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1.
含铁闪锌矿热容的实验测定与分析 总被引：1，自引：0，他引：1
利用美国ＤｕＰｏｎｔ公司的９９００型差示扫描量热仪对３个含铁闪锌矿样品的热容进行了实验测定,并讨论了定压摩尔热容实验值与实验温度的关系。实验结果表明,在实验条件下,含铁闪锌矿的定压摩尔热容与纯闪锌矿的定压摩尔热容存在显著差异,Ｆｅ置换Ｚｎ是造成这种差异的主要原因。 相似文献
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山东蓝色蓝宝石的着色是由Ｔｉ４＋离子与Ｆｅ２＋离子合理配比而成，一般控制在Ｔｉ４＋／Ｆｅ２＋＝１的配比范围内。多余的Ｆｅ２＋和其它Ｆｅ３＋离子存在都不利于蓝色蓝宝石正常呈色。通过穆斯堡尔谱和电子顺磁共振谱分析，测定了山东蓝宝石中铁离子的不同价态和浓度。对Ｆｅ２＋和Ｆｅ３＋离子所引起的吸收光谱特征作了研究，查明只有Ｆｅ３＋浓度很高时才产生４７７ｎｍ吸收峰，是致使山东蓝宝石表观上呈深蓝带黑色调的的重要原因。 相似文献
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锡铁山石晶体结构中Fe3+的两种亚晶位 总被引：1，自引：0，他引：1
对产于青海锡铁山铅锌矿氧化带中的锡铁山石进行了５７Ｆｅ穆斯堡尔谱的研究，在晶体结构分析的基础上进行了谱峰的重新解释，发现由于配位Ｃｌ－离子无序占位引起Ｆｅ３＋离子所占配位八面体的畸变，形成了Ｆｅ３＋的两种亚晶位，并根据结构数据指定了这两种亚晶位各自形成的四极双峰。 相似文献
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蒙脱石中铁的赋存状态的研究 总被引：2，自引：2，他引：2
通过对徐闻、三水、高州等地五个样品的Ｘ射线衍射分析，化学全分析，分析它们为含铁量不同的蒙脱石，层间可交换阳离子主要为Ｃａ＾２＋。几个样品穆斯堡尔谱表明铁主要以Ｆｅ＾３＋的形式存在，含铁量较高的样品ＸＧＡ、ＸＳＡ、ＳＳ的谱可以拟合出Ｆｅ＾３＋的二对四级双峰，表明铁在蒙脱石中占据两种不等同的八面体位置。 相似文献
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混合价态和中间价态硫的Ｆｅ、Ｐｂ和Ｚｎ化合物在带状闪锌矿、黄铁矿－胶黄铁矿和方铅矿中形成普遍的包体和残留物。带状硫化物的品位常随带状的混合价和中间价态硫化物的提高而提高，后者具有纤维状的微细结构。纤维状微细结构同样存在于比利时和波兰Ｚｎ－Ｐｂ矿床中的带状闪锌矿和黄铁矿中。 相似文献
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有关蓝宝石的顺磁共振研究已有很多报道。在以往的报道中,大多偏向于蓝宝石中Ｆｅ谱线的价态归属和含量高低等方面的研究。而对其中Ｆｅ３＋置换Ａｌ３＋以后有关Ｆｅ３＋的占位特征、畸变程度、磁学性质等有关顺磁共振谱与结构之间的关系,讨论得很少。本文对山东蓝色蓝... 相似文献
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墨铜矿的穆斯堡尔谱特征 总被引：1，自引：0，他引：1
墨铜矿是典型的异类矿物结构基元层间层矿物．在其结构中，Ｆｅ可占据硫化物层中四次配位和氢氧化物层中六次配位两种位置。本文通过穆斯堡尔谱研究，确定了墨铜矿的穆斯堡尔谱谱型，并认为高自旋的Ｆｅ２＋占据四次配位位置，与Ｃｕ离子一起可能呈无序占位，配位环境的对称性较低，谱参数为：ＩＳ＝０．４２－０．４８ｍｍ／ｓ、ＱＳ＝０．８１－１．２８ｍｍ／ｓ及Ｈｉ约为２４０ＫＯｅ；低自旋的Ｆｅ３＋占据六配位位置，ＩＳ值为０．３２－０．３６ｍｍ／ｓ、ＱＳ值为０．４４－０．５９ｍｍ／ｓ。 相似文献
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氢化物—原子荧光法测定岩石中痕量硒的干扰及消除 总被引：12，自引：10，他引：12
用ＨＦ－ＨＣｌＯ４－ＨＮＯ３混合酸分解样品，采用Ｆｅ＾３＋作释放剂，研究了不同量的Ｆｅ＾３＋与ＨＣｌ酸度对Ｓｅ荧光强度的影响和干扰离子消除的效果，以及Ｆｅ＾３＋存在Ｔｅ存在下对Ｓｅ测定的影响。方法的检出限为０．０１μｇ／ｇ．样品中Ｓｅ量为０．１μｇ／ｇ的相对标准偏差（ｎ＝１１）是５．４％。用于岩石标样中痕量Ｓｅ的测定，结果较好。 相似文献
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本文对辽宁宽甸碱性玄武岩中巨晶单斜辉石进行穆斯堡尔谱研究，应用晶体结构研究结果较合理地解释了单斜辉石的异常穆斯堡尔谱，结合ＸＲＤ讨论了单斜辉石中Ｆｅ结构态的测定以及穆斯堡尔谱的可应用性，巨晶应结晶于相当氧化的环境。 相似文献
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闪锌矿的吸收光谱和颜色的本质 总被引：1，自引：0，他引：1
本文采用电子吸收光谱和分子轨道（MO）－能带理论模型，系统地研究了不同颜色的闪锌矿呈色的机理和本质。闪锌矿由于其形成条件不同，所含杂质元素各异而颜色变化。黑色闪锌矿含Fe高，其颜色是由于以配位体硫为特征的非键轨道2e到Fe^2 的晶体场型轨道的电子转移在500nm产生吸收所致。只有闪锌矿含Fe低（＜1％）时，它才可具有其他颜色，黄色与受主能级Cu^ 到导带或价带到施主能级Ga^3 的电子跃迁在410nm产生吸收有关；绿色是Co^2 的晶体场跃迁^4A2→^4T2(P)在700nm附近产生的吸收峰所致；红色可能与受主能级Hg^ 到施主能级Ga^3 的电子跃迁在470nm产生宽吸收带有关。当闪锌矿的吸收光谱有其中两个吸收带叠加时，它具有过渡的颜色，如黄绿色或绿黄色、桔黄色或桔红色，主要色调取决于两个吸收带的相对强度。 相似文献
12.
C. A. McCammon I. Jackson A. E. Ringwood J. D. Cashion 《Physics and Chemistry of Minerals》1984,11(4):182-193
(Fe, Mn)S and (Fe, Mg)S solid solutions are examined to study and compare the properties of Fe2+ in two different B1-structured hosts, and also to study the relative stability of the B1 (NaCl) and B8 (NiAs) structures at high pressure. The Mössbauer spectra of (Fe, Mn)S and (Fe, Mg)S B1 solid solutions are quadrupole doublets at 298 K with parameters which vary smoothly with Fe2+ concentration. At 4.2 K the Mössbauer spectra of (Fe, Mn)S and Fe-rich (Fe, Mg)S B1 solid solutions are magnetically split into eight lines, but the spectra of Mg-rich (Fe, Mg)S solid solutions are quadrupole doublets. The line widths of the magnetic spectra are broad, consistent with a multiaxial spin arrangement. Some properties of the hypothetical phase FeS(B1) are calculated from the solid solution data; the phase is inferred to be relatively ionic compared to FeS(B8) and has a molar volume that is 7.2 percent larger than the B8 phase at 298 K. The large inferred volume difference between FeS(B1) and FeS(B8) should cause exsolution of a B8-structured phase from (Fe, Mn)S and (Fe, Mg)S B1 solid solutions at high pressure. This behaviour is confirmed experimentally at high pressure using X-ray diffraction and Mössbauer spectroscopy, and the results are correlated with thermodynamic calculations of the phase boundaries based on estimates of the volume and free energy differences between the B1 and B8 phases of FeS derived from atmospheric pressure data. The absence of an increase in solubility of Mg and Mn in the B8 phase with pressure suggests that any polymorphism in MnS and MgS at high pressure is unlikely to involve the B8 phase. Shock wave data for MgO and Fe0.94O reported in the literature suggest similar behaviour in the system FeO-MgO at high pressure, namely exsolution of essentially pure FeO(hpp) from (Fe, Mg)O B1 solid solutions. 相似文献
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福建尤溪梅仙矿床闪锌矿中黄铜矿交生体的交代成因 总被引：3，自引：2，他引：1
福建尤溪梅仙块状硫化物矿床中的闪锌矿经５０％ＨＮＯ３浸蚀后发现,微米级的黄铜矿交生体呈乳滴状,棒条状,蠕虫状等沿闪锌矿解理面,双晶面和颗粒边界,裂隙等处分布,并且黄铜矿交生体所占体积均在５％以上,因上闪锌矿中有限的Ｃｕ的溶解度使出溶无法解释黄鲷矿交生体的成因,交生体的结构特征以其与黄铜矿脉的关系暗示其可能是交代成因。而对横切黄铜矿乳滴的电子探针分析中铁含量特征的研究,证实梅仙矿区闪锌矿中的黄铜矿交 相似文献
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Crystal chemistry of Fe-containing sphalerites 总被引：2，自引：0，他引：2
Cell dimensions and solvus properties of Fe-containing sphalerites, depending on temperature and sulfur fugacity, were investigated
using equilibrated powdered materials synthesized from elements and binary sulfides under vacuum. The Fe solvus in sphalerite,
determined by optical microscopy and microprobe analysis, are directly correlated with increasing temperature and decreasing
sulfur fugacity controlled by solid-state buffers. The increase of lattice parameters with Fe correlates with an increase
of FeS independent of sulfur fugacity up to 10 mol% FeS within ZnS. Above about 10 mol% the lattice parameters are strongly
depending on the sulfur fugacity controlled Fe3+/Fe2+ ratios. The Fe3+/Fe2+ ratios determined by Moessbauer spectroscopy and involving metal vacancies depend on the sulfur fugacity. The critical Fe2+ content determined by experimental simulations as well as the minimal Fe3+/ Fe2+ ratios agree with the required minimal Fe content for CuFeS2-DIS in sphalerite. The critical Fe2+ content also agrees with the change of Moessbauer signal from a singlet to a doublet for Fe2+ containing sphalerite. Pyrrhotite exsolutions in sphalerite caused by higher sulfur fugacity show orientationally intergrown
with the sphalerite matrix. Density data calculated from lattice parameters and composition are compared with experimental
density measurements.
Received: 25 April 2001 / Accepted: 14 February 2003 相似文献
15.
Quantum mechanical techniques, based on density functional theory, have been used to study the distribution of iron impurities in sphalerite (ZnS) at compositions ranging from 3.125 to 12.5 mol% FeS. Our results show that iron is most easily incorporated by direct substitution onto the zinc site and that energies for solution reactions involving FeS are exothermic when the system is zinc deficient. Furthermore, there appears to be a small driving force for the formation of bound Fe-Fe pairs at low iron concentrations, though there is no particular preference found for larger clusters of iron. The influence of iron on the sphalerite cell parameter is shown to be sensitive to the presence of Fe-Fe pairs and to the degree of sample non-stoichiometry. 相似文献
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本文通过对三种含钕固体,包括玻璃、陶瓷釉层和NdP_5O_(14)晶体中Nd~(3+)的吸收谱进行测定,解释了这三种物质的呈色机理,探讨了在固体中引起Nd离子吸收光谱变化的因素,并给出了在谱图中各个吸收峰所对应的能级。 相似文献
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The partitioning of Fe and Zn between coexisting fahlore and sphalerite and fluid inclusions in sphalerite from the Darasun gold deposit have been studied. These data were used to estimate the formation temperature of the minerals by the sphalerite–fahlore geothermometer. The calculated crystallization temperature of 175–355°С is close to the homogenization temperature of fluid inclusions in sphalerite of 225–385°С.The estimated pressure for fluid inclusion trapping ranged from 340 to 1420 bar. The sulfur fugacity obtained from the FeS content in sphalerite associated with pyrite and the calculated temperature ranges from 10–5.5 to 10–11 bar. 相似文献
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俄罗斯水热法合成祖母绿是珠宝界较关注的产品。选用5粒俄罗斯水热法合成祖母绿样品进行了常规宝石学特征测试、电子探针成分分析、红外吸收光谱和紫外-可见吸收光谱测定。结果表明,俄罗斯水热法合成祖母绿样品以低碱、富Fe与Cr为特征,折射率和相对密度明显偏高,红外吸收光谱特征峰出现在4052cm叫附近;俄罗斯水热法合成祖母绿样品的致色元素为Cr与Fe。同时,对比分析了俄罗斯、桂林水热法合成祖母绿样品和天然祖母绿样品的宝石学特征。 相似文献