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1.
粤北佛冈岩体北缘的白沙岩体细粒黑云母二长花岗岩LA-ICP-MS锆石U-Pb加权平均年龄为130.3±3.0Ma,表明细粒黑云母二长花岗岩侵入于早白垩世。岩体高硅(SiO2=70.64~75.01wt%),高Na2O+K2O(7.62~8.33wt%),低P2O5(0.024~0.100wt%),富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、Ta、La、Ce、Sr、P和Ti等。明显富集轻稀土元素[(La/Yb)N=6.74~54.69],显示明显的负Eu异常(δEu=0.15~0.35),少量正Eu异常(δEu=0.82~1.19)。这些地球化学特征指示细粒黑云母二长花岗岩为高分异I型花岗岩。锆石Hf同位素研究结果表明,εHf(t)=-7.3^-10.6,其平均值为-8.89。其两阶段模式年龄(T2DM)主要为1654~1865Ma(n=8),平均值为1751Ma。佛冈复式岩体早白垩世细粒黑云母二长花岗岩形成于古太平洋板块向欧亚板块俯冲的陆缘弧构造背景下,其地球化学特征表明其物质主要来源于古元古代地壳的杂砂-泥质源岩部分熔融,并有少量幔源物质参与。  相似文献   

2.
本文对江西彭山锡多金属矿集区隐伏花岗岩体进行了详细的锆石U-Pb年代学、Hf同位素组成和岩石地球化学研究。SHRIMP和LA-ICP-MS锆石U-Pb定年表明,该岩体年龄为128~129Ma,属燕山晚期岩浆活动的产物。详细的地球化学分析显示,彭山隐伏花岗岩体具有高硅(SiO2=75.42%~76.46%)、富碱(Na2O+K2O=7.93%~8.35%,K2O/Na2O=1.32~1.61)的特征,极度贫Mg(普遍MgO=0~0.07%),贫Ca(CaO=0.37%~0.69%),弱过铝质(A/CNK=1.04~1.11),富集Rb、Th、U等大离子亲石元素及Hf、Nb等高场强元素,强烈亏损Sr、Ba、Eu、P、Ti。稀土总量偏低(∑REE=41.18×10-6~85.06×10-6),强烈的Eu负异常(Eu/Eu*=0.05~0.11)。104×Ga/Al比值变化于2.75~4.04,平均值为3.19。这些特征均不同于典型的A型和S型花岗岩。岩石学和地球化学特征指示该岩体可能是一个高分异的I型花岗岩。该花岗岩中锆石εHf(t)值偏高,主要集中在-0.6~-4.5,显示在成岩过程中有地幔组分的参与,属壳幔混源花岗岩,推测该岩体的形成可能与燕山晚期华南岩石圈伸展拉张环境有关。  相似文献   

3.
东昆仑可支塔格蛇绿混杂岩的地质地球化学特征   总被引：1，自引：0，他引：1  
东昆仑可支塔格蛇绿混杂岩属于木孜塔格-鲸鱼湖大断裂的西延部分,主要由辉橄岩、辉长岩、闪长岩、斜长花岗岩、辉绿岩、玄武岩及硅质岩等组成,形成时代为早石炭世。为构造强烈破坏的蛇绿混杂岩,形成于俯冲带环境,属SSZ型蛇绿岩。其中辉橄岩以相对低SiO2、TiO2、Al2O3和CaO、高MgO为特征,贫有色金属成矿元素,富集相容元素Cr、Ni、Co。稀土总量低,接近于球粒陨石稀土元素总量,以LREE略富集为特征。闪长岩SiO2、K2O含量较低,MgO、CaO、Na2O较高,稀土总量高,∑REE为90.95μg/g,LREE富集。斜长花岗岩SiO269.8%,Na2O>K2O,K2O/Na2O为0.78,A/CNK为1.68,具有大洋斜长花岗岩的岩石化学特征。闪长岩、斜长花岗岩的微量元素特征相似,表现为大离子亲石元素K、Sr、Rb、Ba相对富集,高场强元素Nb、Ta、Zr、Hf相对亏损。研究表明,辉橄岩来源于亏损的地幔岩,接近于强烈亏损的方辉橄榄岩,而明显不同于结晶分异作用成因的超镁铁质岩石。闪长岩、斜长花岗岩为蛇绿混杂岩的浅色岩组分,是地幔岩浆结晶分异的产物。  相似文献   

4.
曹玉亭  刘良  王超  杨文强  朱小辉 《岩石学报》2010,26(11):3259-3271
地球化学研究显示,阿尔金造山带南缘瓦石峡河附近塔特勒克布拉克二长花岗岩具有高硅(SiO2=63.62%～72.06%)、高碱(ALK=6.39～7.83)、过铝质(ASI=1.27～1.43)的特征,其稀土元素含量中等,Eu负异常较明显,轻稀土相对富集;在原始地幔标准化蛛网图上,大部分样品相对富集LREE、Rb、Th、U等大离子亲石元素,亏损Nb、Ta、Sr、P、Ti等高场强元素,指示其为壳源型高钾钙碱性系列的强过铝质S型花岗岩。锆石Hf同位素研究结果表明,其εHf(t)=-9.1～-10.5,两阶段Hf同位素模式年龄tDMC为1457～1553Ma,反映该花岗岩的源岩主要来自于地壳物质的重熔,其来源也相对单一。岩石中Nb/Ta、Zr/Hf、Th/U比值及高的CaO/Na2O比值(0.3),高的Al2O3、CaO和FeOT+MgO+TiO2总量,暗示该花岗岩是由中下地壳的杂砂岩经过黑云母脱水熔融形成的。较低的Al2O3/TiO2比值以及高的Y和Yb含量表明,该花岗岩的源岩是在较高的温度及较低的压力条件下部分熔融产生的,熔融的残留相可能为斜长角闪岩。阴极发光图像显示,该岩石中的锆石呈自形的长柱状,具有明显的岩浆环带结构,LA-ICP-MS微区原位U-Pb定年获得462±2Ma一组年龄,结合阴极发光图像和锆石微量元素特征(Th/U0.1),推断该年龄值为花岗岩的形成年龄。根据CaO/Na2O-Al2O3/TiO2图解和R1-R2构造判别图解,确定该花岗岩可能形成于碰撞造山后抬升初期。对比花岗岩形成年龄(462Ma)与阿尔金造山带南缘已获得的高压-超高压岩石变质年龄(～500Ma),可推断阿尔金瓦石峡南二长花岗岩形成于阿尔金造山带俯冲碰撞造山后应力释放的初级阶段,在该阶段地壳物质由于压力的降低从而发生部分熔融。  相似文献   

5.
北阿尔金西段出露大量中酸性侵入岩,为探讨西段地区花岗质岩石的成因、形成环境以及北阿尔金地区岩浆活动特点,本文选取北阿尔金西段的正长花岗岩体和闪长岩体作为研究对象,进行了岩石学、地球化学、锆石U-Pb年代学及Hf同位素等方面的研究。研究结果表明,正长花岗岩体形成时代为495.7～502.0Ma,铝饱和指数A/CNK为0.86～1.09小于1.1,P_2O_5与Si O_2含量呈负相关,具I型花岗岩特征。轻稀土富集而重稀土亏损,具有明显的负Eu异常,微量元素特征显示富集Rb、Ba、Th、U、K等元素,相对亏损Nb、Ta、P、Ti等元素。岩石地球化学及锆石Hf同位素特征暗示其源区物质成分不均一,源岩主要为0.95～1.4Ga的新生地壳(变中基性岩),并有1.42～1.83Ga的古老地壳物质的参与。闪长岩体的侵位时代为497.1±3Ma,轻稀土富集而重稀土亏损,较弱的负Eu异常,相对富集Rb、Ba、Th、U、K等元素,而亏损Nb、Ta、P、Ti。锆石ε_(Hf)(t)值为-1.61～+2.16,二阶段模式年龄t_(DM2)为1.34～1.56Ga,暗示其源岩可能主要为新生地壳,并有古老地壳物质参与成岩。北阿尔金西段正长花岗岩、闪长岩均形成于早古生代,具弧型花岗岩特点,结合区域构造背景,认为其形成可能与北阿尔金洋壳俯冲有关,产于陆弧环境。  相似文献   

6.
东昆仑东段哈图地区稀土元素富集与正长花岗岩关系密切。LA- ICP- MS锆石U- Pb同位素定年结果显示哈图正长花岗岩的结晶年龄为251. 6±1. 3 Ma。哈图正长花岗岩富硅（SiO2=74. 78%~75. 78%）和碱（Na2O+K2O=7. 68%~8. 11%），低铝（Al2O3=12. 58%~13. 06%），铝饱和指数A/CNK介于0. 96~1. 03之间，主体为准铝—弱过铝质中钾钙碱性系列。哈图正长花岗岩富集轻稀土元素，亏损重稀土元素，具较明显的Eu负异常（δEu=0. 67~0. 91）；微量元素富集Rb、Th、Ba、Cs等大离子亲石元素（LILE），亏损Nb、Ta、Ti等高场强元素（HFSE），具有较低的Nb/Ta比值和较高的Mg#值。以上显示，哈图正长花岗岩具壳源特征，为镁铁质岩浆底侵下地壳，使其部分熔融形成的原生岩浆再经过分异形成。哈图正长花岗岩具弧岩浆岩地球化学特征，结合东昆仑造山带岩浆岩分布以及沉积地层特征显示，早三叠世东昆仑地区处于布青山- 阿尼玛卿洋的俯冲阶段，大规模的岩浆事件引起东昆仑造山带东段稀土元素成矿作用。  相似文献   

7.
西藏改则蛇绿岩主要由地幔橄榄岩、均质辉长岩、玄武岩、玄武安山岩和斜长花岗岩组成。其中斜长花岗岩主要由石英、基性斜长石组成,SiO2含量较高,为72.18%～74.55%,Mg#均值为42,Na2O含量为1.30%～3.13%,K2O含量很低,为0.26%～0.67%,Na2O/K2O变化范围为3.64～8.23。斜长花岗岩和中基性岩(辉长岩、玄武岩和玄武安山岩)的元素地球化学特征表明,改则斜长花岗岩可能是由基性岩部分熔融形成的,并且斜长花岗岩富集Sr、Rb等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,具有岛弧型火山岩的特点,推测该斜长花岗岩形成于岛弧环境,是SSZ型蛇绿岩的组成单元。LA-ICPMS法测得斜长花岗岩中锆石U-Pb加权平均年龄为189.8±1.9Ma,表明班公湖-怒江缝合带改则地区在早侏罗世发生了俯冲作用,该区的俯冲消减时间要早于西段的班公湖地区,晚于东段丁青地区。  相似文献   

8.
滇西腾冲—梁河地区发育古近纪二长花岗岩和钾长花岗岩,记录了印度-欧亚大陆碰撞的岩浆活动信息。二长花岗岩的锆石U-Pb年龄为51.4±0.4 Ma,其176 Hf/177 Hf值为0.282554~0.282592,εHf(t)=-6.65~-5.30,其二阶段模式年龄为1.46~1.55Ga。腾冲—梁河古近纪花岗岩以高SiO2(68.96%~78.68%)、高K2O(4.56%~6.29%)和高Al2O3(12.40%~16.42%)为特征,K2O/Na2O值为0.93~7.24,Al2O3(K2O+Na2O),A/CNK值为0.99~2.31,属于富钾钙碱性偏铝—强过铝质花岗岩;绝大多数样品具有强烈的负Eu异常(Eu/Eu*为0.19~0.51),富集Cs、Rb,亏损Sr、P、Ti、Ba、Nb、Ta,具有Pb的正异常。元素地球化学特征指示,其主要源于区域上地壳变质杂砂岩的部分熔融;结合区域地质,认为腾梁地区62~51Ma的花岗岩是对印度-欧亚大陆碰撞高峰期的岩浆响应。  相似文献   

9.
阿尔金南缘清水泉地区与超基性岩及斜长花岗岩伴生的斜长角闪岩岩石地球化学组成显示:SiO_2和Al_2O_3含量较高,分别为47.63%~55.26%和16.42%~18.97%,Na_2O+K_2O含量低为4.91%~5.60%,MgO和Mg~#值较低为4.41%~5.72%和44.9~57.9,具有负Eu异常,其Mg#与Ti O2、Fe OT及Cr与Rb呈明显的相关性,表明岩石为地幔岩浆经分异演化形成。岩石富集大离子亲石元素Rb、Ba、Sr及Sm和Th,亏损高场强元素Nb、Ta、Zr、Hf、Yb、Y、Lu及Ti,且Th/Ta为2.61~18.121,Nb/La为0.21~0.661,指示岩石在演化过程中受到了陆壳的混染,推断岩石形成于裂谷环境。利用LA-ICP-MS微区原位定年获得斜长角闪岩中锆石206Pb/238U加权平均年龄为461±4 Ma,指示阿尔金南缘在中奥陶世早期处于伸展的构造动力学背景之下,为研究阿尔金构造带的形成及演化提供了新的证据。  相似文献   

10.
内容提要：滇西腾冲–梁河地区发育古近纪二长花岗岩和钾长花岗岩,记录了印度–欧亚大陆碰撞的岩浆活动信息。二长花岗岩的锆石U-Pb年龄为51.4±0.4Ma,其176Hf/177Hf比值为0.282554~0.282592,εHf(t)= -6.65~-5.30,其二阶段模式年龄为1.46~1.55Ga。腾冲–梁河古近纪花岗岩以高SiO2 (68.96%~78.68%)、高K2O (4.56%~6.29%)和高Al2O3(12.40%~16.42%)为特征,K2O/Na2O比值为0.93~7.24,Al2O3>(K2O+Na2O),A/CNK值为0.99~2.31,属于富钾钙碱性偏铝–强过铝质花岗岩;绝大多数样品具有强烈的负Eu异常(Eu/Eu*为0.19~0.51),富集Cs、Rb,亏损Sr、P、Ti、Ba、Nb、Ta,具有Pb的正异常。元素地球化学特征指示,其主要源于区域上地壳变质杂砂岩的部分熔融;结合区域地质,认为腾梁地区62~51Ma的花岗岩是对印度–欧亚大陆碰撞高峰期的岩浆响应。  相似文献   

11.
  相似文献   

12.
Radiogenic isotopes in fluid inclusions   总被引：7，自引：0，他引：7  
Igor M. Villa   《Lithos》2001,55(1-4):115-124
Radiogenic isotopes studied in fluid inclusions are still a limited field, with great potential for expansion as analytical techniques improve. The main limitation for Sr, Ar and He isotope work is the very small number of radiogenic atoms produced in a typical fluid inclusion. The requirements to analysts are correspondingly high. Examples show that isotopic tracing on fluid inclusion fluids can be a decisive tool in solving geological problems.  相似文献   

13.
硫、氧同位素和放射性同位素比值在示踪岩浆与围岩的反应及在岩浆镍-铜-铂族元素矿床成因中同化过程的重要性方面有很大作用。如1.1Ga的Duluth杂岩、Norilsk地区二叠-三叠纪侵入岩和1.4Ga的Kabanga侵入岩体中矿床的硫同位素测定结果证明硫来自含硫化物和硫酸盐的围岩。1.3Ga的VoisbeysBay矿床矿石的硫同位素δ34S值通常落入公认的地幔硫同位素组成范围(0±2‰)内,而对其元古宙变质沉积围岩进行的详细研究结果显示δ34S的平均值也在此范围。全面了解同位素组成的潜在混染对合理评价提供硫来源的围岩在矿石形成中的作用是非常必要的。用氧同位素和放射性同位素示踪岩浆和围岩相互作用时,必须在开放体系没有扰动同位素系统情况下进行。在氧同位素体系和放射性同位素体系(如Re/Os、Pb同位素体系)中,元素在热液条件下活动性强或主相没有发生同位素交换与吸收,都会导致低温热液过程掩盖高温过程。只有在进行详细的岩相观察和单矿物分析之后,再应用围岩混染同位素模式才是有意义的。  相似文献   

14.
Neoproterozoic chemostratigraphy   总被引：3，自引：0，他引：3  
Chemostratigraphy has diverse applications to investigating the rock record, such as reconstructing paleoenvironments, determining the tectonic setting of sedimentary basins, indirect dating, and establishing regional or global correlations. Chemostratigraphy is thus an integral component of many investigations of the ancient sedimentary record. In this contribution, we review the principle inorganic geochemical methods that have been applied to the Neoproterozoic sedimentary record. Analysis of the traditional stable and radiogenic isotope systems, such as δ13C, δ18O, δ34S, and 87Sr/86Sr, is routine, particularly in successions rich in carbonate. These mainstay applications have yielded invaluable data and information bearing on the chronology and evolution of this eventful era in Earth history. Alongside the growing database of traditional data, a series of novel geochemical techniques have given rise to important new models and constraints on Neoproterozoic biogeochemical change. In particular, a range of proxies for water column redox, mainly obtained from black shales, have shed light on the pace and tempo of Neoproterozoic oxygenation and its link to the appearance of early animal evolution. Increased integration of diverse geochemical, sedimentological, and paleontological datasets, and the gradual radiometric calibration of the stratigraphic record promise to bring the details of the evolution of the Neoproterozoic Earth system into ever greater focus.  相似文献   

15.
Pelagic deposits at Abadeh represent a complete biostratigraphic record across the Permian/Triassic boundary (PTB). The presumed water depth during deposition of these sediments was between 60 and 90 m. Similar to other Permian/Triassic boundary sections, the succession at Abadeh is characterised by a negative carbon isotope shift of approximately 4. The values start to decrease in the lower C. changxingensis - C. deflecta s.l. Zone, reach –0.12 (V-PDB) in the uppermost Permian just below the PTB, remain low to the early I. isarcica Zone (–0.32) and increase subsequently in the upper I. isarcica Zone. For the time interval of the PTB negative carbon isotope excursion, between the C. iranica and the I. isarcica Zones, no correlation exists between the 13Ccarb and the 18Ocarb. The above observations argue against the conclusion of Heydari et al. (2001) that the carbon isotope event at the P/T transition is an alteration artefact and not a global signal. The decrease in 13Ccarb is accompanied by a ~5 (and potentially up to 10) increase in 34SSSS. Together, these features are thought to reflect a complex global event, notably the development of widespread anoxic oceans with anoxic bottom layers rising onto the shelves. For the carbon isotope drop, other factors, such as the collapse of ocean primary productivity may also have played a role. The 87Sr/86Sr ratios of Dzhulfian seawater show only a minor increase from 0.70705 to 0.70710, reaching 0.70720 in the Dorashamian. The increase becomes steeper in the Early Triassic reaching 0.70754 in the N. dieneri Zone. The rise of the strontium isotope values is thought to be related to enhanced continental weathering under humid climatic conditions in the uppermost Permian (C. meishanensis - H. praeparvus Zone) and the lack of a dense land vegetation in the Early Triassic, prior to the Spathian (Upper Olenekian).  相似文献   

16.
In an effort to constrain the mechanism of dolomitization in Neogene dolomites in the Bahamas and improve understanding of the use of chemostratigraphic tracers in shallow‐water carbonate sediments the δ34S, Δ47, δ13C, δ18O, δ44/40Ca and δ26Mg values and Sr concentrations have been measured in dolomitized intervals from the Clino core, drilled on the margin of Great Bahama Bank and two other cores (Unda and San Salvador) in the Bahamas. The Unda and San Salvador cores have massively dolomitized intervals that have carbonate associated sulphate δ34S values similar to those found in contemporaneous seawater and δ44/40Ca, δ26Mg values, Sr contents and Δ47 temperatures (25 to 30°C) indicating relatively shallow dolomitization in a fluid‐buffered system. In contrast, dolomitized intervals in the Clino core have elevated values of carbonate associated sulphate δ34S values indicating dolomitization in a more sediment‐buffered diagenetic system where bacterial sulphate reduction enriches the residual in 34S, consistent with high sediment Sr concentrations and low δ44/40Ca and high δ26Mg values. Only dolomites associated with hardgrounds in the Clino core have carbonate associated δ34S values similar to seawater, indicating continuous flushing of the upper layers of the sediment by seawater during sedimentary hiatuses. This interpretation is supported by changes to more positive δ44/40Ca values at hardground surfaces. All dolomites, whether they formed in an open fluid‐buffered or closed sediment‐buffered diagenetic system have similar δ26Mg values suggesting that the HMC transformed to dolomite. The clumped isotope derived temperatures in the dolomitized intervals in Clino yield temperatures that are higher than normal, possibly indicating a kinetic isotope effect on dolomite Δ47 values associated with carbonate formation through bacterial sulphate reduction. The findings of this study highlight the utility of applying multiple geochemical proxies to disentangle the diagenetic history of shallow‐water carbonate sediments and caution against simple interpretations of stratigraphic variability in these geochemical proxies as indicating changes in the global geochemical cycling of these elements in seawater.  相似文献   

17.
Mineralogical, textural and geochemical investigations were made to determine the post-depositional evolution of Devonian and Early Carboniferous carbonates from Valle de Tena. The carbonate association is made up of low-Mg calcite, which occurs as micrite, spar cements, neomorphic patches and spar filling veinlets. Non-stoichiometric dolomite and ankerite occur as cements (dolomite also as replacements) in the Middle Devonian, post-dating calcite types. All these phases pre-date tectonic stylolites, indicating compaction after stabilization of the carbonate minerals. Strontium concentrations indicate that Early Devonian and Early Carboniferous micrites initially precipitated as aragonite; Middle and Late Devonian micrites precipitated as high-Mg calcites. Both precursors were diagenetically stabilized to low-Mg calcites through interaction with meteoric waters in phreatic environments. Trace elements in dolomite and ankerite indicate precipitation from Sr-enriched meteoric water. All studied carbonates, except Middle Devonian limestones, precipitated in reducing environments, which favoured incorporation of Fe and Mn. Late calcite generations precipitated from more saline waters than micrites. Light 18O values in micrites suggest alteration mainly in meteoric-phreatic environments. The dolomites and ankerites precipitated from more 18O-depleted fluids than the calcites, suggesting a greater contribution from meteoric waters. Variations in 13C of micrites represent primary secular trends, according to published 13C variations. The 13C oscillations within each succession probably relate to sea-level oscillations. Strontium isotopes also point to a meteoric origin of diagenetic fluids. Model calculations suggest that O and Sr isotopes equilibrated between calcites and fluid at relatively low water/rock ratios, whereas C isotopic signatures are inherited from limestones.  相似文献   

18.
Isotope data and trace elements concentrations are presented for volcanic and plutonic rocks from the Livingston, Greenwich, Robert, King George and Ardley islands (South Shetland arc, Antarctica). These islands were formed during subduction of the Phoenix Plate under the Antarctica Plate from Cretaceous to Tertiary. Isotopically (87Sr/86Sr)o ratios vary from 0.7033 to 0.7046 and (143Nd/144Nd)o ratios from 0.5127 to 0.5129. εNd values vary from +2.71 to +7.30 that indicate asthenospheric mantle source for the analysed samples. 208Pb/204Pb ratios vary from 38.12 to 38.70, 207Pb/204Pb ratios are between 15.49 and 15.68, and 206Pb/204Pb from 18.28 to 18.81. The South Shetland rocks are thought to be derived from a depleted MORB mantle source (DMM) modified by mixtures of two enriched mantle components such as slab-derived melts and/or fluids and small fractions of oceanic sediment (EM I and EM II). The isotopic compositions of the subduction component can be explained by mixing between at least 4 wt.% of sediment and 96 wt.% of melts and/or fluids derived from altered MORB.  相似文献   

19.
镁同位素地球化学研究新进展及其应用   总被引：7，自引：3，他引：4  
作为一种新兴的地质示踪剂,Mg同位素正受到国际地学界日益广泛的关注。Mg同位素地球化学研究已取得了巨大的进展,近期研究工作主要包括两个方面。首先,调查了地球各主要储库和陨石的Mg同位素组成特征,结果表明陨石和地球地幔具有均一并且相似的Mg同位素组成,平均δ26Mg值分别为-0.28±0.06‰和-0.25±0.07‰;相反,上地壳和水圈的Mg同位素组成很不均一,δ26Mg值变化范围分别为-4.84‰~+0.92‰和-2.93‰~+1.13‰。其次,对一些地质和物理化学过程中Mg同位素的分馏行为进行研究,结果表明:(1)地表风化作用可以造成大的Mg同位素分馏,导致重Mg同位素残留在风化产物中而轻Mg同位素进入水圈;(2)岩浆分异过程中Mg同位素平衡分馏很小;(3)高温化学扩散和热扩散过程中Mg同位素会发生显著的动力学分馏。基于这些研究成果,Mg同位素体系已经被初步应用于示踪早期地球形成和壳内物质再循环等过程,并有望在不久的将来应用于示踪大陆地壳的化学演化和地质温度计等研究领域。  相似文献   

20.
Lithological, chemical, and stable isotope data are used to characterize lacustrine tufas dating back to pre-late Miocene and later unknown times, capping different surfaces of a Tertiary carbonate (Sinn el-Kedab) plateau in Dungul region in the currently hyperarid south-western Egypt. These deposits are composed mostly of calcium carbonate, some magnesium carbonate and clastic particles plus minor amounts of organic matter. They have a wide range of (Mg/Ca)molar ratios, from 0.03 to 0.3. The bulk-tufa carbonate has characteristic isotope compositions: (δ13Cmean = −2.49 ± 0.99‰; δ18Omean = −9.43 ± 1.40‰). The δ13C values are consistent with a small input from C4 vegetation or thinner soils in the recharge area of the tufa-depositing systems. The δ18O values are typical of fresh water carbonates. Covariation between δ13C and δ18O values probably is a reflection of climatic conditions such as aridity. The tufas studied are isotopically similar to the underlying diagenetic marine chalks, marls and limestones (δ13Cmean = −2.06 ± 0.84‰; δ18Omean = −10.06 ± 1.39‰). The similarity has been attributed to common meteoric water signatures. This raises large uncertainties in using tufas (Mg/Ca)molar, δ13C and δ18O records as proxies of paleoclimatic change and suggests that intrinsic compositional differences in material sources within the plateau may mask climatic changes in the records.  相似文献   

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