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1.
新疆东昆仑鸭子泉蛇绿岩的基本特征及其大地构造意义 总被引：19，自引：2，他引：17
鸭子泉蛇绿岩位于新疆东昆仑祁漫塔格山系中部, 与阿尔金断裂平行产出, 由超基性岩、基性岩和拉斑玄武岩等组成。它侵位于早石炭世含放射虫的深海沉积物中, 可能代表了东昆仑祁漫塔格地区晚古生代的板块俯冲带。蛇绿岩可能来源于俯冲带附近的由小型扩张中心形成的次生洋壳, 之后由于消减作用, 侵位到深海沉积物中, 形成了造山带中的蛇绿岩。 相似文献
2.
东昆仑祁漫塔格山西段鸭子泉志留纪火山岩特征 总被引：4，自引：0，他引：4
在新疆阿牙克库木湖幅一比二十五万区域地质调查中，于东昆仑祁漫塔格山鸭子泉构造混杂岩带中发现大量以蚀变玄武岩、蚀变玄武安山岩、蚀变安山岩及蚀变辉长岩、蚀变闪长岩为主的中基性火成岩，其呈大小不一的岩片岩块存在于构造混杂岩带内。通过岩石学、岩石地球化学的研究其属钙碱性岩系的玄武岩-安山岩；具有稀土总量较低、轻稀土弱富集、重稀土分馏不明显、稀土元素配分曲线呈右倾型、大离子亲石元素富集、Nb、Ti等元素亏损的特征，显示其形成于与俯冲作用有关的岛弧环境；依据同位素测年资料和地质构造演化确定该岛弧火山岩就位于志留纪，这对东昆仑地区的地质构造演化具有重要意义。 相似文献
3.
新疆阿尔泰南缘达拉乌兹双峰式火山岩年龄及岩石成因 总被引：4，自引：3，他引：1
阿尔泰南缘达拉乌兹一带出露了一套玄武岩和流纹岩频繁互层的双峰式火山岩组合。该套双峰式火山岩发生了绿片岩相变质作用,其基性端元——变质玄武岩和酸性端元——变质流纹岩具明显的变余斑状结构。利用LA-ICP-MS锆石U-Pb法获得流纹岩的喷发年龄365.6±1.6Ma和捕获的锆石年龄413.5±2.0Ma。变质玄武岩富TiO2、碱(富钠)(Na2O/K2O=4.43～19.33)和FeOT,贫MgO和CaO,轻微富集LILE和LREE,具弱的Nb、Ta和Ti的负异常,具有高于正常弧火山岩但低于OIB的HFSE元素(Nb、Ta、Zr、Hf)的含量,Eu负异常不明显。流纹岩具有高SiO2和全碱,具有低的TiO2、极低的MgO和FeOT,呈现明显的Ti、P、Sr、Ba负异常,Th、U、Pb的正异常,HFSE元素(Zr、Hf)和LREE略富集但Nb、Ta亏损的特征,并显示Eu的明显负异常(δEu=0.21～0.41)。它们均具有相似于N-MORB的较低的Pb同位素组成。玄武岩与流纹岩来自两个不同的岩浆房,玄武岩为受俯冲物质加入的亏损软流圈地幔部分熔融后并发生结晶分异作用的结果,流纹岩为新生的地壳物质受幔源岩浆加热熔融并与之混合后演化的产物。结合阿尔泰南缘地区的构造演化特征,推测该双峰式火山岩俯冲作用引起的局部拉张作用的产物。 相似文献
4.
祁漫塔格构造带是东昆仑造山带的重要组成部分,在青藏高原北部早古生代汇聚板块边缘地质研究中具有重要意义。祁漫塔格构造带在早古生代通常被认为是弧或弧后盆地,但其早期形成阶段的地质记录尚未报道,初始俯冲的时代也有待进一步限定。本文选择了祁漫塔格东段拉陵高里河地区祁漫塔格群火山岩和闪长岩进行岩石学、地球化学、锆石U-Pb年龄学和Hf同位素研究,探讨了岩石成因和构造意义。火山岩以安山岩为主,安山岩SiO2含量中等(54.02%~63.99%),具有低TiO2(0.19%~0.24%)、Al2O3(10.67%~12.86%)、P2O5(0.03%~0.05%)和低FeOT/MgO比值(0.80%~1.04)的特征,具有高的MgO(7.86%~11.44%)和Mg#(63~69);闪长岩SiO2含量为53.62%~55.81%,也具有低TiO2(0.19%~0.25%)、Al2O3(10.58%~11.52%)、P2O5(0.02%~0.04%)和低FeOT/MgO比值(0.9~1.0)的特征,同样具有高的MgO(9.86%~11.63%)和Mg#(64~66)的特点。高镁安山岩和闪长岩微量元素组成相近,Th(0.22~1.23 μg/g)、Rb(4.11~16.11 μg/g)和Ba(66.7~166 μg/g)含量低,Cr(286~668 μg/g)和Ni(57~181 μg/g)含量高,δEu=0.91~1.47,Sr/Y比值(19.7~36.1)较低,∑REE含量介于11.8~27.3 μg/g,(La/Yb)N = 1.3~4.3,轻重稀土分馏弱。在微量元素原始地幔标准化图解上大离子亲石元素Sr、Ba和Pb具明显的正异常,高场强元素Ta、Nb和Ti具有明显的负异常。高镁安山岩LA-ICP-MS 锆石U-Pb同位素年龄为519 Ma;闪长岩LA-ICP-MS 锆石U-Pb同位素年龄为520 Ma和516 Ma,两者锆石Hf同位素组成相似,εHf(t)值分布在+10.5~+15.8。上述研究结果表明,祁漫塔格东段拉陵高里河地区高镁安山岩/闪长岩源于亏损的地幔楔的部分熔融,形成于原特提斯洋俯冲早期的岛弧环境。本研究进一步证明祁漫塔格构造带古洋盆俯冲时代早于520 Ma,该认识也为恢复东昆仑造山带原特提斯洋早期俯冲演化历史提供了重要地质资料。 相似文献
5.
祁漫塔格位于东昆仑西段,对该地区晚三叠世火成岩的研究不仅有助于认识东昆仑造山带印支期构造—岩浆演化历史,而且为古特提斯洋俯冲时限及洋盆闭合时限提供约束。本次在克停哈尔南的二长花岗岩中获得了219.8±0.5 Ma的锆石U-Pb年龄,结合以往获得的年龄数据,可以确定该期火成岩为晚三叠世岩浆活动的产物。全岩地球化学分析结果显示,祁漫塔格东段晚三叠世火成岩为准铝到弱过铝质岩石,属高钾钙碱性系列,富集轻稀土和Rb、Th、K等大离子亲石元素,不同程度亏损Nb、Ta、P、Ti等高场强元素,具有明显的铕负异常,显示板块俯冲阶段的特征。花岗岩与流纹岩具有相似的Nd、Pb同位素组成,花岗岩ε_(Nd)(t)值介于-4.66～-4.53之间,亏损地幔模式年龄T_(DM2)为1363～1375 Ma,流纹岩ε_(Nd)(t)值为-4.63,T_(DM2)=1368 Ma。在n(~(143)Nd)/n(~(144)Nd)—n(~(206)Pb)/n(~(204)Pb)图解和Pb同位素组成图解中投影点均位于上地壳和EMII地幔端元附近。祁漫塔格东段晚三叠世花岗岩与流纹岩空间分布关系密切,形成时间相近,主、微量元素和Nd、Pb同位素特征方面都具有相似性或一致性,因此,笔者认为它们为同一时期、同一构造环境下的同源岩浆产物。结合区域资料和本文研究,初步分析认为东昆仑地区该时期处于板块俯冲阶段的活动大陆边缘弧环境,古特提斯洋尚未完全闭合。 相似文献
6.
西藏唐加地区甲拉浦组中发育高镁安山岩,通过对其样品U-Pb年代学和地球化学特征分析结果显示,唐加地区甲拉浦组高镁安山岩U-Pb年龄为197.1±2.9 Ma,时代为早侏罗世.地球化学特征显示,甲拉浦组高镁安山岩属于钾钙碱性系列,w(SiO2)在53.04％～54.53％之间,w(MgO)为4.98％～6.18％,w(Al2O3)为17.17％～17.54％,w(CaO)为7.00％～11.34％,FeOT/MgO为1.26～1.48,平均值为1.33,Mg#值为58.7～62.5,平均值为61.2.样品显示轻稀土元素富集,Eu微负异常,大离子亲石元素Rb,Ba,Pb富集,Nb,Ta,Ti等高场强元素亏损.由此可知,唐加地区早侏罗世甲拉浦组高镁安山岩形成于与俯冲消减有关的构造背景,是新特提斯洋北向俯冲洋壳部分熔融的产物. 相似文献
7.
东昆仑喀雅克登塔格晚泥盆世花岗闪长岩的发现与地质意义 总被引：3，自引：0，他引：3
东昆仑西部祁漫塔格喀雅克登塔格地区地质研究程度低,特别是未曾有晚泥盆世侵入岩的报道或记录。本次工作识别出晚泥盆世花岗闪长岩的存在,经LA-ICP-MS锆石U-Pb同位素定年,其形成时代为(380.52±0.92)Ma,即晚泥盆世。这一发现打破了东昆仑造山带加里东造山旋回幔源岩浆底侵作用发生在早泥盆世(408Ma)—中泥盆世(386Ma)的认识,进而将幔源岩浆底侵作用一直延续至晚泥盆世380Ma,为细化东昆仑西部祁漫塔格加里东造山旋回晚泥盆世的构造背景奠定了基础;喀雅克登塔格晚泥盆世花岗闪长岩产于祁漫塔格加里东造山带后造山伸展崩塌的晚期阶段幔源岩浆底侵作用的构造背景。 相似文献
8.
呼斯特岩体是新疆西天山博罗科努岛弧带上的一个与矽卡岩成矿有关的复式杂岩体,由二长花岗岩、花岗闪长岩、正长花岗岩、花岗细晶岩、闪长玢岩、辉长岩和中基性包体等组成。本文对该岩体不同岩相岩石开展了岩石学、锆石LAICP-MS U-Pb同位素定年和Hf同位素研究,探讨岩石成因及构造意义。锆石U-Pb定年结果表明,正长花岗岩、闪长玢岩、花岗闪长岩和二长花岗岩加权平均年龄分别为380.2±4.6Ma、372.8±5.9Ma、367.7±4.5Ma和366.2±4.5Ma,岩体侵位时代为晚泥盆世,在大约15Myr期间,至少发生了3~4次岩浆侵入。在地球化学组成上,除辉长岩外,岩体为准铝质-弱过铝质、高钾钙碱性-低钾(拉斑)系列的I型花岗岩,轻重稀土分馏明显,具Eu负异常;富集Th、U,亏损Ba、P和高场强元素(如Nb、Ta、Zr、Ti),为晚古生代北天山洋向南俯冲于伊犁地块背景下岩浆活动的产物。二长花岗岩锆石Hf同位素组成较为均一,εHf(t)值为1.3~3.0,二阶段Hf模式年龄为1171~1280Ma,远大于成岩年龄,说明原始岩浆从地幔分异后经历了较长时间的地壳滞留。研究认为,高钾中酸性岩(花岗岩、闪长玢岩和中基性包体)由元古代新生基性下地壳部分熔融而成,伴有受俯冲沉积物熔体交代的幔源岩浆混合。低钾花岗闪长岩高Sr、低Y和Yb,属O型埃达克岩,与同源的辉长岩一起由俯冲的大洋板片部分熔融形成,源岩为低钾的拉斑玄武岩。 相似文献
9.
祁漫塔格韧性剪切带是祁漫塔格蛇绿混杂岩带与北昆仑岩浆弧的区域主构造边界,对剪切带内花岗质糜棱岩中绢云母40Ar-39 Ar法年龄测定,获得了(271.1±2.2) Ma的坪年龄,相应的36Ar/40 Ar-39 Ar/40 Ar反等时线年龄为(270.5±3.7)Ma (MSWD=2.7),39Ar/36 Ar-40 Ar/35 Ar正等时线年龄为(270.9±4.7) Ma (MSWD=0.22);坪年龄(271.1±2.2) Ma接近于绢云母矿物的形成年龄,也代表了祁漫塔格韧性剪切带的形成年龄.通过韧性剪切变形带内运动学特征的研究,表明剪切带具有右旋斜冲的性质.祁漫塔格韧性剪切带的形成与古特提斯洋的俯冲作用有关,是古特提斯洋向北俯冲造山过程的远程效应. 相似文献
10.
青海野马泉矽卡岩铁锌多金属矿区侵入岩、交代岩及矿化蚀变特征 总被引：1，自引：0，他引：1
野马泉铁锌多金属矿床位于柴达木盆地西南缘和青海祁漫塔格山之间的盆山结合部位.矿区出露有印支期及海西期侵入岩.矿区内矽卡岩呈层状、似层状产于上石炭统四角羊沟组中,矽卡岩矿物主要是石榴子石、单斜辉石、角闪石、绿帘石、符山石等;金属矿物主要有磁铁矿、黄铜矿、黄铁矿、闪锌矿等.文章基于详细野外地质调查、剖面和钻孔岩芯观察结果,开展了侵入岩和交代岩的岩石地球化学及矽卡岩矿物学的系统研究.结果表明,野马泉矿区闪长岩具有低w(SiO2) (51.90％～59.03％)、高w(MgO) (2.04％～3.44％)、w(TFeO)(5.33％～11.67％),高REE[(318.57×10-6～327.67×10-6)],低LREE/HREE比值(7.36～7.48)的特点;二长花岗岩具有高w(SiO2) (77.36％ ～77.41％)、低w(MgO)(0.04％～0.10％)、w(TFeO) (0.76％～1.08％)的特点,LREE/HREE比值较高(9.14～9.37).透辉石-钾长石交代岩比原岩低w(MgO)(1.17％ ～ 2.86％)、低w(TFeO)(3.89％～7.76％),且具有更强的Eu负异常(δEu=0.07～0.52),LREE/HREE比值更低(3.19～7.87).透辉石-钠长石交代岩相对原岩具有低w(MgO) (0.36％～0.92％)、高w(TFeO)(3.05％ ～8.13％)的特点.野马泉矿区的矽卡岩包括钙矽卡岩和锰质矽卡岩,钙矽卡岩主要产于接触带附近,组成矿物主要为单斜辉石和石榴子石,接近岩体的单斜辉石中透辉石端员组分较高,石榴石主要分布在接触带附近,内环带钙铁榴石组分高于外环带.综合矿物学、岩石地球化学结果,推断野马泉矿区闪长岩具有较大成矿潜力,野马泉矿区钙矽卡岩主要形成于氧化条件,锰质矽卡岩形成于还原条件. 相似文献
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
12.
奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
13.
S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
15.
Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA 总被引：1，自引：0，他引：1
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources. 相似文献
16.
《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
17.
18.
S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
19.
The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km2 area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which
are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite
and quartz veins.
The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock,
alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite,
volcanic tuff, phosphatic rock and chert breccia.
The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow
level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly
alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic
than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits
with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other
as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate
and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction
with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ18O and δ13C) on carbonatites of Samchampi have indicated that the δ13C of the source magma is related to contamination from recycled carbon. 相似文献