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1.
为深入研究华南长江铀矿田内“交点型”铀矿化类型,对书楼丘矿床中位于基性岩脉与硅化碎裂岩交切部位的沥青铀矿开展原位微区U-Pb定年及元素成分研究.激光剥蚀电感耦合等离子体质谱分析结果显示,书楼丘沥青铀矿的U-Pb加权平均年龄为71.3±1.1 Ma;微量元素以富集W、Bi、Mo等亲硫元素,亏损Nb、Ta、Zr、Hf、Th等高场强元素为特征;稀土元素配分模式表现为轻稀土微富集,轻重稀土分异不明显,总量较低,Eu呈现明显的负异常,与富铀围岩长江岩体的稀土元素配分模式基本一致,暗示其铀源可能主要与长江岩体关系密切,与脉型铀矿床稀土元素配分模式的对比及ΣREE-（U/Th）、ΣREE-（LREE/HREE）N图解指示其为低温、中低盐度热液成因,δCe值指示沥青铀矿的成矿环境为还原环境.矿床内“交点型”铀成矿作用主要受南雄断裂80~60 Ma期间拉张活动、产铀长江花岗岩体和基性岩脉的共同控制,进而在交切的构造部位形成了铀矿化信息. 相似文献
2.
《矿物岩石地球化学通报》2020,(3)
为了示踪成矿流体来源,明确铀矿化成因类型,对哈毕力格地区与铀矿化关系密切的铀矿化石英岩、石英岩、花岗闪长岩和大理岩进行了稀土元素地球化学研究。结果表明,铀矿化石英岩样品的ΣREE为11.69×10~(-6)～165.86×10~(-6),稀土配分模式呈微弱的轻稀土富集右倾型;无矿化石英岩的ΣREE为2.09×10~(-6)～10.97×10~(-6),稀土配分模式呈"平坦型";花岗闪长岩的ΣREE为141.50×10~(-6)～204.02×10~(-6),稀土配分模式呈典型的轻稀土富集右倾型。石英岩、矿化石英岩和花岗闪长岩的ΣREE、LREE、HREE以及La_N/Yb_N、Sm_N/Eu_N、Y/Ho等参数表明花岗闪长岩与铀矿化具有成因联系。结合矿物学及同位素地球化学特征,指出古元古代乌拉山群区域变质作用使铀发生了初步富集,主成矿阶段的成矿作用与晚古生代花岗闪长质岩浆分异出的富铀岩浆流体有关。 相似文献
3.
牟定1101铀矿区是康滇地轴中南段发现高品位、巨粒晶质铀矿代表性产地之一.为了解铀矿物的形成时代及成因，利用微区、原位分析技术（EPMA、SEM、LA-ICP-MS）对该区3件沥青铀矿样品开展了主量化学成分、稀土元素分析及年龄测定.沥青铀矿电子探针（EPMA）化学成分具有高PbO、ThO2、Y2O3，低SiO2，Na2O，CaO，K2O，ZrO2含量特征，反映沥青铀矿形成之后遭受后期的蚀变、改造作用较弱.沥青铀矿的稀土元素ΣREE-（U/Th）、ΣREE-（ΣREE/ΣREE）N图解表明其为岩浆作用相关成因、形成于高温环境（T>450℃）.3件沥青铀矿的U-Pb同位素年龄在（950±5 Ma、MSWD=0.025，953±9 Ma、MSWD=0.051，954±8 Ma、MSWD=0.085）之间，表明它们具有相近的形成时代（新元古界晚期）.对比国外不同类型铀矿床，该区的铀成矿作用具有岩浆成因特征.新元古界晚期，Rodinia超大陆由聚合转化为裂解阶段，广泛引起了Pt1j苴林群发生区域变质、混合岩化、铀成矿作用.牟定1101铀矿区的成矿作用与~960 Ma Rodinia超大陆裂解地质事件所对应的晋宁构造运动有关. 相似文献
4.
东北黑土的形成长期备受学者们的关注,然而人类活动不同程度影响着表层黑土的自然特征。地下黑土能较为真实地反映客观属性,但其研究仍然匮乏,由此本文选择松嫩平原黑土区阿荣旗钻孔内的地下黑土为研究对象,进行稀土元素地球化学测试,采用地质统计学分析地下黑土层ΣREE、HREE、LREE的分布特征,结合Ce异常、Eu异常、(La/Yb)N、(La/Sm)N、(Gd/Yb)N、Al2O3/TiO2图解、Ceanom讨论了黑土的物源特征与环境记录。结果显示,阿荣旗地下黑土ΣREE含量较高,平均值为141.45×10-6。球粒陨石标准化曲线表现为向右倾斜,轻稀土富集,δEu微弱负异常,δCe明显负异常。(La/Yb)N平均值7.58,(La/Sm)N平均值为1.14,(Gd/Yb)N平均值为3.54,表明地下黑土重、轻稀土元素分异程度大,轻稀土元素相比重稀土元素分馏... 相似文献
5.
为了探究东南印度洋曼达岬海盆(Mentelle Basin)内沉积物的源-汇过程,利用国际大洋发现计划(IODP)369航次在该海盆内获取的渐新世-中新世岩心沉积物,进行了稀土元素(REE)组成特征及其控制因素和物源指示意义的研究.结果显示,与球粒陨石、上地壳(UCC)和澳大利亚后太古代页岩(PAAS)这三种标准物质相比,所研究沉积物的稀土元素含量(ΣREE)与轻/重稀土含量比值(ΣLREE/ΣHREE)等总体特征与UCC最为相近,其UCC标准化后的稀土元素配分模式则呈现出轻稀土稍富集的整体平缓特征.样品的ΣREE与稀土分馏指标(La/Yb)UCC和(Gd/Yb)UCC明显受控于粒度效应与风化作用,而ΣLREE/ΣHREE、δEu、(La/Sm)UCC和(Sm/Nd)UCC则基本不受上述两种作用的影响.UCC标准化后的稀土元素配分模式、基于稀土元素组成的物源判别函数以及Zr-Th-Sc物源判别三角图均表明伊尔冈克拉通是所研究沉积物最可能的物源区,并且该物源区的主要源岩在13 Ma时由中基性岩向酸性岩... 相似文献
6.
大同盆地是典型的干旱-半干旱内陆盆地,盆地中部地下水碘含量异常,对当地饮用水安全造成了严重威胁.对盆地高碘地下水分布区沉积物组成及稀土元素(REE) 进行了地球化学研究,结果表明,地下水系统呈弱碱性(pH值为7.18~9.64) 的偏还原环境,沉积物多为Ce正常或轻微负异常及Eu负异常;沉积物中碘含量为0~1.78×10-6;ΣREE含量较高,ΣLREE/ΣHREE比值为2.79~4.14,即富集轻稀土元素(LREE) 而亏损重稀土元素(HREE).ΣREE与碘含量呈负相关关系,虽然铁氧化物/氢氧化物矿物的还原性溶解可导致二者的释放,但由于沉积物有机质产生的低结晶矿物对碘的强吸附性,使沉积物中碘含量较高;弱碱性环境中REE的再吸附过程会导致沉积物中富集LREE;沉积物中碘含量与氧化还原敏感组分TOC、U、V及[Eu]N的关系也表明,地下水系统的氧化还原条件及有机质含量是影响碘富集的重要因素. 相似文献
7.
本文利用ICP-MS对2006—2008年采自黄河三角洲湿地系统的208个表层土壤(沉积物)样品进行了14项稀土元素(REE)分析,研究了黄河三角洲不同植被覆盖下REE的配分模式特征。结果表明:上三角洲平原湿地表层土壤稀土元素总量(ΣREE)分布范围为137.29×10-6~267.82×10-6,平均值为166.73×10-6。碱蓬湿地和光滩湿地的配分曲线比较接近;芦苇湿地和柽柳湿地的配分曲线也比较接近,具有配分曲线整体低于碱蓬湿地和光滩湿地的趋势。研究区浅海湿地表层沉积物ΣREE为143.11×10-6~222.48×10-6,平均值为180.80×10-6。黄河上三角洲平原各类湿地稀土元素配分曲线高于黄河浅海湿地的稀土元素配分曲线,黄河浅海湿地的稀土元素配分曲线高于黄河沉积物的稀土元素配分曲线,且其配分曲线LREE较分散,而HREE较集中甚至重合。由此证明,稀土元素与植物分带具有成因关系,即黄河三角洲湿地系统LREE较多的参与到了植被的生物地球化学循环,而HREE在湿地生态系统呈生物化学惰性。 相似文献
8.
浙江八面山萤石矿床稀土元素地球化学特征及成因探讨 总被引：4，自引：2，他引：2
对浙江八面山萤石矿床中不同类型萤石矿石和围岩样品的稀土元素的系统分析表明,细粒萤石矿石的ΣREE〈39×10-6,LREE为14.36×10-6～34.24×10-6,HREE0.96×10-6～2.04×10-6,Y〈3×10-6;巨晶萤石矿石中的ΣREE3.62×10-6～20.81×10-6,LREE2.71×10-6～17.67×10-6,HREE0.24×10-6～1.49×10-6;而围岩花岗岩的ΣREE460.29×10-6,LREE225.97×10-6,HREE91.32×10-6,Y＆gt;140×10-6;沉积岩中的ΣREE20.22×10-6、LREE16.11×10-6、HREE1.61×10-6。矿石与围岩中沉积岩的稀土总量、轻稀土、重稀土和Y的含量接近,与花岗岩的稀土总量、轻稀土、重稀土和Y元素含量相差悬殊。萤石矿石的稀土分布型式主要为轻稀土富集型,（La/Yb）N通常多数大于8,在8.07～17.26间,δEu值在0.45～1.30,δCe在0.89～1.14间,Ce、Eu基本不显异常。矿石与围岩的稀土地球化学研究显示,八面山萤石矿床为受地层、岩体与断裂共同控制＂三位一体＂的低温热液型矿床。 相似文献
9.
包尔图铜矿床位于南天山库米什洋盆俯冲变质带的边缘,矿体受断裂构造控制。矿区围岩为一套中深变质岩,其稀土元素组成具有如下特征:∑REE较高,LREE/HREE=2.46～16.86,轻重稀土元素明显分异,且轻稀土相对富集,负铕异常,配分模式曲线向右倾斜。矿石的∑REE相对较低,LREE/HREE=0.06～0.97,轻重稀土元素明显分异,重稀土相对富集,配分曲线向左倾斜,与混合岩脉体的稀土元素配分模式相近。稀土元素组成特征指示矿床的成矿过程可能与混合岩化作用有关。结合矿床地质特征,认为包尔图铜矿床为变质热液型铜矿床。 相似文献
10.
本文根据64个样品的分析结果,论述浙江北部和江西东部中生代火山岩的稀土元素地球化学特征。区内各地中酸性和酸性火山岩的稀土元素分布型式都很相似,均为向右倾的、彼此近于平行的V型曲线,具铕负异常;它们的稀土元素参数(ΣREE、ΣLREE/ΣHREE、δEu、Ce/Yb、La/sm、La/Yb等)也存在一定差异,铀矿化火山岩特别富集重稀土元素。火山岩的~87sr/~86Sr初始比值介于0.7056—0.7139。这些特征和数据表明火山岩的成岩物质来源于硅铝壳。火山岩的稀土元素分布型式和地球化学参数以及La/Sm—La和Ce/Yb—Eu/Yb图解,可用于探讨成岩成矿物质来源。 相似文献
11.
Jessica Bonhoure Philippe Kister Michel Cuney Etienne Deloule 《Geostandards and Geoanalytical Research》2007,31(3):209-225
A methodology for the determination of the rare earth elements in uranium oxides by ion microprobe has been set up on a Cameca ims-3f instrument. An uranium oxide reference material from a syn-metamorphic uranium deposit related to albitisation has also been developed for this type of analysis. Applications of the methodology are presented for a series of uranium oxides selected from some major uranium deposit types: from the world's highest grade unconformity-related uranium deposit from the Athabasca Basin (Saskatchewan, Canada; the Shea Creek and the McArthur River examples), a perigranitic vein-type deposit (Pen Ar Ran, Vendée, France) and a volcanic caldera-related deposit (Streltsovkoye, Transbaikalia, Russia). Each type of uranium deposit appears to have a specific REE signature. All REE patterns from the Shea Creek and the McArthur deposits are characterised by bell-shaped patterns centred on Tb-Dy and similar to those already published for uranium oxides from unconformity-related deposits from Australia. Such bell-shaped REE patterns centred on Tb-Dy may therefore be considered as a typical signature of uranium oxides from Mesoproterozoic unconformity-related deposits. A smoother bell shape pattern centred on Eu characterises the syn-metamorphic albitisation related deposit of Mistamisk selected for the reference material. The REE patterns from the Pen Ar Ran deposit show a fractionation from LREE to HREE with anomalously high abundances of Sm, Eu and Gd with respect to the other REEs, similar to the REE patterns of uranium oxides from the volcanic-related deposits of Streltsovkoye. 相似文献
12.
总结了内蒙古大石寨地区1∶25万区域地球化学调查获得的1点/4km2的水系沉积物组合样品中的La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu、Y等15种稀土元素的区域地球化学分布特征。稀土元素分布与研究区中部的黑云母花岗岩密切相关,轻稀土主要分布在该岩体外围的二叠系地层中,重稀土主要分布在该岩体上方。该岩体上方和外围地层的稀土元素分布、稀土元素总量、轻重稀土比及δCe、δEu、(La/Sm)N、(La/Tb)N、(La/Lu)N、(Ce/Yb)N、(Gd/Lu)N等稀土元素分馏特征的差异明显。利用区域地球化学调查水系沉积物样品中的稀土元素含量,可获得研究区可靠的稀土元素区域地球化学分布特征,也可反映研究区地质特点,并为区域地球化学异常解译提供参考资料。 相似文献
13.
Stephen B. Castor 《Resource Geology》2008,58(4):337-347
Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor. 相似文献
14.
Abstract: The black shales of the Lower Cambrian Niutitang Formation in Weng’an, on the Yangtze platform of south China, contain voluminous polymetallic sulfide deposits. A comprehensive geochemical investigation of trace, rare earth, and platinum group elements (PGE) has been undertaken in order to discuss its ore genesis and correlation with the tectono-depositional setting. The ore-bearing layers enrich molybdenum (Mo), nickel (Ni), vanadium (V), lead (Pb), strontium (Sr), barium (Ba) , uranium (U) , arsenic (As), and rare earth elements (REE) in abundance. High uranium/thorium (U/Th) ratios (U/Th>1) indicated that mineralization was mainly influenced by the hydrothermal process. The dU value was above 1.9, showing a reducing sedimentary condition. The REE patterns showed high enrichment in light rare earth elements (LREE) (heavy rare earth elements (HREE) (LREE/HREE=5–17), slightly negative europium (Eu) and cerium (Ce) anomalies (dEu=0.81–0.93), and positive Ce anomalies (dCe=0.76–1.12). PGE abundance was characterized by the PGE-type distribution patterns, enriching platinum (Pt), palladium (Pd), ruthenium (Ru) and osmium (Os). The Pt/Pd ratio was 0.8, which is close to the ratios of seawater and ultramafic rocks. All of these geochemical features suggest that the mineralization was triggered by hydrothermal activity in an extensional setting in the context of break-up of the Rodinian supercontinent. 相似文献
15.
The black shales of the Lower Cambrian Niutitang Formation in Weng'an.on the Yangtze platform of south China,contain voluminous polymetallic sulfide deposits.A comprehensive geochemical investigation of trace,rare earth,and platinum group elements(PGE)has been undertaken in order to discuss its ore genesis and correlation with the tectono.depositional setting.The ore-bearing layers enrich molybdenum(Mo),nickeI(Ni),vanadium(V),lead(Pb),strontium(Sr), bariam(Ba),uranium(U),arsenic(As),and rare earth elements(REE)in abundance.High uranium/thorium(U/Th)ratios(U/Th>1)indicated that mineralization was mainly influenced by the hydrothermal process.The δU value Was above 1.9.showing a reducing sedimentary condition.The REE patterns showed high enrichment in Iight rare earth elements (LREE)(heavy rare earth elements (HREE)(LREE/HREE=5-17),slightly negative europium(EU)and cerium(Ce)anomalies(δEu=0.81-0.93).and positive Ce anomalies(δCe=0.76-1.12).PGE abundance was characterized by the PGE-type distribution patterns,enriching platinum(Pt),palladium(Pd),ruthenium(RuJ and osmium(Os).The Pt,Pd ratio was 0.8.which is close to the ratios of seawater and ultramafic rocks.AII of these geochemical features suggest that the mineralization was triggered by hydrothermal activity in an extensionai setting in the context of break-up of the Rodinian supercontinent. 相似文献
16.
MAO Guangzhou HUA Renmin GAO Jianfeng ZHAO Kuidong LONG Guangming LU Huijuan YAO Junming 《《地质学报》英文版》2010,84(3):614-623
<正>Jinshan gold deposit is located in northeastern Jiangxi,South China,which is related to the ductile shear zone.It has a gold reserve of more than 200 tons,with 80%of gold occurring in pyrite. The LREE of gold-bearing pyrite is as higher as 171.664 ppm on average,with relatively higher light rare earth elements(LREE;159.556 ppm) and lower HREE(12.108 ppm).TheΣLREE/ΣHREE ratio is 12.612 and(La/Yb)_N is 11.765.These indicate that pyrite is rich in LREE.The(La/Sm)_N ratio is 3.758 and that of(Gd/Yb)_N is 1.695.These are obvious LREE fractionations.The rare earth element(REE) distribution patterns show obvious Eu anomaly with averageδEu values of 0.664,andδCe anomalies of 1.044.REE characteristics are similar to those of wall rocks(regional metamorphic rocks),but different from those of the Dexing granodiorite porphyry and Damaoshan biotite granite.These features indicate that the ore-forming materials in the Jinshan gold deposit derived from the wall rocks, and the ore-forming fluids derived from metamorphic water.The Co/Ni ratio(average value 0.38) of pyrite suggests that the Jinshan gold deposit formed under a medium-low temperature.It is inferred from the values of high-field strength elements,LREE,Hf/Sm,Nb/La,and Th/La of the pyrite that the ore-forming fluids of the Jinshan gold deposit derived from metamorphic water with ClF. 相似文献
17.
四川稀土矿尾砂的稀土元素和微量元素地球化学特征及开发利用意义 总被引：3，自引：3，他引：0
四川是我国轻稀土的重要产地,稀土开采至今已有二十多年的历史,积存了大量尾砂。尾砂中仍然有丰富的稀土资源,但这部分资源究竟有多大的量、能不能再次回收,如何回收,则是当务之急。为查明稀土尾砂中各类元素的分布特征,本文对A、B、C、D四个稀土矿山的尾砂开展了稀土元素和微量元素地球化学特征的初步研究。结果表明:尾砂中稀土元素配分特征继承了原矿石,稀土氧化物含量普遍偏高(0.78%~2.12%),均超过了现行工业指标的边界品位(0.5%~1.0%),且老尾砂的稀土含量高于新尾砂;除了富集稀土元素之外,B尾砂中Sr含量超过10%,C矿区尾砂中Sr含量为2.7%,A矿区尾砂中Ba含量可达1.8%。同时,不同矿区的尾砂中Mo、Bi、Pb、Ag等有用元素发生了不同程度地富集(值得综合回收利用),尤其是Mo达到了边界品位(磁选后的尾砂Mo含量达到2.275%)。本文提出,今后不仅要加强保护四川稀土尾砂,而且需对富集的有用元素采取恰当的方式加以综合回收。 相似文献