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1.
针对湖南省××磷矿矿石性质及可选特性,采用擦洗脱泥—浮选联合工艺选别,有效降低了能耗和药耗,使P2O5品位由15.78%富集至30.77%,P2O5回收率为82.40%,磷精粉达到酸法加工用磷矿石一等品Ⅰ级标准。  相似文献   

2.
对昆阳磷矿中稀土元素的赋存状态进行了系统研究,结果表明矿体中稀土元素总量在50×10-6~250×10-6之间,以轻稀土元素富集、重稀土元素亏损为特征,Y含量在30×10-6~155×10-6之间,稀土元素总量与胶磷矿含量呈正相关关系。重砂矿物查找结果显示,昆阳磷矿中缺乏独立的稀土矿物。物相分析结果表明,稀土元素主要赋存在胶磷矿中,碳酸盐相和硅酸盐相中稀土元素含量极低。LA-ICPMS测试结果表明,胶磷矿单矿物中稀土元素总量在280×10-6~420×10-6之间,而白云石单矿物中的稀土元素总量均低于10×10-6。综合分析结果表明,昆阳磷矿中的稀土元素应主要以类质同像的形式存在于胶磷矿中。  相似文献   

3.
针对某碳酸盐型磷矿,采用反浮选工艺流程进行试验研究,获得了低镁优质磷精矿。反浮选工艺具有药剂种类少,分选效率高,选矿技术指标先进,操作控制容易等优点,是选别碳酸盐型磷矿的先进浮选工艺。  相似文献   

4.
合理开发利用内蒙古东升庙低品位磷矿资源,针对其矿石性质和赋存状态,对该难选磷矿进行了系统的选矿试验研究。通过正-反浮选工艺流程,最终获得的闭路试验指标为:磨矿细度-0.074mm89.50%,原矿品位P2O5 7.30%、MgO 5.42%,精矿品位P2O5 32.37%、MgO 1.10%,回收率84.73%。  相似文献   

5.
<正> 宜昌磷矿主要工业矿物为呈隐晶的氟磷灰石和碳氟磷灰石,集中呈条带状分布;主要脉石矿物有白云石、水云母、钾长石、石英等,亦聚集成与前者相间的条带。如此结构,适合重介质选矿。但一般磷矿的重介质选矿,对1mm 以下的细粒物料尚无理想的选别手段,影响了对该类型矿床的开发利用。宜昌磷矿原矿中有10%以上细粒(-1~+0mm)物料不能进入重介质选。为此,笔者对宜昌磷矿细粒物料进行了重选试验研究。重液浮沉试验及可选性分析结果表明,这部分物料,有用矿物与脉石矿物的比重差较小,采用水介质重选获得高质量磷精矿和较高回  相似文献   

6.
近几年来对硅钙质胶磷矿采用反正浮选或正反浮选流程的试验研究有了很大突破,克服了单一正浮选磷精矿质量低、磨细度要求高等缺点。根据保康磷矿的反正浮选试验实践和安宁等几个磷矿的试验结果,表明以反浮选为基础流程的工艺是硅钙质胶磷矿矿石性质所决定的。采用此工艺具有矿浆浮选温度低、磨矿粒度较粗、工艺简单且操作稳定、精矿易过滤且尾矿易沉降、精矿质量高等5大特点。此工艺流程易于实现工业化。  相似文献   

7.
滇池地区沉积磷块岩中胶磷矿矿物学特征及其研究意义   总被引:1,自引:0,他引:1  
本文从物理性质、化学成分及其成因结构等方面,对云南滇池地区胶磷矿进行了矿物学特征研究。提出该区胶磷矿主要以三种形式赋存在磷块岩中。对不同矿石类型中胶磷矿做扫描电镜研究,得知胶磷矿主要由超微晶低碳氟磷灰石集合体、磷酸盐显微莓群以及纤维放射状磷灰石等构成。经化学分析、红外、晶胞参数测定,不同胶磷矿有一定差异,特别是碳和磷,经矿物学对比发现,反映随变质作用的加深,胶磷矿有向晶质氟磷灰石演化的趋势,脱碳作用表现明显。本区胶磷矿稀土元素含量不高,钇族较富,铈族较贫。球粒陨石标准化后为铈亏损型模式。  相似文献   

8.
本文选取贵州典型磷矿区海相沉积型磷矿石为研究对象,通过ξ电位测定和纯矿物浮选试验,考察了Ca2+、Mg2+对胶磷矿表面电性及可浮性的影响。结果表明:加入Ca2+、Mg2+后,胶磷矿表面负电性降低,由此可推知,胶磷矿是优先吸附溶液中的Ca2+、Mg2+而使表面负电性降低。Mg2+在胶磷矿表面的吸附使其表面形成类似白云石的覆盖层,从而会降低分选的选择性。在酸性条件下,Ca2+、Mg2+对胶磷矿浮选影响不大,但在中性及碱性条件下,金属离子的加入会明显地抑制胶磷矿的上浮,其原因可能是金属离子与脂肪酸类捕收剂发生沉淀反应,从而消耗捕收剂,并且在碱性条件下形成氢氧化物沉淀,并吸附罩盖在矿物表面,使矿物表面亲水,不易上浮。  相似文献   

9.
××碳酸盐型萤石矿选矿试验研究   总被引:1,自引:0,他引:1  
通过对浙江××碳酸盐型萤石矿的条件试验及开路、闭路流程试验研究,在常温条件下,采用一次粗选六次精选、部分中矿集中再选、抛两个尾矿的选矿工艺流程,取得了较好的选矿指标.  相似文献   

10.
贵州织金含稀土磷矿床稀土元素赋存状态研究   总被引:6,自引:0,他引:6  
利用等离子质谱仪ICP-MS、扫描电镜配合能谱分析、电子探针分析方法,研究了贵州织金含磷岩系剖面稀土含量变化。结果表明,剖面上稀土含量与磷灰石含量变化呈正相关关系,说明稀土主要赋存于磷灰石矿物中;利用扫描电镜、电子探针分析方法对生物碎屑、白云石和胶磷矿进行单矿物微量元素分析研究表明,胶磷矿中稀土含量最高,生物碎屑和白云石稀土含量较低,说明织金含稀土磷矿床稀土元素赋存状态是以类质同象的形式存在于胶磷矿中;利用稀土元素化学物相分析研究同样表明只有少量的稀土元素被磷块岩中粘土矿物所吸附,大量的稀土元素以类质同相形式存在于胶磷矿中。  相似文献   

11.
A fully automated semi-commercial flotation column incorporating state of the art instruments was designed to study the amenability of flotation column for the beneficiation of different minerals. In the present study, beneficiation of sillimanite was investigated by installing the flotation column in the flotation circuit of Orissa Sands Complex, Indian Rare Earths Limited, Chatrapur, Orissa. The effect of process parameters on sillimanite grade and recovery was investigated. At optimum conditions, the flotation column was operated continuously with a feed rate of one ton per hour and demonstrated the efficiency of the technology for the beneficiation of sillimanite. The results show that a concentrate assaying 96% sillimanite at 90% recovery can be obtained in a single column flotation stage.  相似文献   

12.
Column flotation, which is a very effective process in mineral processing especially for easily floatable minerals, is one of the most important new developments to emerge in mineral processing technology in the last years. In this study, the flotation behavior of talc products having different particle shapes produced by different grinding mills (ball and rod mill) was determined by using column flotation process. Shape characteristics of the particles were investigated by the two dimensional measuring technique based on the particle projections obtained from the SEM microphotographs using a COREL Draw 10.0 program. The results showed that particles possessing higher elongation and flatness properties were recovered better during column flotation, whilst roundness and relative width had a negative effect on the flotation behavior of the talc mineral studied. Consequently, as the shape of the particles produced by the mill deviated from the ideal sphere, their floatability was increased.  相似文献   

13.
周建平 《云南地质》2011,30(1):92-94,91
胶磷矿的矿物组成,主要是微碳—低碳磷灰石,及细晶磷灰石。而胶磷矿细微颗粒,经电镜观察鉴定,主要由磷酸盐化有机碎屑及藻席碎屑组成,早寒武世磷块岩的形成是生物学、沉积学、古地理—古构造等综合因素沉积作用的产物。  相似文献   

14.
A model is developed by taking into account the simultaneous mechanisms of true flotation and entrainment in a conventional flotation cell. The total volume of the cell is divided into three compartments: pulp collection zone, pulp quiescent zone and froth region, with the mechanisms being modeled as occurring at the same time but originating at different places: true flotation from the collection zone and entrainment from the quiescent one. A particle is referred to as suspended in water or attached to an air bubble, depending upon its original state before crossing the pulp–froth interface (whether or not it remains in that state all the way to the concentrate launder). The model is obtained by solving a set of equations describing the mass conservation of solids and water between adjacent compartments. The principal mass transfer factors are identified as: the flotation rate constant, the mean residence time in the collection zone, the froth recovery of attached particles, the degree of entrainment through the froth and the water recovery from the feed to the concentrate. The development presented here allows the intricate nature of the mass transfer in a flotation cell to be reduced to one single equation, overcoming the need of numerical methods for simulation purposes. Moreover, it is shown that reliable prediction of grade and recovery can be obtained without detailed information on the pulp hydrodynamics or on any froth sub-process either than drainage, bubble bursting and bubble coalescence.  相似文献   

15.
The effects of oxidation potential (Eh) and zinc sulphate on the separation of chalcopyrite from pyrite were investigated at pH 9.0. The flotation recovery of these minerals is Eh dependent with maximum separation obtained at 275 mV SHE. Zinc sulphate addition improved this mineral separation at an Eh value of 275 mV by selectively depressing pyrite flotation. A different result was obtained at lower Eh values where zinc sulphate addition improved chalcopyrite flotation but had no or little effect on pyrite flotation. These opposite effects of zinc sulphate on mineral flotation were reconciled by examining the surface species of these minerals. The selective depression of pyrite flotation by zinc sulphate was also confirmed in the flotation of two copper ores.  相似文献   

16.
The effect of sodium bisulphite on the xanthate-induced flotation of copper-activated sphalerite has been studied using batch flotation testing, surface analysis techniques (XPS and ToF-SIMS), and FTIR. The various techniques have been used to identify the mechanisms of interaction of sulphite ions with both collector and the sphalerite surface. The results indicate that sodium bisulphite depressed the flotation of sphalerite particles pre-treated with copper and xanthate at pH 9 with nitrogen and air purging. It was found that sodium bisulphite interacts with the sphalerite surface, as well as with xanthate in its adsorbed state. Based on the evidence obtained in the present study, and in conjunction with previous work, the mechanisms involved in the depression of the xanthate-induced flotation of copper-activated sphalerite by sulphite are proposed. It is suggested that copper xanthate decomposition on the surface of the activated sphalerite and the decomposition of the hydrophobic copper-sulphide-like species on the sphalerite surface are the active mechanisms for sphalerite depression by sodium bisulphite.  相似文献   

17.
Hallimond tube flotation experiments have been carried out on the two calcium minerals scheelite and calcite using dodecylammonium chloride as collector. The main variables studied were the calcium ion concentration and the pH.In the case of scheelite, addition of calcium chloride markedly lowered the flotation recovery. Recovery was also lowered when the pH was reduced below about 10. Since it is known that the zeta potential of scheelite is almost independent of pH this confirms that co-adsorption of un-ionized amine is necessary for good flotation. Other un-ionized long-chain molecules can replace the amine; thus it was shown that excellent flotation can be obtained event at about pH 7 by adding dodecanol together with dodecylammonium chloride. With the completely ionic trimethyldodecylammonium chloride recoveries were poor and were independent of pH.In the case of calcite, calcium chloride had no immediate effect on flotation recovery, but at low collector concentrations marked depression occurred after many hours standing in the presence of calcium ions. The effect of pH on flotation of calcite was anomalous and there appear to be two pH regions in which recoveries are high.The results are discussed and attention is drawn to the need for more thorough studies of the calcium carbonate/water interface.  相似文献   

18.
The market requirements for higher-grade concentrates of iron to improve the productivity of the iron and steel industry, has increased the importance of the flotation process with respect to the conventional preconcentration of ore by gravity or magnetic separation. The flotation method most commonly applied is the one that is based on cationic flotation of silica and silicates (reverse flotation), and which is preceded, or not, by desliming or selective flocculation.  相似文献   

19.
The generalised optimisation of a flotation network is studied by means of using variable connections (structural parameters) and variable enhancement factors which are used instead of a flotation model to describe the separation process. The enhancement factors are functions of variables affecting the flotation process. These functional relationship may be derived by means of using a flotation model. Bounds are placed on the enhancement factors by means of either using a flotation model or by inspection of existing pilot or commercial plant data. These bounds, together with external, system and mass balance constraints and an appropriate objective function, define the general optimisation problem for a flotation network.The optimisation problem above may be solved by non-linear programming methods, however, it is easily transformable into a Linear Programme which is easy to solve. The procedure has been applied to a flotation circuit comprising three banks of cells for which an optimal set of connections and enhancement factors has been computed for varying constraints.A simulation procedure based on a gamma flotation model has been applied to one of the optimal circuits so as to compute the flotation variables.  相似文献   

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