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1.
巴音苏赫图二长花岗岩位于西伯利亚板块东南缘陆缘增生带与二连—贺根山板块对接带北缘之间。该岩体由石炭纪及三叠—侏罗纪两期花岗岩组成,均以高硅、富Al2O3、K2O、Na2O,贫MgO、CaO为特征。微量元素表现为富集LILE、亏损HFSE。弱富集LREE,Eu负异常明显。岩石学和地球化学综合研究表明:两期花岗岩早期为高钾钙碱性、准铝质-过铝质花岗岩碰撞期I型花岗岩,晚期花岗岩具有A型花岗岩特点。Sr-Nd同位素研究表明:石炭纪二长花岗岩(87Sr/86Sr)i比值较低(0.700 62~0.704 82),εNd(t)为正值(0.9~1.5),岩浆来自于增生的岛弧或年轻的幔源物质,在岩浆上升过程中遭受了少量地壳物质的混染;晚三叠世—早侏罗世花岗岩(87Sr/86Sr)i比值较高(0.709 96~0.710 19),εNd(t)较低,为-0.3~0.3,该期次花岗岩与晚石炭世花岗岩同源,受地壳混染程度相对较高。应用LA-ICP-MS法测得石炭纪花岗岩U-Pb年龄为(296±3.5)Ma,结合区域构造演化特点及所测三叠纪花岗岩的地球化学特征认为,在晚石炭世,南蒙古额尔德尼查干地区已进入碰撞期构造环境,在三叠—侏罗纪仍有同碰撞花岗岩侵入,晚石炭世以后的碰撞期持续时间较长。  相似文献   

2.
西准噶尔地区广泛发育晚古生代后碰撞花岗岩,年龄多集中于300Ma左右,在时代上属于晚石炭世,A型花岗岩具有具有高硅、低铝、富碱、准铝质-弱过铝质、贫钙、低镁,10000×Ga/Al比值较大,强烈富集高场强元素(HFSE)及Zr、Y、Ga等元素,Sr、Ba强烈亏损,稀土配分模式图呈现典型的右倾“海鸥型”等,并且在A1—A2型花岗岩判别图解显示具有典型的铝质A型的A2型花岗岩特征,表明A型花岗岩可能是年轻地壳(洋壳和岛弧)部分熔融形成的美云闪长-花岗闪长岩质岩浆经进一步分离结晶作用的产物,具备规模成矿的条件.  相似文献   

3.
新疆西准噶尔庙尔沟岩体的地球化学及年代学研究   总被引:4,自引:1,他引:3  
新疆西准噶尔庙尔沟岩体侵入于早中石炭世海相火山-沉积建造中,主体由碱长花岗岩组成,局部分布有紫苏花岗岩和碱长花岗岩脉。碱长花岗岩及岩脉高硅、富碱、贫钙,里特曼指数(δ)=2.17~2.98,A/CNK=0.96~1.03,A/NK=1.08~1.13,为准铝质-弱过铝质高钾钙碱性花岗岩,其富集LILEs(Rb、U、K、Th),相对亏损HFSEs(Nb、Ta、P、Ti)和Ba、Sr等,以及强烈Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70370~0.70541,εNd(t)=+4.10~+6.79,tDM=0.57~0.99Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为309±1.4Ma,表明岩体碱长花岗岩的形成时代为晚石炭世。紫苏花岗岩的SiO 2含量为60.88%~62.06%,Al2O3含量为15.50%~15.72%,里特曼指数(δ)=2.59~2.77,A/CNK=0.86~0.88,A/NK=1.50~1.53,为准铝质钙碱性-高钾钙碱性过渡的花岗岩,相对富集LREE(Rb、U、K、Th),而亏损HREE(Nb、Ta、P、Ti)和Sr,以及较显著的Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70382~0.70388,εNd(t)=+6.67~+6.98,tDM=0.59~0.62Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为302.1±2.1Ma,表明岩体紫苏花岗岩的形成时代为晚石炭世。综合庙尔沟岩体的地质特征、地球化学特征、年代学和区域地质背景,认为庙尔沟岩体碱长花岗岩及岩脉为A2型花岗岩,紫苏花岗岩具有A型花岗岩的地球化学性质,且它们是可能来自同一个岩浆源区,属于西准噶尔后碰撞阶段的岩浆活动产物。  相似文献   

4.
胶东地区郭家岭花岗闪长岩的地球化学特征及成因   总被引:14,自引:26,他引:14  
本文系统地报道了郭家岭花岗闪长岩的主量元素、微量元素和Sr-Nd同位素组成,重点讨论了郭家岭花岗闪长岩的岩石成因、成岩物质来源及其地质意义.研究结果表明,郭家岭花岗闪长岩的SiO2含量从62%至72%,Na2O/K2O=0.64-1.79,多数样品大于1.0;K2O+Na2O值为7.34-8.49%,铝指数A/CNK=0.82~1.1,属于准铝质或过铝质Ⅰ型花岗岩;高Sr含量(Sr>800μg/g)、低Y和Yb含量(Y<10μg/g;Yb<1.0μg/g)、轻重稀土分馏强烈(LaN/YbN=17.4~47.8);这些地球化学特征类似于adakite、太古代TTG岩系、Na质花岗岩及HiSrBa花岗岩而不同于岛弧环境的英安岩.高的初始87Sr/86Sr比值(0.7094~0.7114),负的δNd(t)值(-11.2~-17.5),表明花岗闪长岩与adakite、HiSrBa花岗岩的成因不同而类似于Na质花岗岩和TTG岩系,即郭家岭花岗闪长岩是由下部地壳镁铁质岩石脱水部分熔融作用形成的.Nd同位素与胶东地区基性脉岩的Nd同位素组成相近,表明二者有可能具有相似或相同的源区.但基性脉岩出露面积明显小于花岗岩,二者之间存在着SiO2成分间隔,并且基性脉岩的不相容元素明显高于花岗闪长岩,从而表明花岗闪长岩不是基性脉岩结晶分异的产物,这与由幔源岩浆直接分异形成的高Sr、Ba花岗岩(HiSrBa)的成因不同.因此,花岗闪长岩有可能来源于早先与脉岩源区相似的基性岩浆底侵作用而形成的下地壳镁铁质岩石.其地球化学特征表明母岩浆在岩浆演化过程中经历了少量地壳混染作用.Mg#>50的岩石具有高Sr、Sr/Y、La/Yb等地球化学特征,表明岩浆形成时源区残留相中含有密度较大的石榴石,从而可能引起下地壳物质及岩石圈地幔的拆沉.这对研究胶东地区地区乃至中国东部在中生代期间岩石圈强烈减薄作用的机制和过程具有重要的地质意义.  相似文献   

5.
熊子良  张宏飞  张杰 《地学前缘》2012,19(3):214-227
文中研究了北祁连东段冷龙岭地区毛藏寺岩体和黄羊河岩体的年代学、地球化学和Sr-Nd同位素组成。毛藏寺岩体主要岩石类型为花岗闪长岩。锆石U-Pb定年获得花岗闪长岩岩浆结晶年龄为(424±4)Ma。花岗闪长岩具有高的Mg#(约55),K2O/Na2O=0.77~0.91,A/CNK=0.92~0.94,表明岩石属准铝质。在微量元素组成上,花岗闪长岩富集LILE、亏损HFSE,轻重稀土分异明显[(La/Yb)N=16.9~19.5],具有弱的Eu负异常(Eu/Eu*=0.75~0.83);花岗闪长岩具有ISr=0.706 3~0.706 5,εNd(t)=-1.5~-1.1,TDM=1.10~1.16Ga。这些地球化学特征和Sr-Nd同位素组成表明,花岗闪长岩岩浆源区为基性下地壳变玄武质岩石,但在成岩过程中有少量幔源物质的加入。黄羊河岩体主要由钾长花岗岩组成,其岩浆结晶年龄为(402±4)Ma。岩石富碱(K2O+Na2O=6.91‰~7.66%),K2O/Na2O>1,A/CNK=0.97~1.05。钾长花岗岩富集LILE及HFSE,轻重稀土元素分馏中等[(La/Yb)N=10.6~17.8],并具有明显的负Eu异常(Eu/Eu*=0.43~0.68),表明钾长花岗岩具有铝质A型花岗岩的地球化学特征。钾长花岗岩具有ISr=0.710 3~0.711 3,εNd(t)=-6.7~-6.0,TDM=1.46~1.55Ga,反映岩浆主要来自地壳中长英质物质的部分熔融。冷龙岭地区花岗岩类的岩石成因及其岩浆演化揭示了北祁连山造山带从加里东早期的挤压构造体制向加里东晚期的伸展构造体制的演化。这些花岗岩类形成于碰撞后构造背景,岩浆的产生可能与俯冲的北祁连洋板片的断离作用有密切联系。  相似文献   

6.
张望  王居里  胡洋 《岩石学报》2021,37(4):1139-1158
塞勒肯特岩体出露于谢米斯台中东部,岩性主要为二长花岗岩、石英闪长岩及花岗闪长岩。本文通过锆石U-Pb年代学、岩石地球化学和Sr-Nd-Hf同位素等研究,探讨其形成的构造环境及岩石成因。结果表明,二长花岗岩(400.9±4.3Ma)和石英闪长岩(398.1±4.5Ma)形成于早泥盆世,花岗闪长岩(381.7±2.9Ma)形成于晚泥盆世。岩体整体富碱,属于准铝质-弱过铝质高钾钙碱性花岗岩类。轻重稀土分馏较明显且富集轻稀土((La/Yb)_N=5.09~9.22),Eu异常不明显,相对富集Rb、Th、U、K等元素,亏损Nb、Ta、Ti等高场强元素;二长花岗岩和石英闪长岩具有低的(~(87)Sr/~(86)Sr)_i值(0.7040~0.7043),正ε_(Nd)(t)值(+4.85~+6.18),年轻的t_(DM1)(Nd)年龄(663~732Ma),二长花岗岩锆石ε_(Hf)(t)值为+7.94~+12.12,t_(DM2)(Hf)=648~889Ma;花岗闪长岩也具有低的(~(87)Sr/~(86)Sr)_i值(0.7045~0.7046),正ε_(Nd)(t)值(+4.61~+4.80),年轻的t_(DM1)(Nd)年龄(731~749Ma),花岗闪长岩锆石εHf(t)值为+4.26~+11.69,tDM2(Hf)=631~1103Ma。综合研究表明,塞勒肯特岩体形成于俯冲背景下的大陆边缘弧环境,可能是俯冲板片脱水交代地幔楔产生的玄武质岩浆上涌,导致新生下地壳发生部分熔融。二长花岗岩及石英闪长岩均来源于新生下地壳的部分熔融;花岗闪长岩主要来源于新生下地壳的部分熔融,并有少量幔源物质的加入,花岗闪长岩中的暗色微粒包体可能是幔源物质与新生下地壳部分熔融的岩浆未发生完全混合,最终冷凝结晶的产物。谢米斯台地区与俯冲相关的中酸性岩浆活动至少从晚奥陶世一直延续至晚泥盆世。  相似文献   

7.
孔吾萨依花岗岩体位于新疆西天山阿拉套山南坡东侧,岩体主要由碱长花岗岩、粗粒钾长花岗岩、细粒钾长花岗岩组成。碱长花岗岩的~(206)Pb/~(238)U加权平均年龄值为293.1±3.6Ma,细粒钾长花岗岩的年龄为293±3.7Ma。三类花岗岩具相似的地球化学特征,属准铝质—弱过铝质的高钾钙碱性系列花岗岩。从碱长花岗岩到粗粒钾长花岗岩再到细粒钾长花岗岩,其Eu负异常程度越来越高,元素Ba、Sr、P、Ti等的亏损及Rb、Th、U等的富集程度逐步增高,显示三者的岩浆之间具有结晶分异趋势。碱长花岗岩、粗粒钾长花岗岩及细粒钾长花岗岩均富Ga(10~4Ga/Al比值2.6~3.5)、高Fe~*值(=FeO~T/(FeO~T+MgO),0.88~0.97)和具较高的TiO_2/MgO比值(0.51~1.25),显示出典型A型花岗岩的特征。研究区A型花岗岩具有高的锆石饱和温度(853.86~931.56℃)和低的锆石Ce(Ⅳ)/Ce(Ⅲ)比值(1.9~77),暗示该A型花岗岩岩浆形成于高温和低氧逸度条件下。三类花岗岩具较高的Y含量(43.3×10~(-6)~106×10~(-6))、较高的ε_(Nd)(t)(+3.0~+5.2)和较低的(~(87)Sr/~(86)Sr)_i值(0.7027~0.7069),表明孔吾萨依A型花岗岩可能源于玄武质地壳的部分熔融。但与西天山石炭纪玄武岩相比,孔吾萨依花岗岩的ε_(Nd)(t)值较低,而(~(87)Sr/~(86)Sr)_i值较高,因此孔吾萨依花岗岩的岩浆源区应有古老地壳物质的加入。  相似文献   

8.
北山柳园地区分布大量的花岗岩类岩石,岩石类型有花岗闪长岩、二长花岗岩、钾长花岗岩和斑状花岗岩。锆石SHRIMP U—Pb 定年分析结果为:花岗闪长岩的侵位年代为423±8Ma 辉铜山以东(HT-)钾长花岗岩和二长花岗岩的侵位分别为436±9Ma 和397±7Ma。该区花岗质岩石都具有大离子亲石元素和轻稀土元素相对富集,K、Ni、Ta、P 和 Ti 负异常的特征,属于准铝质到过铝质的高 K 花岗岩。花岗闪长岩无 Sr 和 Eu负异常的特征,ε_(Nd)(t)=-2.5~-0.8,其岩浆源于岩石圈地幔或是软流圈与岩石圈地幔相混合的岩浆熔融,并受到了含有火山弧组分的年轻地壳的混染。钾长花岗岩和二长花岗岩具有 Sr 和 Eu 负异常的特征,ε_(Nd)(t)值分别为 1.4、-4.0~-2.0和-2.7~-0.3。HT-钾长花岗岩岩浆主要源于由于岩石圈地幔岩浆作用而导致上覆年轻地壳物质的部分熔融;花牛山附近(HN-)钾长花岗岩岩浆主要源于软流圈地幔部分熔融,可能受到了部分年轻地壳物质的混染;二长花岗岩岩浆主要源于年轻地壳的部分熔融。柳园地区4类花岗岩类岩石都是后碰撞构造背景下的岩浆产物,岩浆形成可能与俯冲板片断离有关。  相似文献   

9.
大桦背岩体由钾长花岗岩和似斑状黑云母二长花岗岩组成。锆石LA-MC-ICP-MS U-Pb定年获得其侵位年龄为328.3±1.5Ma,表明该岩体属早石炭世岩浆活动产物。大桦背岩体总体上富硅(Si O2=70.59%~76.04%)、富碱(Na2O+K2O=8.41%~8.99%)、准铝质-弱过铝质(A/CNK=0.98~1.11),形成温度较低(620~810℃),属于高分异高钾钙碱性I型花岗岩。岩石富集大离子亲石元素K、Rb、Th、U和LREE,亏损高场强元素Nb、Ta、Ti、P和HREE,具有较高的Th/Ta比值(10.30~21.60)及较低的Ce/Pb比值(0.90~3.13),显示大陆弧岩浆岩地球化学特征。除暗色微粒包体广泛发育外,岩体具有均一Sr-Nd同位素组成((87Sr/86Sr)i=0.704799~0.706272,εNd(t)=-8.8~-8.2)和较大变化范围的锆石Hf同位素(εHf(t)=-8.3~-2.6),暗示岩体为岩浆混合成因。结合区域地质背景,认为大桦背岩体的形成与古亚洲洋向华北克拉通之下的俯冲密切相关,是俯冲板片流体交代诱发熔融的岩石圈地幔岩浆与下地壳岩浆相混合的产物。混合岩浆在上升侵位过程中又发生了显著的分离结晶作用和较弱的地壳物质的同化混染。  相似文献   

10.
湖南金鸡岭铝质A型花岗岩的厘定及构造环境分析   总被引:43,自引:4,他引:43  
湘南九嶷山中生代金鸡岭复式花岗岩体出露面积约 390 km2,由螃蟹木和金鸡岭岩体组成.该岩体以富 Si(SiO2 75.00%~ 76.86% )、富碱 (ALK 6.60%~ 8.88% )、贫 Mg (MgO 0.01%~ 0.19% )和 Ca (CaO 0.30%~ 0.93% )以及高 FeO /MgO比值 (7~ 86,平均 39)为特征.其 K2O/Na2O > 1、 NK/A=0.70~ 0.92(平均 0.86),A/CNK=1.00~ 1.20,属偏铝-过铝质钙碱-弱碱性岩石. 在微量元素和同位素组成上,岩石富 Ga、 Th、 Y、 Zr、 U和 Nb等高场强元素及亏损 Ni、 Cr、 Eu、 Ti、 V、 P和 Sr等元素. 10 000× Ga/Al比值 (2.9~ 4.9,平均 3.3)较高, Isr值 (0.713 01~ 2.957 41)变化大.在 Zr、 Nb、 Ce和 Y对 Ga/Al以及 FeO /MgO 和 (Na2O K2O)/CaO对 (Zr Nb Ce Y)等 A型花岗岩多种判别图上,投影点主要落在 A型花岗岩区,而与高分异的 I、 S型花岗岩明显不同.上述特征表明,金鸡岭复式花岗岩与国内外铝质 A型花岗岩 (如广东南昆山、江苏苏州和澳大利亚 Lachlan褶皱带铝质 A型花岗岩 )十分相似.与一般 A型花岗岩相比,金鸡岭复式花岗岩的ε Nd(t)(- 6.7~- 7.5)较低, Nd模式年龄 (1 486~ 1 556 Ma)小于区域上变质基底和中国东南部中生代花岗岩类的平均 Nd模式年龄,表明其主要来源于地壳物质的熔融,但可能有少量新生地幔物质加入.区域岩石地球化学和岩石组合特点显示 ,研究区铝质 A型花岗岩形成于大陆边缘裂谷环境.  相似文献   

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This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

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最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

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Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

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This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

19.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

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