共查询到17条相似文献，搜索用时 156 毫秒
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次火山热变质煤中Ge、Ga、As、S的分布特征 总被引：5，自引：1，他引：4
五牧场区是内蒙东部伊敏褐煤盆地中一个因次火山侵入作用形成的局部的烟煤区。在煤变质过程中,锗、硫从高变质煤中逸出,并在上部低变质煤中富集。锗、硫、砷与煤中有机质呈正相关,镓与煤中灰分呈正相关,随变质程度增加相关性下降。 相似文献
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样品采自伊敏褐煤盆地中一个因次火山活动形成的烟煤区,包含了从褐煤到瘦煤的变质系列。红外光谱分析表明,煤的含氧基团在褐煤阶段已开始消失,烷基和芳环同步增加,在R°=1.10%时达最大值。顺磁共振自由基浓度和X-衍射参数La/Lc介于区域变质煤和岩浆接触热变质煤之间,芳核外官能团的热演化超前于芳核骨架及R°的演化。 相似文献
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煤结构与煤变质程度关系初探 总被引：1，自引：0，他引：1
本文研究了煤大分子结构的芳香性和缩合程度,查明了由褐煤到低变质烟煤,从低变质烟煤到高变质烟煤,再到无烟煤,煤结构变化有不同的特征,从而可以根据化学组成和结构特征划分煤变质阶段。 相似文献
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伊敏盆地五牧场煤变质作用及煤层气地质特征研究 总被引：2，自引：0，他引：2
伊敏盆地五牧场区大磨拐图河组煤变质梯度△Ｒ°ｍ／１００＝０．５４％，从褐煤到贫煤均有发育。地震资料和围岩蚀变证实在大磨拐图河组之下发育一小型岩株，其埋深为２０００ｍ左右。岩浆热力引起的高温低压变质条件导致煤中孔隙裂隙的充分发育。含煤段之上厚３００ｍ的泥岩有效阻止煤层气的逸散，煤储层可具有较高的含气饱和度。五牧场区烟煤储量丰富，单层煤厚度多在２ｍ以上，煤累计厚度达３０ｍ以上，富煤带与中变质煤区大部分重叠。煤层埋深３５０ｍ～１０００ｍ，倾角在１５°以内，具备较好的煤层气勘探开发条件。 相似文献
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贵州省煤炭资源赋存规律 总被引：2，自引：0，他引：2
通过系统收集、整理贵州省50余年来的各项煤田地质勘查资料和科研成果,以聚煤规律和构造控煤作用为切入点,对贵州省煤炭资源赋存规律进行研究。结果表明:贵州含煤区主要位于扬子陆块南部被动边缘褶冲带上,赋煤单元划分为4个赋煤带9个煤田,共有5类15种控煤构造样式,控煤构造方向有近南北向、北东向、北西向和近东西向4组;本区主要含煤地层为上二叠统,沉积古地理自西向东由陆相逐渐向海相过渡,其中三角洲平原相聚煤最好,聚煤中心在西部盘县、水城一带,煤层以中灰分、中-高硫煤为主,煤的变质作用类型主要为深成变质作用和区域岩浆热变质作用。研究结果为贵州省煤炭资源潜力评价提供依据,对煤炭资源进一步勘查具有指导意义。 相似文献
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宁夏煤炭资源丰富,煤类多,在区域和垂向上呈现出明显的规律性。晚古生代煤层以中、高变质的烟煤、无烟煤为主,中生代煤层以低变质的烟煤为主,从各含煤区分布看,贺兰山、香山含煤区多为高变质的烟煤和无烟煤,灵盐、固原含煤区以低变质烟煤为主,青铜峡-固原深断裂西部的煤变质程度明显高于东部。分析认为深成变质作用对各时代煤变质具有普遍意义,在此基础上,岩浆热力变质作用和动力变质作用也是导致局部地区煤变质增高的因素,如贺兰山含煤区的汝箕沟矿区,受隐伏岩浆热力影响,以岭大井田为中心,呈现北东向展布的半环带状煤级分带;香山含煤区各时代煤类分布方向与区域构造线方向一致,推测可能在深成变质作用下叠加了岩浆热力变质和动力变质作用。 相似文献
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样品采自伊敏褐煤盆地中一个因次火山活动形成的烟煤区，包含了从褐煤到瘦煤的变质系列。红外光谱分析表明，煤的含氧基团在褐煤阶段已开始消失，烷基和芳环同步增加，在Ｒ＾Ｏ＝１．１０％时达最大值。顺磁共振自由其浓度和Ｘ－衍射参数Ｌａ／Ｌｃ介于区域变质和岩浆接触热变质煤之间，芳核外官能团的热演化超前于芳核骨架及Ｒ＾ｏ的演化。 相似文献
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通过对鹤岗煤田区域地层、区域构造、岩浆活动规律的分析研究，阐述了鹤岗煤田煤变质作用以区域变质作用为主，局部出现接触变质作用。在走向上煤的变质程度由南向北逐渐增高，在倾向上煤层随赋存深度的增大变质程度逐渐增高。 相似文献
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山东黄河北煤田岩浆岩特征及其对煤层煤质的影响 总被引：3，自引：0，他引：3
论述了山东省黄河北煤田岩浆岩特性特征、空间分布特点及其对煤层煤质的影响。认为三层岩浆岩是由不同时期从两个方向侵入到本区的,对煤层煤质都有不同程度的影响,形成煤的变质分带。 相似文献
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Daishe Wu Haiwen Deng Baoshan Zheng Wuyi Wang Xiuyi Tang Huayun Xiao 《Applied Geochemistry》2008,23(8):2082-2090
To determine the I distribution in Chinese coals, a nationwide survey was undertaken based on the distribution, periods of formation, rank and production yields of various coal deposits. A total of 305 coal samples were collected and their I contents were determined by catalytic spectrophotometry with pyrohydrolysis. The geochemistry of I during coalification (including both peat diagenesis and coal metamorphism) was assessed. It was found that the I contents of Chinese coals range from 0.04 mg kg–1 to 39.5 mg kg–1 and exhibit a lognormal distribution, with a geometric mean of 1.27 mg kg–1. Statistical correlation analysis and the observation that I contents increase with coal rank indicate that coal I is chalcophile in nature, and not generally organically bound. When peat developed into lignite through diagenesis, 95–99.9% of the original I was lost. The composition and structure of clay minerals present in the coal were controlled by the original depositional environment. The higher the I content of coals, the more likely the original sediments were affected by a marine environment. Iodine contents increased from lignite through sub-bituminous and bituminous coals to anthracite. This indicates that coal absorbed excess I from hydrothermal fluids during metamorphism (including geothermal metamorphism and telemagmatic metamorphism). The telemagmatic metamorphism was caused by magmatic activities that depended on the specific geological structure of the region. In China, most high-rank coals were formed by telemagmatic metamorphism. 相似文献
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中国包含多种煤阶煤层,由于煤质、地质条件等差异,不同煤层中的水分赋存情况也具有较大差异性。煤阶、饱水度作为影响液氮低温致裂效果的两个重要因素,有必要对其进行深入研究。为此,分别选择褐煤、烟煤与无烟煤3种煤阶煤样,并制备得出饱水度分别为0%、33%与99%的煤样进行液氮溶浸处理,使用摄像机定点拍摄、观察煤样表面宏观裂隙处理前后的演化规律,并对煤样进行氮气渗流试验。试验结果表明：液氮溶浸后褐煤因产生的一条与多条贯穿裂隙发生整体结构上的断裂,烟煤表面有新裂隙产生,原生宏观裂隙有一定的扩展与延伸,无烟煤表面宏观裂隙无明显发育;煤样饱水度越高,液氮的致裂增透效果越显著;液氮溶浸对3种煤阶煤样的致裂增透效果关系为：褐煤>烟煤>无烟煤,在完全干燥状态下,由于热应力不足以破坏颗粒间链接,烟煤与无烟煤的增透效果近似相等;对于褐煤,液氮溶浸处理对完全干燥状态下的煤体即产生有效致裂,渗透率平均增幅高达559.35%,对于烟煤,在饱水度为33%和99%的状态下,液氮溶浸对煤体具有明显致裂效果,渗透率平均增幅分别为330.60%和448.77%,对于无烟煤,在饱水度为99%的状态下液氮溶浸处理才能对煤体产生有效致裂,渗透率平均增幅为185.53%。 相似文献
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湘赣中南部地区煤的岩浆热变质作用 总被引：6，自引：0，他引：6
湘赣中南部地区的煤主要是高变质煤。虽然深成变质作用存在,但煤本身变化显著,煤与石墨、天然焦同层异矿,煤层围岩蚀变和煤变质带展布与侵入岩体及火山岩的分布密切相关等,都证明岩浆热变质作用是湘赣中南部地区煤变质作用的主要类型。印支—燕山期的岩浆活动形成广阔的高温区,从而形成这一地区大量的高变质烟煤和无烟煤。侵入岩体周围形成煤变质正向环带,岩体群之间则形成反向环带;接触带煤变质呈现向石墨或天然焦两个不同的演化方向;叠加在深成变质作用基础上的岩浆热变质作用控制了这一地区煤变质带展布的格局。 相似文献
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Canada's coal resources occur in 16 sedimentary basins or groups of basins and range in age from Devonian to Tertiary. The Western Canada Sedimentary Basin (WCSB), which contains the vast majority (about 90%) of the nation's coal resources of immediate interest, underlies a large area in the provinces of British Columbia, Alberta, Saskatchewan and Manitoba, extending northward to about the 62nd Parallel in Yukon and Northwest Territories. Coal deposits in the WCSB range in age from Early Carboniferous (Mississippian) to Paleocene. Rank ranges from lignite to semianthracite. About 36% of the total estimated 71,000 megatonnes of resources of immediate interest in the WCSB is bituminous coal, including a high proportion in the medium to low volatile range. Their low sulphur contents and acceptable ash levels make these medium and low volatile bituminous coals attractive 3s coking feedstocks and large quantities are mined for that purpose. The lower rank western Canadian coals are used mainly for electricity generation.Significant resources of bituminous coal occur in the coalfields of Atlantic Canada where they have been mined since 1720. Most of these coals are classed as high volatile A bituminous and most are used for power generation. Large resources of coal (lignite to anthracite) also occur in more remote regions of Canada, such as the Bowser Basin in northwestern British Columbia, and Sverdrup Basin/ Franklinian Geosyncline in the Arctic Islands. Information on distribution and compositional attributes of these frontier region coals is commonly scarce. 相似文献
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Forms of selenium in bituminous coal, anthracite, and cokeite (natural coke) from Huaibei Coalfield, Anhui, China, have been determined by sequential solvent extraction. The selenium content in bulk samples is 4.0, 2.4, and 2.0 μg/g in bituminous coal, anthracite, and cokeite, respectively. The six forms of selenium determined by six-step solvent extraction are water-leachable, ion-exchangeable, organic matter-associated, carbonate-associated, silicate-associated, and sulfide-associated. The predominant forms of selenium in bituminous coal are organic matter-associated (39.0%), sulfide-associated (21.1%), and silicate bound (31.8%); these three forms account for 92% of the total. The organic matter bound-selenium decrease dramatically from bituminous coal (39.0%) to anthracite (11.6%) and to cokeite (0%), indicating that organic matter bound selenium is converted to other forms during metamorphism of the coal, most likely sulfide-form. The sulfide-associated form increased remarkably from bituminous coal (21.1%) to anthracite (50.4%) and cokeite (54.5%), indicating the formation of selenium sulfide, possibly in pyrite during the transformation of bituminous coal to anthracite and cokeite. The silicate-associated selenium in bituminous coal (31.8%) is much higher than that in anthracite (16.4%) and cokeite (15.8%), indicating that silicate-associated selenium is partly converted to sulfide during metamorphism. 相似文献
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呼和诺尔盆地属海拉尔盆地群,为张性盆地,区域性的北东向断裂控制了盆地的形态和规模。盆地主要含煤地层为下白垩统伊敏组,发育11个煤组,其中4煤组、8煤组煤层较稳定,全区大部可采;11煤组煤层稳定,厚度达15～20m,为全区主要可采煤层。根据伊敏组含煤地层沉积特征,,划分了四个沉积旋回,分析了影响煤层沉积的主要因素,认为盆地沉积明显受同沉积断层的控制,表现在断层两盘岩层生长指数和沉积特征均有明显的差异。本次研究将对海拉尔盆地乃至相邻蒙古国盆地的煤田勘查提供借鉴。 相似文献