共查询到10条相似文献，搜索用时 234 毫秒
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扫描电镜-X射线能谱仪在丹巴地区铂族矿物物相特征分析中的应用 总被引：2，自引：2，他引：0
丹巴地区铜镍硫化物铂族矿床品位低、铂族矿物颗粒细、铂族元素间的类质同象普遍,此类铂族资源的赋存状态研究及矿石的选冶长期以来都是较为棘手的问题。本文采用扫描电镜-X射线能谱仪器组合,对丹巴铜镍硫化物铂族矿床中含量达到1‰的元素进行快速的定性/定量分析,研究了铂族矿物原位的赋存状态和形貌特征。通过扫描电镜观察到该矿床的铂族矿物主要为砷铂矿、锑钯矿、碲锑钯矿,其次以自然铂、硫砷铑矿、硫砷铱矿,呈椭圆状、纺锤状等形式赋存于黄铁矿、磁黄铁矿及蛇纹石中,部分以类质同象的形式存在,极少量的铂与钯元素呈固溶体形式存在。X射线能谱分析表明该矿床中主要的铂族元素为Pt、Pd,其次为Ru、Rh、Ir、Os; 点分析表明砷铂矿中Pt的含量为52.84%,锑钯矿中Pd的含量为45.15%; 线扫描和面扫描分析表明铂族元素主要分布在含铁的硫化物中,Pt、Pd等铂族元素的含量与铁、镍的含量成正相关关系,反映了丹巴地区铂族元素亲铁、亲镍、亲硫的地球化学特征。 相似文献
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红石砬铂矿地球化学异常组分简单,仅发育Ｐｔ和Ｐｄ的强异常,部分伴生Ａｕ异常,不伴生Ｃｒ、Ｃｏ、Ｃｕ、Ｎｉ、Ｖ、Ａｓ、Ｓｂ、Ａｇ、Ｐｂ等元素异常。岩石、土壤、水系沉积物中Ｐｔ、Ｐｄ的分布和异常模式与铂族矿化特征、矿体剥蚀程度及其表生地球化学行为等有关。矿体出露地表时,Ｐｔ、Ｐｄ呈强异常分布,异常的ｗ（Ｐｔ）／ｗ（Ｐｄ）比值与矿石中ｗ（Ｐｔ）／ｗ（Ｐｄ）比率基本一致;隐伏矿体上方,Ｐｄ有明显的浓集,ｗ（Ｐｔ）／ｗ（Ｐｄ）比值小于地表矿体。表生环境中,Ｐｔ、Ｐｄ可以呈矿物碎屑、可溶态等多种形式迁移,在疏松沉积物中形成异常。因此,以Ｐｔ、Ｐｄ作为直接指示元素,进行地球化学勘查,可以发现这种类型的铂族矿床。 相似文献
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某矿床为一大型的铜镍铂钯矿床,原矿石化学分析有用元素为：Ｐｔ１－３８ｇｔＰｄ２－３６ｇｔ、Ｃｕ０－１４％、Ｎｉ０－２２％。显微镜观察发现,矿石主要金属矿物为黄铜矿、紫硫镍矿、黄铁矿、磁铁矿、铬铁矿,脉石矿物为蛇纹石、辉石等。经显微镜观察以及电子探针扫描分析,铂钯矿物在矿石中嵌布颗粒粒度细小,与不同矿物连生,根据电子探针分析,仍有许多超显微状态的铂钯矿物赋存在硫化矿物中。１ 样品制备与仪器设备及实验条件从原矿石中挑选部分有代表性矿石,切割抛光制成矿石光片,经显微镜镜下鉴定后,留待进行电子探针分… 相似文献
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The paper discusses the results of studying the contents of platinum group elements (PGE) and platinum group minerals (PGM) in ores of the Kingash deposit. The bulk of PGE has been established as concentrated in disseminated sulfide chalcopyrite–pyrrhotite–pentlandite ore and is represented by palladium bismuth–tellurides. During melt differentiation, the content and relationship of PGE are changed; the Pd/Pt value increases (up to 1.9 and 4.2 in dunite and wehrlite, respectively) with decreasing Mg number. The distribution of PGE, sulfur, and REE in various ore types suggests two formation mechanisms of high-grade ores: (1) the product of liquid immiscibility and gravity separation at the early magmatic stage and (2) involvement of the residual melt saturated in volatiles, which contributed to transportation and segregation of PGE at the late magmatic stage. The evolution of the ore system of the Kingash massif is characterized by sequential enrichment of PGM in Ni from high-Mg to low-Mg rocks similarly to sulfide minerals of disseminated ore. The criteria for ore content in utramafics of the Kansk block have been identified based on compared ore element and PGE concentrations in ultramafic rocks of the Kingash and Idar complexes. 相似文献
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I. V. Kubrakova A. V. Fortygin S. G. Lobov I. Ya. Koshcheeva O. A. Tyutyunnik M. V. Mironenko 《Geochemistry International》2011,49(11):1072-1084
In order to explore the behavior of platinum group elements in the ecosystems of mineral deposits, the migration characteristics
of platinum and palladium were determined in the pH range typical of surface waters. Model sorption experiments on the precipitation
of platinum and palladium on iron oxyhydroxide in the presence of major natural inorganic and organic ligands showed that
platinum interacts most actively with an iron oxyhydroxide (ferrihydrite) precipitate within the whole pH range, both in the
absence and presence of natural organic substances, whereas palladium is preferentially bound to dissolved, suspended, and
sedimentary humic substances. The thermodynamic calculation of coexisting platinum and palladium species is qualitatively
consistent with experimental data on the character of accumulation and migration of these elements. The obtained data suggest
that the migration of platinum and palladium into highly colored waters in the zones of platinum group element deposits results
in their extensive deposition on natural geochemical barriers. 相似文献
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加布呀地区地处班公错-怒江金、铬、铂、钯、镍成矿亚带,成矿地质条件较为优越,找矿潜力较大。本文在分析区域铜多金属成矿规律基础上,利用WorldView-2高分辨率遥感数据对加布呀地区成矿有利信息进行遥感地质解译,利用Aster数据提取的蚀变异常信息,综合分析加布呀地区成矿有利信息特征,构建了铜多金属矿找矿模型、圈定了找矿靶区,经野外查证发现了铜多金属矿化。 相似文献
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新疆阿尔金地区清水泉铜金铂矿床特征及成因浅析 总被引：1，自引：0，他引：1
阿尔金南缘断裂带是一条深达上地幔的区域性大断裂。沿断裂分布着众多基性—超基性杂岩体。岩浆结晶分异晚期，铜、金、铂、钯元素富集，在后期断裂及热液作用下形成工业矿体，仅清水泉一处即发现三个规模较大的矿化带，通过对该化带地质特征及矿床成因分析，指出该带找矿前景极佳。 相似文献
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N. M. Chernyshov 《Geology of Ore Deposits》2009,51(8):684-697
High-carbonaceous stratified formations and related metasomatic rocks of global abundance are among highly promising sources of gold and platinum-group metals (PGMs) in the 21st century. The Au-PGM mineralization of the black-shale type hosted in the Early Karelian Kursk and Oskol groups in central Russia is characterized by complex multicomponent and polymineralic composition (more than 60 ore minerals, including more than 20 Au and PGM phases) and diverse speciation of noble metals in form of (1) native elements (gold, palladium, platinum, osmium, silver); (2) metallic solid solutions and intermetallic compounds (Pt-bearing palladium, Fe-bearing platinum, gold-platinum-palladium, osmiridium, rutheniridosmin, platiridosmin, platosmiridium, Hg-Te-Ag-bearing gold, gold-silver amalgam, arquerite, palladium stannide (unnamed mineral), platinum-palladium-gold-silver-tin); (3) PGM, Au, and Ag sulfoarsenides, tellurides, antimonides, selenides, and sulfosalts (sperrylite, irarsite, hessite, Pd and Pt selenide (unnamed mineral)), testibiopalladinite, Pd antimonide (unnamed mineral), etc.; and (4) impurities in ore-forming sulfides, sulfoarsenides, tellurides, antimonides, and selenides. The chemical analyses of PGM and Au minerals are presented, and their morphology and microstructure are considered. 相似文献
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喀拉通克铜镍硫化矿区二、三号矿床的两个岩体为隐伏的中－基性岩体，受北西向断裂的控制，侵位于石炭统南明水组上段之下部地层中，为岩浆熔离型铜镍硫化矿床。矿物成分以磁黄铁矿、镍黄铁矿、黄铜矿为主。有用元素除铜、镍外，尚伴生有金、银、铂、色、钴、硫可综合利用。它国内外同类型矿床相比，具有成岩、成矿时代新，岩体基性程度低、铜大于镍等特点，因而又具有新的地质找矿意义。 相似文献