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1.
峨嵋叶蜡石矿储量大,矿石类型主要有石英叶蜡石型、硬水铝石叶蜡石型、叶蜡石型、明矾石叶蜡石型等。各类矿石中的叶蜡石经提纯后,测试结果表明它们分别具有不同的多型,其中石英叶蜡石型为2M_1型,硬水铝石叶蜡石型及青灰色、紫红色叶蜡石型为2M_1+1TC(混合)型,明矾石叶蜡石型为1TC(为主)型。本文在对各类矿石及叶蜡石的多型特征进行较详细论述的同时,还对多型与矿石类型的关系及成因发表了看法。 相似文献
2.
叶蜡石矿床是一种重要的非金属矿产,主要分布于东南沿海地区侏罗纪—白垩纪的中酸性火山岩地层中,受控于区域大规模断裂和伸展断陷盆地。文章对中国内外叶蜡石矿床的地质和矿产特征进行了综合分析,总结了浙闽地区叶蜡石矿床特征和成因。浙闽地区叶蜡石矿床的赋矿原岩为流纹质火山碎屑岩和凝灰岩等,具有高硅高铝的特点。矿床成因类型主要包括火山热液交代型和火山热液充填型。结合泰顺龟湖、青田周村和山口等典型叶蜡石矿床的实例研究,文章揭示了火山热液交代型叶蜡石矿床普遍发育硅化、叶蜡石化、明矾石化、黄铁矿化的垂直分带特征,中酸性火山岩组分在热液作用下发生交代、分解,使铝有规律的富集成矿;火山热液充填型叶蜡石矿床围岩蚀变分带不明显,从围岩中淋滤、萃取的硅铝组分沿着构造裂隙运移,在有利的空间成矿。因此,笔者认为侏罗纪—白垩纪中酸性火山岩与凝灰岩、区域断裂带和火山岩带、围岩蚀变垂直分带以及陡峭山峰是叶蜡石矿的重要找矿标志。 相似文献
3.
在野外地质工作、镜下观察的基础上,采用电子探针、X射线粉晶衍射、氢氧稳定同位素测试等方法对江西上饶龙门高岭石-叶蜡石矿床矿石进行了分析。其主要组成矿物为高岭石族矿物、叶蜡石和石英,其次有少量的绢云母、黄铁矿和赤铁矿等。矿石中高岭石族矿物Hinckley指数为0.33～0.94,整体属于较无序高岭石,叶蜡石有2M型和1Tc型两种多型,以2M型为主。矿石的δ18O值为4.5‰～6.6‰,δD值为-71.7‰～-98.5‰。综合分析认为该矿床为晶屑玻屑凝灰岩受热液蚀变而成,其成矿热液主要来自大气降水,成矿温度为75℃～300℃,压力<1kb。 相似文献
4.
寿山石是一种以黏土矿物为主要成分的用于工艺美术雕刻、印章篆刻的玉石,因主要产于福建省寿山而得名。本文在野外地质调查的基础上,通过肉眼、偏光显微镜和扫描电子显微镜(SEM)的观察以及电子探针、X射线粉晶衍射、红外光谱和差热等分析手段,对福建寿山石各矿床的主要矿石的类型及其特征、矿石的主要组成矿物、显微结构及其晶体结构特征等方面进行深入研究。根据对高山、旗降、峨嵋、月尾四个寿山石矿床矿石的成分分析,将寿山石原生矿石分为迪开石型、高岭石型、叶蜡石型和伊利石型四种主要类型。寿山石的结构主要有显微隐晶、显微隐晶-微晶、显微微晶结构。高山矿石由纯净的有序迪开石组成,峨嵋矿石由纯净的2M型叶蜡石组成,部分月尾矿石由纯净的2M1型伊利石组成,旗降矿石以有序高岭石为主,含有少量迪开石或高岭石-迪开石的过渡矿物,部分旗降矿石以2M型叶蜡石为主,含有少量高岭石。根据矿床地质产状、矿石结构、矿物共生组合等特征分析,寿山石的成矿环境为还原环境,属于热液蚀变成因。 相似文献
5.
本文对江苏溧阳叶蜡石矿物、岩石进行薄片鉴定、差热分析、红外光谱分析、电镜分析、X衍射分析等研究,作者认为叶蜡石矿物与叶蜡石岩石的含义不同;本区叶蜡石岩中发现有两种不同类型的叶蜡石矿物;叶蜡石矿的俗称实质上是叶蜡石岩矿床的简称。作者对叶蜡石岩进行了初步的分类。 相似文献
6.
根据寿山早白垩世火山喷发盆地内典型雕刻用叶蜡石矿成矿地质条件、火山构造、贮矿部位以及蚀变矿物组合特征综合分析,认为寿山火山盆地雕刻用叶蜡石矿主要控制因素以火山构造为主体,叠加区域断裂构造。寿山火山盆地发育17个Ⅴ级火山群或破火山组合体控制了叶蜡石矿的产出,Ⅴ级复活火山机构控制了雕刻用叶蜡石成矿的地段;并提出找矿标志,初步圈定找矿靶区。 相似文献
7.
我国几个矿区叶蜡石X射线粉晶衍射研究 总被引：4，自引：0，他引：4
对我国几个主要类型叶蜡石矿的叶蜡石做了X射线粉晶衍射研究。从大量实验结果发现,所研究叶蜡石存在单斜晶系和三斜晶系两种多型。单斜晶系(2M);空间群G_(2h)~6-C2/c,a=5.175A,b=8.902A,c=18.673A,β=100.1°,Z=4;三斜晶系(1Tc):空间群P_c,a=5.162A,b=8.965A,c=9.346A,a=91.2°,β=99.96°,γ=89.91°,Z=2。 相似文献
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9.
叶蜡石高温相转变的实验研究 总被引：1，自引：0，他引：1
通过差热分析、X射线衍射分析、红外光谱分析和魔角旋转核磁共振等测试手段,研究了日本广岛胜光山叶蜡石在20~1 300 ℃下煅烧的相转变过程。结果表明,叶蜡石的高温相转变经历了4 个阶段:叶蜡石阶段(室温~662 ℃),偏叶蜡石阶段(662~1 100 ℃),不定形SiO2 与莫来石形成阶段(1 100~1 200 ℃)和莫来石与方石英共存阶段(1 300 ℃~)。叶蜡石在662 ℃时失去结构水转变为偏叶蜡石。偏叶蜡石从1 100 ℃开始转变为莫来石,同时伴随有不定形SiO2 生成。1 300 ℃时,不定形SiO2 进一步结晶形成方石英。 相似文献
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叶腊石微结构及其晶体结构缺陷的高分辨透射电镜分析 总被引：2，自引：0，他引：2
采用场发射扫描电镜（FE-SEM）、高分辨透射电镜（HRTEM）结合选区电子衍射（SAED）、X射线粉晶衍射（XRD）及X射线荧光光谱（XRF）等对浙江青田叶腊石的微结构特征进行较系统的研究。结果表明：①粉晶X射线衍射证实青田叶腊石具有典型的单斜晶系特征,该结论与叶腊石粉体选区电子衍射结果吻合,且其伴生矿为石英。②叶腊石微晶体呈＂复式板片＂构型,且＂复式＂板片中薄片厚度约为8±2 nm。③在高能电子束辐照下,叶腊石矿物颗粒形貌及晶格结构发生明显的改变,且由此产生晶格膨胀,并最终形成非晶态。 相似文献
12.
Tetsuichi TAKAGI Sang–Mo KOH Moon–Young KIM Kazuki NAITO Sadahisa SUDO 《Resource Geology》2000,50(4):243-256
Abstract: The Milyang pyrophyllite deposit, which is embedded in the Late Cretaceous Yuchon Group of the Kyongsang Supergroup, is one of the largest hydrothermal clay deposits in the Kyongsang basin, southeast Korea. Host rocks of the deposit are porphyritic andesite lava and minor andesitic lapilli tuff. In the Milyang district, a hydrothermally altered zone is about 2 × 3 km in extent; we can recognize the concentric arrangement of advanced argillic, propylitic, and sericitic alteration zones from the central to peripheral parts of the zone. The Milyang pyrophyllite deposit forms a part of the advanced argillic alteration zone. The Milyang pyrophyllite deposit is subdivided into the following four zones based on mineral assemblages: the pyrophyllite zones 1, 2, 3, and the silicified zone. The pyrophyllite zone 1, which occupies the central part of the deposit, comprises mainly pyrophyllite, kaolinite, and diaspore without quartz. Diaspore nodules often concentrate in beds 40–50 cm thick. Andalusite, dumortierite, and tourmaline locally occur as network veins, crack‐filler, or small spherulitic spots. The Al2O3 content of the ore ranges from 27 to 36 wt%. The pyrophyllite zone 2, which constitutes a major part of the deposit, comprises mainly pyrophyllite, kaolinite, and quartz. The Al2O3 content of the ore ranges from 15 to 24 wt%. The pyro‐phyllite zone 3 is the hematite‐rich marginal facies of the deposit. The silicified zone, which occurs as beds and septa, is mostly composed of quartz with minor pyrophyllite and kaolinite; the SiO2 contents range from 79 to 90 wt%. Comparing chemical compositions of the high‐Al ores with those of unaltered host andesite, the Fe, Ca, alkalis, HFSE, and HREE contents are significantly depleted, whereas S, B, As, Sr, and LREE are enriched. The hydrothermal alteration of the Milyang pyrophyllite deposit can be classified into the following four stages: 1) extensive sericitic and propylitic alteration, 2) medium‐temperature (200–250°C) advanced argillic alteration, 3) high‐temperature (250–350°C or more) advanced argillic alteration, and 4) retrograde low‐temperature alteration. The heat and some volatile components such as B and S would be derived from the Pulguksa Granite intruded underneath the deposit. 相似文献
13.
福建福安上后洋叶蜡石矿呈似层状，赋存于晚侏罗世南园组中部火碎屑岩中，共发现有4个矿体，矿石可分为2种类型。即石英叶蜡石型和伊利石质叶蜡石型，以石英叶蜡石型为主，矿体明显受地层岩性控制，属火山热液顺层交代蚀变的似层状叶蜡石矿床。 相似文献
14.
This work deals with the identification and kinetics of crystallisation of the wollastonite polytypes which form in the system
CaO-SiO2 in the temperature range 700–1000 °C. The kinetics of phase transformations in the system have been determined from analysis
of in situ synchrotron X-ray powder diffraction data. Two different systems with the same compositions were investigated:
one is more reactive, having grains with a larger surface area per unit volume, the other is less reactive, being composed
of grains with a smaller surface area per unit volume. 1T-wollastonite forms first and progressively transforms in an intermediate
1Td-wollastonite disordered form. Both phases in turn transform into 2M-wollastonite polytype. Differences in the polytypes
forming and reaction kinetics were observed for the two systems. In the more reactive system, the conversion 1T to 1Td polytypes
is the dominant process. The kinetic parameters calculated using the Avrami models fully describe the reaction process of
formation of both polytypes and transformation of one polytype into the other.
Received: 3 August 1999 / Accepted: 20 March 2000 相似文献
15.
浙江青田单斜晶系叶腊石微结构的高分辨透射电镜研究 总被引：2，自引：2，他引：0
采用X射线粉晶衍射(XRD)、高分辨透射电镜(HR-TEM)及X射线荧光光谱(XRF)对青田叶腊石的矿物学特征进行了较为系统的研究。结果表明:叶腊石矿物颗粒微结构中最基本的构成单元为纳米板片,且该板片多呈聚集态,单层板片面积大小不一,厚度为(8±2)nm。XRF分析结果表明青田叶腊石原矿混合物中SiO2与Al2O3的分子个数比为6.2,明显高于纯叶腊石中SiO2与Al2O3的分子个数比4.0。HR-TEM对叶腊石晶体结构的研究证实青田叶腊石具有典型的单斜晶系特征,该结论与叶腊石XRD结论一致;且XRD分析结果证实其伴生矿为石英,该结论与XRF所获得的青田叶腊石的"富硅"特征吻合。此外,叶腊石微结构中存在着较明显的晶体缺陷。在高能电子束辐照作用下,叶腊石晶体结构发生明显的破坏,并最终转变为非晶态结构。 相似文献
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17.
D. Ayres 《Australian Journal of Earth Sciences》2013,60(3):273-278
156 samples of naturally‐occurring molybdenite from 87 localities in Australia have been examined to determine the distribution of the hexagonal (2H1) and rhombohedral (3R) polytypes. 90% of the specimens examined are 2H1 polytypes, the remainder being 3R and mixtures of 2H1 and 3R polytypes. The 3R and mixed polytypes are more abundant in porphyry copper deposits or as disseminations, in veins, and in garnet‐quartz pipes in granite. 2H1 polytypes are the sole modification observed in pegmatites, quart‐pegmatite pipes, simple quartz veins, and skarns. The highest average concentrations of rhenium are in molybdenite from porphyry copper deposits, quartz porphyry pipes, skarn deposits, garnet‐quartz pipes, and pegmatites. Low concentrations occur in molybdenite which is disseminated or in quartz veins in granite and in quartz or pegmatitic pipes. Molybdenites in which the 2H1 polytype is dominant have a lower average rhenium content than those with dominant 3R polytype. 相似文献
18.
M. B. Geilikman 《Physics and Chemistry of Minerals》1982,8(1):2-7
Two mechanisms of solid-state formation of polytypes are suggested. The first is structural-kinetic by nature, the stabilization of short-period polytype (for example, 4H) being due to the fact that there are two possible structural types of nuclei in the wurtzite structure: when new phase growth takes place by means of two-dimensional nucleation, these short-period polytypes become kinetically stable although they do not correspond to the minimum of free energy, and appear as transitional phases. The second mechanism of polytype formation below the transition temperature is influenced by impurities which stabilize the hexagonal modification, in which case polytypes may arise as states that are stable with respect to a diffusionless structural wurtzite-sphalerite transformation and metastable relative to small fluctuations of impurity concentration. 相似文献
19.
寿宁—福州一带蕴藏丰富的叶蜡石矿资源，多产于南园群火山碎屑岩地层中，小溪组地层为最主要赋矿层位，围绕火山机体发育的环状断裂为成矿最有利部位，近矿围岩普遍发育次生石英岩化，围岩蚀变具有明显的水平及垂直分带现象。 相似文献
20.
A systematic theoretical deduction of polytype structures of mica that can result by the spiral growth mechanism operating in faulted 1M, 2M 1 and 3T basic matrices is reported. As a prerequisite, all possible intrinsic and extrinsic stacking fault configurations in each of the basic matrices have been worked out and their stacking fault energy (SFE) estimated. The deduction of polytype structures on the basis of the “faulted-matrix model” takes into account (i) the introduction of each of the low energy fault configurations in the exposed ledge of the screw dislocations, (ii) the change in the layer-position of the fault within the exposed ledge and (iii) the variation of the strength of the generating screw dislocation. At each stage, the spirally-grown polytypes are deduced for each basic structure. The most probable structures are predicted on the basis of the lowest SFE for the same strength of the screw dislocation and are then compared with the polytype structures reported in the literature. It was found that the faulted matrix model accounts successfully for the origin of all the polytype structures in mica. Furthermore, it may provide a basis for limiting the number of trial structures for determining the structures of long period polytypes. 相似文献