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1.
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2.
A great deal of early-to-mid Early Cretaceous magmatic activities have been recorded in the Zhalantun area of Inner Mongolia,while the late Early to Late Cretaceous magmatic rocks have been barely reported(Guo et al.,2018;Zhang Xiangxin et al.,2017).At present,only a few Late Cretaceous magmatic activities were reported in the Arongqi area,such as volcanic rocks of the Gushanzhen Formation.However,the Gushanzhen Formation lacks accurate isotopic age,and contemporaneous intrusive rocks has not been reported yet.In this work,we collected the volcanic rocks from the Gushanzhen Formation and contemporaneous intrusive rocks in the Zhanlantun and nearby,and aim to figure out the formation ages of volcanic rocks of the Gushanzhen Formation and accompanied intrusive rocks by analyzing zircon U-Pb isotopes(Fig.1).  相似文献   

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4.
<正>Objective The Susong complex zone(SCZ)is a relatively lowgrade metamorphic unit mostly with an epidoteamphibolite facies,located in the southernmost part of the Dabie orogen.However,its rock compositions,ages,metamorphic processes and petrogenesis are still  相似文献   

5.
A new style of komatiite-associated sulfide-poor platinum-group element (PGE: Os, Ir, Ru, Rh, Pt, Pd) mineralisation has been identified at Wiluna in the strongly nickel sulfide (NiS) mineralised Agnew – Wiluna Greenstone Belt, Western Australia. The komatiite sequence at Wiluna is ～200 m thick and comprises a basal pyroxenite layer, a thick ortho-to-mesocumulate-textured peridotite core, which is overlain by rhythmically layered wehrlite, oikocrystic pyroxenite and thick upper gabbroic margins. Pegmatoid and dendritic (harrisitic) domains are common features, whereas spinifex-textured horizons and flow-top breccias are absent. The presence of anomalous PGE-enriched horizons (ΣPt – Pd = 200 – 500 ppb) in the oikocrystic pyroxenite and in the layered melagabbro and gabbronorite horizons directly overlying the wehrlite unit is due to the presence of fine-grained (1 – 10 μm) platinum-group minerals (PGMs). More than 70 PGM grains were identified, and a considerable mineralogical variability was constrained. However, only Pd – Pt-bearing phases were identified, whereas no Ir – Ru-bearing PGMs were found in any of the sections examined. Interestingly, all PGMs are not in paragenetic association with sulfides, and only sulfide-poor/free intervals contain significant PGM concentrations. The whole-rock PGE sequence largely reflects the PGM distribution. It is hypothesised that the Pd – Pt enrichment in the oikocrystic pyroxenite and melagabbros and the overall Ir – Ru depletion in the upper mafic section of the sequence are the result of extensive olivine and chromite crystallisation in the basal ultramafic section. PGE saturation was driven by extensive crystallisation of silicate and oxide phases in a sulfide-undersaturated environment. The crystallisation of clinopyroxene in the oikocrystic pyroxenite horizon may have triggered the formation of Pt – Pd-bearing alloys and arsenides, which were the first PGMs to form. Stratiform sulfide-poor PGE mineralisation at Wiluna is more similar in stratigraphic setting, style and composition to PGE-rich sulfide-poor mineralisation zones in thick differentiated intrusions, rather than to other PGE-enriched zones in komatiite-hosted systems, where PGE enrichment is directly associated with accumulations of magmatic sulfides.  相似文献   

6.
This paper presents an approach conducive to an evaluation of the probability density function (pdf) of spatio-temporal distributions of concentrations of reactive solutes (and associated reaction rates) evolving in a randomly heterogeneous aquifer. Most existing approaches to solute transport in heterogeneous media focus on providing expressions for space–time moments of concentrations. In general, only low order moments (unconditional or conditional mean and covariance) are computed. In some cases, this allows for obtaining a confidence interval associated with predictions of local concentrations. Common applications, such as risk assessment and vulnerability practices, require the assessment of extreme (low or high) concentration values. We start from the well-known approach of deconstructing the reactive transport problem into the analysis of a conservative transport process followed by speciation to (a) provide a partial differential equation (PDE) for the (conditional) pdf of conservative aqueous species, and (b) derive expressions for the pdf of reactive species and the associated reaction rate. When transport at the local scale is described by an Advection Dispersion Equation (ADE), the equation satisfied by the pdf of conservative species is non-local in space and time. It is similar to an ADE and includes an additional source term. The latter involves the contribution of dilution effects that counteract dispersive fluxes. In general, the PDE we provide must be solved numerically, in a Monte Carlo framework. In some cases, an approximation can be obtained through suitable localization of the governing equation. We illustrate the methodology to depict key features of transport in randomly stratified media in the absence of transverse dispersion effects. In this case, all the pdfs can be explicitly obtained, and their evolution with space and time is discussed.  相似文献   

7.
We synthesize reaction rims between thermodynamically incompatible phases in the system MgO-Al2O3-SiO2 applying uniaxial load using a creep apparatus. Synthesis experiments are done in the MgO-SiO2 and in the MgO-Al2O3 subsystems at temperatures ranging from 1150 to 1350 °C imposing vertical stresses of 1.2 to 29 MPa at ambient pressure and under a constant flow of dry argon. Single crystals of synthetic and natural quartz and forsterite, synthetic periclase and synthetic corundum polycrystals are used as starting materials. We produce enstatite rims at forsterite-quartz contacts, enstatite-forsterite double rims at periclase-quartz contacts and spinel rims at periclase-corundum contacts. We find that rim growth under the “dry” conditions of our experiments is sluggish compared to what has been found previously in nominally “dry” piston cylinder experiments. We further observe that the nature of starting material, synthetic or natural, has a major influence on rim growth rates, where natural samples are more reactive than synthetic ones. At a given temperature the effect of stress variation is larger than what is anticipated from the modification of the thermodynamic driving force for reaction due to the storage of elastic strain energy in the reactant phases. We speculate that this may be due to modification of the physical properties of the polycrystals that constitute the reaction rims or by deformation under the imposed load. In our experiments rim growth is very sluggish at forsterite-quartz interfaces. Rim growth is more rapid at periclase-quartz contacts. The spinel rims that are produced at periclase-corundum interfaces show parabolic growth indicating that reaction rim growth is essentially diffusion controlled. From the analysis of time series done in the MgO-Al2O3 subsystem we derive effective diffusivities for the Al2O3 and the MgO components in a spinel polycrystal as ${\rm D}_{MgO} = 1.4 \pm 0.2 \cdot 10^{-15}$  m2/s and ${\rm D}_{Al_2O_3} = 3.7 \pm 0.6 \cdot 10^{-16}$  m2/s for T?=?1350 °C and a vertical stress of 2.9 MPa.  相似文献   

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9.
The occurrence of landslide in the hilly region of Darjeeling during monsoon season is a matter of serious concern. Every year this natural hazard damages the major roads at several places and thus disrupts the transport and communication system in this region. This paper tries to prepare a landslide susceptibility zone (LSZ) map for the Gish River basin. A total number of 16 spatial parameters have been taken for this study and these are categorised under six factor clusters or groups for example, triggering factors, protective factor, lithological factors, morphometric factors, hydrological factors and anthropogenic factors. The LSZ map is prepared by integrating all the parameters adopting the weighting base as logistic regression. The landslide susceptibility map shows that nearly 9.11% of the area falls under the very high landslide-susceptible zone while 40.28% of the area of the total basin lies under the very low landslide-susceptible zone. The landslide-susceptible model is validated through the receiver operating characteristic curve. This curve shows 86% success rate in defining landslide-susceptible zones and 83.40% prediction rate for the occurrence of landslides. The spatial relationship between the landslide susceptibility model and other factors’ groups shows that the morphometric factors’ cluster (mainly slope) is the focalone for the determination of landslide-susceptible zone.  相似文献   

10.
On the Elimination of Bias Averaging-Errors in Proxy Records   总被引：2，自引：2，他引：0  
Knowledge of and insight into past environmental conditions can be obtained by processing and analyzing proxies. The proxies need to be processed as precisely and accurately as possible, otherwise the conclusion of the analysis will be biased. A calibration method which reduces bias errors in the proxy measurements due to averaging is presented. Sampling with nonzero sample sizes causes an averaging of the true proxy signal over the volume of the sample. The method is applied on a linear synthetic record which results in an optimal correction for frequency components ranging from the dc-frequency (DC) to one half of the sample frequency (f s /2). Next, the method is tested on non-linear synthetic data where the signal is reconstructed reasonably well. Finally, the method is applied to a real vessel density record of R. mucronata from Makongeni, Kenya, and to a real delta deuterium record of ice core EDC from dome C, Antarctica. The method discussed in this paper is a valuable tool for the calibration of proxy measurements; it can be applied as a correction for low resolution measurements and expanded to other types of samples and proxies. Working with small sample sizes (high resolution) amounts to working near the detection limit, where the signal-to-noise-ratio is low. This correction method provides an alternative in which low resolution measurements can be upgraded to minimize the loss of information due to larger sample sizes.  相似文献   

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12.
Mg-rich and Fe-rich metatholeiites intruded the Willyama Supergroup of the southern Australian Curnamona Province in the Late Palaeoproterozoic at ca 1700 Ma and 1685 Ma, respectively. Intrusion of the Fe-rich metatholeiites occurred during a period of punctuated extension in the Willyama basin. Major-element concentrations are variable (SiO2 45.4 – 56.5 wt%; Fe2O3? 8.5 – 20.7; TiO2 0.46 – 2.52 wt%; Mg# 70.5 – 29.1) and, in conjunction with trace-element data, support near-closed-system fractionation of a mantle-derived melt with little or no replenishment. Fractionation produced progressively Fe-rich derivative melts. Crystallising phases were dominated by clinopyroxene and olivine, whereas Fe – (Ti) oxide crystallisation was hindered. Primitive mantle-normalised immobile trace elements are characterised by variable Th, Nb, Sr, P and Ti anomalies. Chondrite-normalised rare-earth element patterns for the most primitive, Mg-rich samples from the western Broken Hill Domain have LaN/SmN < 1, whereas the most evolved Fe-rich samples from the Olary Domain have ratios of LaN/SmN > 1. Initial εNd values range between – 2.2 and + 2.7 for the majority of the samples, with the isotopic compositions showing no correlation with differentiation or assimilation. The combined geochemical and isotopic data suggest that the southern Curnamona Province metatholeiites were extracted from a depleted mantle in the western Broken Hill Domain, and a variably enriched, heterogeneous subcontinental lithospheric mantle in the Olary Domain. Magmatism most likely occurred in a backarc basin or intracontinental setting. It is speculated that the geochemically enriched mantle component was derived from subduction-related processes, probably related to pre-Willyama basin accretionary processes along the southern and eastern margins of the North Australian Craton.  相似文献   

13.
New geochemical, isotopic, and geochronological data and interpretations are presented for late Neoproterozoic intrusive carbonates and related rocks of southern Sinai, Egypt (northernmost Arabian–Nubian Shield). The Tarr carbonates are coarsely crystalline and related to explosive emplacement of hypabyssal and volcanic albitite at 605 ± 13 Ma. The carbonates associated with the albitites are divisible into two types: primary dolomitite and secondary breunneritite (Fe-rich magnesite). The dolomitite was clearly intrusive but differs from classic igneous carbonatites, containing much lower abundances of incompatible elements, such as REE, U, Th, Rb, Nb, Y, P, Sr, Zr, Ba, and total alkalies. The breunneritite is a secondary replacement of dolomitite, probably marking the roots of a vigorous hydrothermal system. Albitites show pristine abundances of major and trace elements and were not subjected to a major metamorphic overprint. They are relatively more fractionated, alkaline and related to within-plate A-type magmas, were emplaced in an extensional or non-compressive tectonic regime in the cupola of high-level A-type granite. Tarr albitites may represent residual magma remaining after near-total crystallization of an A-type granite pluton at depth, forcibly emplaced into the roof above the cooling pluton. The intrusive dolomitite exsolved from highly differentiated albitite melt, in the apical regions of a still-buried alkaline “A-type” granite pluton that was rich in CO2; these volatiles migrated upwards and towards the cooler margins of the magma body. Late NNE-SSW extension allowed a shallow-level cupola to form, into which albitite melts and carbonate fluids migrated, culminating in explosive emplacement of albitite breccia and intrusive carbonate. Isotopic compositions of Tarr dolomitite and albitite indicate these are consanguineous and ultimately of mantle origin. Magmatic volatiles fenitized the wall rock, while submarine hydrothermal activity transformed some of the dolomitite into breunneritite. Recognition of Tarr-type should encourage similar hypabyssal complex intrusions to be sought for in association with A-type granitic plutons elsewhere.  相似文献   

14.
The Pliocene to possibly Pleistocene uppermost Orubadi and Era Formations, southwest margin of the Papuan Peninsula, are interpreted as having been deposited in alluvial-fan, fan-delta and shallow-marine environments. The alluvial-fan facies consists primarily of lenticular, coarse-grained conglomerate (up to 2 m boulders) and cross-bedded and horizontally laminated sandstone. Conglomerate and sandstone were deposited in shallow fluvial channels and by overbank sheetfloods. The facies also contains thick mudflow diamictite and minor tuff and terrestrial mudstone. The shallow-marine and fan-delta facies, in contrast, consists of heterogeneously interbedded marine and terrestrial mudstone, sandstone, diamictite, conglomerate and limestone. Marine mudstone is calcareous, sandy, bioturbated, and contains marine shells. Limestone is mostly packstone that has a varied, open-marine fauna. Rare coral boundstone is also present. Marine sandstone is burrowed to bioturbated and is hummocky cross-stratified in places. Some marine mudstone contains sandstone pillows formed by loading of unconsolidated sand by storm waves. Other sandstone in the fan-delta facies is cross-bedded, lacks shells and was probably deposited by fluvial processes. Several conglomerate beds in the fan-delta facies are well sorted and imbricated and were also deposited by stream floods. The synorogenic Orubadi and Era Formations were deposited in a foreland basin formed from loading of the Papuan–Aure Fold and Thrust Belt on the edge of the Australian craton. Deformation in the fold and thrust belt was probably related to docking and compression of the Finisterre Terrane–Bismarck Arc against the New Guinea Orogen. The Era Formation interfingers with the reefal Wedge Hill Limestone in which reef facies likely grew on a deforming anticline. Era Formation siliciclastics were sourced from volcanic, metamorphic and sedimentary rocks that were uplifted in the orogen to the northeast. Volcanic sediment was derived mostly from a then-active volcanic arc likely related to southward subduction at the Trobriand Trough.  相似文献   

15.
The tectonic evolution of SE China block since late Paleozoic remains debated.Here we present a new set of zircon U-Pb geochronological,Lu-Hf isotopic data and whole-rock geochemistry for two stages of basicintermediate dykes from the southwestern Fujian.The samples were collected from the NE-trending(mainly diabases) and NW-trending(mainly diabasic diorites) dykes and yielded zircon U-Pb ages of 315 and 141 Ma,with ε_(Hf)(t) values of-8.90 to 7.49 and-23.39 to-7.15(corresponding to T_(DM2) values of 850 to 1890 Ma and 737 to 2670 Ma),respectively.Geochemically these rocks are characterized by low TiO_2(0.91-1.73 wt.%)and MgO(3.04-7.96 wt.%),and high Al_2O_3(12.5-16.60 wt.%) and K_2O(0.60-3.63 wt.%).Further they are enriched in LREEs and ULEs(Rb,Ba,Th and K).but depleted in HFSEs(Nb,Ta and Zr).The tectonic discrimination analysis revealed that the dykes were formed in an intraplate extensional environment.However,the NW trending dykes show crust-mantle mixed composition,which indicate an extensional tectonic setting with evidence for crustal contamination.The SE China block experienced two main stages of extensional tectonics from late Carboniferous to early Cretaceous.The tectonic evolution of the SE China block from late Devonian to Cretaceous is also evaluated.  相似文献   

16.
This paper presents a methodology to conduct geostatistical variography and interpolation on areal data measured over geographical units (or blocks) with different sizes and shapes, while accounting for heterogeneous weight or kernel functions within those units. The deconvolution method is iterative and seeks the point-support model that minimizes the difference between the theoretically regularized semivariogram model and the model fitted to areal data. This model is then used in area-to-point (ATP) kriging to map the spatial distribution of the attribute of interest within each geographical unit. The coherence constraint ensures that the weighted average of kriged estimates equals the areal datum.This approach is illustrated using health data (cancer rates aggregated at the county level) and population density surface as a kernel function. Simulations are conducted over two regions with contrasting county geographies: the state of Indiana and four states in the Western United States. In both regions, the deconvolution approach yields a point support semivariogram model that is reasonably close to the semivariogram of simulated point values. The use of this model in ATP kriging yields a more accurate prediction than a naïve point kriging of areal data that simply collapses each county into its geographic centroid. ATP kriging reduces the smoothing effect and is robust with respect to small differences in the point support semivariogram model. Important features of the point-support semivariogram, such as the nugget effect, can never be fully validated from areal data. The user may want to narrow down the set of solutions based on his knowledge of the phenomenon (e.g., set the nugget effect to zero). The approach presented avoids the visual bias associated with the interpretation of choropleth maps and should facilitate the analysis of relationships between variables measured over different spatial supports.  相似文献   

17.
In recent years, climate and environment changes since the Little Ice Age have become a focus in modern research. The paper selected the sediment (77 cm) of Sihu Lake, which was located in Guilin, southern China, as the research object and analyzed the karst wetland environmental changes within nearly 450 years. According to the vertical profile of indicators and geochemical elements in sediment core, the regional environmental evolution was divided into four stages. The former two stages were mainly influenced by Little Ice Age (1562–1895). The third stage climate has changed slowly. The fourth stage was mainly affected by human activities and global warming. The factor analysis of geochemical elements indicated that karst wetland regional environmental change was affected by four major factors. In the 53–77 cm stage (1562–1703), F1 (erosion factor), F2 (watershed runoff and diagenesis factor) and F3 (regional background factor) were reduced, indicating that it was in cold and dry stage of Little Ice Age. In the 20–53 cm stage (1703–1895), F1 and F2 increased, indicating that it was in cold and wet stage of Little Ice Age. In the 4–20 cm stage (1895–1987), F1, F2 and F4 (human activity factor) increased slowly, indicating that the climate was affected by global warming and more precipitation. In the 0–4 cm stage (1987–2007), F1 and F2 reduced and F4 increased, indicating the reduced precipitation, rising temperature and more impact of human activities. In addition, it was proposed that the Little Ice Age in Guilin District in southern China started in the 1560s and lasted until the 1895s or so.  相似文献   

18.
Quantitative rock physics analyses were used to determine the lithology and pore fluid of a reservoir in the Niger Delta. Inaccurate prediction of lithology and pore fluid results in the inaccurate determination of other petrophysical properties and parameters such as porosity, permeability, and net pay. This research is to predict lithology and pore fluid using rock physics analysis. However, reservoir zones were also predicted. Density, compressional wave velocity, and shear wave velocity logs were used as input to calculate elastic parameters such as velocity ratio, Poisson’s ratio, and bulk modulus. The calculated velocity ratio log was used to differentiate between sand and shale. Poisson’s ratio and velocity ratio using Goodway interpretation template were carried out and used to delineate pore fluid content, gas sand, oil sand, and sandstone formation from crossplot analysis.  相似文献   

19.
Jurassic plants excavated from a 12 × 5 m site, at Lune River, southern Tasmania, include an araucarian tree and numerous pteridophytes, belonging to the orders Osmundales, Filicales and Bennettitales. The fossils occur in 2 – 3 m of immature volcanilithic sandstone beds. The sandstone consists primarily of clasts from granitic basement rocks underlying much of southeast Tasmania and mafic clasts containing feldspathic microliths, and primary, phreatomagmatic quartz crystals. Detrital zircons from the sandstones are mostly Early Jurassic (Toarcian) in age (182 ± 4 Ma) with minor Triassic (226 Ma), Devonian (380 – 360 Ma) and Proterozoic populations. Basaltic andesite, hereafter referred to as andesite, caps the volcanilithic units and displays similar ratios of fluid-immobile trace elements (e.g. Zr/Nb, Ti/V), to the Jurassic dolerite found in Tasmania, indicative of a common source. The andesites are correlated with the Jurassic Kirkpatrick Basalts (Trans-Antarctic Mountains, Antarctica) based on their field relationships with bounding strata, age, and distinctive similarities in major-element composition and fluid-immobile trace-element ratios. The andesite is interpreted as an extrusive equivalent of the Tasmanian dolerite. Importantly, drillcore from Lune River contains stoped clasts of andesite in fine-grained dolerite, indicating that the andesite pre-dates the dolerite. Thermal alteration index of microfossils (3 – 3.3) and reflectance of organic material within the sediments (0.54 – 0.77 Ro) resulted from contact metamorphism associated with the emplacement of this basalt. The sedimentology and stratigraphy of the depositional environment, plus the presence of hydrophilic pteridophytes and gymnosperms, indicates that the Toarcian environment was temperate to warm and humid, with an abundant supply of water.  相似文献   

20.
Two main deformational phases are recognised in the Archaean Boorara Domain of the Kalgoorlie Terrane, Eastern Goldfields Superterrane, Yilgarn Craton, Western Australia, primarily involving south-over-north thrust faulting that repeated and thickened the stratigraphy, followed by east-northeast – west-southwest shortening that resulted in macroscale folding of the greenstone lithologies. The domain preserves mid-greenschist facies metamorphic grade, with an increase to lower amphibolite metamorphic grade towards the north of the region. As a result of the deformation and metamorphism, individual stratigraphic horizons are difficult to trace continuously throughout the entire domain. Volcanological and sedimentological textures and structures, primary lithological contacts, petrography and geochemistry have been used to correlate lithofacies between fault-bounded structural blocks. The correlated stratigraphic sequence for the Boorara Domain comprises quartzo-feldspathic turbidite packages, overlain by high-Mg tholeiitic basalt (lower basalt), coherent and clastic dacite facies, intrusive and extrusive komatiite units, an overlying komatiitic basalt unit (upper basalt), and at the stratigraphic top of the sequence, volcaniclastic quartz-rich turbidites. Reconstruction of the stratigraphy and consideration of emplacement dynamics has allowed reconstruction of the emplacement history and setting of the preserved sequence. This involves a felsic, mafic and ultramafic magmatic system emplaced as high-level intrusions, with localised emergent volcanic centres, into a submarine basin in which active sedimentation was occurring.  相似文献   

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