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1.
内蒙古锡林浩特毛登牧场大石寨组细碧-角斑岩系地球化学特征、锆石U-Pb年龄及地质意义 总被引：3，自引：0，他引：3
本次1∶5万区域地质调查工作在内蒙古锡林浩特毛登牧场地区大石寨组地层中发现了细碧-角斑岩系,单颗粒锆石LA-ICP-MS U-Pb法获得其年龄为(287.4±1.7) Ma (MSWD=0.63),形成于早二叠世早期。细碧岩具有高SiO2、Al2O3(>16%)、Na2O、TiO2(>13%)含量,低CaO、MgO含量的特征;(石英)角斑岩具有高SiO2、Na2O含量,低Al2O3、TiO2、K2O、CaO含量的特征。Zr/TiO2-Nb/Y微量元素分类图解显示细碧岩与(石英)角斑岩呈典型的双峰式岩石组合,在SiO2-FeO/MgO图解中均位于钙碱性岩石系列区域;大离子亲石元素较相邻高场强元素明显富集,稀土配分曲线总体特征相似,细碧岩与(石英)角斑岩微量元素、稀土元素分布曲线显示岛弧环境的特征。综合细碧-角斑岩系岩石组合、岩石系列以及岩石地球化学特征,该套岩系形成于大陆边缘弧局部裂陷环境,细碧岩与(石英)角斑岩为同源岩浆演化的结果,其源区应为流体交代的楔形地幔。 相似文献
2.
颗粒的破碎强度随着粒径的增大而减小,即颗粒破碎的尺寸效应,分形模型为解释固体颗粒破碎的尺寸效应提供了可行的方法。根据岩石颗粒破碎时的分形特征,采用Sammis破碎准则,通过模拟分析得出岩石颗粒破碎能量和强度的分形模型,建立和验证用分维D来表示岩石颗粒破碎的能量和强度准则,得出并验证了岩石颗粒破碎分维的确定方法。利用离散元软件PFC2D的黏结颗粒模型BPM（Bonded Particle Model）模拟了小孔隙率n=0.12和大孔隙率n=0.3,即密实和松散两种情况。其中小孔隙率采用在模型上添加小颗粒的新方法,分别做了400组粒径不等的数值模拟试验,从粒径与破碎强度、破碎能量之间的关系和应力-应变曲线3个方面进行了统计,验证了岩石颗粒破碎强度与分维D的理论关系为σf∝dD-3,并得出颗粒破碎时的能量和与分维D之间的关系为Ef∝dD-1。验证了分形理论在分析颗粒破碎的尺寸效应中的较好应用,为确定岩石颗粒的破碎强度和岩石堆砌体剪切强度提供新的方法和参考意见。 相似文献
3.
作为计算太阳总辐射(Rs)的主要公式,Angstrom公式参数(a、b)的合理取值是计算参照腾发量(ET0)的重要前提。针对FAO所提出的a、b建议值(a=0.25、b=0.5)在中国无辐射观测资料地区被大量使用,而其合理性尚未得到系统评价的情况,基于中国104个地面站的观测数据,在逐月时间尺度上,讨论了a、b变化对ET0的影响,分析了a、b的地区分布规律,评价了FAO建议值所导致的ET0计算误差,进而阐明了该建议值在中国7个区域的适用性。提出了无辐射资料情况下a、b的地区综合取值方法。主要研究结论是:①参数a、b偏差对ET0的计算有重要影响,在中国无资料地区采用FAO建议值将导致较大的太阳总辐射(Rs)和ET0计算误差。②大多数站点,a的率定值较FAO建议值明显偏小,而b的率定值明显偏大。新疆地区和华南地区a、b率定值分布比较集中,而在其它区域比较分散。③FAO建议参数值在东北、西北和新疆3个区域计算ET0的适用性较好,而在西南和华南两个区域的适用性很差,计算的ET0偏高较大。④提出的地区综合取值方法,能使Rs和ET0的计算精度较FAO建议值显著提高。 相似文献
4.
5.
研究区位于大兴安岭兴安地块的东北部。本文主要讨论了碱长花岗岩和花岗斑岩两种岩石类型,并对其成岩年代、地球化学特征、成因及构造环境进行了深入讨论。研究结果显示：具有高SiO2、A12O3、TFeO/MgO,贫MgO、TiO2、P2O5等特征;A/NK-A/CNK和w（K2O）-w（SiO2）图解显示,样品主要为过铝质、高钾钙碱性岩石。并且（Na2O+K2O）/CaO-w（Zr+Nb+Ce+Y）、TFeO/MgO-w（Zr+Nb+Ce+Y）图解和锆石饱和温度都显示,研究区花岗岩类岩石具有高分异Ⅰ型花岗岩的特征。锆石LA-ICP-MS U-Pb定年研究获得128~124 Ma的岩体侵位年龄,其形成的大地构造背景为蒙古-鄂霍茨克洋消亡之后,陆陆碰撞造山演化晚期地壳伸展背景,岩浆起源于壳内火成岩源岩的部分熔融。 相似文献
6.
通过压实黄土在不同中主应力系数和不同σ3时的真三轴试验,研究了中主应力对压实黄土变形特性的影响。研究表明:随着中主应力系数的增大,达到同一主应变的主应力差σ_1~σ_3越大,且曲线从一开始就呈硬化型,证明中主应力对压实黄土的强度有一定的加固作用。不同的中主应力系数下,ε_1~ε_v关系曲线除b=1之外均出现"峰值",且大约在主应变发展至4%~6%左右出现了交叉,交叉后曲线变化有明显的区间效应。随着中主应力系数b的增加,达到相同广义剪应变对应的广义剪应力q也越大。对广义剪应力与平均主应力比(q/p)与主应变(ε_1)归一化,随着b值的增加,曲线依次降低。在b=0~0.5之间,曲线之间的区分度较好,曲线降低幅度较大。b=0.5~1之间曲线之间的区分度较差,曲线几乎重合。 相似文献
7.
为了客观地确定数据点投图后分布的主要区域,本文提出了一种基于数据密度确定数据主要分布区域的方法。利用该方法可以更加直观地了解数据分布,并可以作为数据清洗的预处理手段。本文基于GEOROC大数据,以全碱对硅（TAS）图解为例,进行了分析和验证。通过提取GEOROC 数据库中与TAS 图解相关的岩石样本中SiO2、Na2O、K2O 和烧失量含量数据,通过数据常规清洗和归算,最终获得24 个种类合计13.3 万条有效数据。通过数据投点、分区统计和提取80% 数据的分布区域,验证了24种岩石样品与TAS图解的吻合程度。通过综合研究分析发现,有6类岩石的数据分布与TAS图解定义区域基本一致,18类岩石的数据分布与TAS图解定义区域有系统性偏差。大数据研究证明了TAS图解的不足之处,利用全碱和SiO2作为指标,难以实现提升总体分类的准确性。 相似文献
8.
采用自主研发的新型固化剂对天津城市污泥进行固化处理,通过GCTS真三轴仪对污泥固化土进行不固结不排水试验,探讨其在干湿循环作用下的应力-应变特征和强度指标变化规律。试验结果表明:污泥固化土应力-应变曲线在初始阶段近似表现为线性关系,同等条件下,破坏应力随中主应力比b的增大而增大;相同b值下,破坏应力随干湿循环次数的增大而逐渐减小。经过干湿循环1,3,5,7,10次之后,不同围压下污泥固化土的破坏应力值均呈现下降趋势。当循环次数超过5次后,其降低幅度趋于平缓。在b值较小、循环次数小于3时,应力-应变曲线产生应变软化现象,随着围压和b值的增大表现为硬化型。污泥固化土c、φ值随干湿循环次数的增大呈现出降低趋势,并最终趋于稳定。在此基础上,对不同中主应力比条件下的c、φ值变化规律进行分析,分别建立其与干湿循环次数和中主应力比之间的关系式,并构建出能够考虑不同围压及中主应力比影响的初始弹性模量Ei和主应力差渐近值（σ1?σ3）ulti预测公式。 相似文献
9.
由于加筋土界面作用的复杂性,加筋土工程建设中铺设土工格栅时往往采用经验的方法,很大程度上造成了土工格栅的浪费及工程安全隐患,理清不同填料筋土界面作用的影响范围,有助于确定加筋土结构的合理加筋间距。为了揭示不同填料筋土界面作用的影响范围,采用4种不同类型的砂土与格栅在不同法向应力下进行了一系列的拉拔试验,并结合数字图像量测技术,分析了不同类型砂土下界面剪切带厚度、颗粒位移矢量、格栅拉拔阻力峰值及应变等演变规律。研究表明：界面剪切带厚度H随法向应力σv与砂土平均粒径d50的增加而增大,通过多变量拟合的方法,得到了H、σv与d50三者之间的函数表达式;格栅在拉拔过程中,砂土颗粒位移矢量以土工格栅为界有着显著的差别,格栅上部的颗粒位移矢量明显大于下部颗粒,且在格栅上下一定范围内会形成颗粒位移矢量集中带;拉拔阻力峰值随σv及d50的增加而增大;不同类型砂土各区段的格栅应变均表现出由前向后依次递减的趋势。 相似文献
10.
内蒙古锡林浩特吉日嘎朗图晚泥盆世侵入岩分布于内蒙古自治区二连-贺根山板块对接带北部,其岩石组合为石英闪长岩、英云闪长岩和花岗闪长岩.岩石化学成分SiO2含量为64.23%~74.47%,Al2O3为13.59%~16.26%,TiO2为0.19%~0.76%,Na2O+K2O为6.28%~8.15%,属钙碱性系列,A/CNK=1.06-1.21,属过铝质花岗岩.An-Ab-Or图显示T2G1G2QM组合,属TTG岩类.微量元素显示为火山弧花岗岩.稀土元素以高度分馏的稀土模式和亏损HREE为特征,显示TTG岩类特征.综合反映该套岩石具典型TTG岩类特征,显示为洋壳向陆壳俯冲的产物.在花岗闪长岩中取单颗粒锆石U-Pb年龄为361.1±1.0 Ma,为晚泥盆世侵入岩,因此,西伯利亚板块与华北板块的缝合时间至少应当在晚泥盆世之后. 相似文献
11.
Behavior of epidote at high pressure and high temperature: a powder diffraction study up to 10 GPa and 1,200 K 总被引：1，自引：0，他引：1
G. Diego Gatta Marco Merlini Yongjae Lee Stefano Poli 《Physics and Chemistry of Minerals》2011,38(6):419-428
The thermo-elastic behavior of a natural epidote [Ca1.925 Fe0.745Al2.265Ti0.004Si3.037O12(OH)] has been investigated up to 1,200 K (at 0.0001 GPa) and 10 GPa (at 298 K) by means of in situ synchrotron powder diffraction.
No phase transition has been observed within the temperature and pressure range investigated. P–V data fitted with a third-order Birch–Murnaghan equation of state (BM-EoS) give V
0 = 458.8(1)Å3, K
T0 = 111(3) GPa, and K′ = 7.6(7). The confidence ellipse from the variance–covariance matrix of K
T0 and K′ from the least-square procedure is strongly elongated with negative slope. The evolution of the “Eulerian finite strain”
vs “normalized stress” yields Fe(0) = 114(1) GPa as intercept values, and the slope of the regression line gives K′ = 7.0(4). The evolution of the lattice parameters with pressure is slightly anisotropic. The elastic parameters calculated
with a linearized BM-EoS are: a
0 = 8.8877(7) Å, K
T0(a) = 117(2) GPa, and K′(a) = 3.7(4) for the a-axis; b
0 = 5.6271(7) Å, K
T0(b) = 126(3) GPa, and K′(b) = 12(1) for the b-axis; and c
0 = 10.1527(7) Å, K
T0(c) = 90(1) GPa, and K’(c) = 8.1(4) for the c-axis [K
T0(a):K
T0(b):K
T0(c) = 1.30:1.40:1]. The β angle decreases with pressure, βP(°) = βP0 −0.0286(9)P +0.00134(9)P
2 (P in GPa). The evolution of axial and volume thermal expansion coefficient, α, with T was described by the polynomial function: α(T) = α0 + α1
T
−1/2. The refined parameters for epidote are: α0 = 5.1(2) × 10−5 K−1 and α1 = −5.1(6) × 10−4 K1/2 for the unit-cell volume, α0(a) = 1.21(7) × 10−5 K−1 and α1(a) = −1.2(2) × 10−4 K1/2 for the a-axis, α0(b) = 1.88(7) × 10−5 K−1 and α1(b) = −1.7(2) × 10−4 K1/2 for the b-axis, and α0(c) = 2.14(9) × 10−5 K−1 and α1(c) = −2.0(2) × 10−4 K1/2 for the c-axis. The thermo-elastic anisotropy can be described, at a first approximation, by α0(a): α0(b): α0(c) = 1 : 1.55 : 1.77. The β angle increases continuously with T, with βT(°) = βT0 + 2.5(1) × 10−4
T + 1.3(7) × 10−8
T
2. A comparison between the thermo-elastic parameters of epidote and clinozoisite is carried out. 相似文献
12.
The high-pressure elastic behaviour of a synthetic zeolite mordenite, Na6Al6.02Si42.02O96·19H2O [a=18.131(2), b=20.507(2), c=7.5221(5) Å, space group Cmc21], has been investigated by means of in situ synchrotron X-ray powder diffraction up to 5.68 GPa. No phase transition has been observed within the pressure range investigated. Axial and volume bulk moduli have been calculated using a truncated second-order Birch–Murnaghan equation-of-state (II-BM-EoS). The refined elastic parameters are: V
0=2801(11) Å3, K
T0= 41(2) GPa for the unit-cell volume; a
0=18.138(32) Å, K
T0(a)=70(8) GPa for the a-axis; b
0=20.517(35) Å, K
T0(b)=29(2) GPa for the b-axis and c
0=7.531(5) Å, K
T0(c)=38(1) GPa for the c-axis [K
T0(a): K
T0(b): K
T0(c)=2.41:1.00:1.31]. Axial and volume Eulerian finite strain versus “normalized stress” plots (fe–Fe plot) show an almost linear trend and the weighted linear regression through the data points yields the following intercept values: Fe(0)=39(4) GPa for V; Fe
a
(0)=65(18) GPa for a; Fe
b
(0)=28(3) GPa for b; Fe
c
(0)=38(2) GPa for c. The magnitudes of the principal Lagrangian unit-strain coefficients, between 0.47 GPa (the lowest HP-data point) and each measured P>0.47 GPa, were calculated. The unit-strain ellipsoid is oriented with ε1 || b, ε2 || c, ε3 || a and |ε1|> |ε2|> |ε3|. Between 0.47 and 5.68 GPa the relationship between the unit-strain coefficient is ε1: ε2: ε3=2.16:1.81:1.00. The reasons of the elastic anisotropy are discussed.An erratum to this article can be found at 相似文献
13.
Simulation of geological surfaces using fractals 总被引：2，自引：0，他引：2
Methods suggested in the past for simulated ore concentration or pollution concentration over an area of interest, subject to the condition that the simulated surface is passing through specifying points, are based on the assumption of normality. A new method is introduced here which is a generalization of the subdivision method used in fractals. This method is based on the construction of a fractal plane-to-line functionf(x, y, R, e, u), where(x, y) is in[a, b]×[c, d], R is the autocorrelation function,e is the resolution limit, andu is a random real function on [–1, 1]. The simulation using fractals escapes from any distribution assumptions of the data. The given network of points is connected to form quadrilaterals; each one of the quadrilaterals is split based on ways which are extensions of the well-known subdivision method. The quadrilaterals continue to split and grow until resolution obtained in bothx andy directions is smaller than a prespecified resolution. If thex coordinate of theith quadrilateral is in[a
i
,b
i
] and they coordinate is in[c
i
,d
i
], the growth of this quadrilateral is a function of(b
i
–a
i
) and(d
i
–c
i
); the quadrilateral could grow toward the positive or negativez axis with equal probability forming four new quadrilaterals having a common vertex.This paper was presented at Emerging Concepts, MGUS-87 Conference, Redwood City, California, 13–15 April 1987. 相似文献
14.
The elastic behaviour and the high-pressure structural evolution of a natural topaz, Al2.00Si1.05O4.00(OH0.26F1.75), have been investigated by means of in situ single-crystal X-ray diffraction up to 10.55(5) GPa. No phase transition has been observed within the pressure range investigated. Unit-cell volume data were fitted with a third-order Birch-Murnaghan Equation of State (III-BM-EoS). The III-BM-EoS parameters, simultaneously refined using the data weighted by the uncertainties in P and V, are: V
0=345.57(7) Å3, K
T0=164(2) GPa and K′=2.9(4). The axial-EoS parameters are: a
0=4.6634(3) Å, K
T0(a)=152(2) GPa, K′(a)=2.8(4) for the a-axis; b
0=8.8349(5) Å, K
T0(b)=224(3) GPa, K′(b)=2.6(6) for the b-axis; c
0=8.3875(7) Å, K
T0(c)=137(2) GPa, K′(c)=2.9(4) for the c-axis. The magnitude and the orientation of the principal Lagrangian unit-strain ellipsoid were determined. At P−P
0=10.55 GPa, the ratios ε1:ε2:ε3 are 1.00:1.42:1.56 (with ε1||b, ε2||a, ε3||c and |ε3| > |ε2| > |ε1|). Four structural refinements, performed at 0.0001, 3.14(5), 5.79(5) and 8.39(5) GPa describe the structural evolution in terms of polyhedral distortions. 相似文献
15.
Sicheng Wang Xi Liu Yingwei Fei Qiang He Hejing Wang 《Physics and Chemistry of Minerals》2012,39(3):189-198
Using a conventional high-T furnace, the solid solutions between magnesiochromite and manganochromite, (Mg1−x
Mn
x
)Cr2O4 with x = 0.00, 0.19, 0.44, 0.61, 0.77 and 1.00, were synthesized at 1,473 K for 48 h in open air. The ambient powder X-ray diffraction
data suggest that the V–x relationship of the spinels does not show significant deviation from the Vegard’s law. In situ high-T powder X-ray diffraction measurements were taken up to 1,273 K at ambient pressure. For the investigated temperature range,
the unit-cell parameters of the spinels increase smoothly with temperature increment, indicating no sign of cation redistribution
between the tetrahedral and octahedral sites. The V–T data were fitted with a polynomial expression for the volumetric thermal expansion coefficient (aT = a0 + a1 T + a2 T - 2 \alpha_{T} = a_{0} + a_{1} T + a_{2} T^{ - 2} ), which yielded insignificant a
2 values. The effect of the composition on a
0 is adequately described by the equation a
0 = [17.7(8) − 2.4(1) × x] 10−6 K−1, whereas that on a
1 by the equation a
1 = [8.6(9) + 2.1(11) × x] 10−9 K−2. 相似文献
16.
The problem of determining capillary pressure functions from centrifuge data leads to an integral equation of the form
a
x
K(x,t)f(t)dt=g(x),x[a,b],(1)where the kernel K is known exactly and given by the underlying mathematical model. g is only known with a limited degree of accuracy in a finite and discrete set of points x
1,...,x
M
. However, the sought function f(t) is continuous. By the nature of the right-hand side, g(x), equation (1) is a discrete inverse problem which is ill-posed in the sense of Hadamard [9]. By a parameterization of the sought function, equation (1) reduces to a system of linear equations of the form
Ac=b+ ,where b is the observation vector and A arises from discretization of the forward problem. is the error vector associated with b, and c contains the model parameters. The matrix A is usually ill-conditioned. The ill-conditioning is closely connected to the parameterization of the problem [23].In this paper a semi-iterative regularization method for solving the Volterra integral equation in the 2-norm, namely, Brakhage's -method [2], is investigated. The iterative method is tested on synthetically generated, and on experimental data. 相似文献
17.
The thermoelastic behaviour of anthophyllite has been determined for a natural crystal with crystal-chemical formula ANa0.01
B(Mg1.30Mn0.57Ca0.09Na0.04) C(Mg4.95Fe0.02Al0.03) T(Si8.00)O22
W(OH)2 using single-crystal X-ray diffraction to 973 K. The best model for fitting the thermal expansion data is that of Berman
(J Petrol 29:445–522, 1988) in which the coefficient of volume thermal expansion varies linearly with T as α
V,T
= a
1 + 2a
2 (T − T
0): α298 = a
1 = 3.40(6) × 10−5 K−1, a
2 = 5.1(1.0) × 10−9 K−2. The corresponding axial thermal expansion coefficients for this linear model are: α
a
,298 = 1.21(2) × 10−5 K−1, a
2,a
= 5.2(4) × 10−9 K−2; α
b
,298 = 9.2(1) × 10−6 K−1, a
2,b
= 7(2) × 10−10 K−2. α
c
,298 = 1.26(3) × 10−5 K−1, a
2,c
= 1.3(6) × 10−9 K−2. The thermoelastic behaviour of anthophyllite differs from that of most monoclinic (C2/m) amphiboles: (a) the ε
1 − ε
2 plane of the unit-strain ellipsoid, which is normal to b in anthophyllite but usually at a high angle to c in monoclinic amphiboles; (b) the strain components are ε
1 ≫ ε
2 > ε
3 in anthophyllite, but ε
1 ~ ε
2 ≫ ε
3 in monoclinic amphiboles. The strain behaviour of anthophyllite is similar to that of synthetic C2/m
ANa B(LiMg) CMg5
TSi8 O22
W(OH)2, suggesting that high contents of small cations at the B-site may be primarily responsible for the much higher thermal expansion
⊥(100). Refined values for site-scattering at M4 decrease from 31.64 epfu at 298 K to 30.81 epfu at 973 K, which couples with similar increases of those of M1 and M2 sites. These changes in site scattering are interpreted in terms of Mn ↔ Mg exchange involving M1,2 ↔ M4, which was first detected at 673 K. 相似文献
18.
Summary Anandite has an approximate formula of Ba(Fe3+, Fe2+)3[Si2(Fe3+, Fe2+, Si)2O10–x(OH)x] (S, Cl) (OH), withx=0–1, and belongs to the 2 O brittle mica group. It is orthorhombic; space groupPnmn;a=5.468(9) Å,b=9.489(18)Å,c=19.963(11) Å;Z=4.The structure was determined from 3dim. Weissenberg-data, starting with an approximate structure in the pseudo space groupCcmm. Least squares refinement resulted inR=0.061 for 409 photometric intensities, andR=0.131 for all 853 observedhkl-reflexions.The iron of the tetrahedral layer is concentrated in one of the two crystallographically different kinds of tetrahedra. The basal oxygen rings of the tetrahedral layer form approximate hexagons and have not the ditrigonal configuration of the common micas. This peculiarity is considered to be a consequence of the size and charge of the barium ion. The role of OH in the common micas is played partly by S2– and Cl– in anandite.
With 4 Figures 相似文献
Die Kristallstruktur des 2 O Sprödglimmers Anandit
Zusammenfassung Anandit hat die ungefähre Formel Ba(Fe3+, Fe2+)3[Si2(Fe3+, Fe2+, Si)2O10–x(OH)x] (S, Cl) (OH) mitx=0–1 und gehört zur 2O Sprödglimmergruppe. Er ist rhombisch; RaumgruppePnmn; a=5,468(9) Å,b=9,489(18) Å,c=19,963(11) Å;Z=4.Die Struktur wurde aus Weissenberg-Daten bestimmt, wobei mit einer approximativen Struktur in der PseudoraumpruppeCcmm begonnen wurde. Die Verfeinerung nach der Methode der kleinsten Quadrate führte für 409 photometrierte Reflexe aufR=0,061 und für alle 853 beobachtetenhkl-Reflexe aufR=0,131.Der Eisengehalt der Tetraederschicht ist in einer der beiden kristallographisch verschiedenen Tetraederarten konzentriert. Die basalen Sauerstoffringe der Tetraederschicht bilden annäherungsweise Sechsecke und haben nicht die ditrigonale Konfiguration der gewöhnlichen Glimmer. In Anandit spielen S2– und Cl– teilweise die Rolle der Hydroxylgruppen in den gewöhnlichen Glimmern.
With 4 Figures 相似文献
19.
Solid solubility and structural phase transitions in (Ca
x
Sr1-x
)TiOGeO4have been studied by means of in situ high temperature X-ray powder diffraction. The displacive A2/a–P21/a phase transition analogous to titanite has been followed across the solid solution. Strain analysis indicates a transition
temperature of T
c=594 ± 10 K for SrTiOGeO4 and the additional occurrence of an isosymmetric anomaly at T
i
=800 ± 25 K, in analogy to the isomorphous compound CaTiOGeO4. Lattice parameters as a function of temperature and composition have been determined by X-ray powder diffraction between
room temperature and a maximum temperature of 1123 K. The e
11 and e
13 components dominate the strain tensor. All compositions across the solid solution exhibit close to tricritical phase transitions
P21/a–A2/a. The critical temperature remains almost unaffected by substitution of Sr for Ca, but the magnitude of the spontaneous strain
drops significantly with even small amounts of Sr present. 相似文献
20.
D. W. Fan M. N. Ma W. G. Zhou S. Y. Wei Z. Q. Chen H. S. Xie 《Physics and Chemistry of Minerals》2011,38(2):95-99
The high-pressure X-ray diffraction study of a natural arsenopyrite was investigated up to 28.2 GPa using in situ angle-dispersive
X-ray diffraction and a diamond anvil cell at National Synchrotron Light Source, Brookhaven National Laboratory. The 16:3:1
methanol–ethanol–water mixture was used as a pressure-transmitting medium. Pressures were measured using the ruby-fluorescence
method. No phase change has been observed up to 28.2 GPa. The isothermal equation of state (EOS) was determined. The values
of K
0, and K′
0 refined with a third-order Birch–Murnaghan EOS are K
0 = 123(9) GPa, and K′
0 = 5.2(8). Furthermore, we confirm that the linear compressibilities (β) along a, b and c directions of arsenopyrite is elastically isotropic (β
a
= 6.82 × 10−4, β
b
= 6.17 × 10−4 and β
c
= 6.57 × 10−4 GPa−1). 相似文献