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1.
矽线石莫来石化的X射线定量分析 总被引：2，自引：0，他引：2
本文介绍用X射线粉晶衍射分析方法对夕线石在不同温度的烧制品中的莫来石进行定量分析;指出莫来石和矽线石的(220)峰可作为特征峰,并发现莫来石起始生成和完全莫来石化的温度随原料杂质和粒度因素而变化;认为d(020)=0.383 7nm,d(040)=0.191 7nm是矽线石JCPDS卡片中不曾标定的衍射峰,d(020)=0.3845nm是莫来石不曾标定的衍射峰,它们的强度变化是莫来石化行为特征之一。 相似文献
2.
硫化物吸附金属离子的实验研究──Ⅰ类型 总被引：1，自引：0，他引：1
合成ＰｂＳ、ＺｎＳ对金属离子Ａｇ＋、Ｃｕ（２＋）、Ｃｄ（２＋）、Ｚｎ（２＋）、Ｆｅ（２＋）、Ｍｎ（２＋）、Ｍｇ（２＋）、Ｓｂ（３＋）和Ｂｉ（３＋）的吸附等温线（５０℃）研究表明，其可分为Ａ、Ｂ、Ｃ三类：Ａ类，线性型，即吸附量随吸附离子浓度增加而呈线性上升，并表现出百分之百吸附，属于此类的吸附有ＰｂＳ对Ａｇ＋、Ｃｕ（２＋）离子吸附和ＺｎＳ对Ａｇ＋、Ｃｕ（２＋）、Ｃｄ（２＋）离子的吸附；Ｂ类，朗谬尔型，即随吸附离子的浓度增加，吸附量逐趋向一饱和值，属于此类的有ＰｂＳ对Ｆｅ（２＋）、Ｓｂ（３＋）、Ｂｉ（３＋）等离子及ＺｎＳ对Ｆｅ（２＋）、Ｍｎ（２＋）、Ｍｇ（２＋）等离子的吸附；Ｃ类，反朗谬尔型，即吸附量随吸附离子浓度增加而呈非线性增加。属此类吸附的有ＰｂＳ对Ｚｎ（２＋）、Ｃｄ（２＋）等离子的吸附。合成ＰｂＳ、ＺｎＳ对金属离子的吸附量与天然方铅矿和闪锌矿中微量元素含量可类比，这意味着吸附作用可能在硫化物矿物微量元素形成过程中起着重要的作用。 相似文献
3.
以太原市南郊蔬菜区为对象，对污灌的１４种蔬菜中有害元素镉（Ｃｄ），铅（Ｐｂ）和有抗癌抗衰作用的元素锶（Ｓｒ），锰（Ｍｎ）的含量进行了测试分析，结果表明，不同蔬菜中Ｃｄ，Ｐｂ，Ｓｒ，Ｍｎ的含量差异很大，说明不同的蔬菜对不同元素具有选择富信的特性。 相似文献
4.
太原南郊蔬菜中镉(Cd)、铅(Pb)、锶(Sr)、锰(Mn)等元素含量的分析研究 总被引：2，自引：0，他引：2
以太原市南郊蔬菜区为对象，对污灌的１４种蔬菜中有害元素镉（Ｃｄ）、铅（Ｐｂ）和有抗癌抗衰老作用的元素锶（Ｓｒ）、锰（Ｍｎ）的含量进行了测试分析，结果表明，不同蔬菜中Ｃｄ、Ｐｂ、Ｓｒ、Ｍｎ的含量差异很大。说明不同的蔬菜对不同元素具有选择富集的特性。 相似文献
5.
研究了混合增效试剂ＣＴＭＡＢ和Ｂｒｉｊ－３５对Ｃｄ（Ⅱ）－Ｈ２Ｑｓ体系的影响，在Ｃｄ（Ⅱ）－Ｈ２Ｑｓ体系中加入ＣＴＭＡＢ＋Ｂｒｉｊ－３５后，比单独使用ＣＴＭＡＢ或Ｂｒｉｊ－３５效果更好。大大提高了反应的灵敏度，在０－４．０μｇ／２５ｍＬＣｄ范围内，Ｃｄ深度与△Ｆ值呈良好的线性关系，方法检测限为９．１２ｎｇ／ｍＬ，ＲＳＤ为１．９３％，可用于地质样品中镉的测定。 相似文献
6.
高岭石—莫来石反应系列：^27Al和^29SiMAS NMR研究 总被引：21，自引：2，他引：21
根据艰我国八个不同成因和特征的高岭土样品在４５０－１４５０℃热处理产物的ＭＡＳ ＮＭＲ谱和ＸＲＤ，ＩＲ，ＤＴＡ等研究结果，结合有关资料讨论了高岭石－莫来石反应序列的几个重要问题：１．高岭石的结构，尤其是五配位铝；２．９８０℃放热峰后的高温相是γ－Ａｌ２Ｏ３而不是Ａｌ－Ｓｉ尖晶石；３．对于莫来石化过程，认为初始莫来石８５０－９５０℃变高岭石形成，二次莫来石由分凝的ＳｉＯ２和γ－Ａｌ２Ｏ３在１２００－ 相似文献
7.
内蒙古大青山造山带含假蓝宝石尖晶石片麻岩的成因网格及动力学 总被引：5，自引：3，他引：2
内蒙古大青山造山带中存在着一类特殊的岩石类型极度富铝贫硅的含假蓝宝石尖晶石片麻岩。含假蓝宝石尖晶石片麻岩的岩石学和矿物学的研究表明,变晶序列为Ｓａｐ＋Ｓｉｌ＋Ｇｔ＋Ｐｌ＋Ｂｉ（早期）→Ｓｐ＋Ｇｔ＋Ｓｉｌ＋Ｐｌ＋Ｐｅｒｔｈ＋Ｂｉ（峰期）→Ｃｏｒｄ＋Ｃｏｒｕ＋Ｍｔ＋Ｐｌ＋Ｍｉｃ＋Ｂｉ（峰后）。利用Ｇｉｂｂｓ相律和Ｓｃｈｒｅｉｎｅｍａｋｅｒｓ分析方法对该岩质系的矿物演化历史进行了理论推导,结果表明其与实 相似文献
8.
法国国立巴黎高等矿业学院（ＥＮＳＭＰ）创立于１７８３年,是法国最古老的高等学府之一。１８１６年搬迁至目前的地址：６０,Ｂｄ．ＳａｉｎｔＭｉｃｈｅｌ,７５００６Ｐａｒｉｓ。１９６７年在枫丹白露（Ｆｏｎｔａｉｎｅｂｌｅａｕ）和埃夫立（Ｅｖｒｙ）建立分部,１９７６年又在索非亚（Ｓｏｐｈｉａ）和尼斯（Ｎｉｃｅ）建立分部。（１）人员组成（如附表）人 员巴黎总部枫丹白露国立高等技术学院马恩拉瓦莱巴莱佐埃夫立索非亚教研人员７１９２６６４９３７７０管理与技术人员１６３８０４２５４８４０博士生,硕士生９４… 相似文献
9.
阿尔泰地区中、新生代岩浆活动的同位素年龄证据 总被引：25，自引：1，他引：25
长期以来，对阿尔泰地区有无印支、燕山期岩浆活动一直存在争议。本研究得到以下年龄结果：将军山花岗岩（＾４０Ａｒ／＾３９Ａｒ坪年龄）２２０Ｍａ、康布铁堡花岗岩（＾４０Ａｒ／＾３９Ａｒ高温视年龄）２１４Ｍａ、尚可兰花岗岩（Ｒｂ－Ｓｒ全岩等时线年龄）１７６Ｍａ、阿拉尔花岗岩（＾４０Ａｒ／＾３９Ａｒ坪年龄）１３１Ｍａ。以上数据和与本区处在同一构造单元的前苏联矿区阿尔泰及山区阿尔泰１２个浅色花岗岩锆石Ｕ－Ｐｂ 相似文献
10.
张苗云 《矿物岩石地球化学通报》1995,(2)
氡对环境的影响及其作用张苗云（中国科学院地球化学研究所，贵阳５５０００２）关键词氡同位素，放射性，环境在自然界，氡没有稳定同位素，只有三个天然放射性同位素２２２Ｒｎ、２２０Ｒｎ、２１９Ｒｎ。２２２Ｒｎ半衰期为３．８２５ｄ，钍射气（２２０Ｒｎ）半衰期为... 相似文献
11.
Metapelitic granulites from Jetty Peninsula,east Antarctica: formation during a single event or by polymetamorphism? 总被引：5，自引：0，他引：5
M. HAND I. SCRIMGEOUR R. POWELL K. STÜWE C. J. L. WILSON 《Journal of Metamorphic Geology》1994,12(4):557-573
Granulite facies metasedimentary gneiss exposed on Jetty Peninsula, east Antarctica, contains assemblages involving garnet-sillimanite-biotite-cordierite-spinel-ilmenite-rutile and garnet-orthopyroxene-cordierite-biotite, as well as quartz and K-feldspar. Peak assemblages involve garnet + sillimanite + ilmenite (±rutile) and garnet + orthopyroxene. P-T calculations suggest formation conditions of approximately 800d? C at 7-7.5 kbar. Cooling from peak conditions is suggested by biotite + garnet (±sillimanite) overprinting some peak assemblages. A subsequent increase in temperature is inferred from the formation of cordierite + garnet + biotite + ilmenite, garnet + sillimanite + cordierite + ilmenite and cordierite + orthopyroxene assemblages during D2. In slightly zincian bulk compositions, hercynitic spinel + cordierite + sillimanite constitutes the peak D2 assemblage. Average pressure calculations indicate peak pressures of 5.9 ±0.4 kbar at 700d? C for the cordierite-bearing D2 assemblages. Available radiometric data suggest that peak metamorphism occurred at c. 1000 Ma and D2 occurred after 940 ± 20 Ma. The following two possibilities exist for the metamorphic evolution. (1) The formation of the lower pressure cordierite-bearing assemblages is associated with a separate metamorphic event (M2), unrelated to the peak assemblage (M1), and the lower pressure assemblages have no relevance in terms of a single tectonothermal event. (2) The cordierite-bearing assemblages formed during a progression from peak conditions. In this case, the lower pressure assemblages reflect a broadly decompressional metamorphic evolution, during which temperatures fluctuated. Comparison with P-T paths from granulites of similar age in adjacent areas suggests that the second possibility should be preferred. The cooling interval between peak conditions and the development of cordierite-bearing coronas and symplectites suggests affinities with isobarically cooled granulites of similar age immediately to the west, and the low-P/high-T post-peak conditions are similar to the later stages of decompressional paths recognized in much of east Antarctica. 相似文献
12.
W. E. Cameron 《Physics and Chemistry of Minerals》1977,1(3):265-272
Complete solid solution between sillimanite and mullite is shown to occur when Fe3+, in the virtual absence of Ti, replaces AlVI. All members of the series adopt the sillimanite (Al, Si)IV ordering scheme in preference to the modulated structure typical of synthetic and titaniferous natural mullites. 相似文献
13.
L. Wondraczek G. Heide M. Kilo N. Nedeljkovic G. Borchardt R. A. Jackson 《Physics and Chemistry of Minerals》2002,29(5):341-345
Defect structure and the defect formation in mullites and sillimanites have been investigated using computer simulation techniques.
From point defect chemistry and computer simulations, oxygen vacancies are identified as the majority defect responsible for
oxygen transport in mullite. The defect formation energies are between 3 and 4 eV. Using supercell calculation methods, the
random structure is identified to be stable in mullites, whereas the ordered structure can be confirmed to be more stable
in sillimanite. An energy of 0.7–1.0 eV for the association of oxygen vacancies with cations is estimated.
Received: 11 May 2001 / Accepted: 12 December 2001 相似文献
14.
M. J. RUBENACH 《Journal of Metamorphic Geology》1992,10(3):333-346
In the Hazeldene area, situated in the Mount Isa Inlier, Queensland, the metamorphic grade changes from chlorite zone, through biotite and cordierite zones, to sillimanite/K-feldspar zone.
Microstructural studies of rocks near the sillimanite isograd demonstrate that cordierite grew early during the development of a steep foliation (S2), was replaced by biotite, andalusite and sillimanite at the metamorphic peak late in S2, and in turn by kyanite + chlorite adjacent to localized small post-D2 shear zones. Although the anticlockwise P–T–t path is well defined, the precise P–T conditions are uncertain because of problems with experimental and thermodynamic data. The best estimate for the metamorphic peak for rocks close to the sillimanite isograd is around 600° C at 4 kbar.
The metamorphism has been dated at 1544 Ma, and was synchronous with a major crustal shortening event. Because proposed extensional events occurred more than 60 Ma earlier, their contribution to the peak metamorphic thermal perturbation would have been insignificant. The syn-metamorphic Mica Creek Pegmatites, the abundance of high heat-producing elements in the nearby pre-D2 Sybella Granite, and advective heat by fluids which caused considerable metasomatism in the Hazeldene area, may have each contributed to the thermal budget. However, the metamorphic thermal gradient may be 80°C km-1 or higher, strongly suggesting a local magmatic control. As none are known in the area, such syn-metamorphic plutons would have to lie beneath the exposed high-grade rocks. 相似文献
Microstructural studies of rocks near the sillimanite isograd demonstrate that cordierite grew early during the development of a steep foliation (S2), was replaced by biotite, andalusite and sillimanite at the metamorphic peak late in S2, and in turn by kyanite + chlorite adjacent to localized small post-D2 shear zones. Although the anticlockwise P–T–t path is well defined, the precise P–T conditions are uncertain because of problems with experimental and thermodynamic data. The best estimate for the metamorphic peak for rocks close to the sillimanite isograd is around 600° C at 4 kbar.
The metamorphism has been dated at 1544 Ma, and was synchronous with a major crustal shortening event. Because proposed extensional events occurred more than 60 Ma earlier, their contribution to the peak metamorphic thermal perturbation would have been insignificant. The syn-metamorphic Mica Creek Pegmatites, the abundance of high heat-producing elements in the nearby pre-D2 Sybella Granite, and advective heat by fluids which caused considerable metasomatism in the Hazeldene area, may have each contributed to the thermal budget. However, the metamorphic thermal gradient may be 80°C km
15.
浙西南八都群泥质麻粒岩的变质演化与pT轨迹 总被引：2，自引：0，他引：2
浙西南古元古界八都群是目前华夏地块最古老的变质基底,以往研究认为其变质程度仅达角闪岩相。近来在对遂昌地区八都群富铝片麻岩的研究过程中,发现了具有"石榴石+夕线石+正/反条纹长石+黑云母"特征组合的泥质麻粒岩,表明该地体曾经历麻粒岩相变质改造。通过岩相学与矿物化学分析,确定该岩石经历了3个阶段的演化过程,即:早期进变质阶段(M1),形成"石榴石+黑云母+白云母+夕线石+斜长石+石英"的矿物组合;变质峰期阶段(M2-3),形成"石榴石+夕线石+三元长石+黑云母+石英"的矿物组合;峰期后降压冷却阶段(M4),形成"黑云母+白云母+新生斜长石+石英"的矿物组合。岩石中石榴石普遍发育与降温过程有关的扩散成分环带和与降压过程有关的斜长石后生合晶。通过石榴石-黑云母温度计和GASP压力计估算变质峰期的温压条件为800~850℃、0.6~0.7 GPa,峰期后退变质阶段的温压条件为560~590℃、0.25~0.33 GPa,具有顺时针样式的pT演化轨迹,反映一种陆壳碰撞增厚、后又拉伸减薄的动力学过程。 相似文献
16.
Silvia Volante Amaury Pourteau William J. Collins Eleanore Blereau Zheng-Xiang Li Matthijs Smit Noreen J. Evans Adam R. Nordsvan Chris J. Spencer Brad J. McDonald Jiangyu Li Christina Günter 《Journal of Metamorphic Geology》2020,38(6):593-627
The final assembly of the Mesoproterozoic supercontinent Nuna was marked by the collision of Laurentia and Australia at 1.60 Ga, which is recorded in the Georgetown Inlier of NE Australia. Here, we decipher the metamorphic evolution of this final Nuna collisional event using petrostructural analysis, major and trace element compositions of key minerals, thermodynamic modelling, and multi-method geochronology. The Georgetown Inlier is characterised by deformed and metamorphosed 1.70–1.62 Ga sedimentary and mafic rocks, which were intruded by c. 1.56 Ga old S-type granites. Garnet Lu–Hf and monazite U–Pb isotopic analyses distinguish two major metamorphic events (M1 at c. 1.60 Ga and M2 at c. 1.55 Ga), which allows at least two composite fabrics to be identified at the regional scale—c. 1.60 Ga S1 (consisting in fabrics S1a and S1b) and c. 1.55 Ga S2 (including fabrics S2a and S2b). Also, three tectono-metamorphic domains are distinguished: (a) the western domain, with S1 defined by low-P (LP) greenschist facies assemblages; (b) the central domain, where S1 fabric is preserved as medium-P (MP) amphibolite facies relicts, and locally as inclusion trails in garnet wrapped by the regionally dominant low-P amphibolite facies S2 fabric; and (c) the eastern domain dominated by upper amphibolite to granulite facies S2 foliation. In the central domain, 1.60 Ga MP–medium-T (MT) metamorphism (M1) developed within the staurolite–garnet stability field, with conditions ranging from 530–550°C at 6–7 kbar (garnet cores) to 620–650°C at 8–9 kbar (garnet rims), and it is associated with S1 fabric. The onset of 1.55 Ga LP–high-T (HT) metamorphism (M2) is marked by replacement of staurolite by andalusite (M2a/D2a), which was subsequently pseudomorphed by sillimanite (M2b/D2b) where granite and migmatite are abundant. P–T conditions ranged from 600 to 680°C and 4–6 kbar for the M2b sillimanite stage. 1.60 Ga garnet relicts within the S2 foliation highlight the progressive obliteration of the S1 fabric by regional S2 in the central zone during peak M2 metamorphism. In the eastern migmatitic complex, partial melting of paragneiss and amphibolite occurred syn- to post- S2, at 730–770°C and 6–8 kbar, and at 750–790°C and 6 kbar, respectively. The pressure–temperature–deformation–time paths reconstructed for the Georgetown Inlier suggest a c. 1.60 Ga M1/D1 event recorded under greenschist facies conditions in the western domain and under medium-P and medium-T conditions in the central domain. This event was followed by the regional 1.56–1.54 Ga low-P and high-T phase (M2/D2), extensively recorded in the central and eastern domains. Decompression between these two metamorphic events is ascribed to an episode of exhumation. The two-stage evolution supports the previous hypothesis that the Georgetown Inlier preserves continental collisional and subsequent thermal perturbation associated with granite emplacement. 相似文献
17.
LIU Fulai SHEN Qihan Institute of Geology Chinese Academy of Geological Sciences Beijing 《《地质学报》英文版》2003,77(1):28-35
The early Precambrian khondalite series is widely distributed in the Jining-Zhuozi-Fengzhen-Liangcheng area, southeastern Inner Mongolia. The khondalite series mainly consists of sillimanite garnet potash feldspar (or two-feldspar) gneiss and garnet biotite plagioclase gneiss. These gneissic rocks have commonly experienced granulite-facies metamorphism. In zircons separated from sillimanite garnet potash feldspar gneisses, many mineral inclusions, including Sil, Grt, Ky, Kfs, Qtz and Ap, have been identified by the Laser Raman spectroscopy. Generally, prograde metamorphic mineral inclusion assemblages such as Ky + Kfs + Qtz + Ap and Ky + Grt + Kfs + Qtz are preserved in the core of zircon, while peak granulite-facies metamorphic minerals including Sil + Grt + Kfs + Qtz and Sil + Grt + Kfs + Qtz + Ap are identified in the mantle and rim of the same zircon. However, in some zircons are only preserved the peak metamorphic minerals such as Sil + Grt + Kfs + Qtz and Sil + Grt + Kfs + Qtz + Ap from core to ri 相似文献
18.
Decompressional coronas and symplectites in granulites of the Musgrave Complex, central Australia 总被引：2，自引：0，他引：2
Abstract In granulite facies metapelitic rocks in the Musgrave Complex, central Australia, reaction between S1 garnet and sillimanite involves the development in S2 of both garnet + cordierite + hercynitic spinel + biotite and hercynitic spinel + cordierite + sillimanite + biotite. The S2 assemblages occur either in coronas and symplectites, mainly around garnet, or, in rocks in which S2 is more strongly developed, as recrystallized assemblages. Ignoring the presence of biotite and ilmenite, the mineral textures can be accounted for qualitatively by a consideration of the model system FeO-MgO-Al2 O3 -SiO2 (FMAS); the textural relationships accord with decompression accompanying the change from S1 to S2. However, since biotite and ilmenite are involved in the assemblages, the parageneses are better accounted for in terms of equilibria in the expanded model system K2 O-FeO-MgO-Al2 O3 -SiO2 -H2 -TiO2 -Fe2 O3 (KFMASHTO), i.e. AFM + TiO2 + Fe2 O3 . The coronas reflect the tectonic unroofing of at least part of the Musgrave Complex from peak S1 conditions of about 8 kbar to S2 conditions of about 4 kbar. 相似文献
19.
The Barro Alto complex, central Brazil, is a layered mafic–ultramafic intrusion, which was subjected to granulite facies metamorphism during the Neoproterozoic. Ultra-high-temperature conditions are recorded by parageneses that occur in some lenses of quartz-bearing rock (metagranite, metapelite and impure quartzite). The peak paragenesis consists of spinel+quartz±cordierite±leucosome (recording the former presence of melt with quartz in excess), which is replaced by either orthopyroxene+sillimanite or garnet+sillimanite. Quartz+biotite±sillimanite±garnet symplectites are ubiquitous and indicate reactions between Fe–Mg phases and melt. Late kyanite porphyroblasts have overgrown these symplectites. The direct replacement of spinel+quartz±cordierite by orthopyroxene+sillimanite or garnet+sillimanite occurred around the [Sa] invariant point, which appears only in a petrogenetic grid with inverted topology. The topology inversion occurs at conditions of high oxygen fugacity or due to the presence of ZnO-bearing spinel. Minimum peak conditions of ultra-high-temperature metamorphism were calculated as c. 980 °C and c. 7.9 kbar. The succession of observed mineral textures can be explained by a near-isobaric cooling P–T path, with a cooling stage occurring between c. 980 and 750 °C. 相似文献