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1.
The study was performed on inertinite concentrates prepared from 19 samples of bituminous, mostly coking, coal (Rr = 0.87–1.42%) from the Upper Silesian Coal Basin of Poland. In all examined samples, total semifusinite differs from fusinite, in terms of mean values, by higher frequencies of the D1 and D4 band position and lower frequency of the D3 band position, higher G band FWHM, the AD3/AALL and AD4/AALL ratios (where AALL means the surface of all the Raman bands), and lower D1 band FWHM, the ID1/IG and AD1/AALL ratios. Similar differences exist between reactive and non-reactive semifusinites. The diameter of coherent domains (La) increases in the following sequence: reactive semifusinite < non-reactive semifusinite < fusinite. The AD3 + D4/AALL ratio reflects inertinite reactivity in bituminous coals, and decreases with the increase of mean reflectance (Rr) of semifusinite and fusinite. Using the AD3 + D4/AALL, ID1/IG and AD1/AALL ratios or the D3 band position it is possible to interpret thresholds dividing, in terms of mean values, total semifusinite and fusinite, coming from different coals. The results of the study suggest that the term “semifusinite” should only comprise reactive and semi-reactive components. Non-reactive semifusinite should be considered fusinite. Semifusinite from bituminous coals (of Rr ≈ 0.9–1.4%), defined in the proposed way, would be characterized by the AD3 + D4/AALL ratio ≥ 0.35, or the ID1/IG ratio ≤ 1.03.  相似文献   

2.
This paper presents two models of texture of carbon materials possessing porosity. For both models, RMAX, RINT and RMIN values of reflectance have been calculated by modified Ting's 3A method [Ting, F.T.C., 1978. Petrographic techniques in coal analysis. In: C. Karr (Ed.), Analytical Methods for Coal and Coal Products, Vol. 1. Academic Press, New York, 1978, pp. 3–25]. It has been found that the reflectance indicating surface (RIS) for the studied models of texture changes from a biaxial negative up to a biaxial positive one (the type A texture) depending on the shape and size of pores. In particular case, for the type B texture and the isometry of pores, a uniaxial negative RIS is merely obtained.  相似文献   

3.
A systematic investigation of the petroleum exploratory well N-13 within the Huangqiao region, Lower Yangtze Basin, East China, has been carried out using multiple analytical techniques of organic geochemistry. The past occurrence of a thermal event has been recognized based on changes in optical vitrinite reflectance (Ro), pyrolysis peak temperature (Tmax) and chemical hydrogen index (HI), potential degradation rate (D), the atomic H/C ratio and dimethylphenanthrene ratios (DPR, DPR1 and DPR2) in the sedimentary rocks. The geological significance of this thermal event is discussed in this paper.  相似文献   

4.
The effect of coal composition, particularly the organic fraction, upon gas sorption has been investigated for Bowen Basin and Sydney Basin, Australia coals. Maceral composition influences on gas retention and release were investigated using isorank pairs of hand-picked bright and dull coal in the rank range of high volatile bituminous (0.78% Ro max) to anthracite (3.01% Ro max). Adsorption isotherm results of dry coals indicated that Langmuir volume (VL) for bright and dull coal types followed discrete, second-order polynomial trends with increasing rank. Bright coals had a minimum VL at 1.72% Ro max and dull coals had a minimum VL at 1.17% Ro max. At low rank, VL was greater in bright coal by about 10 cm3/g, but as rank increased, the bright and dull trends converged and crossed at 1.65% Ro max. At ranks higher than 1.65% Ro max, both bright and dull coals followed similar trends. These competing trends mean that the importance of maceral composition on VL varies according to rank. In high volatile bituminous coals, increases in vitrinite content are associated with increases in adsorption capacity. At ranks higher than medium to low volatile bituminous, changes in maceral composition may exert relatively little influence on adsorption capacity. The Langmuir pressure (PL) showed a strong relationship of decreasing PL with increasing rank, which was not related to coal type. It is suggested that the observed trend is related to a decrease in the heterogeneity of the pore surfaces, and subsequent increased coverage by the adsorbate, as coal rank increases. Desorption rate studies on crushed samples show that dull coals desorb more rapidly than bright coals and that desorption rate is also a function of rank. Coals of lower rank have higher effective diffusivities. Mineral matter was found to have no influence on desorption rate of these finely crushed samples. The evolution of the coal pore structure with changing rank is implicated in diffusion rate differences.  相似文献   

5.
一种页岩含气性热演化规律研究的模拟实验方法   总被引：2，自引：1，他引：1  
目前针对页岩气赋存规律研究的热模拟实验主要是沿袭常规油气热模拟方法,以粉末态样品开展模拟,研究对象为岩石生成并排出的烃类气体,这种模拟方式未明确页岩气的实质为"滞留气",并且模拟后样品无法开展扫描电镜分析,不能确定岩石孔隙结构变化规律。本文通过石英玻璃管封装块状样开展页岩生烃热模拟实验,并结合一套数据处理方法,尝试建立了一种适合页岩气研究的热模拟实验方法,研究泥页岩在不同演化阶段(Ro范围为0.596%~2.143%)不同赋存状态气体的含量以及岩石微观孔隙特征的变化情况。结果表明,泥岩及油页岩样品的排出气及解析气含量在高成熟度阶段(400℃以后)有明显增加的趋势,结合扫描电镜微观结构分析显示这是由于有机质生气量以及无机孔隙均有增加。本方法可以研究页岩热演化过程中不同赋存状态气体含量及微观孔隙结构的变化,为页岩气勘探开发提供了一种可参考的方法。  相似文献   

6.
The Rock-Eval pyrolysis and TOC analysis have been widely used to evaluate the source rock quality. The atomic H/C ratio of kerogen, however, has been overlooked in source rock evaluation. In this study, coal and carbonaceous samples, including 26 from northwestern Taiwan, 12 from China, and 4 from the United States were analyzed, and integrated with 157 published data, to explore the significance of atomic H/C ratio as a parameter of source rock evaluation. Two different linear trends were observed in the cross-plot of S 1 versus S 2. Field outcropped shale or C-shale exhibits a steeper slope compared to that of coal samples which can be attributed to the compositional difference in their organic material. A rather strong positive correlation for H% versus S 2 illustrates the contribution of H-containing macerals, especially exinite. Organic matters in the samples studied are of type II/III kerogen based on the relationship between HI and T max. The H/C ratio, as well as the HI, S 1, and S 2, generally decreases with the maturity increasing. The H/C ratio decreases slightly from 1.1 to 0.7 with the maturity increasing from R o 0.55 to 0.85%. Samples with H/C ratio in this range show significant change in certain other geochemical parameters (e.g. HI, S 1, S 2, S 1 + S 2, S 1/(S 1 + S 2), S 1/TOC, (S 1 + S 2)/TOC, T max). The (S 1 + S 2)/TOC ratio (defined as QI) was used as an indicator of the hydrocarbon potential. The QI, HI, and H/C ratio show a certain correlation, all increasing accordingly. The QI of the samples analyzed in this study is approximately 100–380 (mgHC/gTOC), similar to that of most humic coals for oil and gas generation. Samples with R o value lower than 0.55% always show significant variation in their HI, ranging from 80 to 520 mgHC/gTOC. It is inferred that hydrocarbon potential started from R o 0.55% and atomic H/C ratio 1.1 in this study.  相似文献   

7.
The results of the study of optical properties of 13 anthracites from different parts of the world are presented in this paper. Measurements of reflectance values were made on non-oriented vitrinite grains for a minimum of 300 points per sample. The reconstruction of Reflectance Indicating Surfaces (RIS) were made by Kilby's method [Kilby, W.E., 1988. Recognition of vitrinite with non-uniaxial negative reflectance characteristics. Int. J. Coal Geol. 9, 267–285; Kilby, W.E., 1991. Vitrinite reflectance measurement — some technique enhancements and relationships. Int. J. Coal Geol. 19, 201–218]. It was found that the use of Kilby's method for strongly anisotropic materials like anthracites did not give unambiguous results. Some improvement in Kilby's method, consisting of the division of the cumulative cross-plot into several elemental components, is suggested. Each elemental cross-plot corresponds to a textural class of anthracite, which is characterized by the values of RIS main axes RMAX(k), RINT(k) and RMIN(k) (k=1,2,…n; n — number of classes). The global texture of anthracite is characterized as a RIS with main axes calculated as the weighted means of , and for each class of this anthracite.The division of cumulative Kilby's cross-plot on elemental components makes possible the calculation of new coefficients Ht and H10 characterizing the heterogeneity of the structure and texture of anthracites. The results of our study show that all anthracites have biaxial negative textures, but their heterogeneity varies in a wide range of Ht and H10 coefficients depending upon the individual coal basin.  相似文献   

8.
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9.
运用电感耦合等离子体质谱和煤质分析等技术方法,对内蒙古胜利煤田0-1号钻孔揭露的早白垩世1、2和4号煤层(共20个煤分层,1个夹矸)进行了研究。结果显示,1、2号煤层的挥发分产率大于44%,透光率小于50%,煤类为褐煤;4号煤层挥发分产率42%,透光率53%,煤类为次烟煤(长焰煤);1、2号煤层灰分和硫含量较高,4号煤层灰分和硫含量较低。与世界煤微量元素含量平均值相比,1、2和4号煤层中Sb富集,V、Zr、Nb、Hf、W等元素轻微富集,其它微量元素的含量接近或低于世界煤含量的平均值。1、2和4号煤层中稀土元素和钇(REY)含量较低,根据上地壳标准值(La/Lu)N比值,所有煤分层均显示重稀土富集类型特征,而煤中泥岩夹矸则显示轻稀土富集类型特征。  相似文献   

10.
The maceral and microlithotype composition of selected coals has been investigated with respect to the grinding properties, specifically Hardgrove grindability index (HGI), of the coals. The study expands upon previous investigations of HGI and coal petrology by adding the dimension of the amount and composition of the microlithotypes. Coal samples, both lithotypes and whole channels, were selected from restricted rank ranges based on vitrinite maximum reflectance: 0.75–0.80% Rmax, 0.85–0.90% Rmax and 0.95–1.00% Rmax. In this manner, the influence of petrographic composition can be isolated from the influence of rank. Previous investigations of high volatile bituminous coals demonstrated that, while rank is an important factor in coal grindability, the amount of liptinite and liptinite-rich microlithotypes is a more influential factor. In this study, we provide further quantitative evidence for the influence of microlithotypes on HGI and, ultimately, on pulverizer performance.  相似文献   

11.
Abdo  Hazem Ghassan 《Natural Hazards》2020,104(1):681-703

Floods are one of the most severe hydrological hazards that cause an excessive threat to landscape stability, population welfare, infrastructure and spatial development in the Syrian coastal region. Al-Hussain river basin, like other Syrian coastal basins, is prone to a hazardous, frequent-flooding threat. However, investigating the probable areas of flooding risk is a difficult challenge that results from the almost complete absence of spatially distributed geo-hydrological measurements in Al-Hussain river basin. In this regard, geohydromorphometric parameters (Stream number Nu, Stream length Lu, Bifurcation ratio Rb, Form factor F, Elongation ratio Eb, Drainage density Dd, Stream frequency Fs, Drainage texture Td, Lemniscate ratio K, Compactness index C, Circulatory ratio Rc, Ruggedness number Rn, Basin relief Hr, and Relief ratio Rr) derived from remote sensing data in the GIS environment can provide a comprehensive and objective approach that can be utilized to map the spatial distribution of flood hazards at the level of delineated sub-basins. This being the case, the present research focuses on exploring the spatial distribution of flood risk in ten sub-basins belonging to Al-Hussain river basin by using spatial techniques tools in order to overall determine the hydro-prioritization of conservation. The geo-visualization map of generated flash flood susceptibility evaluates five degrees of the flood risk: very low, low, moderate, high, and very high. The flood risk map indicates that Qalea, and Talaa sub-basins have massive hydrodynamic risk, which, in turn, indicates the urgent need of soil and water maintaining measures. This hydrological dynamic in these sub-basins is explained by high values of Dd, F, Rr, Rn, Rc, and K, respectively. Overall, the spatial outcomes of the current work successfully proved the efficiency of extracted geohydromorphometric layers from RS data in the context of the spatial assessment of flash flood hazard; they also ensure ecological sustainability and productivity of the study basin.

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12.
The structural evolution of tectonically deformed coals（TDC） with different deformational mechanisms and different deformational intensities are investigated in depth through X-ray diffraction（XRD） analysis on 31 samples of different metamorphic grades(Ro,max:0.7%-3.1%) collected from the Huaibei coalfield.The results indicated that there are different evolution characteristics between the ductile and brittle deformational coals with increasing of metamorphism and deformation.On the one hand,with the increase of metamorphism,the atomic plane spacing (d002) is decreasing at step velocity,the stacking of the BSU layer（Lc） is increasing at first and then decreasing,but the extension of the BSU layer（La） and the ratio of La/Lc are decreasing initially and then increasing.On the other hand,for the brittle deformational coal,d002 is increasing initially and then decreasing,which causes an inversion of the variation of Lc and La under the lower-middle or higher-middle metamorphism grade when the deformational intensity was increasing.In contrast,in the ductile deformational coals,d002 decreased initially and then increased,and the value of Lc decreased with the increase of deformational intensity.But the value of La increased under the lower-middle metamorphism grade and increased at first and then decreased under the higher-middle metamorphism grade.We conclude that the degradation and polycondensation of TDC macromolecular structure can be obviously impacted during the ductile deformational process,because the increase and accumulation of unit dislocation perhaps transforms the stress into strain energy.Meanwhile,the brittle deformation can transform the stress into frictional heat energy,and promote the metamorphism and degradation as well.It can be concluded that deformation is more important than metamorphism to the differential evolution of the ductile and brittle deformational coals.  相似文献   

13.
The objective of the study was to characterize changes of reflectance, reflectance anisotropy and reflectance indicating surface (RIS) shape of vitrinite, sporinite and semifusinite subjected to thermal treatment under inert conditions. Examination was performed on vitrinite, liptinite and inertinite concentrates prepared from channel samples of steam coal (Rr = 0.70%) and coking coal (Rr = 1.25%), collected from seam 405 of the Upper Silesian Coal Basin. The concentrates were heated at temperatures of 400–1200 °C for 1 h time in an argon atmosphere.All components examined in this study: vitrinite, sporinite and semifusinite as well as matrix of vitrinite and liptinite cokes, despite of rank of their parent coal, show, in general, the most important changes of reflectance value and optical anisotropy when heated at 500 °C, 800 °C (with the exception of bireflectance value of sporinite) and 1200 °C.After heating the steam coal at 1200 °C, the vitrinite and the semifusinite reveal similar reflectances, whereas the latter a slightly stronger anisotropy. Sporinite and matrix of liptinite coke have lower reflectances but anisotropy (Rbi and Ram values) similar to those observed for vitrinite and semifusinite. However, at 1000 °C sporinite and matrix of liptinite coke have the highest reflectivity of the studied components. The RIS at 1200 °C is the same for all components.The optical properties of the three macerals in the coking coal become similar after heating at 1000 °C. Coke obtained at 1200 °C did not contain distinguishable vitrinite grains. At 1200 °C semifusinite and vitrinite coke matrix have highest Rr values among the examined components. Maximum reflectance (Rmax) reach similar values for vitrinite and sporinite, slightly lower for semifusinite. Matrix of liptinite coke and matrix of vitrinite coke have considerably stronger anisotropy (Rbi and Ram values) than other components. RIS at 1200 °C is also similar for all components.  相似文献   

14.
The molecular composition of Carboniferous–Permian coals in the maturity range from 0.66 to 1.63% vitrinite reflectance has been analysed using organic geochemistry to investigate the factors influencing the biomarker compositions of humic coals. The Carboniferous–Permian coal has a variable organofacies and is mainly humic-prone. There is a significant difference in the distribution of saturated and aromatic hydrocarbons in these coals, which can be divided into three types. The Group A coals have biomarker compositions typical of humic coal, characterised by high Pr/Ph ratios, a lower abundance of tricyclic terpanes with a decreasing distribution from C19 tricyclic terpane to C24 tricyclic terpane and a high number of terrigenous-related biomarkers, such as C24 tetracyclic terpane and C29 steranes. The biomarker composition of Group B coals, which were deposited in a suboxic environment, have a higher abundance of rearranged hopanes than observed in Group A coals. In contrast, in Group C coals, the Pr/Ph ratio is less than 1.0, and the sterane and terpane distributions are very different from those in groups A and B. Group C coals generally have abnormally abundant tricyclic terpanes with a normal distribution maximising at the C23 peak; C27 steranes predominates in the m/z 217 mass fragmentograms. The relationships between biomarker compositions, thermal maturity, Pr/Ph ratios and depositional environments, indicate that the biomarker compositions of Carboniferous–Permian coals in Ordos Basin are mainly related to their depositional environment. This leads to the conclusion that the biomarker compositions of groups A and B coals collected from Shanxi and Taiyuan formations in the northern Ordos Basin are mainly related to their marine–terrigenous transitional environment, whereas the biomarker compositions for the Group C coals from Carboniferous strata and Shanxi Formation in the eastern Ordos Basin are associated with marine incursions.  相似文献   

15.
Palaeoproterozoic black shales form an essential part of the Birimian volcanosedimentary belt in Burkina Faso, West Africa. The mean Rmax values and the atomic H/C values of the bulk carbonaceous matter (BCM), together with rock structures and mineral assemblages, indicate that these carbon‐rich rocks were metamorphosed to sub‐greenschist and low‐grade greenschist facies. X‐ray diffraction reveals that the (002) ‘graphite’ peak width in half maximum (FWHM) ranges from 0.43 to 0.71 °2θ in sub‐greenschist facies and from 0.27 to 0.41 °2θ in greenschist facies rocks, but the d(002) values in both groups of rocks are approximately the same (～3.35 Å). The BCM of individual samples is composed of particles with very variable shape, reflectance and Raman spectra. Type I particles that predominate in sub‐greenschist facies are fine‐grained, irregular or elongate bodies 1 to 3 μm in size. Their maximum reflectance (Rmax) ranges between 2.5% and 8.2%, and Raman parameters R1 and R2 range from 0.5 to 1.4 and 0.5 to 0.8, respectively. Type II particles are lath‐shaped, up to 40 μm large bodies, commonly arranged parallel to white mica flakes. The number of these particles increases from sub‐greenschist to greenschist facies. Maximum reflectance varies between 6% and 11.2% and R1 and R2 Raman parameters range from 0.05 to 0.7 and from 0.1 to 0.5, respectively. Type III particles occur in hydrothermally altered and sheared rocks; these are nodular aggregates composed of grains up to 10 μm in size. This type of particles has very high reflectance (Rmax = 11–15%) and its Raman spectra indicate a very high degree of structural ordering corresponding to well‐ordered graphite. Type I particles represent original organic matter in the metasediments. Type II particles are believed to have been formed either in situ by solid‐state transformation of Type I particles or by crystallization from metamorphic fluids. Gradual graphitization of the Type I organic particles and the growth of lath‐shaped Type II particles from a fluid phase is assumed to have taken place under the peak metamorphic conditions associated with the burial of Birimian sediments during thrust tectonism, progressive tectonic accretion and crustal thickening during the D1 event of the Eburnean orogeny. The growth of equant, high‐reflectance postkinematic nodular aggregates of Type III particles is ascribed to the reduction of CO2‐rich fluids during a hydrothermal event associated with Late Eburnean D2 exhumation and strike–slip movements. Type I carbonaceous particles were only slightly affected by high‐temperature, low‐pressure contact metamorphism during intrusion of Late Eburnean magmatic bodies, whereas formation of Type II or III particles was not recorded in contact‐metamorphosed rocks at all.  相似文献   

16.
Coals from the D-2 and D-3 boreholes in the Grove Center 7 1/2 min quadrangle, Union County, KY, have been found to be highly brecciated and mineralized. The mineralization is dominated by a carbonate assemblage with minor sulfides and sulfates. Included among the secondary minerals is the lead selenide, clausthalite. Overall, the emplacement of secondary vein minerals was responsible for raising the rank of the coals from the 0.6–0.7% Rmax range found in the area to as high as 0.95–0.99% Rmax.A 1.3-m-thick coal found in one of the boreholes is unique among known Western Kentucky coals in having less than 50% vitrinite. Semifusinite and fusinite dominate the maceral assemblages. The coal is also low in sulfur coal, which is unusual for the Illinois Basin. It has an ash yield of less than 10%; much of it dominated by pervasive carbonate veining. The age of the thick coal in core D-2 is similar to that of the Elm Lick coal bed, found elsewhere in the Western Kentucky coalfield. The coals in D-3 are younger, having Stephanian palynomorph assemblages.  相似文献   

17.
Marine, organic-rich rock units commonly contain little for vitrinite reflectance (VR0) measurement, the most commoly used method of assessing thermal maturity. This is true of the Lower Jurassic “Nordegg Member”, a type I/II, sulphur-rich source rock from the Western Canada Sedimentary Basin. This study examines the advantages and pitfalls associated with the use of Rock-Eval Tmax and solid bitumen reflectance (BR0) to determined maturity in the “Nordegg”. Vitrinite reflectance data from Cretaceous coals and known coalification gradients in the study area are used to extrapolate VR0 values for the “Nordegg”.Tmax increases non-linearly with respect to both BR0 and extrapolated VR0 values. A sharp increase in the reflectaance of both solid bitumen and vitrinite occurs between Tmax 440–450°C, and is coincident with a pronounced decrease in Hydrogen Index values and the loss of solid bitumen and telalginite fluorescence over the same narrow Tmax interval. This Tmax range is interpreted as the main zone of hydrocarbon generation in the “Nordegg”, and corresponds to extrapolated VR0 values of 0.55–0.85%. The moderate to high sulphur contents in the kerogen played a significant role in determining the boundaries of the “Nordegg” oil window.A linear relationship between BR0 and extrapolated VR0, as proposed elsewhere, is not true for the “Nordegg”. BR0 increases with respect to extrapolated VR0 according to Jacob's (1985) formula (VR0=0.618×(BR0)+0.40) up to VR0≈0.72% (BR0≈0.52%). Beyond this point, BR0 increases sharply relative to extrapolated VR0, according to the relatioship VR0 = 0.277 × (BR0) + 0.57 (R2 = 0.91). The break in the BR0−VR0 curve at 0.72%VR0 is thought to signifiy the peak of hydrocarbon generation and represents a previously unrecognized coalification jump in the solid bitumen analogous to the first coalification jump of liptinites.  相似文献   

18.
Rank evaluation of South Brazilian Gondwana coals according to the American (American Society for Testing and Materials, ASTM) and German (Deutsche Industrie Normen, DIN) standard specifications or on the basis of Alpern's Universal Classification has too often led to conflicting results.When any attempt is made to determine the rank of Brazilian coals by using methods established for the Northern Hemisphere coals, two sorts of difficulties arise: namely, (1) the reflectence measurements do not indicate the real degree of coalification of the organic matter because of the liptinitic impregnations of the vitrinites, and (2) random reflectance values (Rran, moisture, volatile-matter and carbon contents as well as the calorific value do not correlate when plotted on the ASTM and DIN classification schemes.In addition, when rank determinations are carried out by using fluorescence measurements and geochemical analyses the results are at variance in relation to those determined by the conventional chemical and physical parameters.It is suggested that the rank evaluation of South Brazilian coals is far more meaningful if carried out by reflectance measurements on vitrinites along with fluorescence measurements on sporinites, alginites and coal extracts.  相似文献   

19.
Raman spectroscopy was used as a supplementary method to characterise the thermal maturity of Ediacaran organic matter (OM) from the East European Craton. Because this method is based on organic particles measurement, it appears to be a good supplementary method in addition to the acquisition of biomarker data, which is based on extractable organic matter and may be affected by potential contamination. Raman spectroscopy seems to be particularly useful for lower Palaeozoic rocks, which do not contain vitrinite. Here, we compared C31 22S/(S + R) homohopane ratio results (obtained using gas chromatography – mass spectrometry), with various Raman parameters including: G_STA, Gmax position, Dmax/Gmax, FWHMG, RAR, D_STA, and PDmax. Close correlations were observed between C31 22S/(S + R) and G_STA, Gmax position, Dmax/Gmax, and FWHMG, reaching values of R2 = 0.5‒0.6, whereas no correlation existed between homohopane ratio and the RAR, D_STA, and PDmax parameters. Raman spectroscopy results divided Ediacaran samples into two distinctive groups: (i) immature (Russian, Lithuanian, and Belarusian), characterised by relatively higher values of G_STA, Dmax/Gmax, and FWHMG and relatively lower values of PGmax, and (ii) mature (Polish and Ukrainian), with relatively lower values of G_STA, Dmax/Gmax, and FWHMG and relatively higher values of PGmax. Within each group no statistically confirmed differences were found. However, significant discrepancies were observed between the hopane ratio and Raman parameters in Lithuanian samples, in relation to other samples from the group (i). Values of the C31 22S/(S + R) ratio for Lithuanian samples are close to those for the group (ii) and significantly higher than those for the group (i). However, all Raman parameters are the same as those of the rest samples from the group (i), indicating the immature character of OM from Lithuanian rocks. We interpret this discrepancy as representing contamination of the cores with drilling fluids, resulting in increased values for the C31 22S/(S + R) ratio. In this case, Raman spectroscopy is a useful tool for detecting extract contamination and appears to be an effective and decisive method in the case of rocks suspected of contamination.  相似文献   

20.
Characteristics of ungauged catchments can be studied from the hydrological model parameters of gauged catchments. In this research, discharge prediction was carried out in ungauged catchments using HEC-HMS in the central Omo-Gibe basin. Linear regression, spatial proximity, area ratio, and sub-basin mean were amalgamated for regionalization. The regional model parameters of the gauged catchment and physical characteristics of ungauged catchments were collated together to develop the equations to predict discharge from ungauged catchments. From the sensitivity analysis, crop coefficient (CC), storage coefficient (R), constant rate (CR), and time of concentration (TC) are found to be more sensitive than others. The model efficiency was evaluated using Nash–Sutcliffe Efficiency (NSE) which was greater than 0.75, varying between ?10% and +10% and the coefficient of determination (R2) was approximated to be 0.8 during the calibration and validation period. The model parameters in ungauged catchments were determined using the regional model (linear regression), sub-basin mean, area ratio, and spatial proximity methods, and the discharge was simulated using the HEC-HMS model. Linear regression was used in the prediction where p-value ≤ 0.1, determination coefficient (R2) = 0.91 for crop coefficient (CC) and 0.99 for maximum deficit (MD). Constant rate (CR), maximum storage (MS), initial storage (IS), storage coefficient (R), and time of concentration (TC) were obtained. The result is that an average of 30 m3/s and 15 m3/s as the maximum monthly simulated flow for ungauged sub-catchments, i.e. Denchiya and Mansa of the main river basin .  相似文献   

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