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1.
黑龙江洋灰洞子斑岩型铜矿床地处兴蒙造山带东段、吉黑褶皱带北部,矿体主要赋存在花岗闪长斑岩和构造角砾岩中。为厘定洋灰洞子铜矿床的成岩成矿时代和构造背景,笔者对洋灰洞子花岗闪长斑岩进行了元素地球化学和LA--ICP--MS锆石U--Pb年代学的相关研究。岩石地球化学特征显示,花岗闪长斑岩富硅贫镁,属于过铝质钙碱性系列,富集轻稀土元素(LREE),(La/Yb)N=10.49~19.79,Eu显示弱负异常或正异常,高Sr低Y和Yb,富集大离子亲石元素(LILE),相对亏损高场强元素(HFSE),具有埃达克岩或埃达克质岩的特征。LA--ICP--MS锆石U--Pb测年结果显示,花岗闪长斑岩锆石206Pb/238U加权平均年龄为204.4±2.8 Ma和201.2±1.7 Ma。综合研究认为,洋灰洞子斑岩型铜矿床的成岩成矿时代可能为晚三叠世—早侏罗世之交,该矿床形成于古亚洲洋闭合后的陆陆碰撞造山环境,是加厚下地壳部分熔融形成的岩浆流体作用的结果。  相似文献   

2.
大黑山斑岩型钼矿花岗质岩体主要岩石类型为花岗闪长岩和花岗闪长斑岩,呈复式岩体状产出.含矿的花岗闪长斑岩体具有较高的Al2O3含量(A/CNK=1.04~1.25),较低的Mg指数(Mg#=21~44);轻重稀土分馏明显,没有或具有轻微的负铕异常(δEu=0.82~1),表明可能源区基本没有斜长石残留;富集大离子亲石元素Rb、Ba、Sr,相对亏损Nb、Ta、Y、Yb、Th、P和Ti,高Sr/Y、Sr/Yb比值,类似中国东部的"C型"埃达克岩.不含矿的花岗闪长岩A/CNK=1.01~1.03,轻稀土富集,重稀土亏损,中等的负铕异常(δEu=0.62~0.63),富集大离子亲石元素Rb、Th元素,亏损Nb、Ta、Zr等高场强元素,强烈亏损P和Ti元素相,比较低的Sr/Y、Sr/Yb比值.Hf同位素特征显示,大黑山花岗质岩体是由中—新元古代亏损地幔中增生的新生地壳,在中生代发生熔融而形成的.结合太平洋板块构造演化史以及近年获得的黑龙江杂岩碎屑锆石年龄和黑龙江群蛇绿混杂岩中蓝片岩相变质作用的年龄,表明太平洋板块晚三叠世—早侏罗世开始向西俯冲,说明大黑山花岗质岩体的形成与太平洋板块俯冲有关.  相似文献   

3.
西藏多不杂斑岩铜矿位于西藏北部,是青藏高原中部发现的第一个斑岩铜矿。多不杂斑岩铜矿内有两期花岗闪长斑岩和最晚期的闪长玢岩侵位,其中第二期侵位的花岗闪长斑岩是多不杂矿床的主要成矿斑岩。本文开展了多不杂矿床三期斑岩的锆石U-Pb年龄、全岩岩石地球化学和Sr-Nd-Hf同位素组成分析。锆石U-Pb测年结果显示,斑岩在120Ma集中侵位。较早侵位的两期花岗闪长斑岩均富集轻稀土、大离子亲石元素,亏损重稀土、高场强元素,Eu异常不明显,显示出岛弧岩浆岩的特征,均具有高Sr低Y的特征,(87 Sr/86 Sr)i值0.7057~0.7062和0.7059~0.7064,εNd(t)值为较小的负值(-2.5~-1.7和-6.2~-4.0),第二期花岗闪长斑岩的εHf(t)值为3.7~7.5,显示两期花岗闪长斑岩均属于类埃达克质岩石,可能起源于新生下地壳角闪岩相,有幔源物质混入。最晚侵位的闪长玢岩与两期花岗闪长斑岩岩石化学特征类似,但具有富钠特征,其MgO、Y、Yb等含量相对较高,可能表明闪长玢岩与花岗闪长斑岩源区相同,有更多幔源物质混入。多不杂斑岩铜矿可能形成于班公湖-怒江洋向北俯冲末期,可能产出于陆缘弧环境。  相似文献   

4.
波龙斑岩铜金矿床是近年来在青藏高原中部发现的最大的斑岩型矿床,波龙矿床发育两期花岗闪长斑岩和一期花岗斑岩,两期花岗闪长斑岩是波龙矿床的成矿斑岩。本文开展了波龙矿床三期斑岩锆石U-Pb年龄、全岩岩石地球化学和Sr-Nd-Hf同位素组成分析。锆石U-Pb测年结果显示,三期斑岩在120Ma集中侵位。两期花岗闪长斑岩均富集轻稀土、大离子亲石元素,亏损重稀土、高场强元素,Eu异常不明显,显示出岛弧岩浆岩的特征;两期花岗闪长斑岩的(87Sr/86Sr)i值分别为0.70562-0.70711和0.70567-0.70850,εNd(t)分别为-4.0--3.1和-8.0--2.4,εHf(t)值分别变化于2.5-6.9和3.3-6.9,表明两期花岗闪长斑岩起源于新生的下地壳;花岗斑岩也具有岛弧岩浆岩的岩石化学特征,但其具有较高εNd(t)值(-0.7--0.2)和εHf(t)值(1.3-12.2),可能表明花岗斑岩也起源于下地壳,但有更多幔源物质混入。波龙斑岩铜金矿床形成于班公湖-怒江洋壳向北俯冲末期,其成岩-成矿可能与洋壳俯冲关系密切,但波龙矿床的三期斑岩均起源于新生的下地壳,可能表明在120Ma南羌塘地块南缘开始逐步加厚。  相似文献   

5.
冯晓曦 《地质与勘探》2014,50(2):369-381
白乃庙铜钼矿是华北地块北缘最重要的大型铜钼矿,矿区中部花岗闪长斑岩与成矿关系密切。为探讨成岩成矿关系,笔者选取花岗闪长斑岩进行了LA-ICP-MS锆石U-Pb定年和岩石地球化学特征研究。花岗闪长斑岩测年分别为432.4±2.2 Ma、440.7±2.1Ma和443±1Ma,岩体侵位时代为早志留世,与铜矿石中辉钼矿Re-Os等时线年龄440.5±4.4Ma(待刊)基本一致。岩体属高钾钙碱性岩石组合系列,稀土曲线右倾,δEu 14.83~-19.54,弱亏损,富集Rb、Ba、Th、U、K,亏损Nb、Ta、Ti,具有岛弧花岗岩的地球化学性质。结合区域地质背景,认为白乃庙铜钼矿成矿与早志留世花岗闪长斑岩岩浆期后热液活动密切相关,成矿构造背景为早古生代古亚洲板块向华北板块俯冲形成的白乃庙古火山岛弧带。  相似文献   

6.
内蒙古太平川铜钼矿成矿斑岩时代、地球化学及地质意义   总被引:27,自引:9,他引:18  
内蒙古太平川Cu-Mo矿床位于得尔布干成矿带北段额尔古纳地区,为新近发现的斑岩型矿床。矿区内发育环带状热液蚀变,由内向外主要为硅化-绢云母化和泥化。热液蚀变围绕花岗闪长斑岩分布,Cu-Mo矿化主要受控于硅化-绢云母化蚀变,主要分布在花岗闪长斑岩中。本文获得成矿斑岩岩浆锆石U-Pb谐和年龄为202±5.7Ma,指示该矿床可能形成于晚三叠世。同时在样品中也发现继承锆石(784Ma),表明该地区可能存在晚元古基底。成矿斑岩的元素地球化学数据表明,主量元素SiO2(65.86%~68.84%)56%、Al2O3(15.18%~16.28%)15%、MgO(0.84%~1.06%)3%、Na2O/K2O1;微量元素亏损重稀土,Sr(471×10-6~513×10-6)400×10-6、Y(15.0×10-6~17.9×10-6)18×10-6、Yb(1.27×10-6~1.81×10-6)1.9×10-6,表明该花岗闪长斑岩具有明显的埃达克质岩石的地球化学特征。同时成矿斑岩具有相对高的SiO2、Yb含量和Th/Nb、Ce/Nb比值,而相对低的Al2O3、TiO2、MgO、Sr、Th含量和Th/Ce比值,这些特征与源于俯冲板片的埃达克岩相似。然而成矿斑岩(87Sr/86Sr)i(0.70943~0.71019)较大,εNd(t)为-3.4~-3.9,我们推测额尔古纳地块在岩浆上升过程中贡献了部分物质。结合区域构造演化,我们认为该矿区成矿斑岩岩浆形成于俯冲洋壳的部分熔融,矿床形成背景为早中生代蒙古-鄂霍茨克洋向额尔古纳地块俯冲的陆缘弧环境。  相似文献   

7.
针对对铜陵桂花冲花岗闪长斑岩进行岩石学、岩石地球化学及锆石U-Pb同位素年代学研究,结果表明该花岗闪长斑岩高硅富碱(w(SiO2)平均为63.60%,w(Na2O+K2O)平均为7.09%,K2O/Na2O为0.51~0.68),属高钾钙碱性系列岩石。岩石稀土总量低(ΣREE在187.43×10-6和209.19×10-6之间),但轻稀土富集而重稀土亏损(ΣLREE/ΣHREE为15.00~16.49,(La/Yb)N为22.37~28.45),且具弱负Eu异常(δEu在0.75~0.83,平均为0.80)。同时,岩石富集大离子亲石元素(Rb,Ba,Th和U),而亏损高场强元素(Nb和Ta)。锆石LA-ICP-MS U-Pb定年测得花岗闪长斑岩年龄为(138.3±1.4)Ma,表明该岩体的形成时代为早白垩世,与铜陵矿集区中生代主要成矿岩体的年龄(137.5 Ma±1.1Ma~151.8Ma±2.6Ma)一致。该花岗闪长斑岩形成于碰撞后构造环境,是由壳幔混合岩浆冷却结晶形成的。  相似文献   

8.
甘肃毛藏寺铜钼矿是与花岗质岩石有关的斑岩型矿床,矿区内花岗质岩石类型主要为似斑状二长花岗岩和花岗闪长岩。对矿区岩体进行年龄、地球化学研究,以约束其形成时代,并探讨岩石成因及其与成矿的关系。LA-ICP-MS锆石UPb测年分别获得似斑状二长花岗岩与花岗闪长岩谐和年龄为455.8±3.1Ma和425.0±2.8Ma,属于晚奥陶世和晚志留世岩浆活动的产物。地球化学数据显示,似斑状二长花岗岩属于过铝质钙碱性岩浆系列,花岗闪长岩属于准铝质高钾钙碱性岩浆系列,二者均富集大离子亲石元素,亏损高场强元素,稀土元素配分曲线呈右倾型,轻、重稀土元素分馏明显。似斑状二长花岗岩具有弱正Eu异常(δEu=1.18~1.24),显示埃达克岩的地球化学特征,形成于北祁连洋俯冲消减阶段,由俯冲洋壳(含海洋沉积物)部分熔融形成,源区主要残留物为石榴子石。花岗闪长岩显示弱负Eu异常,形成于碰撞后伸展环境,是洋壳板片断离后软流圈上涌诱发的下地壳玄武质岩石部分熔融的产物。似斑状二长花岗岩符合成矿期埃达克岩特征,具有较好的成矿条件。结合前人资料,在北祁连东段寻找和勘查与埃达克岩有关的铜-钼-金矿可能是一个新的方向。  相似文献   

9.
北部拉萨地块晚中生代的地壳生长时间和机制存在争论。本文报道了北部拉萨地块的改则亚多侵入体的年代学、地球化学资料。改则亚多侵入体形成于早白垩世晚期(~106 Ma),其岩石类型包括二长闪长岩、闪长岩、花岗闪长斑岩、花岗斑岩。岩石属于钙碱性系列岩石,显示轻稀土富集,Nb和重稀土亏损,其中花岗闪长斑岩、花岗斑岩显示了埃达克质岩的地球化学特征。主体岩石样品具有一致的εNd(t)(2.65~1.42)和(~(87)Sr/~(86)Sr)i(0.7045~0.7049)。二长闪长岩、闪长岩由俯冲流体交代的地幔橄榄岩熔融产生的玄武质岩浆经过地壳混染和分离结晶作用形成。花岗闪长斑岩、花岗斑岩由增厚的新底侵玄武质下地壳熔融形成。早白垩世晚期(118~105 Ma),俯冲的班公湖–怒江特提斯洋岩石圈板片后撤过程中,诱发软流圈上涌,导致其上覆地幔熔融或其自身发生减压熔融,来自亏损地幔的岛弧岩浆连续底侵加入到北部拉萨地块的地壳或喷出地表,导致了该区在晚中生代的地壳生长。  相似文献   

10.
哈日扎铜钼多金属矿床位于东昆仑成矿带东段,是大型斑岩型铜钼多金属矿床.笔者利用锆石LA-ICP-MS U-Pb法,获得花岗闪长斑岩的成岩年龄为(234.5±4.8) Ma(MSWD=0.24);花岗闪长斑岩为其成矿母岩.对哈日扎花岗闪长斑岩的岩石学和地球化学研究表明,花岗闪长岩富SiO2(70.94%~76.08%)、K2O(4.91% ~6.07%),贫CaO(0.16% ~2.01%)、Na2O(0.24% ~0.78%),属钾玄岩系列及高钾钙碱性系列.稀土元素总量变化较大(124.69×10-6~178.68×10-6),稀土元素配分曲线为平缓的右倾型,轻稀土元素相对富集,重稀土元素相对亏损.δEu变化范围0.26~0.30,具有弱负Eu异常.岩石微量元素相对富集大离子亲石元素(LILE),贫高场强元素(HFSE),即相对富集Rb、U、La和Nd,而亏损Ba、Sr、Nb和Y.花岗闪长斑岩形成于同碰撞构造环境.  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

14.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

15.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

16.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

17.
18.
We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al2O3-SiO2 ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.  相似文献   

19.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

20.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

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