首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 269 毫秒
1.
This paper reports a geochemical study of trace metals and Pb isotopes of sediments from the lowermost Xiangjiang River, Hunan province (P. R. China). Trace metals Ba, Bi, Sc, V, Cr, Mn, Co, Ni, Cu, Zn, Mo, Cd, Sn, Sb, Pb, Tl, Th, U, Zr, Hf, Nb and Ta were analyzed using ICP-MS, and Pb isotopes of the bulk sediments were measured by MC-ICP-MS. The results show that trace metals Cd, Bi, Sn, Sc, Cr, Mn, Co, Ni, Cu, Zn, Sb, Pb and Tl are enriched in the sediments. Among these metals, Cd, Bi and Sn are extremely highly enriched (EF values >40), metals Zn, Sn, Sb and Pb significantly highly (5 < EF < 20), and metals Sc, Cr, Mn, Co, Ni, Cu and Tl moderately highly (2 < EF < 5) enriched in the river sediments. All these metals, however, are moderately enriched in the lake sediments. Geochemical results of trace metals Th, Sc, Co, Cr, Zr, Hf and La, and Pb isotopes suggest that metals in the river sediments are of multi-sources, including both natural and anthropogenic sources. Metals of the natural sources might be contributed mostly from weathering of the Indosinian granites (GR) and Palaeozoic sandstones (PL), and metals of anthropogenic sources were contributed from Pb–Zn ore deposits distributed in upper river areas. Metals in the lake sediments consist of the anthropogenic proportions, which were contributed from automobile exhausts and coal dusts. Thus, heavy-metal contamination for the river sediments is attributed to the exploitation and utilization (e.g., mining, smelting, and refining) of Pb–Zn ore mineral resources in the upper river areas, and this for the lake sediments was caused by automobile exhausts and coal combustion. Metals Bi, Cd, Pb, Sn and Sb have anthropogenic proportion of higher than 90%, with natural contribution less than 10%. Metals Mn and Zn consist of anthropogenic proportion of 60–85%, with natural proportion higher than 15%. Metals Sc, Cr, Co, Cu, Tl, Th, U and Ta have anthropogenic proportion of 30–70%, with natural contribution higher than 30%. Metals Ba, V and Mo might be contributed mostly from natural process.  相似文献   

2.
柴达木察尔汗贝壳堤剖面Sr同位素及其环境意义   总被引：6，自引：0，他引：6  
根据对柴达木盆地察尔汗古湖贝壳堤剖面酸不溶组分和酸溶组分的提取及其87Sr/86Sr的测定,结合沉积物中Rb/Sr的变化,指出Sr同位素组成特征可有效指示源区化学风化和沉积区古环境变化;依据酸溶组分中盐度指标Sr/Ca, Sr/Ba值与Sr同位素组成曲线的对比分析,揭示酸溶组分Sr同位素可以较好的指示水体形成时的盐度。通过分析贝壳堤剖面化学风化和部分盐度变化过程,探讨了研究区晚更新世39.6~ 17.1 ka BP(未经校正的AMS 14C测年结果,全文同)湖泊高湖面的演化历史。  相似文献   

3.
Lead concentrations and isotopic composition of sediment samples collected from three sites within the Lebanese coastal zones were measured: at Akkar, Dora and Selaata. Akkar is located far from any direct source of contamination, while Dora and Selaata receive urban and industrial wastes, respectively. Low Pb concentrations (6–16 μg g−1) were detected in the Akkar sediments, and high concentrations of Pb (70–101 μg g−1) were detected in the Dora sediments. Measuring stable isotope ratios of Pb makes it possible to identify the principal sources of Pb in the Akkar sediments as Pb emitted from gasoline combustion and Pb originating from natural sources. On the other hand, Pb stable isotopic ratios in Dora sediments indicate that they are more highly influenced by anthropogenic sources. Isotopic Pb ratios in the Selaata deposits, where Pb concentrations range between 5 and 35 μg g−1, have an exceptional radiogenic signature for marine sediments 1.25 < 206Pb/207Pb < 1.6 and 0.5 < 206Pb/208Pb < 0.67, which shows the impact of the phosphogypsum discharged by Selaata’s chemical plant. Isotopic Pb analysis applied to EDTA extracts, to test the mobility of Pb, shows that that this mobility is high (>60%) after 24 h of extraction, and that the extracted Pb is less radiogenic than the residual Pb.  相似文献   

4.
黄旗海湖泊沉积记录的早中全新世大湖期环境的差异性   总被引：2，自引：0，他引：2  
内蒙古黄旗海H6剖面揭示了最近间冰期古湖泊涨缩的一个完整旋回。基于OSL年代、粒度并结合沉积物地球化学等数据,分析了黄旗海在早、中全新世（约（11.4±1.1～6.7±0.7）ka）大湖期指标记录特点与环境意义。研究认为黄旗海全新世大湖期可分为三个阶段:1）（11.4±1.1～9.3±0.9） ka BP,半深水环境、湖水盐度低、流域存在有利于化学风化的湿润气候条件;2）（9.3±0.9～7.7±0.7） ka BP,湖水变浅、湖泊萎缩、湖泊盐度升高,流域可能存在不利于化学风化的干燥气候;3）（7.7±0.7～6.7±0.7） ka BP,大湖期结束,指标记录存在剧烈波动,揭示气候具有宽幅震荡特征。同时,研究初步认为Mn/Li比值可以作为流域化学风化的指标指示。  相似文献   

5.
Two Holocene sediment cores were retrieved respectively from the enclosed Lake Daihai in the monsoon/arid transition zone of North China and the Taihu Lake coast in the monsoonal area of the Yangtze delta, Eastern China. Distribution of major geochemical elements and their ratios were employed to reveal the characteristics of Holocene climate and associated environmental implications in the two regions. It is suggested that the temporal distribution of major elements serve as a useful indicator to denote the variations of monsoon effective precipitation for the enclosed lake area. High values of resistant elements such as Al2O3, SiO2, TiO2, (FeO + Fe2O3), MnO in the lake sediments correspond to the depressed chemical weathering and weakened mon-soon effective precipitation, while the highs of mobile and easy soluble elements such as MgO, CaO, Na2O reflect the enhanced chemical weathering and increased monsoon effective precipitation in the lake basin. In comparison, the behaviors of the major elements in sediments of the Taihu Lake coast were largely controlled by the changes both in sea transgression in the different Holocene time periods and the monsoon precipitation. The relatively highs of Al2O3, TiO2, (FeO + Fe2O3), in marine-influenced sediments suggest relatively strong coastal hydrodynamics and chemical weathering, and vice versa. Meanwhile, the lows of SiO2, Na2O and CaO in the non-marine-influenced sediments also denote relatively strong hydrodynamics and chemical weathering due to enhanced monsoon precipitation, and vice versa. Sedimentary environment should be taken into account when achieving a full understanding of their climate implications.  相似文献   

6.
New research results are presented on the processes of carbonate sedimentation in shallow saline lakes of Western Transbaikalia by the example of the Holocene bottom sediments of Sul’fatnoe Lake (the Selenga Dauria). The techniques of X-ray diffractometry (XRD), IR spectroscopy, laser granulometry, and isotope and elemental analyses were used. By means of decomposition the XRD profiles using the Pearson VII function, the carbonate phases were identified and their quantitative ratios were determined. The evolution of the lake basin caused by climate changes in the Holocene was reconstructed by comparing the carbonate record to the concentrations determined for the 18O and 13C stable isotopes and to lithological, geochemical, and palynological data in the dated sedimentary section.  相似文献   

7.
Thermokarst lakes are a widespread feature of the Arctic tundra, in which highly dynamic processes are closely connected with current and past climate changes. We investigated late Quaternary sediment dynamics, basin and shoreline evolution, and environmental interrelations of Lake El'gene‐Kyuele in the NE Siberian Arctic (latitude 71°17′N, longitude 125°34′E). The water‐body displays thaw‐lake characteristics cutting into both Pleistocene Ice Complex and Holocene alas sediments. Our methods are based on grain size distribution, mineralogical composition, TOC/N ratio, stable carbon isotopes and the analysis of plant macrofossils from a 3.5‐m sediment profile at the modern eastern lake shore. Our results show two main sources for sediments in the lake basin: terrigenous diamicton supplied from thermokarst slopes and the lake shore, and lacustrine detritus that has mainly settled in the deep lake basin. The lake and its adjacent thermokarst basin rapidly expanded during the early Holocene. This climatically warmer than today period was characterized by forest or forest tundra vegetation composed of larches, birch trees and shrubs. Woodlands of both the HTM and the Late Pleistocene were affected by fire, which potentially triggered the initiation of thermokarst processes resulting later in lake formation and expansion. The maximum lake depth at the study site and the lowest limnic bioproductivity occurred during the longest time interval of ～7 ka starting in the Holocene Thermal Maximum and lasting throughout the progressively cooler Neoglacial, whereas partial drainage and an extensive shift of the lake shoreline occurred ～0.9 cal. ka BP. Correspondingly, this study discusses different climatic and environmental drivers for the dynamics of a thermokarst basin.  相似文献   

8.
中国过去2000年湖泊沉积记录的高分辨率研究:现状与问题   总被引：22，自引：1，他引：22  
吉磊 《地球科学进展》1995,10(2):169-175
过去２ｋａ地球环境的变化规律和原因是全球变化研究的关键内容之一，与其它自然记录相比，湖泊沉积具有储存信息量大，时间分辨率高和地理覆盖面广的优势。中国８０年代后期以来已陆续开展了全新世湖泊沉积与气候，环境演化研究，并有迅速发展之势，对于过去２ｋａ湖泊沉积的高分辨率研究，需要重视以下几方面问题，即提高核素测年的精度，建立环境指标的转换函数，注意早期化学成岩作用，选择分层湖和年层沉积，探讨气候要素有效指  相似文献   

9.
早全新世降温事件的湖泊沉积证据   总被引：12，自引：1，他引：12  
我国华北干旱－半干旱区封闭湖泊流域化学风化历史记录了全新世以来次级的气候环境波动过程。高精度的沉积物地球化学、物理及生物参数变化表明，在全新世早－中期过渡阶段存在一次强降温气候事件，具体表现为流域化学风化减弱（高Rb/Sr比）、湖泊产生力减弱（低有机碳）以及湖泊水位下降。虽然该事件的寒冷程度比Younger Dryas弱，但是其与来自湖沼（包括北极、非洲、北美、西欧、青藏高原、祁连山等）、海洋（比北大西洋、地中海、加勒比海等）、欧－美大陆生物组合、极地冰芯等在内的环境记录的冷事件发生时间基本一致，集中发生于8.0-8.5ka B.P.之间。  相似文献   

10.
Both monsoons and westerlies have exerted influence on climate dynamics over the Tibetan Plateau (TP) since the last deglaciation, producing complex patterns of paleohydroclimatic conditions. Diverse proxy records are essential to forge a robust understanding of the climate system on the TP. Currently, there is a general lack of understanding of the response of inland lakes over the TP to climate change, especially glacier‐fed lakes. Paleohydrological reconstructions of such lakes could deepen our understanding of the history of lake systems and their relationship to regional climate variability. Here we use records of n‐alkanes and grain size from the sediments of Bangong Co in the western TP to reconstruct paleohydrological changes over the past 16,000 years. The Paq record (the ratio of non‐emergent aquatic macrophytes versus emergent aquatic macrophytes and terrestrial plants) is generally consistent with the variations in summer temperature and precipitation isotopes. The changes in grain‐size distributions show a similar trend to Paq but with less pronounced fluctuations in the early‐middle Holocene. The new data combined with previous results from the site demonstrate that: 1) Bangong Co experienced relatively large water‐level fluctuations during the last deglaciation, with a steadily high lake‐level during the early‐middle Holocene and a decreasing lake‐level in the late Holocene; 2) The lake level fluctuations were driven by both high summer temperatures via the melting water and monsoon precipitation. However, the dominant factor controlling lake level changed over time. The lake‐level history at Bangong Co deduced from the n‐alkanes and grain‐size records reveals the past hydrological changes in the catchment area, and stimulates more discussion about the future of glacier‐fed lakes under the conditions of unprecedented warming in the region.  相似文献   

11.
北疆地区早全新世环境演化的湖泊沉积记录   总被引：3，自引：0，他引：3  
通过对北疆地区艾比湖沉积物的孢粉组合及其碳酸盐δ^18O,δ^13C,δ^13Corg，TOC，TON和Rb/Sr比等地球化学指标分析，重点对全新世早期气候环境演化特征进行了研究。结果表明，研究时段（8.0-11.cal ka B.P.)温度总体偏低，初期（11.5-10.6cal ka B.P.)较为温湿；早全新世向中全新世转换时期（8.9-8.0cal ka B.P.)气候波动显著。特别是3层泥炭沉积显示了艾比湖地区早全新世气候的强烈不稳定性。泥炭的发育程度及其同位素、孢粉分析数据等都显示，8.2cal ka B.P.,8.6cal ka B.P.,10.5cal ka B.P.的气候状况具有显著的冷湿特征，反映了早全新世的3次冷湿事件。  相似文献   

12.
Economic reform in China since 1978 has accelerated economic development nationwide hugely, but has also brought about some environmental pollution. In order to identify the primary Pb source to the atmosphere in the central Guizhou region, Pb isotopic ratios in the acid soluble fraction of sediment from Hongfeng Lake were investigated. Lead isotopes in the lake sediments record the history of regional atmospheric Pb pollution. Before the economic reform in 1978, the 208Pb/206Pb and 206Pb/207Pb ratios in the leachates of lake sediments were constant, with a range of 2.0060 to 2.0117 and of 1.2314 to 1.2355, respectively. In the early period of economic reform (1978 to 1988), with the rapid industrial growth in Guizhou province, the acid soluble Pb isotope ratios in the lake sediments changed sharply: the 208Pb/206Pb ratios increased from 2.0212 to about 2.05, while the 206Pb/207Pb ratios decreased from 1.2251 to 1.2060. Emissions from Pb-ore-related industries are suggested to be the major pollution source of Pb in this period. Due to output from a local power plant since 1988, the isotope ratios of the acid soluble Pb in sediments in 1990s are characterized by a little higher radiogenic Pb (208Pb/206Pb = 2.0340–2.0400; 206Pb/207Pb = 1.2122–1.2158) than for the 1980s.  相似文献   

13.
流域生物、化学风化对小冰期气候变化的响应   总被引：2，自引：3，他引：2  
岱海近500年沉积物的孢粉，介形类和地球化学记录表现了流域生物，化学风化对全球性小冰期气候波动明显而快速的响应，孢粉量的下降，化学风化强度的减弱（高Rb/Sr比值）以及意外湖花介（Limnocythere inopinata)的繁盛反映了小冰期最盛期岱海地区以干旱为特征的气候环境及其造成的高矿化度湖水，其中，介形类丰度及种类对环境变化的反应最迅速，植被生长的调节则要缓慢一些，内陆湖泊流域植被的衰弱与干旱环境下化学风化强度的减弱以及风尘作用的加强是相辅相成的。  相似文献   

14.
In this review, the shifts in organic matter (OM) accumulation and C:N ratios in lake sediments to reconstruct paleoclimate and paleo-environmental changes since the early Holocene period are presented. The C:N proxy data of total OM reflect wet climatic conditions during early Holocene (10 to 8.2 kyrs BP) due to enhanced southwest monsoon. This was followed by intermittent arid conditions during the mid and late Holocene period (8.2 to 2.8 kyr BP). Enhanced values of C:N ratio during middle to late Holocene (7.8–2.3 kyrs B.P) indicate periods with lower lake levels and minimum precipitation, while decreased C:N ratio point to stronger SW monsoon and expansion of the lakes. Further, C:N and δ13C results from the lake sediments reveal a detailed and continuous paleo-environmental changes in the relative sources of OM (allochthonous vs autochthonous). Proxy records using such natural archives have also been utilized to reconstruct past extreme events and environmental changes around the lake systems, such as causes for lake desiccation, hydrographic changes, alternations between C3 and C4 vegetation and historical disturbances in the catchment area since the early-late Holocene period coupled with the Indian summer monsoon.  相似文献   

15.
宁晋泊地区全新世温暖期以来气候与环境变化研究   总被引：6，自引：0，他引：6  
宁晋泊沉积物的环境指标高分辨率分析,揭示了作新世温暖期以来气候变化规律和湖泊演化过程。全新世温暖期早期,气候温暖,降水丰沛,环境稳定,湖泊水草茂美;其中在５５００－６０００ａＢＰ有一个短暂的降温过程;温暖期晚期,气候波动明显。全新世晚期,气候呈规律性波动,与华北地区文史资料一致,具有良好的可比性。  相似文献   

16.
Sediments of the Lagoa Vermelha (Red Lake), situated in the Ribeira Valley, southeastern Brazil, are made of a homogeneous, organic-rich, black clay with no visible sedimentary structures. The inorganic geochemical record (Al, As, Ba, Br, Co,Cs, Cr, Fe, Mn, Ni, Rb, Sc, Sb, V, Zn, Hg and Pb) of the lake sediments was analyzed in a core spanning 2430 years. The largest temporal changes in trace metal contents occurred approximately within the last 180 years. Recent sediments were found to be enriched in Pb, Zn, Hg, Ni, Mn, Br and Sb (more than 2-fold increase with respect to the “natural background level”). The enhanced accumulation of Br, Sb, and Mn was attributed to biogeochemical processes and diagenesis. On the other hand, the anomalous concentrations of Pb, Zn, Hg and Ni were attributed to pollution. As Lagoa Vermelha is located in a relatively pristine area, far removed from direct contamination sources, the increased metal contents of surface sediments most likely resulted from atmospheric fallout. Stable Pb isotopes provided additional evidence for anthropogenic contamination. The shift of 206Pb/207Pb ratios toward decreasing values in the increasingly younger sediments is consistent with an increasing contribution of airborne anthropogenic lead. In the uppermost sediments (0-10 cm), the lowest values of the 206Pb/207Pb ratios may reflect the influence of the less radiogenic Pb from the Ribeira Valley District ores (206Pb/207Pb between 1.04 and 1.10), emitted during the last 50 years.  相似文献   

17.
Comparison of catchment geomorphology and lithostratigraphical analysis of sediments in two small neighbouring alpine lakes show that the minerogenic influx into the lakes has varied significantly during the Holocene, despite similarities in environmental setting. One lake contains a homogeneous organic‐rich sediment sequence whereas the sediment of the other lake is laminated and has a higher minerogenic content. X‐ray radiographs are used to visualise lithostratigraphical structures and provide high‐resolution density data. We find that moderate differences in geomorphology and process activity in the lakeshore region around alpine lakes can significantly affect the lake sediment composition. Minerogenic sediment accumulation rates vary strongly over time, owing to different depositional processes, which complicate temporal reconstructions. We also find that non‐glacial processes deposit minerogenic sediment layers with similar characteristics (high density, low organic content) as layers interpreted as having a glaciofluvial origin. This has implications for palaeoclimate studies based on proglacial lacustrine sediment. Our results indicate that erosion of surface sediments in the catchments characterised the early Holocene. A low and constant minerogenic inflow indicates that stable environmental conditions (with little fluvial erosion) were established in the catchments during the middle Holocene. The variability in sediment composition increased again in the late Holocene, possibly as a result of short‐term climate fluctuations superimposed on a general climate deterioration trend. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

18.
湖泊沉积物是记录过去气候变迁的自然档案，分析湖泊沉积物的地球化学特征可以恢复湖区的古环境。在安固里淖湖心区钻取一沉积剖面，并以1cm为间隔分样，测得剖面各段的化学元素组成。根据岩心化学元素组成的变化和元素比值指标的变化，结合岩心纹层年代，获得湖区全新世以来的环境变化信息： 8507～7543a BP气候略干冷,但向暖湿方向发展；7453～4617a BP以湿润气候为主，但是存在相对干旱的时段(5137～4617a BP);4617～574a BP以干冷气候为主，在4617a BP和2494～1924a BP期间出现强干冷气候突变事件；574a BP以来，前期气候向湿润方向发展，但是在383a BP以后又转为干旱。安固里淖湖区全新世的环境变化状况与我国北方同期的气候状况具有很好的可比性。  相似文献   

19.
Reconstructions of past climatic changes on the northeastern Tibetan Plateau(NETP) can provide insights into the Asian summer monsoon(ASM) variability. However, the regional climate changes on both orbital and suborbital time scales since the late Glacial remain controversial. Here we present the results of high-resolution geochemical and grain-size analyses of a sediment core from Genggahai Lake, a small, shallow lake in this area. Changes of the accumulation rate of the core sediments show a similar trend with variations of the coarse fraction. Accordingly, the chronological framework is constructed using a grain-size age model. In addition, the histories of chemical weathering and aeolian activity since the late Glacial are reconstructed based on the Al/Ti ratios and coarse fractions, respectively. The results suggest that an enhanced chemical weathering and a weakened aeolian activity occurred on the NETP under a warmer, wetter climate during the early to mid-Holocene(11.3–6.3 ka cal BP), compared with the late Glacial(17.1–11.3 ka cal BP) and the late Holocene(6.3 ka cal BP to present), which responded mainly to the strengthened ASM on orbital time scale. In addition, the synchronous occurrences of weakened chemical weathering, low lake level and intense aeolian activity on suborbital time scale reflect several episodes of weakened ASM. Furthermore, these episodes largely coincide with the centennial-to millennial-scale cold events in the North Atlantic, which demonstrates the close connection between the ASM and the cooling at high latitudes.  相似文献   

20.
Late Pleistocene paleoclimatic history on northeastern Qinghai–Tibetan Plateau (QTP) has been reconstructed mainly from lake sediments; however, data regarding dry–wet climate changes reported in this region are still not clear and controversial. Based on shoreline features and highstand lacustrine sediments around lakes on the QTP, high lake level histories in this paper were summarized and compared with paleoclimatic records from lake sediments, ice core and glaciation evolution surrounding mountains on the NE QTP during late Pleistocene. The results indicate that periods of high lake level occurred at MIS 5, MIS 3 and early-middle Holocene and most likely corresponding to warm and wet climate periods, while periods of low lake level existed in intervening intervals, corresponding to cold and dry climate periods, which most likely coincide with glacial advances surrounding high mountains. With an exception, no wide glacial advance in study area was found during MIS 3, possibly suggesting that effective moisture is lower than that in the other region of NE QTP in this period.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号