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1.
硼磷镁石 (Lueneburgite,)系一种稀少的含水含磷硼酸盐矿物。该矿物1870年发现于德国汉诺威的吕内堡。现已知国外产地有:美国新墨西哥二叠纪含盐盆地,苏联里海的卡拉—博加兹—戈尔海湾及喀尔巴阡的斯捷布尼克等地区。此  相似文献   

2.
Reconstructions of fossil animals are widespread and often very high profile, yet many of these reconstructions exhibit low standards of scientific accuracy.  相似文献   

3.
The need for more agricultural or residential land has encouraged reclamation at the coastal areas of Korea since 1200 ad (approximately). The groundwaters of these reclaimed areas could be expected to reveal hydrogeochemical properties different from those of areas directly affected by seawater intrusion. The purpose of this study, therefore, was to examine the salinization of shallow groundwater in a coastal reclaimed area and to identify the effect of land reclamation on groundwater quality. Major cations and anions, iodide, total organic carbon, δD, δ 18O and δ 13C were measured to assist the hydrogeochemical analysis. Chloride, δD and δ 18O data clearly show that the Na–Cl type water results from mixing of groundwater with seawater. In particular, the δD and δ 18O of Ca+Mg–Cl+NO3 type groundwaters are close to the meteoric water line, but Na–Cl type waters enriched in chloride are 18O-enriched with respect to the meteoric water line. Meanwhile, carbon isotopic data and I/Cl ratios strongly suggest that there are various sources of salinity. The δ 13C values of Na–Cl type groundwaters are generally similar to those of Ca+Mg–Cl+NO3 type waters, which are depleted in 13C with respect to seawater. I/Cl ratios of Na–Cl type groundwater are 10–100 times higher than that of seawater. Because the reclamation has incorporated a large amount of organic matter, it provides optimum conditions for the occurrence of redox processes in the groundwater system. Therefore, the salinization of groundwater in the study area seems to be controlled not only by saltwater intrusion but also by other effects, such as those caused by residual salts and organic matter in the reclaimed sediments.  相似文献   

4.
The Mono estuary is an infilled, microtidal estuary located on the wave-dominated Bight of Benin coast which is subject to very strong eastward longshore drift. The estuarine fill comprises a thick unit of lagoonal mud deposited in a ‘central basin’between upland fluvial deposits and estuary-mouth wave-tide deposits. This lagoonal fill is capped by organic-rich tidal flat mud. In addition to tidal flat mud, the superficial facies overlying the ‘central basin’fill include remnants of spits resting on transgressive/washover sand, an estuary-mouth association of beach, shoreface, flood-tidal delta and tidal inlet deposits, and a thin sheet of fluvial sediments deposited over tidal flat mud. After an initial phase of spit intrusion over the infilled central basin east of the present Mono channel, the whole estuary mouth became bounded by a regressive barrier formed from sand supplied by the Volta Delta during the middle Holocene eustatic highstand. Barrier progradation ceased late in the Holocene following the establishment of an equilibrium plan-form shoreline alignment that allowed through-drift of Volta sand to sediment sinks further downdrift. Over the same period, accretion, from fluvially supplied sediments, of the estuarine plain close to the limit of spring high tides, or, over much of the lower valley, into a fluvial plain no longer subject to tidal flooding, induced marked meandering of the Mono and its tidal distributaries in response to confinement of much of the tidal prism to these channels. The process resulted in erosion of spit/washover and regressive barrier sand, and in reworking of the tidal flat and floodbasin deposits. The strong longshore drift, equilibrium shoreline alignment and the year-round persistence of a tidal inlet maintained by discharge from the Mono and from Lake Ahémé have resulted in a stationary barrier that is reworked by a mobile inlet. The Mono example shows that advanced estuarine infill may result in considerable facies reworking, obliteration of certain facies and marked spatial imbrication of fluvial, estuarine and wave-tide-deposited facies, and confirms patterns of sedimentary change described for microtidal estuaries on wave-influenced coasts. In addition, this study shows that local environmental factors such as sediment supply relative to limited accommodation space, and strong longshore drift, which may preclude accumulation of sediments in the vicinity of the estuary mouth, may lead to infilled equilibrium or near-equilibrium estuaries that will not necessarily evolve into deltas.  相似文献   

5.
The Pinxiang weathering profile is well developed on Early Triassic dacite lavas of the Baisi Formation. At the top of the profile is developed a red clay zone which is characterized mineralogically by kaolinite, iron oxide minerals, quartz, and a small amount of illite, montmorillonite and vermiculite. In going downwards the red clay zone gives way to a saprolite zone in which plagioclase pseudomorphs have been well preserved although replaced by kaolinite. Beneath the saprolite zone is the saprock zone characterized by less weathering for dacite. At the bottom of the weathering profile is the parent material, dacite, which is composed mainly of plagioclase, quartz, K-feldspar and biotite which have been largely altered into chlorite owing to submarine extrusion of dacite lavas. Some layers in the weathering profile show obvious sodium enrichment and potassium depletion relative to others. In the Al2O3-(CaO* Na2O)-K2O triangular diagram, the weathering trends of these layers in the middle stage are remarkably deviated from normal ones. Both mineralogy and micro-morphology of these layers indicate such deviation resulted from sodic metasomatism of orthoclase.  相似文献   

6.
 Surface contamination with radioactive caesium introduced into the environment after the accident at the Chernobyl nuclear plant was high enough in the Crimean Mountains to allow using radiocaesium as an indicator of penetration of radioactive contamination into a karst system. Caesium concentrations have been studied in soils above Marble Cave, Tchatyrdag Plateau, in percolation waters and in sediments transported by percolation waters within the cave. Contamination of the daylight surface with 137Cs is about 30 kqB m–2 which is approximately 13 times higher than the density of global fallouts. Besides 137Cs, almost all samples showed presence of 134Cs with the 137Cs/134Cs ratio close to that of Chernobyl contaminations. Concentrations of 137Cs range from 9 to 15 mBq l–1 in the present percolation waters in the cave. In sediments related to percolation waters 134Cs is detected in some samples besides 137Cs, although the effect of 228Ac is not ruled out. Surprisingly, the highest concentrations of radiocaesium were measured in "old" sediments in the cave's lower series. These sediments are not associated with modern percolation and are represented by a clay/moonmilk alternating sequence deposited in an old dried cave lake. Moonmilk layers have higher caesium content than clay. It is assumed that Chernobyl caesium was transported into the cave with aerosols which were then deposited mainly in areas where condensation occurs. The sampling site is located just in the boundary between two microclimatic zones with a temperature gradient of 0.5  °C. Active condensation processes occur in this area. Caesium was not detected in another similar sampling site (old lake deposits) located within homogeneous microclimatic conditions. If the above interpretation is correct, these results show the geochemical significance of the aerosol-condensation mechanism of mass transport and localisation. Received: 1 June 1995 · Accepted: 4 December 1995  相似文献   

7.
The Pliocene Norwest Bend Formation is a well‐preserved succession of terrestrial and shallow‐marine deposits in the Murray Basin, South Australia. Sediments in this unit consist of two discrete terrigenous clastic‐rich, decametre‐scale sequences, or informal members, which record episodes of marine incursion during the Early and Late Pliocene respectively. The base of each sequence is a transgressive lag and/or strandline deposit that is transitional upwards into a highstand, subtidal, terrigenous clastic and cool‐water carbonate sediment accumulation. The top of each sequence is incised by fluvial channels that are filled by river deposits which formed as relative sea‐level fell and terrestrial environments prograded basinward. Sedimentological data suggest that gross stratigraphic architecture was primarily determined by glacioeustasy. Differences in sedimentary style between these two sequences, however, reflect a major climatic change that took place in southern Australia during the mid‐Pliocene. The lower quartzose sand member is formed of siliciclastic sediment derived from prolonged, deep, subaerial weathering and contains a bivalve‐dominated, cool‐temperate, open‐marine mollusc assemblage. These sediments accumulated under an equitable, relatively warm, humid climate. The Murray Basin during this time, because of high fluvial discharge, was a salt‐wedge estuary with typical estuarine circulation. In contrast, the upper, oyster‐rich member is typified by large monospecific oyster buildups that grew in restricted coastal environments. Strandline deposits contain a warm‐temperate skeletal assemblage. Contemporaneous aeolian sediments accumulated under warm, semi‐arid climatic conditions. Well‐developed ferricrete, silcrete and calcrete horizons reflect cyclic conditions of rainwater infiltration and evaporation in the seasonally dry climate that typifies southern Australia today. Highly seasonal rainfall produced an estuary that fluctuated annually from being well to partially mixed. These Pliocene sediments support the notion that mollusc‐rich facies are the signature of cool‐water carbonate accumulations in inboard neritic environments. Unlike bryozoans that dominate the outer parts of Cenozoic cool‐water carbonate shelves, molluscs evolved to exploit an array of coastal ecosystems with wide salinity variations and variable sedimentation rates.  相似文献   

8.
In many countries, argillaceous formations are being considered as potential host rocks for repositories of radioactive waste. Therefore, in 1995 several organisations decided to start an international research project in the reconnaissance gallery of the Mont Terri motorway tunnel, in north-western Switzerland, in a Mesozoic shale formation, the Opalinus Clay (Aalenian).

This project is under the patronage of the Swiss National Hydrological and Geological Survey. The following organisations are also partners in the project: ANDRA and IPSN (France), BGR (Germany), ENRESA (Spain), Nagra (Switzerland), JNC and Obayashi (Japan), SCKCEN (Belgium).

The aims of the project are to analyse the hydrogeological, geochemical and rock mechanical properties of an argillaceous formation, the changes of these properties induced by the excavation of galleries and to evaluate and improve appropriate investigation techniques. In January, 1996, eight niches were excavated for the project and 15 experiments were started in boreholes of no more than 30 m in length. In the winter of 1997–1998 a new research gallery was excavated to host further experiments. Different excavation, drilling and investigation techniques have been tested and improved. Significant results of the different experiments are already available. Some of those dealing with hydrochemistry, porewater pressure measurements and the evolution of the excavation disturbed zone (EDZ) are reported in this paper.  相似文献   


9.
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10.
Acid-cleaned ceramic plates placed upstream and downstream from a Cu-Zn-Pb sulfide deposit (Magruder mine) developed a precipitate of Fe-Mn oxides in a 36-day period. Copper and Zn concentrations on the coated surface, normalized to surface area and ratios with Fe and/or Mn, are distinctly anomalous for a distance of 2 km downstream from the mine.The major source of metals in the coatings is interpreted to be groundwater percolating into the stream bed. Anomalous concentrations of Cu and Zn in groundwater from the Magruder mine area, due to oxidation of sulfide minerals, probably accounts for the anomaly identified on the ceramic plates.  相似文献   

11.
Proglacial Quaternary lacustrine sediments deposited along the Caribou River Valley, Yukon, Canada, formed in a lake impounded by glacial ice that was retreating downslope. Sedimentation in the lake was dominated by turbid sediment underflows generated from the upslope, previously deglaciated region. The base of the sedimentary succession indicates a gradual transition from sporadic low-density distal flows to higher density proximal flows. Continued sediment accumulation resulted in the construction of a subaqueous clay and silt bank. Sedimentation was dominated by deposition of suspension load clay carried by subseasonal bottom countercurrents induced by katabatic winds. This sedimentation pattern prevailed until the subaqueous bank was disturbed by mass movement. Removal of the sediment bank increased the depth of the nearshore area sufficiently to allow turbid underflows to dominate sedimentation once more. The changing sedimentation patterns reflect events in the areas away from the ice front, rather than changes in the activity of the impounding glacier. Similar successions could be developed in other glacial lakes impounded by glaciers which moved up topographical slopes, either pre-existing or generated by glacioisostatic depression.  相似文献   

12.
The distribution and chemistry of the springs in the Tuscarora Creek watershed is controlled by both geologic structure and karst dissolution. The watershed is located in eastern West Virginia in the structurally complex Great Valley of the Appalachian Valley and Ridge province. The upper portion of the stream parallels strike along a mapped fault zone and is bordered by clastic rocks that comprise North Mountain. The lower reaches of the stream flow cross-strike through Cambro-Ordovician carbonates. The controlling chemical signature in the spring water is carbonate dissolution. Little evidence was seen for the recharge from adjacent clastic rocks although differences in the Ca/Mg molar ratio between springs indicated the presence of localized spring basins in headwater reaches. Na, Cl and Ca generally increased from upstream to downstream in the cross-strike reaches. Comparison of stream and cumulative spring discharge was consistent with significant groundwater base-flow contribution directly to the creek, particularly in the strike-parallel region. The largest spring in the watershed (>162 L/s) was sampled during and after a large storm event along with the adjacent creek. The creek displayed a typical dilution response with each flood pulse, whereas the spring had only a limited or delayed response. The overall chemical and thermal stability of the spring, relative to the creek, indicated the lack of significant direct hydraulic connection between the two. The conceptual model for the area includes localized flowpaths in the headwater region where the stream flow is parallel to strike and a thrust fault. In addition to the shallow localized flowpaths, a deeper, more regional flowpath likely exists for a large spring further downstream.  相似文献   

13.
The long-lived (about 20 yr) bryozoan Adeonellopsis sp. from Doubtful Sound, New Zealand, precipitates aragonite in isotopic equilibrium with seawater, exerting no metabolic or kinetic effects. Oxygen isotope ratios (δ18O) in 61 subsamples (along three branches of a single unaltered colony) range from −0.09 to +0.68‰ PDB (mean = +0.36‰ PDB). Carbon isotope ratios (δ13C) range from +0.84 to +2.18‰ PDB (mean = +1.69‰ PDB). Typical of cool-water carbonates, δ18O-derived water temperatures range from 14.2 to 17.5 °C. Adeonellopsis has a minimum temperature growth threshold of 14 °C, recording only a partial record of environmental variation. By correlating seawater temperatures derived from δ18O with the Southern Oscillation Index, however, we were able to detect major events such as the 1983 El Niño. Interannual climatic variation can be recorded in skeletal carbonate isotopes. The range of within-colony isotopic variability found in this study (0.77‰ in δ18O and 1.34 in δ13C) means that among-colony variation must be treated cautiously. Temperate bryozoan isotopes have been tested in less than 2% of described extant species — this highly variable phylum is not yet fully understood.  相似文献   

14.
J.A. Wolff  J.B. Toney 《Lithos》1993,29(3-4):285-293
Interstitial glass and pyroxene in a nepheline syenite described by Wolff (1987) have been more precisely and accurately re-analysed using a cryogenic microprobe technique. The glass compositions, with Na2O = 13.4−17.0 wt.% and (Na+K)/Al = 1.81−2.26 at SiO2 = 53−56.5 wt.% (on a 100% normalised basis) are more extreme than any known erupted magma. ZrO2 contents of the glasses are 1.4%–1.8% by weight, while F ranges between 1% and 1.4%. The high Zr content is due to the failure of a Zr-silicate phase to precipitate, despite predicted zircon saturation of the liquids above their probable quench temperatures. Partitioning of Zr between pyroxene and liquid is highly variable and apparently controlled by sector zoning; Zr is preferentially incorporated into aegirine {001} growth sectors. The glasses demonstrate the extent to which peralkaline phonolitic liquids can be fractionated in closed magma systems.  相似文献   

15.
Anthropogenic sources of carbon from landfill or waste leachate can promote reductive dissolution of in situ arsenic (As) and enhance the mobility of As in groundwater. Groundwater from residential-supply wells in a fractured crystalline-rock aquifer adjacent to a Superfund site in Raymond, New Hampshire, USA, showed evidence of locally enhanced As mobilization in relatively reducing (mixed oxic-anoxic to anoxic) conditions as determined by redox classification and other lines of evidence. Redox classification was determined from geochemical indicators based on threshold concentrations of dissolved oxygen (DO), nitrate (NO 3 – ), iron (Fe2+), manganese (Mn2+), and sulfate (SO 4 2– ). Redox conditions were evaluated also based on methane (CH4), excess nitrogen gas (N2) from denitrification, the oxidation state of dissolved As speciation (As(III) and As(V)), and several stable isotope ratios. Samples from the residential-supply wells primarily exhibit mixed redox conditions, as most have long open boreholes (typically 50–100?m) that receive water from multiple discrete fractures with contrasting groundwater chemistry and redox conditions. The methods employed in this study can be used at other sites to gauge redox conditions and the potential for As mobilization in complex fractured crystalline-rock aquifers where multiple lines of evidence are likely needed to understand As occurrence, mobility, and transport.  相似文献   

16.
 The response of a Wilderness cherty loam series soil to repeated dosages of metals (as sewage sludge) using a two-step sequential extraction procedure was investigated. Variations in metal content between amended and control soils were related to organic matter, clay content, and clay mineralogy. Of the four metals investigated, Cu was found to accumulate in the top 20 cm of amended soils; Pb and Zn were present in even smaller amounts with respect to the control soils, and Cr concentrations were unaffected with respect to both depth and amendment. None of the metals indicated accumulation in deeper (>20 cm) parts of the soil profile. Overall, results suggest that the metals remobilize in the top 20 cm, being readily uptaken by the fescue grass growing in this lot. Precipitation of insoluble forms of metal into deeper parts of the soil profile was proven unlikely based on the distribution of metal concentrations throughout the profile. Received: 15 December 1997 · Accepted: 23 March 1998  相似文献   

17.
Storm event beds in the Paleoproterozoic riftogenic sedimentary succession of Aravalli Supergroup are described from a 12.8 m-thick sandstone-mudstone interbedded unit in Zawar area, Rajasthan, India. The storm event beds include different primary structural assemblages indicating deposition from waning storm current. Sequential arrangement of beds with characteristic primary structural assemblages suggests deposition under a transgressive phase, and overall retrogradational evolution of the storm-succession provides evidence in favour of faster downsagging of the basin floor. The Pb-Zn sulphide ore bearing sedimentary succession of Zawar records repeated downsagging and exhumation of the basin floor in the frame of continental rift tectonics.  相似文献   

18.
青海同仁县隆务峡地区首次发现镁铁质——超镁铁质岩带   总被引：10，自引：4，他引：10  
在青海省同仁县隆务峡南段的二叠纪地层中首次发现了北西—南东向分布的镁铁质—超镁铁质岩带,命名为隆务峡镁铁质—超镁铁质岩带。该岩带的岩石组合包括纯橄岩、辉石橄榄岩、辉长岩、辉绿岩、枕状玄武岩等。从超镁铁岩—下部堆晶岩—辉绿岩—上部堆晶岩,其稀土元素总量逐渐增加,稀土元素配分型式总体一致,从超镁铁岩的Eu正异常到上部辉长岩的Eu负异常,显示了各岩石间的同源性。根据对其两侧沉积岩中化石的研究,推测该镁铁质—超镁铁质岩带的形成时代为二叠纪。该岩带位于西秦岭造山带与祁连造山带的接舍部,对于揭示秦岭和祁连接合部的大地构造演化有重要意义。  相似文献   

19.
Diffusion experiments with HTO, 36Cl−, Br−, I−, 22Na+, 85Sr2+ and 134Cs+ at trace concentrations in a single sample of Opalinus Clay are modeled with PHREEQC’s multicomponent diffusion module. The model is used first in a classical approach to derive accessible porosities, geometrical factors (the ratio of pore tortuosity and constrictivity) and sorption behavior of the individual tracers assuming that the clay is homogeneous. The accessible porosity for neutral species and cations is obtained from HTO, the anion exclusion volume from 36Cl− and Br−, and the cation exchange capacity from 22Na+. The homogeneous model works well for tritium, the anions and 22Na+. However, the 85Sr2+ and 134Cs+ experiments show an early arrival of the tracer and a front-form that suggest a dual porosity structure. A model with 10% dead-end pores, containing 19% of the total exchange capacity, can satisfactorily calculate all the experimental data. The Cs+ diffusion model builds on a 3-site exchange model, constructed from batch sorption data. The excellent agreement of modeled and measured data contradicts earlier reports that the exchange capacity for Cs+ would be smaller in diffusion than in batch experiments.The geometrical factors for the anions are 1.5 times larger than for HTO, and for the cations 2-4 times smaller than for HTO. The different behavior is explained by a tripartite division of the porespace in free porewater, diffuse double layer (DDL) water, and interlayer water in montmorillonite. Differences between estimated and observed geometrical factors for cations are attributed to increased ion-pairing of the divalent cations in DDL water as a result of the low relative dielectric permittivity. Interlayer and/or surface diffusion contributes significantly to the diffusive flux of Cs+ but is negligible for the other solutes. The geometrical factors for anions are higher than estimated, because pore constrictions with overlapping double layers force the anions to take longer routes than HTO and the cations. Small differences among the anions can also be attributed to different ion-pairing in DDL water.  相似文献   

20.
A groundwater/surface-water interaction model was developed for the shallow alluvial aquifer of the Choele Choel Island in Patagonia, Argentina. In this semiarid climate, agriculture is sustained by an irrigation/drainage system. During the irrigation season, seepage losses through unlined distribution canals in irrigated fields contribute to elevated groundwater levels, jeopardizing fruit productivity in some areas. Moreover, high stream stages during the irrigation season interfere with groundwater drainage. The model utilized MODFLOW and its stream package, and was successfully calibrated for a historical irrigation season. Modeling results indicate that drainage through streams is significantly higher than drainage through artificial drains. The stream/aquifer relationship proved very responsive to water table rises caused by irrigation. This response manifested as changes in the gaining/losing character of stream reaches. A synthetic run aimed at isolating the effect of streamflow changes on groundwater levels showed that the effect of higher streamflows dissipates toward the interior of the island, disappearing completely at the island center. Even though some results were qualitative, the model helped to provide a better understanding of the coupled system to elucidate some of the causes of a rising water table on the island.
Leticia B. RodríguezEmail:
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