地幔橄榄岩为经历过部分熔融和熔体抽取的亏损残余地幔岩石。REE配分型式为中稀土亏损的"V"型或"U"型,原始地幔标准化元素比值(La/Sm)N为0.5~8.0,表明泽当地幔橄榄岩经历过交代作用。矿物化学与地球化学数据表明泽当地幔橄榄岩形成于MOR环境,后受到SSZ环境的改造。 相似文献
4.
西藏班公湖—怒江缝合带中段蓬湖蛇绿岩中的洋脊型二辉橄榄岩 总被引：1，自引：0，他引：1
蓬湖蛇绿岩产于西藏藏北湖区的蓬湖西侧,属班公湖-怒江缝合带中段白拉拉弄-依拉山亚带。该蛇绿岩主要由地幔橄榄岩、堆晶岩和辉绿岩等组成。其中地幔橄榄岩由方辉橄榄岩和二辉橄榄岩组成。蓬湖二辉橄榄岩的橄榄石Fo值介于88.85～90.33之间、斜方辉石的Al2O3含量范围在4.26%～6.60%。与原始地幔相比,蓬湖二辉橄榄岩岩石有较高的MgO含量和较低的Al2O3、CaO和TiO2等易熔组分含量;稀土元素总量介于1.11×10-6～1.53×10-6之间,明显低于原始地幔值,配分模式为轻稀土轻微亏损。在原始地幔微量元素蛛网图中,蓬湖二辉橄榄岩显示Rb、Zr亏损,U、Ta、Sr强烈富集特征。蓬湖二辉橄榄岩的铂族元素总量介于22.9×10-9～27×10-9之间,PGEs球粒陨石标准化图解显示其为接近原始地幔的"平坦型"。以上特征与深海橄榄岩相似,指示它们可能形成于大洋中脊环境。定量模拟估算表明,蓬湖二辉橄榄岩可能来源于地幔中尖晶石相二辉橄榄岩源区,系经历了约5%～10%的部分熔融残余。蓬湖堆晶岩矿物结晶顺序为橄榄石-单斜辉石-斜长石,其中异剥橄榄岩中的单斜辉石Mg#值介于86.92～89.93之间、橄榄石Fo平均值为84.45,明显不同于MOR型蛇绿岩堆晶岩。蓬湖堆晶岩的矿物组成、岩浆结晶顺序和矿物成分均与俯冲带上SSZ型蛇绿岩形成的堆晶岩类似。以上结果表明,蓬湖二辉橄榄岩形成于大洋脊环境,为尖晶石二辉橄榄岩源区经历了不超过10%部分熔融的残余,后期由于洋内俯冲作用经历了岩石-熔体反应,形成了SSZ型堆晶岩和含较高Cr#值尖晶石的方辉橄榄岩。 相似文献
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白云山蛇绿岩是北山造山带保存最好的蛇绿岩之一,其起源存在较大的争议。该蛇绿岩主要由橄榄岩、辉长岩以及基性火山岩等组成。橄榄岩主体为方辉橄榄岩以及少量二辉橄榄岩。这些岩石均发生不同程度的蛇纹石化以及强烈的变形变质作用。研究选取9件橄榄岩样品进行了全岩主量元素分析及单矿物电子探针分析,结果显示岩石均来自地幔。岩石中的尖晶石和辉石组分用来限定白云山蛇绿岩的成因及形成环境。样品包含了高Cr#(46.7～68.1)的尖晶石以及低Al2O3(0.78%～2.94%)含量的单斜辉石。矿物化学特征显示,地幔橄榄岩熔融程度为23%～36%,表明白云山地幔橄榄岩可能经历了多个阶段。矿物学及全岩地球化学特征表明,白云山蛇绿岩形成于洋中脊(MOR)环境,后受到俯冲带(SSZ)环境的改造。 相似文献
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洞错地幔橄榄岩、均质辉长岩矿物化学特征及其构造意义 总被引：2，自引：0，他引：2
洞错蛇绿岩出露于改则县洞错北约20 km处,去申拉以南,地表形态为楔状体,大致沿日土-改则-丁青断裂带分布;侵位于侏罗系木嘎岗日群中,并被下白垩统朗山组不整合覆盖.蛇绿岩剖面各岩石单元发育齐全:主要由地幔橄榄岩(方辉橄榄岩、二辉橄榄岩)、堆晶岩、辉绿岩墙和壳层熔岩组成.对洞错蛇绿岩地幔橄榄岩和均质辉长岩中尖晶石和辉石化学成分测定和构造环境判别分析显示:洞错地区尖晶石二辉橄榄岩(XDC28)投点于深海橄榄岩区域,指示尖晶石二辉橄榄岩经历了少于10％的熔体提取,而方辉橄榄岩分别经历了13％ ～30％的亏损,代表了亏损程度较弱的地幔橄榄岩残留(＜30％),明显不同于岛弧环境地幔橄榄岩强烈亏损的特征.辉石化学成分研究确认了尖晶石二辉橄榄岩属于深海橄榄岩.斜方辉石和单斜辉石具有不同的形态和化学成分,反映了不同的结晶温度(分别为900 ～1000℃,＜500 ～600℃).前者为岩石的形成温度,而后者则为冷却变质或重结晶过程中达到再平衡时的温度. 相似文献
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达拉布特蛇绿岩中地幔橄榄岩的主体为方辉橄榄岩,含少量纯橄岩和二辉橄榄岩,岩石遭受强烈蚀变。方辉橄榄岩单斜辉石、斜方辉石、橄榄石和尖晶石的主量元素特征均显示从深海地幔橄榄岩向SSZ地幔橄榄岩过渡的特征,与斜方辉石原位LA-ICP-MS微量元素特征一致,二辉橄榄岩具有深海地幔岩的性质。采用尖晶石-橄榄石平衡氧逸度计算方法,得出方辉橄榄岩的Δlog(fo2)FMQ在-0.14至+0.96log FMQ之间,具有MOR地幔橄榄岩向SSZ地幔橄榄岩过渡的特点或弧后盆地至岛弧过渡的特征。尖晶石Ga-Ti-Fe3+#图解显示纯橄岩成因可能和地幔橄榄岩与岛弧拉斑玄武岩的反应有关,而方辉橄榄岩可能为地幔橄榄岩与MOR熔体反应以及SSZ环境中含水熔体反应后的残余。纯橄岩和方辉橄榄岩∑REE都低于球粒陨石,且具有LREE富集的U型稀土元素配分模式,暗示了岩石和流体/熔体之间的相互作用。综合以上研究表明,达拉布特蛇绿岩形成于弧后扩张脊并受俯冲流体/熔体影响。 相似文献
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赣东北蛇绿岩作为华南少有的前寒武纪蛇绿岩长期都是华南大地构造研究中的热点。该蛇绿岩地幔橄榄岩以方辉橄榄岩为主,稀土总量为0.83×10-6~2.62×10-6,远低于原始地幔的含量,而Mg O含量高于原始地幔。稀土元素表现为LREE相对富集,微量元素表现为大离子亲石元素(LILE)富集,高场强元素Nb明显亏损的特征,这表明赣东北地幔橄榄岩具有亏损地幔源区特征,同时也有不同程度的俯冲带流体的交代特征。HREE模拟的部分熔融程度为10%~30%;同时,赣东北蛇绿岩地幔橄榄岩中同时包含Cr#60和Cr#60两种不同成因的铬尖晶石,说明其经历了MOR(mid-ocean ridge)和SSZ(supra-subduction zone)两种构造环境。结合前人资料,笔者推测赣东北蛇绿岩早先可能形成于洋中脊环境(约1060 Ma),随后在洋内俯冲作用下(约970 Ma),位于俯冲带上部的地幔橄榄岩受到了来自俯冲带的流体/熔体的交代,经历了SSZ环境的改造。 相似文献
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达机翁蛇绿岩位于雅鲁藏布江缝合带的西段北亚带,该蛇绿岩主要由地幔橄榄岩、玄武岩以及硅质岩组成,其中地幔橄榄岩以方辉橄榄岩为主,同时含有少量的纯橄榄岩,纯橄岩主要呈不规则透镜状或团块状分布于方辉橄榄岩中。在达机翁地幔橄榄岩中产出有3种不同类型的铬铁矿,分别为块状,豆状以及浸染状铬铁矿。文章主要对达机翁地幔橄榄岩的方辉橄榄岩及豆荚状铬铁矿进行了研究,结合岩石的主量元素和铂族元素,对地幔橄榄岩和豆荚状铬铁矿的成因以及雅鲁藏布江缝合带的找矿远景进行了探讨。达机翁地幔橄榄岩具有较高的Mg O含量以及较低的Al2O3和Ca O等含量,这种亏损的全岩成分指示了达机翁地幔橄榄岩经历了较高的部分熔融作用,同时方辉橄榄岩的PGEs的总量为23.68×10-9~31.02×10-9,高于原始地幔的值,Pd和Cu 2个元素的含量较为分散明显偏离部分熔融曲线,指示了达机翁方辉橄榄岩可能遭受了熔体的改造,在熔体-岩石反应的过程中,导致了富含PPGE的硫化物的加入。达机翁豆荚状铬铁矿为高Cr型铬铁矿,具有IPGE和Rh明显富集以及Pt,Pd明显亏损的特征,不同类型的铬铁矿之间具有一致的PGEs的分配模式。雅鲁藏布江缝合带内大量分布的超镁铁岩体在岩石组合、地球化学特征、成因以及形成时代等方面,均具有相似性,是中国铬铁矿找矿的有利远景区。 相似文献
10.
西藏雅鲁藏布江缝合带西段普兰蛇绿岩地幔橄榄岩矿物学研究和成因探讨 总被引：4，自引：3，他引：1
西藏普兰蛇绿岩以出露面积约600km2的特大型地幔橄榄岩体而引人注目。我们在普兰岩体的东段,完成了一条近垂直走向并穿过岩体的长约10km的地质剖面,其目的是探讨地幔橄榄岩体岩相的变化及其成因。研究表明,岩体主体为方辉橄榄岩,分布于岩体内部,二辉橄榄岩呈条带状,分布于岩体边部,方辉橄榄岩和二辉橄榄岩出露面积之比约为4∶1。剖面显示,二辉橄榄岩向方辉橄榄岩岩相渐变,Ol和Sp含量增加,Opx和Cpx减少,橄榄石Fo值和NiO含量也呈逐渐增加的特征。斜方辉石主要为顽火辉石(En=85~90),Mg#值变化于88~92之间,Al2O3含量0.89%~5.16%。单斜辉石包括顽透辉石和透辉石,以低铝(Al2O3=1.16%~6.02%),高镁(Mg#值为90~94)为特征。二辉橄榄岩的铬尖晶石Cr#值在19~32之间,低于方辉橄榄岩的Cr#值(25~72),两者之间呈连续变化。另一方面,方辉橄榄岩的各矿物百分含量、成分特征及部分熔融程度在岩体东部变化较大。结合前人成果,认为岩体中部分方辉橄榄岩不仅仅为单一的地幔残余,而可能经历了后期流体/熔体交代作用。依据尖晶石-橄榄石/单斜辉石矿物化学成分,估算出二辉橄榄岩是地幔源区经历约5%~12%部分熔融作用形成,而方辉橄榄岩则最终经历了约12%~32%部分熔融作用。研究结果表明,从二辉橄榄岩到方辉橄榄岩的演变,起因于部分熔融的差别,没有证据表明是受构造背景变化制约,因此,简单地用铬尖晶石等矿物成分的变化判断地幔橄榄岩的产出构造背景的方法值得商榷。 相似文献
11.
Major and trace elements and water contents were analyzed in 16 peridotite xenoliths embedded by the Cenozoic basalts in Pingnan (southeastern Guangxi Province), to constrain the chemical composition and evolution of the lithospheric mantle located in the central part of the South China Block (SCB). The peridotites are mainly moderately refractory harzburgites and lherzolites (Mg#-Ol?=?90.3–91.7) and minor fertile lherzolites (Mg#-Ol?=?88.9–89.9). Clinopyroxenes in the peridotites show LREE-depleted pattern, and commonly exhibit negative anomalies in Nb and Ti, suggesting the peridotites probably represent residues after 1–10% of partial melting without significant mantle metasomatism. Water contents range from 146 to 237 ppm wt. H2O in clinopyroxene, and from 65 to 112 ppm wt. H2O, in orthopyroxene but are below detection limit (2 ppm wt. H2O) in olivine. Calculated bulk water contents, based on the mineral modes and partition coefficient, range from 14 to 83 ppm wt. H2O (average 59 ppm wt. H2O). There is a correlation between melting indices (such as Mg#-Ol, Ybn in clinopyroxene) and water contents in clinopyroxene and orthopyroxene, but no correlation is observed between the whole-rock water contents and the redox state (Fe3+/∑Fe ratios in spinel), suggesting that water contents in the peridotites are mainly controlled by the degree of partial melting rather than by oxygen fugacity. The lithospheric mantle beneath the interior of the SCB may not be compositionally stratified; fertile and moderately refractory mantle coexist at the similar depths. Geochemical data and water contents of the studied peridotites are similar to the proposed MORB source and indicate that the ancient refractory lithospheric mantle was irregularly eroded or reacted by the upwelling asthenosphere, and eventually replaced by juvenile fertile accreted mantle through the cooling of the asthenosphere. 相似文献
12.
对来自滇东南马关木厂的尖晶石二辉橄榄岩中名义上无水矿物(NAMs)进行显微傅里叶变换红外光谱(Micro-FTIR)分析,结果显示,单斜辉石、斜方辉石和橄榄石中均含有以羟基形式存在的结构水,单斜辉石的水含量为160×10~(-6)~557×10~(-6)(质量分数,下同),斜方辉石的水含量为85×10~(-6)~207×10~(-6),橄榄石的水含量为5×10~(-6)~12×10~(-6),根据矿物百分比含量估算的全岩水含量为46×10~(-6)~137×10~(-6);元素地球化学特征表明,本次研究的橄榄岩包体是岩石圈地幔经历较低程度部分熔融的残余;低(La/Yb)N值(0.22~0.57)以及高Ti/Eu比值(4 076~6 772)暗示橄榄岩可能经历了以硅酸盐熔体为交代介质的微弱地幔交代作用;单斜辉石的微量元素组成比较单一,整体表现出高场强元素、大离子亲石元素以及轻稀土元素的同步亏损;结合中国东部地区已经发表的橄榄岩包体含水量数据来看,滇东南马关木厂岩石圈地幔具有明显富水的特征,可能与该区自中生代以来遭受的新特提斯洋壳大规模俯冲流体交代作用有关;与华北克拉通含水量的明显差异有可能反映的是两地岩石圈地幔正处于不同的演化阶段。 相似文献
13.
Dmitri A. Ionov 《Contributions to Mineralogy and Petrology》2007,154(4):455-477
Clinopyroxene-rich, poorly metasomatised spinel lherzolites are rare worldwide but predominate among xenoliths in five Quaternary
basaltic eruption centres in Tariat, central Mongolia. High-precision analyses of the most fertile Tariat lherzolites are
used to evaluate estimates of primitive mantle compositions; they indicate Mg#PM = 0.890 while lower Mg# in the mantle are likely related to metasomatic enrichments in iron. Within a 10 × 20 km area, and
between ~45 and ≥60 km depth, the sampled xenoliths suggest that the Tariat mantle does not show km-scale chemical heterogeneities
and mainly consists of residues after low-degree melt extraction at 1–3 GPa. However, accessory (<1%) amphibole and phlogopite
are unevenly distributed beneath the eruption centres. Ca abundances in olivine are controlled by temperature whereas Al and
Cr abundances also depend on Cr/Al in coexisting spinel. Comparisons of conventional and high-precision analyses obtained
for 30 xenoliths show that high-quality data, in particular for whole-rocks and olivines, are essential to constrain the origin
of mantle peridotites.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
14.
U. Wiechert Dmitri A. Ionov Karl Hans Wedepohl 《Contributions to Mineralogy and Petrology》1997,126(4):345-364
Spinel peridotite xenoliths from the Atsagin-Dush volcanic centre, SE Mongolia range from fertile lherzolites to clinopyroxene(cpx)-bearing
harzburgites. The cpx-poor peridotites typically contain interstitial fine-grained material and silicate glass and abundant
fluid inclusions in minerals, some have large vesicular melt pockets that apparently formed after primary clinopyroxene and
spinel. No volatile-bearing minerals (amphibole, phlogopite, apatite, carbonate) have been found in any of the xenoliths.
Fifteen peridotite xenoliths have been analysed for major and trace elements; whole-rock Sr isotope compositions and O isotope
composition of all minerals were determined for 13 xenoliths. Trace element composition and Sr-Nd isotope compositions were
also determined in 11 clinopyroxene and melt pocket separates. Regular variations of major and moderately incompatible trace
elements (e.g. heavy-rare-earth elements) in the peridotite series are consistent with its formation as a result of variable
degrees of melt extraction from a fertile lherzolite protolith. The Nd isotope compositions of LREE (light-rare-earth elements)-depleted
clinopyroxenes indicate an old (≥ 1 billion years) depletion event. Clinopyroxene-rich lherzolites are commonly depleted in
LREE and other incompatible trace elements whereas cpx-poor peridotites show metasomatic enrichment that can be related to
the abundance of fine-grained interstitial material, glass and fluid inclusions in minerals. The absence of hydrous minerals,
ubiquitous CO2-rich microinclusions in the enriched samples and negative anomalies of Nb, Hf, Zr, and Ti in primitive mantle-normalized
trace element patterns of whole rocks and clinopyroxenes indicate that carbonate melts may have been responsible for the metasomatic
enrichment. Low Cu and S contents and high δ34S values in whole-rock peridotites could be explained by interaction with oxidized fluids that may have been derived from
subducted oceanic crust. The Sr-Nd isotope compositions of LREE-depleted clinopyroxenes plot either in the MORB (mid-ocean-ridge
basalt) field or to the right of the mantle array, the latter may be due to enrichment in radiogenic Sr. The LREE-enriched
clinopyroxenes and melt pockets plot in the ocean island-basalt field and have Sr-Nd isotope signatures consistent with derivation
from a mixture of the DMM (depleted MORB mantle) and EM (enriched mantle) II sources.
Received: 18 January 1996 / Accepted: 23 August 1996 相似文献
15.
İbrahim Uysal A. Dündar Şen E. Yalçın Ersoy Yildirim Dilek Samet Saka Federica Zaccarini Monica Escayola Orhan Karslı 《Mineralogy and Petrology》2014,108(1):49-69
We present the whole-rock and the mineral chemical data for upper mantle peridotites from the Harmanc?k region in NW Turkey and discuss their petrogenetic–tectonic origin. These peridotites are part of a Tethyan ophiolite belt occurring along the ?zmir-Ankara-Ercincan suture zone in northern Turkey, and include depleted lherzolites and refractory harzburgites. The Al2O3 contents in orthopyroxene and clinopyroxene from the depleted lherzolite are high, and the Cr-number in the coexisting spinel is low falling within the abyssal field. However, the orthopyroxene and clinopyroxene in the harzburgites have lower Al2O3 contents for a given Cr-number of spinel, and plot within the lower end of the abyssal field. The whole-rock geochemical and the mineral chemistry data imply that the Harmanc?k peridotites formed by different degrees of partial melting (~%10–27) of the mantle. The depleted lherzolite samples have higher MREE and HREE abundances than the harzburgitic peridotites, showing convex-downward patterns. These peridotites represent up to ~16 % melting residue that formed during the initial seafloor spreading stage of the Northern Neotethys. On the other hand, the more refractory harzburgites represent residues after ~4–11 % hydrous partial melting of the previously depleted MOR mantle, which was metasomatized by slab-derived fluids during the early stages of subduction. The Harmanc?k peridotites, hence, represent the fragments of upper mantle rocks that formed during different stages of the tectonic evolution of the Tethyan oceanic lithosphere in Northern Neotethys. We infer that the multi-stage melting history of the Harmanc?k peridotites reflect the geochemically heterogeneous character of the Tethyan oceanic lithosphere currently exposed along the ?zmir-Ankara-Erzincan suture zone. 相似文献
16.
The sub-arc mantle that experienced hydrous melting is commonly characterized by refractory geochemical compositions. Nevertheless, minor lherzolites with fertile compositions have also been reported for mantle peridotites from subduction zone. The petrogenesis and mantle source of the lherzolites are still controversial. The New Caledonia ophiolite(Peridotite Nappe) has been regarded as an allochthonous body of forearc lithosphere. This is supported by refractory compositions of its dominant mantle rocks.A few isolated lherzolitic massifs have also been observed in the northern part of New Caledonia.Those lherzolites are compositionally similar to abyssal peridotites, with negligible subduction-related modification. Here, we present new comprehensive geochemical compositions, in particular highprecision Sr-Nd-Hf isotope data, for the lherzolites. The initial176 Hf/177 Hf ratios display moderate correlations with sensitive indicators for the extent of melting(i.e., olivine Fo, whole-rock Mg# and Yb contents in clinopyroxene) and whole-rock initial187 Os/188 Os ratios. Some samples have ancient radiogenic Hf isotopes and unradiogenic Os isotope compositions, implying the preservation of ancient depletion signals in the lherzolites. The Nd isotope compositions, together with trace elements and mineral micro-textures, suggest that the lherzolites have been overprinted by a recent melt-rock interaction event. The high equilibrium temperatures of the studied samples have been estimated by the twopyroxene REE thermometer, yielding temperatures of 1066–1315 ℃. The lherzolites have more depleted Nd-Hf isotope compositions and higher equilibrium temperatures than the New Caledonia harzburgites.This indicates that the lherzolites may represent the residues of asthenosphere mantle trapped within the forearc region. Our studies on the New Caledonia lherzolites with ancient depletion signals suggest that ancient mantle domains in the convective mantle can be emplaced in forearc region by the upwelling of asthenosphere during the early stage of subduction initiation. 相似文献
17.
New major- and trace-element data of bulk-rocks and constituent minerals, and whole-rock Re-Os isotopic compositions of samples from the Lherz Massif, French Pyrenees, reveal complex petrological relationships between the dominant lithologies of lherzolite ± olivine-websterite and harzburgite. The Lherz peridotite body contains elongate, foliation parallel, lithological strips of harzburgite, lherzolite, and olivine-websterite cross-cut by later veins of hornblende-bearing pyroxenites. Peridotite lithologies are markedly bimodal, with a clear compositional gap between harzburgites and lherzolites ± olivine-websterite. Bulk-rock and mineral major-element oxide (Mg-Fe-Si-Cr) compositions show that harzburgites are highly-depleted and result from ∼20-25 wt.% melt extraction at pressures <2 GPa. Incompatible and moderately-compatible trace-element abundances of hornblendite-free harzburgites are analogous to some mantle-wedge peridotites. In contrast, lherzolites ± olivine-websterite overlap estimates of primitive mantle composition, yet these materials are composite samples that represent physical mixtures of residual lherzolites and clinopyroxene dominated cumulates equilibrated with a LREE-enriched tholeiitic melt. Trace-element compositions of harzburgite, and some lherzolite bulk-rocks and pyroxenes have been modified by; (1) wide-spread interaction with a low-volume LREE-enriched melt +/− fluid that has disturbed highly-incompatible elements (e.g., LREEs, Zr) without enrichment of alkali- and Ti-contents; and (2) intrusion of relatively recent, small-volume, hornblendite-forming, basanitic melts linked to modal and cryptic metasomatism resulting in whole-rock and pyroxene Ti, Na and MREE enrichment.Rhenium-Os isotope systematics of Lherz samples are also compositionally bimodal; lherzolites ± olivine-websterite have chondritc to suprachondritic 187Os/188Os and 187Re/188Os values that overlap the range reported for Earth’s primitive upper mantle, whereas harzburgites have sub-chondritic 187Os/188Os and 187Re/188Os values. Various Os-model age calculations indicate that harzburgites, lherzolites, and olivine-websterites have been isolated from convective homogenisation since the Meso-Proterozoic and this broadly coincides with the time of melt extraction controlled by harzburgite Os-isotope compositions. The association between harzburgites resulting from melting in mantle-wedge environments and Os-rich trace-phases (laurite-erlichmanite sulphides and Pt-Os-Ir-alloys) suggests that a significant portion of persistent refractory anomalies in the present-day convecting mantle of Earth may be linked to ancient large-scale melting events related to wide-spread subduction-zone processing. 相似文献