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安基山和铜山铜（钼）矿床为分别位于宁镇山脉弧形构造拐转处和弧形构造中段的两个中型矿床。前者为与燕山晚期花岗闪长斑岩石英闪长玢岩有关的、以斑岩型和矽卡岩型为主的铜（钼）矿床，岩体的单矿物Ｋ－Ａｒ同位素年龄为１２３．１×１０６—１０６．０×１０６ａ，Ｋ－Ａｒ等时线值为１２３．０×１０６ａ；后者为与燕山晚期石英闪长玢岩有关的矽卡岩型铜（钼）矿床，主岩体的Ｋ－Ａｒ同位素年龄为１１７．０×１０６ａ。从安基山铜（钼）矿床的细脉浸染型钼矿石和铜山铜（钼）矿床的浸染状钼矿石中选取了辉钼矿纯样并对其进行了Ｘ射线衍射分析，结果表明：安基山矿床的辉钼矿为２Ｈ１＋３Ｒ型，铜山矿床的辉钼矿为２Ｈ１型。采用同位素稀释－等离子体质谱法测定了辉钼矿中的１８７Ｒｅ和１８７Ｏｓ，并以衰变常数λ（１８７Ｒｅ）＝１．６４×１０－１１ａ－１计算出两矿床内辉钼矿的成矿年龄分别为（１０８±２）×１０６ａ和（１０６±３）×１０６ａ，分别比相关岩体的年龄晚１５×１０６ａ和１１×１０６ａ 相似文献
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华北地台钼（铜）矿床成矿年代学研究——辉钼矿铼－锇年龄及其地质意义 总被引：25，自引：10，他引：25
华北地台北缘的燕辽和南缘的东秦岭两个钼矿带闻名遐迩。本文用同位素稀释－等离子体质谱法，直接测定了燕辽钼矿带中兰家沟钼矿床的Ｒｅ－Ｏｓ等时线年龄为（１８６．５±０．７）×１０６ａ，杨家杖子和肖家营子钼矿床的Ｒｅ－Ｏｓ模式年龄为（１８７±２）×１０６～（１９１±６）×１０６ａ和（１７７±５）×１０６ａ，小寺沟和寿王坟铜（钼）矿床的Ｒｅ－Ｏｓ模式年龄为（１３４±３）×１０６ａ和（１４８±４）×１０６ａ，大湾和大庄科钼矿床的Ｒｅ－Ｏｓ模式年龄为（１４４．４±７．４）×１０６ａ和（１４４．７±１０．７）×１０６～（１４７．１±６．６）×１０６ａ。结合东秦岭钼矿带内钼矿床的Ｒｅ－Ｏｓ年龄，证明华北地台内有早元古代钼矿化，两个钼矿带中的钼或铜（钼）矿床的成矿时代主要为印支期和燕山早期或中—晚期。Ｒｅ－Ｏｓ法不仅是直接测定钼（铜）硫化物矿床成矿年龄的一种新手段，而且所获结果为研究区域成矿演化提供了确实的依据。 相似文献
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东秦岭地区钼矿床的铼－锇同位素年龄及其意义 总被引：51，自引：10，他引：51
金属矿床的成矿年龄多年来一直是矿床地质工作者关注的问题之一。中国地质科学院岩矿测试技术研究所建立的铼－锇同位素定年实验室，为研究钼矿床的形成时代提供了新的手段。因辉钼矿是最主要的含铼矿物之一，且基本上不含普通锇，其中所含￣（１８７）Ｏｓ是由￣（１８７）Ｒｅ衰变而来，故放射成因￣（１８７）Ｏｓ的积累是矿物年龄及铼含量的函数，本文采用同位素稀释－等离子体质谱法，测定了东秦岭钼矿带中几个不同类型的大型钼矿床的Ｒｅ－Ｏｓ年龄：黄龙铺碳酸岩脉型钼（铅）矿氏的Ｒｅ－Ｏｓ年龄为印支期，其余的斑岩型钼矿床和斑岩－矽卡岩型钼（钨）矿床的Ｒｅ－Ｏｓ年龄均为燕山期。 相似文献
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柿竹园钨多金属矿床的Re—Os同位素等时线年龄研究 总被引：72，自引：4，他引：72
柿竹间钨多金属矿床科于千里山复式岩体与泥盆系碳酸盐岩的接触部位，其成矿时代以往都是用矿体附近的花岗岩体年龄来间接推断。我们最近采用辉钼矿的Ｒｅ－Ｏｓ等时线定年法直接测定与千里山第一期花岗岩有关的夕卡岩型矿体的矿化年龄为１５１．０±３．５Ｍａ。该年龄晚于第一期花岗岩，但早于第二期花岗岩，从而证实钨多金属矿化在花岗岩系列的早期早阶段也可以成矿。该年龄与野外观察的地质情况十分吻合，而辉钼矿是热液矿床中的 相似文献
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特大型矿床成矿偏在性研究的新进展 总被引：5，自引：2，他引：5
特大型矿床成矿偏在性研究的新进展ＮｅｗＡｄｖａｎｃｅｓｉｎｔｈｅＳｔｕｄｙｏｆＭｅｔａｌｌｏｇｅｎｅｓｉｓＰｒｅｆｅｒｅｎｔｉａｌｉｔｙｏｆＧｉａｎｔＯｒｅＤｅｐｏｓｉｔｓ裴荣富，吴良士（中国地质科学院矿床地质研究所，北京）特大型矿床系指其规模为大—... 相似文献
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在 2 0世纪 90年代 ,ＲｅＯｓ同位素体系定年受到许多矿床学家的瞩目 ,因为与其他同位素体系定年方法比较 ,这种方法能对金属矿物直接进行定年 ,有助于研究矿床的形成与成矿动力学过程。目前较广泛应用的测定对象是辉钼矿。在这种矿物中 ,Ｒｅ由于其地球化学性质 ,能置换矿物晶格中的Ｍｏ ,Ｗ等元素 ,赋存晶格中 ,而初始普通Ｏｓ含量很低 ,可以忽略 ,因此很适合用于定年 ,也有许多成功的经验。但在ＲｅＯｓ法对金属矿物进行定年时 ,仍存在一些技术问题。对辉钼矿定年时 ,一般不考虑初始普通Ｏｓ,这样可以用模式年龄法测年 ,但有时某些样品中… 相似文献
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Ｔｅｌｆｅｒ金矿位于澳大利亚西部的Ｐａｔｅｒｓｏｎ省，是澳大利亚大型金矿之一。该矿自１９７７年开采以来其产金总量已超过１２５ｔ。矿床产于北西向的Ｔｅｌｆｅｒ穹隆内，金和伴生铜呈一系列垂向上叠置的层控或层状的金－铜硫化物石英矿脉产出。成矿时代为晚元古代（７００￣６００Ｍａ），成矿主岩为上Ｙｅｎｅｅｎａ群（约１０００￣７５０Ｍａ）低变质海相沉积岩系。硫化物矿石和蚀变矿物（碳酸盐和电气石）的Ｃ、Ｏ、Ｂ、 相似文献
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辉钼矿铼－锇同位素年代学研究简介 总被引：1，自引：0，他引：1
辉钼矿铼－锇同位素年代学测定依据该矿物中含有由１８７Ｒｅ通过β－衰变而形成的放射性成因１８７Ｏｓ。这一同位素年代学方法由于８０年代以来微量铼、锇同位素质谱技术的成熟而逐渐应用于研究中，获得了具有地质意义的年龄值。对辉钼矿年龄测定的成功与否，选择适当的样品至关重要。一般而言，红外透光性（ｉｎｆｒａｒｅｄｔｒａｎｓｐａｒｅｎｃｙ）大于３．５的辉钼矿样品适合于铼－锇同位素年代学研究，其辉钼矿的铼－锇同位素年龄值十分接近于围岩的钾－氩或其它常规同位素方法的年龄值。 相似文献
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浙江省桐村钼矿床Re-Os同位素年龄及地质意义 总被引：4，自引：0，他引：4
浙江桐村斑岩型钼矿床位于钦杭成矿带东段,紧邻赣东北成矿带,矿床的形成与燕山早期侵入的同熔型花岗岩有关,含矿岩体的成岩年龄165 ～168Ma.辉钼矿矿石呈浸染状产于岩体内部或岩体与围岩的接触带.本文首次对矿床中3件辉钼矿样品进行了Re-Os同位素年代学研究,测得辉钼矿的等时线年龄为162.2Ma±1.3 (MSWD =0.006),代表了成矿年龄.成矿成岩年龄具有一致性,矿床成因类型为斑岩-矽卡岩型钼(铜)矿床. 相似文献
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Jiantang Peng Mei-Fu Zhou Ruizhong Hu Nengping Shen Shunda Yuan Xianwu Bi Andao Du Wenjun Qu 《Mineralium Deposita》2006,41(7):661-669
The Yaogangxian deposit in the central Nanling region, South China consists of vein-type ore bodies hosted in Cambrian to Jurassic strata and Mesozoic granitic intrusions. Wolframite and molybdenite are the dominant ore minerals intergrown with gangue minerals of quartz, feldspar, phlogopite, and muscovite. We have carried out molybdenite Re–Os and phlogopite and muscovite 40Ar/39Ar dating to better understand the timing and genesis of mineralization. Re–Os dating of eight molybdenite samples yielded model ages ranging from 152.0±3.5 to 161.1±4.5 Ma, with an average of 156.0 Ma. The Re–Os analyses give a well-defined 187Re/187Os isochron with an age of 154.9±2.6 Ma (MSWD=2.4). Hydrothermal phlogopite and muscovite display extremely flat 40Ar/39Ar age spectra. Phlogopite yields a 40Ar/39Ar plateau age of 153.0±1.1 Ma, whereas muscovite yields a plateau age of 155.1±1.1 Ma. Both 40Ar/39Ar ages are in good agreement with the Re–Os ages, placing the timing of tungsten mineralization at about 154 Ma. This age is consistent with the field relationships. Our new data, when combined with published geochronological results from other major deposits in this region, suggest that large scale W–Sn mineralization occurred throughout the central Nanling region in the Late Jurassic. 相似文献
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Re-Os法能够直接厘定内生金属矿床成矿时代,但是封闭Carius管法化学流程复杂,且有一定的危险性。本文建立了一种简便快速测定辉钼矿Re-Os年龄及其Re含量的方法。用3 mL浓硝酸在10 mL比色管中溶解5~15 mg辉钼矿样品,将溶液中的钼酸沉淀分离后稀释定容,直接采用质谱测量187和185质量数比值(M187/M185)。利用辉钼矿Re-Os年龄标准物质JDC和HLP的M187/M185值与其年龄的正相关线性关系计算未知辉钼矿样品的Re-Os年龄,并通过185Re计数利用相对法计算Re含量。本方法应用于测量13.26~2130 Ma的辉钼矿,Re-Os年龄的测定值与推荐值的相对偏差多数在0.36%~7.42%之间,由于放射性积累较多,长年龄样品测量的准确度较高。与传统Carius管法相比,该方法不需要加入稀释剂,省去了封闭和打开Carius管环节以及Re-Os分离纯化流程,适合于辉钼矿Re-Os年龄的初步分析。 相似文献
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含辉钼矿全岩样品Re-Os同位素定年研究:在北京大庄科钼矿床中的应用 总被引：1，自引：1，他引：0
采用硝酸在比色管中对辉钼矿样品中Re含量进行初测的方法,测得辉钼矿标准样品JDC Re含量与推荐值在误差范围内基本一致,与传统的Carius管法相比,该方法具有简便快速的特点。传统的辉钼矿Re-Os同位素定年分析对象为辉钼矿单矿物,根据所测得的187Re/187Os值获得辉钼矿的Re-Os年龄,Re、Os在辉钼矿中大量富集,而在硅酸盐矿物中几乎没有,探索性地对含有辉钼矿的全岩样品进行Re-Os同位素定年,虽然所得Re、Os含量偏低,但187Re/187Os值不会变。该方法省去了选样过程花费的大量时间,避免了选样过程中可能造成的交叉污染。采用同位素稀释Carius管逆王水法探索性地对北京大庄科钼矿床中含辉钼矿全岩样品进行Re-Os同位素年龄测定,获得了(137.6±3.7)Ma精确的等时线年龄,与挑选出辉钼矿单矿物样品的Re-Os同位素等时线年龄(136.8±2.6)Ma吻合较好,直接厘定了大庄科钼矿的成矿时代。该年龄与矿区汉家川石英二长岩锆石U-Pb年龄一致,表明大庄科钼矿的形成与汉家川石英二长岩关系较为密切,为中国东部第二期大规模成矿作用的产物,形成于中国东部岩石圈伸展环境。 相似文献
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Re–Os and U–Pb Geochronology of Porphyry and Skarn Types Copper Deposits in Jilin Province,NE China 
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下载免费PDF全文 Yong Zhang Shu–Wen Xing Quan–Heng Song Yan Wang Zheng–Tao Yu Xiao–Hui Du Yu–Bo Ma Zeng–Jie Zhang 《Resource Geology》2015,65(4):394-404
Jilin Province in NE China lies on the eastern edge of the Xing–Meng Orogenic Belt. Mineral exploration in this area has resulted in the discovery of numerous large, medium, and small sized Cu, Mo, Au, and Co deposits. To better understand the formation and distribution of both the porphyry and skarn types Cu deposits of the region, we examined the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of the mineralization. The Binghugou Cu deposit yields a zircon U–Pb age for quartz diorite of 128.1 ± 1.6 Ma; the Chang'anpu Cu deposit yields a zircon U–Pb age for granite porphyry of 117.0 ± 1.4 Ma; the Ermi Cu deposit yields a zircon U–Pb age for granite porphyry of 96.8 ± 1.1 Ma; the Tongshan Cu deposit yields molybdenite Re–Os model ages of 128.7 to 130.2 Ma, an isochron age of 129.0 ± 1.6 Ma, and a weighted mean model age of 129.2 ± 0.7 Ma; and the Tianhexing Cu deposit yields molybdenite Re–Os model ages of 113.9 to 115.2 Ma, an isochron age of 114.7 ± 1.2 Ma, and a weighted mean model age of 114.7 ± 0.7 Ma. The new ages, combined with existing geochronology data, show that intense porphyry and skarn types Cu mineralization was coeval with Cretaceous magmatism. The geotectonic processes responsible for the genesis of the Cu mineralization were probably related to lithospheric thinning. By analyzing the accumulated molybdenite Re–Os, zircon U–Pb, and Ar–Ar ages for NE China, it is concluded that the Cu deposits formed during multiple events coinciding with periods of magmatic activity. We have identified five phases of mineralization: early Paleozoic (~476 Ma), late Paleozoic (286.5–273.6 Ma), early Mesozoic (~228.7 Ma), Jurassic (194.8–137.1 Ma), and Cretaceous (131.2–96.8 Ma). Although Cu deposits formed during each phase, most of the Cu mineralization occurred during the Cretaceous. 相似文献
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马家洼金钼矿床位于小秦岭北缘,矿体发育在由近东西向脆韧性断裂构造带控制的石英脉中。对该矿床辉钼矿样品进行的Re-Os同位素年代学研究表明:模式年龄范围是232.5～268.4 Ma,等时线年龄为(232±11)Ma,即钼成矿作用时代为早、中三叠世。辉钼矿样品的Re含量范围是(0.474～0.791)×10~(-6),初始~(187)Os/~(188)Os比值为2.4±6.4,Re-Os同位素组成特征指示了成矿物质主要来源于地壳。马家洼石英脉型金钼矿床是区域伸展体制下构造-流体成矿事件的产物。在华北板块南缘太古宙基底岩系中的脆韧性断裂构造带中寻找印支期和燕山期石英脉型金钼矿床和钼矿床是一个新的找矿方向。 相似文献
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Ran Wang Yong‐Jun Li Xin Han Jun‐Nian Wang Jing Yan Yu‐Mei Zhao 《Resource Geology》2013,63(4):412-420
The Karamay porphyry Mo–Cu deposit, discovered in 2010, is located in the West Junggar region of Xinjiang of northwest China. The deposit is hosted within the Karamay granodiorite porphyry that intruded into Early Carboniferous sedimentary strata and its exo‐contact zone. The LA‐ICPMS U–Pb method was used to date the zircons from the granodiorite samples of the porphyry. Analyses of 12 spots of zircons from the granodiorite samples yield a U–Pb weighted mean age of 300.8 ± 2.1 Ma (2σ). Re–Os dating for five molybdenite samples obtained from two prospecting trenches and three outcrops in the deposit yield a Re–Os isochron age of 294.6 ± 4.6 Ma (2σ), with an initial 187Os/188Os of 0.0 ± 1.1. The isochron age is within the error of the Re–Os model ages, demonstrating that the age result is reliable. The Re–Os isochron age of the molybdenite is consistent with the U–Pb age of the granodiorite porphyry, which indicates that the deposit is genetically related with an Early Permian porphyry system. The ages of the Karamay Mo–Cu deposit and the ore‐bearing porphyry are similar to the ages of intermediate‐acid intrusions and Cu–Mo–Au polymetallic deposits in the West Junggar region. This consistency suggests the same geodynamic process to the magmatism and related mineralization. 相似文献
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《International Geology Review》2012,54(14):1763-1785
Central Jilin Province lies along the eastern edge of the Xing–Meng orogenic belt of northeast China. At least 10 Mo deposits have been discovered in this area, making it the second-richest concentration of Mo resources in China. To better understand the formation and distribution of porphyry Mo deposits in the area, we investigated the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of mineralization. Our new geochronological data show the following: the Jidetun Mo deposit yields molybdenite Re–Os model ages of 164.6–167.1 Ma, an isochron age of 168 ± 2.5 Ma, and a weighted mean model age of 165.9 ± 1.2 Ma; the Houdaomu Mo deposit yields molybdenite Re–Os model ages of 167.4–167.7 Ma, an isochron age of 168 ± 13 Ma, and a weighted mean model age of 167.5 ± 1.2 Ma; and the Chang’anpu Mo deposit yields a zircon U–Pb age for granodiorite porphyry of 166.9 ± 1.5 Ma (N = 16). These new age data, combined with existing molybdenite Re–Os dates, show that intense porphyry Mo mineralization was coeval with magmatism during the Middle Jurassic (167.8 ± 0.4 Ma, r > 0.999). The geotectonic mechanisms responsible for Mo mineralization were probably related to subduction of the Palaeo-Pacific plate beneath the Eurasian continent. Combining published molybdenite Re–Os and zircon U–Pb ages for northeast China, the Mo deposits are shown to have been formed during multiple events coinciding with periods of magmatic activity. We identified three phases of mineralization, two of which had several stages: the Caledonian (485–480 Ma); the Indosinian comprising the Early–Middle Triassic (248–236 Ma) and Late Triassic (226–208 Ma) stages; and the Yanshanian phase comprising the Early–Middle Jurassic (202–165 Ma), Late Jurassic–early Early Cretaceous (154–129 Ma), and Early Cretaceous (114–111 Ma) stages. Although Mo deposits formed during each phase/stage, most of the mineralization occurred during the Early–Middle Jurassic. 相似文献
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含有普通锇的辉钼矿Re-Os同位素定年研究 总被引：14，自引：3，他引：11
通过大量数据统计,表明较高比例的辉钼矿中存在普通锇。普通锇可能以类质同像形式存在于辉钼矿样品中,理论上辉钼矿中可能含有较高含量普通锇。辉钼矿样品含有较高含量普通锇可能对Re-Os定年结果产生很大影响,从原理上并结合实例证实了普通锇含量对辉钼矿Re-Os年龄影响程度。对于一般辉钼矿样品来讲,如果187Os总量(放射成因187Os与非放射成因187Os之和)与普通锇比值小于20,需要考虑普通锇对Re-Os模式年龄的影响,并提出了对于含有普通锇辉钼矿模式年龄的计算方法。先做出187Os/188Os-187Re/188Os等时线,求得初始187Os/188Os值,再根据初始187Os/188Os值和单个样品的普Os含量求得非放射成因的普Os中187Os的量。最后根据Re含量以及放射成因187Os含量得到模式年龄。 相似文献