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1.
In this study, sapphirine‐bearing granulites and sapphirine‐absent garnet–sillimanite gneisses from the Tuguiwula area in the eastern segment of the Khondalite Belt, North China Craton (NCC) are interpreted to show a P–T evolution involving cooling at pressures of 8–9 kbar from >960°C to the solidus (~820°C) and late subsolidus decompression. This interpretation is based on the sequence of mineral appearance and thermodynamic modelling of phase equilibria. Sapphirine is observed to coexist with spinel within the peak assemblages. This observation conflicts with the traditional view that spinel generally appears prior to sapphirine and thus indicates pre‐Tmax compression. For ultrahigh‐temperature (UHT) metapelites at Tuguiwula, a clockwise P–T path may be more likely, which would be consistent with the clockwise P–T evolution of the extensive “normal” granulites (Tmax <900°C) and UHT granulites at other localities in the eastern segment of the Khondalite Belt. At Tuguiwula, for UHT metapelites with low bulk‐rock Mg/(Mg+FeT), the oxidation state/Fe3+ content is interpreted to be a significant factor in controlling the mineral assemblages. We find that these compositions tend to contain sapphirine under oxidized conditions but spinel (without sapphirine) under reduced conditions. This difference may account for the simultaneous presence of both sapphirine‐bearing UHT granulites and sapphirine‐absent garnet–sillimanite UHT gneisses at Tuguiwula. LA‐ICP‐MS U–Pb dating of metamorphic zircon in the UHT metapelites yields mean 207Pb/206Pb ages of c. 1.92 Ga (two samples), which are interpreted to record the timing of cooling of the UHT rocks to the solidus. The UHT metamorphism is interpreted to have been generated by mantle upwelling and emplacement of mafic magmas within a post‐orogenic setting.  相似文献   

2.
The island of Seram, part of the northern limb of the Banda Arc in eastern Indonesia, exposes an extensive Mio‐Pliocene granulite facies migmatite complex (the Kobipoto Complex) comprising voluminous leucosome‐rich diatexites and scarcer Al–Fe‐rich residual granulites. The migmatites are intimately associated with ultramafic rocks of predominantly lherzolitic composition that were exhumed by substantial lithospheric extension beneath low‐angle detachment faults; heat supplied by the lherzolites was evidently a major driver for the granulite facies metamorphism and accompanying anatexis. Residual garnet–sillimanite granulites sampled from the Kobipoto Mountains, central Seram, contain scarce garnet‐hosted inclusions of hercynite spinel (~1.5 wt% ZnO) + quartz (± ilmenite) in direct grain‐boundary contact – an assemblage potentially indicative of metamorphism under ultrahigh‐temperature (UHT) conditions. thermocalc ‘Average P–T’ reactions and melanosome‐specific thermocalc , T–MO, and P–T pseudosections in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3 (NCKFMASHTO) chemical system, supported by Ti‐in‐garnet thermobarometry, are permissive of the rock having experienced a clockwise P–T path peaking at 925 °C and 9 kbar – thus narrowly reaching UHT conditions – before undergoing near‐isothermal decompression to ~750 °C and ~4 kbar. Spinel + quartz assemblages are interpreted to have formed at or just after the metamorphic peak from localized reactions between sillimanite, ilmenite and surrounding garnet. Further decompression of the rock resulted in the formation of complex reaction microstructures comprising cordierite ± plagioclase coronae around garnet, and symplectic intergrowths of cordierite + spinel + ilmenite around sillimanite. Small grains of sapphirine + corundum developed subsequently within spinel by localized quartz‐absent reactions. The post‐peak evolution of the granulites may be related to previously published U–Pb zircon and 40Ar/39Ar ages of c. 16 Ma, further substantiating the claim for the Kobipoto Complex granulites having recorded Earth's youngest‐identified episode of UHT metamorphism, albeit at slightly lower temperature and higher pressure than previously inferred. The Kobipoto Complex granulites demonstrate how UHT conditions may be achieved in the ‘modern’ Earth by extreme lithospheric extension, which, in this instance, was driven by slab rollback of the Banda Arc.  相似文献   

3.
The time‐scales and P–T conditions recorded by granulite facies metamorphic rocks permit inferences about the geodynamic regime in which they formed. Two compositionally heterogeneous cordierite–spinel‐bearing granulites from Vizianagaram, Eastern Ghats Province (EGP), India, were investigated to provide P–T–time constraints using petrography, phase equilibrium modelling, U–Pb geochronology, the rare earth element composition of zircon and monazite, and Ti‐in‐zircon thermometry. These ultrahigh temperature (UHT) granulites preserve discrete compositional layering in which different inferred peak assemblages are developed, including layers bearing garnet–sillimanite–spinel, and others bearing orthopyroxene–sillimanite–spinel. These mineral associations cannot be reproduced by phase equilibrium modelling of whole‐rock compositions, indicating that the samples became domainal on a scale less than that of a thin section, even at UHT conditions. Calculation of the P–T stability fields for six compositional domains within which the main rock‐forming minerals are considered to have attained equilibrium suggests peak metamorphic conditions of ~6.8–8.3 kbar at ~1,000°C. In most of these domains, the subsequent evolution resulted in the growth of cordierite and final crystallization of melt at an elevated (residual) H2O‐undersaturated solidus, consistent with <1 kbar of decompression. Concordant U–Pb ages obtained by SHRIMP from zircon (spread 1,050–800 Ma) and monazite (spread 950–800 Ma) demonstrate that crystallization of these minerals occurred during an interval of c. 250 Ma. By combining LA‐ICP‐MS U–Pb zircon ages with Ti‐in‐zircon temperatures from the same analysis sites, we show that the crust may have remained above 900°C for a minimum of c. 120 Ma between c. 1,000 and c. 880 Ma. Overall, the results suggest that, in the interval 1,050 to 800 Ma, the evolution of the Vizianagaram granulites culminated with UHT conditions from c. 1,000 Ma to c. 880 Ma, associated with minor decompression, before further zircon crystallization at c. 880–800 Ma during cooling to the solidus. However, these rocks are adjacent to the Paderu–Anantagiri–Salur crustal block to the NW that experienced counterclockwise P–T–t paths, and records similar UHT peak metamorphic conditions (7–8 kbar, ~950°C) followed by near‐isobaric cooling, and has a similar chronology during the Neoproterozoic. The limited decompression inferred at Vizianagaram may be explained by partial exhumation due to thrusting of this crustal block over the adjacent Paderu–Anantagiri–Salur crustal block. The residual granulites in both blocks have high concentrations of heat‐producing elements and likely remained hot at mid‐crustal depths throughout a period of relative tectonic quiescence in the interval 800–550 Ma. During the Cambrian Period, the EGP was located in the hinterland of the Denman–Pinjarra–Prydz orogen. A later concordant population of zircon dated at 511 ± 6 Ma records crystallization at temperatures of ~810°C. This age may record a low‐degree of melting due to limited influx of fluid into hot, weak crust in response to convergence of the Crohn craton with a composite orogenic hinterland comprising the Rayner terrane, EGP, and cratonic India.  相似文献   

4.
The Huai’an Complex in the north-western Trans-North China Orogen, North China Craton is recognized to have undergone high-pressure metamorphism with controversial ages. Two mafic granulite samples (17HT13 and 16HT22) from Huangtuyao of the Huai’an Complex are documented for metamorphism based on petrography, mineral chemistry, phase equilibria modelling and zircon dating. The rocks comprise garnet, clinopyroxene, orthopyroxene, amphibole, plagioclase and ilmenite. They show clockwise P-T paths involving the pre-Tmax decompressional heating, the Tmax and the post-Tmax cooling stages. The pre-Tmax decompressional heating is revealed by the core-rim/mantle anorthite-ascending zoning in coarse-grained plagioclase. The Tmax stage is constrained to 8.5–10.5 kbar/980–1010 °C (17HT13) and 7.5–9.5 kbar/1000–1030 °C (16HT22) by the high Ti content of amphibole, and the anorthite content of coarse-grained plagioclase rims/mantles and fine-grained plagioclase cores. These temperatures are slightly higher than the results of amphibole thermometers (∼940–980 °C). The post-Tmax cooling is defined by the later growth of amphibole and some conventional geothermobarometers. Because it is dominated by temperature with ilmenite present, the Ti content of amphibole is proposed as a reliable thermometer, and the Ti-rich amphibole with Ti > 0.28 p.f.u. or TiO2 > 2.4–2.6 wt% is indicative of ultrahigh-temperature (>900 °C, UHT) conditions. The anorthite content of plagioclase is also significant in confining peak temperatures for UHT granulite but requires defining proper water content. Zircon dating for 17HT13 yields an upper intercept age of 1910 ± 35 Ma, representing the cooling of UHT granulite. We conclude that the Huai’an Complex may have at least locally undergone UHT metamorphism at ∼1.92–1.91 Ga after high-pressure granulite metamorphism at ∼1.95 Ga, similar to the Jining Complex. Therefore, the Huai’an and Jining Complexes share the same tectonic evolution involving ∼1.95 Ga crustal thickening, ∼1.92–1.91 Ga extension with regional or local UHT metamorphism, and subsequent cooling and uplifting.  相似文献   

5.
High‐pressure (HP) metagreywacke from the Namche Barwa Complex, Eastern Himalayan Syntaxis (EHS), consists of garnet, biotite, plagioclase, quartz, rutile and ilmenite with or without K‐feldspar, sillimanite, cordierite, spinel and orthopyroxene. Two types of metagreywacke are recognized: medium‐temperature (MT) and high‐temperature (HT) types. Garnet in the MT metagreywacke shows significant growth zoning and contains lower MgO than the weakly zoned garnet in the HT metagreywacke. Petrographic observations and phase equilibria modelling for four representative samples indicate that both types of metagreywacke experienced clockwise P–T paths subdivided into three stages: stage I is the pre‐peak prograde to pressure peak (Pmax) stage characterized by progressive increase in P–T conditions. The Pmax conditions are estimated using the garnet composition with maximum CaO, being 12.5–13.5 kbar and 685–725 °C for the MT metagreywacke, and 15–16 kbar and 825–835 °C for the HT one. Stage II is the post‐Pmax decompression with heating or near‐isothermal to Tmax stage and the Tmax conditions, constrained using the garnet compositions with maximum MgO, are 11 kbar and 760 °C for the MT metagreywacke, and ~12 kbar and 830–845 °C for the HT one. The modelled mineral assemblages at Tmax are garnet + biotite + K‐feldspar + rutile + plagioclase ± ilmenite in the presence of melt for both types of metagreywacke, consistent with the petrographic observations. Stage III is the post‐Tmax retrograde metamorphism, characterized by decompression and cooling. The modelling suggests that the melts with high Na/K ratios (1.7–5.2) have been produced during stages I and II, which could be responsible for the formation of sodium‐rich leucogranites. This study and previous results indicate that the Higher Himalayan Crystallines in the EHS consist of MT–HP and HT–HP metamorphic units separated by a speculated tectonic contact. Petrological and structural discontinuities within the EHS cannot be easily interpreted with ‘tectonic aneurysm’ model.  相似文献   

6.
The East Hebei terrane of North China Craton is characterized by the dome-and-keel structure, a common feature in most Archean cratons, where supracrustal rocks of granulite facies commonly occur as enclaves or rafts in tonalite–trondhjemite–granodiorite (TTG) gneisses. The metamorphic P–T paths of the granulites are significant for addressing the Archean tectonic regimes. Two types of granulite facies paragneiss with pelitic and greywacke compositions from the western margin of Qian'an gneiss dome are documented for their petrography, mineral chemistry, phase equilibria modelling using thermocalc, and zircon dating. Anticlockwise P–T paths involving the pre-peak pressure increase to the ultra-high temperature peak conditions and post-peak cooling and decompression processes were recognized. The pre-peak pressure increase process was constrained for a pelitic granulite mainly based on the spinel and cordierite inclusions in garnet and rutile corona around ilmenite, where the transition from spinel to garnet is modelled at 6–7 kbar at a fixed T = 1,000°C. For greywacke granulite, the pre-peak pressure increase evolution can be ascertained from the textural relation that orthopyroxene is surrounded by garnet, and the outwards increasing grossular (from 0.03 to 0.05) in the core of the atoll-like garnet (Grt-A), to occur from ~7 kbar at ~1,000°C. The peak P–T conditions for pelitic granulite are roughly limited to 7–11 kbar/890–1,050°C on the basis of the stability of the inferred peak assemblage involving garnet, perthite, sillimanite, rutile/ilmenite, and quartz. The peak P–T condition for greywacke granulite can be well constrained as 9–10 kbar/>1,000°C on the basis of the maximum grossular content (XGrs = 0.045–0.050) in the core of subhedral garnet (Grt-B) and the mantle of Grt-A together with an average re-integrated anorthite content (XAn = 0.07) in K-feldspar. The peak temperature condition is consistent with the ternary feldspar thermometer results mostly of 950–1,020°C for antiperthite and perthite in greywacke granulite, and in accordance with the development of oriented needle-like exsolution of Ti±Fe oxides in garnet from pelitic granulite. The post-peak cooling and decompression process was consistent with the decreasing XGrs in the mantle of Grt-A and core of Grt-B in greywacke sample, and the final-stage cooling conditions can be well constrained from the stability of final assemblages marked by the later growth of biotite, as 8–9 kbar/820–880°C for pelitic granulite and 6–9 kbar/840–890°C for greywacke granulite. Zircon dating yields provenance ages from 3.34 to 2.57 Ga and metamorphic ages of c. 2.50 Ga for the two types of granulite. The metamorphic ages overlap the final pulse of the Neoarchean magmatic activity of TTGs that ranges from c. 2.56 to c. 2.48 Ga with a peak at c. 2.52 Ga. Combining the development of dome-and-keel structures, the penecontemporaneity between the metamorphism of supracrustal rocks and TTG magmatic activity, and also the unique anticlockwise P–T paths, we prefer a vertical sagduction regime to interpret the tectonic evolution of the East Hebei terrane, which may be also significant for other Archean cratons.  相似文献   

7.
Paleoproterozoic granulite facies rocks are widely distributed in the North China Craton (NCC). The Huai'an terrane, located within the northern segment of the Trans-North China Orogen (TNCO), a major Paleoproterozoic collisional belt in the central NCC expose mafic and pelitic granulites as well as TTG (tonalite-trondhjemite-granodiorite) gneisses. Here we investigate the pelitic granulites from this complex and identify four distinct mineral assemblages corresponding to different metamorphic stages. The prograde metamorphism (M1) is recorded by relict biotite and the compositional profile of Xca (grt) isopleths. The Pmax (M2) is distinguished by the Xca (grt) isopleths, which corresponds to the kyanite stable area with an inclusion mineral assemblage of Grt-c–(Ky)-Qz-Rt-Kfs-liq suggesting that the pressures were higher than 12 kbar with a temperature below 900 °C. However, kyanite is absent in thin sections suggesting its consumption during later stages. The Tmax metamorphism (M3) is characterized by the assemblage: Grt-m-Qz-Pl-Rt-Kfs-Sil-liq in the garnet mantle and also reflected in the compositional profile. Two-feldspar geothermometry yields a P-T range of 940 °C–950 °C and 9.5–10.5 kbar, indicating ultra-high temperature (UHT) metamorphic overprinting. The subsequent retrograde metamorphic stage (M4) is characterized by Grt-r-Bt-Sil-Kfs-Pl-Qz ± Rt ± Ilm with symplectites of Bt-Sil-Qz in the garnet rim suggesting garnet breakdown with P-T conditions estimated as 770 °C–840 °C and 6.5–8 kbar. The pelitic granulites show a clockwise path, with P-T estimates higher than those in estimated in previous studies using conventional techniques.LA-ICP-MS U–Pb analysis of metamorphic zircon grains yield two groups of ages at 1972.9 ± 8.1 Ma and 1873.3 ± 9.9 Ma. We suggest that the protoliths of the Manjinggou HP-UHT granulites were deep subducted where they experienced HP metamorphism associated with the collision of the Ordos and Yinshan blocks at ca. 1.97 Ga. Subsequently, the UHT metamorphic overprint occurred during the assembly of the unified Western and Eastern Blocks of the NCC along the TNCO at ca. 1.87 Ga.  相似文献   

8.
The South Altyn orogen in West China contains ultra high pressure (UHP) terranes formed by ultra‐deep (>150–300 km) subduction of continental crust. Mafic granulites which together with ultramafic interlayers occur as blocks in massive felsic granulites in the Bashiwake UHP terrane, are mainly composed of garnet, clinopyroxene, plagioclase, amphibole, rutile/ilmenite, and quartz with or without kyanite and sapphirine. The kyanite/sapphirine‐bearing granulites are interpreted to have experienced decompression‐dominated evolution from eclogite facies conditions with peak pressures of 4–7 GPa to high pressure (HP)–ultra high temperature (UHT) granulite facies conditions and further to low pressure (LP)–UHT facies conditions based on petrographic observations, phase equilibria modelling, and thermobarometry. The HP–UHT granulite facies conditions are constrained to be 2.3–1.6 GPa/1,000–1,070°C based on the observed mineral assemblages of garnet+clinopyroxene+rutile+plagioclase+amphibole±quartz and measured mineral compositions including the core–rim increasing anorthite in plagioclase (XAn = 0.52–0.58), core–rim decreasing jadeite in clinopyroxene (XJd = 0.20–0.15), and TiO2 in amphibole (TiM2/2 = 0.14–0.18). The LP–UHT granulite facies conditions are identified from the symplectites of sapphirine+plagioclase+spinel, formed by the metastable reaction between garnet and kyanite at <0.6–0.7 GPa/940–1,030°C based on the calculated stability of the symplectite assemblages and sapphirine–spinel thermometer results. The common granulites without kyanite/sapphirine are identified to record a similar decompression evolution, including eclogite, HP–UHT granulite, and LP–UHT granulite facies conditions, and a subsequent isobaric cooling stage. The decompression under HP–UHT granulite facies is estimated to be from 2.3 to 1.3 GPa at ~1,040°C on the basis of textural records, anorthite content in plagioclase (XAn = 0.25–0.32), and grossular content in garnet (XGrs = 0.22–0.19). The further decompression to LP–UHT facies is defined to be >0.2–0.3 GPa based on the calculated stability for hematite‐bearing ilmenite. The isobaric cooling evolution is inferred mainly from the amphibole (TiM2/2 = 0.14–0.08) growth due to the crystallization of residual melts, consistent with a temperature decrease from >1,000°C to ~800°C at ~0.4 GPa. Zircon U–Pb dating for the two types of mafic granulite yields similar protolith and metamorphic ages of c. 900 Ma and c. 500 Ma respectively. However, the metamorphic age is interpreted to represent the HP–UHT granulite stage for the kyanite/sapphirine‐bearing granulites, but the isobaric cooling stage for the common granulites on the basis of phase equilibria modelling results. The two types of mafic granulite should share the same metamorphic evolution, but show contrasting features in petrography, details of metamorphic reactions in each stage, thermobarometric results, and also the meaning of zircon ages as a result of their different bulk‐rock compositions. Moreover, the UHT metamorphism in UHP terranes is revealed to represent the lower pressure overprinting over early UHP assemblages during the rapid exhumation of ultra‐deep subducted continental slabs, in contrast to the cause of traditional UHT metamorphism by voluminous heat addition from the mantle.  相似文献   

9.
High Mg-Al spinel-sapphirine granulites, orthopyroxene-bearing quartzofeldspathic granulites, two pyroxene-bearing mafic granulites and metapelitic gneisses are exposed around Paderu, Eastern Ghats Belt. Geothermobarometry in orthopyroxene-bearing quartzofeldspathic granulites and mafic granulites indicate near isobaric cooling through 90°C from ca. 720°C to 630°C, at 8.0 kbar. However, signatures of ultrahigh temperature metamorphism are recorded from the mineralogy and reaction textures in the high Mg-Al granulites. Mineral reactions deduced in this work, when combined with others described by Lalet al (1987) from the same area and plotted in an appropriate petrogenetic grid in the system FMASO indicate an ACW path comprising a high dT/dP prograde arm reaching Pmax − Tmax = 9.5 kbar, ∼ 1000°C, followed by near-isobaric cooling down to 9 kbar, 900°C and subsequent decompressive reworking.  相似文献   

10.
A combined study of petrology and geochemistry was carried out for granulites from the Tongbai orogen in central China. The results reveal the tectonic evolution from collisional thickening to extensional thinning of the lithosphere at the convergent plate boundary. Petrographic observations, zircon U–Pb dating, and pseudosection calculations indicate that the granulites underwent four metamorphic stages, which are categorized into two cycles. The first cycle occurred at 490–450 Ma and involves high-P (HP) metamorphism (M1) at 785–815°C and 10–14 kbar followed by decompressional heating to 840–880°C and 8–9 kbar for medium-pressure granulite facies metamorphism (M2), defining a clockwise P–T path. The high pressure is indicated by the occurrence of inclusions of rutile+kyanite+K-feldspar in the garnet mantle. The second cycle occurred at c. 440 Ma and shows an anticlockwise P–T path with continuous heating to ultrahigh-temperature (UHT) metamorphism (M3) at 890–980°C and 9–11 kbar, followed by decompressional cooling to 740–880°C and 7–9 kbar (M4) till 405 Ma. The HP metamorphism is synchronous with the ultrahigh-pressure eclogite facies metamorphism in the Qinling orogen, indicating its relevance to the continental collision in the Cambrian. The UHT metamorphism took place at reduced pressures, indicating thinning of the collision-thickened orogenic lithosphere. Therefore, the Tongbai orogen was initially thickened by the collisional orogeny and then thinned, possibly as a result of foundering of the orogenic root. Such tectonic evolution may be common in collisional orogens where compression during continental collision switched to extension during continental rifting.  相似文献   

11.
The Fuping Complex is one of the important basement terranes within the central segment of the Trans‐North China Orogen (TNCO) where mafic granulites are exposed as boudins within tonalite–trondhjemite–granodiorite (TTG) gneisses. Garnet in these granulites shows compositional zoning with homogeneous cores formed in the peak metamorphic stage, surrounded by thin rims with an increase in almandine and decrease in grossular contents suggesting retrograde decompression and cooling. Petrological and phase equilibria studies including pseudosection calculation using thermocalc define a clockwise P–T path. The peak mineral assemblages comprise garnet+clinopyroxene+amphibole+quartz+plagioclase+K‐feldspar+ilmenite±orthopyroxene±magnetite, with metamorphic P–T conditions estimated at 8.2–9.2 kbar, 870–882 °C (15FP‐02), 9.6–11.3 kbar, 855–870 °C (15FP‐03) and 9.7–10.5 kbar, 880–900 °C (15FP‐06) respectively. The pseudosections for the subsequent retrograde stages based on relatively higher H2O contents from P/T–M(H2O) diagrams define the retrograde P–T conditions of <6.1 kbar, <795 °C (15FP‐02), 5.6–5.8 kbar, <795 °C (15FP‐03), and <9 kbar, <865 °C (15FP‐06) respectively. Data from LA‐ICP‐MS zircon U–Pb dating show that the mafic dyke protoliths of the granulite were emplaced at c. 2327 Ma. The metamorphic zircon shows two groups of ages at 1.96–1.90 Ga (peak at 1.93–1.92 Ga) and 1.89–1.80 Ga (peak at 1.86–1.83 Ga), consistent with the two metamorphic events widely reported from different segments of the TNCO. The 1.93–1.92 Ga ages are considered to date the peak granulite facies metamorphism, whereas the 1.86–1.83 Ga ages are correlated with the retrograde event. Thus, the collisional assembly of the major crustal blocks in the North China Craton (NCC) might have occurred during 1.93–1.90 Ga, marking the final cratonization of the NCC.  相似文献   

12.
The Wuhe Complex in the Bengbu area of the Jiao–Liao–Ji Belt, southeast North China Craton, contains garnet-bearing mafic granulites that have undergone high-pressure (HP) and ultrahigh-temperature (UHT) metamorphism. These granulites also experienced partial melting and occur as lenses within marbles. Petrographic observations and quantitative phase equilibria modeling reveal clockwise P–T paths, involving an inferred HP stage followed by decompressional, medium-pressure, granulite-facies metamorphism and subsequent cooling. The HP assemblage of garnet + clinopyroxene + plagioclase + K-feldspar ± amphibole ± quartz ± rutile indicates P–T conditions of 840–980 °C and 12–17 kbar. This was followed by post-peak, near-isothermal decompression with the development of orthopyroxene + clinopyroxene + plagioclase + K-feldspar + garnet + amphibole + ilmenite at 850–960 °C and 7–10 kbar, resulting in the development of orthopyroxene rims on resorbed garnet. Pyroxene and ternary feldspar thermometry yielded high temperatures of ~1150 °C and 1055–1087 °C at 10 kbar, respectively, which constrain the minimum crystallization temperatures of the igneous protoliths. The host and lamellae of the pyroxene and ternary feldspar are relict magmatic minerals/textures that survived metamorphism due to the silica-undersaturated bulk-rock conditions. Zr-in-rutile thermometry yielded temperatures of ~935 °C and 800 °C, with the former being consistent with the predicted peak metamorphic temperatures. Small amounts of melts (up to 5%) were generated during decompression of the Bengbu mafic granulites. The generated partial melts were mainly (quartz) monzonite at 900–920 °C, and the silica contents of the melts were controlled by the quartz stability field in P–T pseudosections. The partial melts were enriched in Na and strongly depleted in Fe–Mg at the peak pressure of ~14 kbar and 920 °C, and later evolved to Fe–Mg-rich and high-K compositions during decompression. The melt compositions in the studied rocks are similar when the pressures reached ~9 kbar. The modal proportion of amphibole increased as the melt H2O content decreased at lower pressures, indicating that the limited H2O remaining in the host rocks was consumed to produce amphibole. U–Pb geochronology of zircon containing inclusions of clinopyroxene, plagioclase, and apatite constrains the timing of metamorphism to 1930–1840 Ma, as is the case for HP granulites from Shandong, Liaoning, and southern Jilin in the central and northeastern Jiao–Liao–Ji Belt. The Wuhe HP–UHT mafic granulites were ultimately sourced from upwelling asthenosphere-derived magma at ~2.1 Ga, which intruded and crystallized at shallower depths. The igneous protoliths were then buried to middle–lower crustal levels and experienced HP–UHT granulite-facies metamorphism and partial melting at 1.95–1.90 Ga related to continental subduction and overthickening. The HP–UHT mafic granulites were rapidly exhumed at ~1.85 Ga and generated small volumes of (quartz) monzonite during decompression. The newly discovered Paleoproterozoic HP–UHT mafic granulites associated with partial melting suggest that the continent materials were deeply subducted to the lower crustal levels and that additional heating was not involved. The finding of the HP–UHT granulites, together with the widespread distributions of the granulite-facies metamorphic rocks and the determination of the clockwise P–T–t paths, reveal that the Paleoproterozoic Jiao–Liao–Ji orogenic belt extends at least 1000 km, starting from southern Jilin, passing through the southeastern Liaoning and Jiaobei terranes, and elongating to the Bengbu area in Anhui.  相似文献   

13.
The Xilingol Complex comprises biotite gneisses and amphibolite interlayers with extensive migmatization. Four representative samples were documented and found to record either two or three metamorphic stages. Phase modelling using thermocalc suggests that the observed assemblages represent the final stages that underwent cooling from temperature peaks, and are consistent with a fluid‐absent solidus in P–T pseudosections. Their P–T conditions are further constrained to be 5–6 kbar/680–725°C and 4–5 kbar/650–680°C for two garnet‐bearing gneiss samples, 4–5 kbar/660–730°C for a cordierite‐bearing gneiss sample, and 4–5 kbar/680–710°C for an amphibolite sample based on mineral composition isopleths, involving measured Mg content in biotite, anorthite in plagioclase, grossular and pyrope in garnet and Ti content in amphibole. The peak temperature conditions recovered are 760–790°C or >760°C at 5–6 kbar based on the composition isopleths of plagioclase, biotite, garnet and especially the comparison of melt contents between the calculated and observed. A pre‐peak heating process with slight decompression can be suggested for some samples on the basis of the core–rim increase in the plagioclase anorthite, and the stability of ilmenite. Zircon U–Pb dating using the LA‐ICP‐MS method provides systemic constraints on the metamorphic ages of the Xilingol Complex to be 348–305 Ma, interpreted to represent the post‐peak cooling stages. Moreover, metagabbroic dykes that intruded into the Xilingol Complex yield 317 ± 3 Ma from magmatic zircon, and are considered to have played a significant role for heat advection triggering the high‐T and low‐P metamorphism. Thus, the clockwise P–T paths involving pre‐peak heating, peak and post‐peak cooling recovered for the Xilingol Complex are consistent with an extensional setting in the Carboniferous that developed on a previous orogen in response to addition of mantle‐derived materials probably together with upwelling of the asthenospheric mantle.  相似文献   

14.
Garnet amphibolites can provide valuable insights into geological processes of orogenic belts, but their metamorphic evolution is still poorly constrained. Garnet amphibolites from the Wutai–Hengshan area of the North China Craton mainly consist of garnet, hornblende, plagioclase, quartz, rutile and ilmenite, with or without titanite and epidote. Four samples selected in a south–north profile were studied by the pseudosection approach in order to elucidate the characteristics of their metamorphic evolution, and to better reveal the northwards prograde change in P–T conditions as established previously. For the sample from the lower Wutai Subgroup, garnet exhibits obvious two‐substage growth zoning characteristic of pyrope (Xpy) increasing but grossular (Xgr) decreasing outwards in the core, and both Xpy and Xgr increasing outwards in the rim. Phase modelling using thermocalc suggests that the garnet cores were formed by chlorite breakdown over 7–9 kbar at 530–600 °C, and rims grew from hornblende and epidote breakdown over 9.5–11.5 kbar at 600–670 °C. The isopleths of the minimum An in plagioclase and maximum Xpy in garnet were used to constrain the peak P–T conditions of ~11.5 kbar/670 °C. The modelled peak assemblage garnet + hornblende + epidote+ plagioclase + rutile + quartz matches well the observed one. Plagioclase–hornblende coronae around garnet indicate post‐peak decompression and fluid ingress. For the samples from the south Hengshan Complex, the garnet zoning weaken gradually, reflecting modifications during decompression of the rocks. Using the same approach, the rocks are inferred to have suprasolidus peak conditions, increasing northwards from 11.5 kbar/745 °C, 12.5 kbar/780 °C to 13 kbar/800 °C. Their modelled peak assemblages involve diopside, garnet, hornblende, plagioclase, rutile and quartz, yet diopside is not observed petrographically. The post‐peak decompression is characterized by diopside + garnet + quartz + melt = hornblende + plagioclase, causing the diopside consumption and garnet compositions to be largely modified. Thus, the pesudosection approach is expected to provide better pressure results than conventional thermobarometry, because the later approach cannot be applied with confidence to rocks with multi‐generation assemblages. U–Pb dating of zircon in the Wutai sample records a protolith age of c. 2.50 Ga, and a metamorphic age of c. 1.95 Ga, while zircon in the Hengshan samples records metamorphic ages of c. 1.92 Ga. The c. 1.95 Ga is interpreted to represent the pre‐peak or peak metamorphic stages, and the ages of c. 1.92 Ga are assigned to represent the cooling stages. All rocks in the Wutai–Hengshan area share similar clockwise P–T morphologies. They may represent metamorphic products at different crustal depths in one orogenic event, which included a main thickening stage at c. 1.95 Ga followed by a prolonged uplift and cooling after 1.92 Ga.  相似文献   

15.
A new quantitative approach to constraining mineral equilibria in sapphirine‐bearing ultrahigh‐temperature (UHT) granulites through the use of pseudosections and compatibility diagrams is presented, using a recently published thermodynamic model for sapphirine. The approach is illustrated with an example from an UHT locality in the Anápolis–Itauçu Complex, central Brazil, where modelling of mineral equilibria indicates peak metamorphic conditions of about 9 kbar and 1000 °C. The early formed, coarse‐grained assemblage is garnet–orthopyroxene–sillimanite–quartz, which was subsequently modified following peak conditions. The retrograde pressure–temperature (P–T) path of this locality involves decompression across the FeO–MgO–Al2O3–SiO2 (FMAS) univariant reaction orthopyroxene + sillimanite = garnet + sapphirine + quartz, resulting in the growth of sapphirine–quartz, followed by cooling and recrossing of this reaction. The resulting microstructures are modelled using compatibility diagrams, and pseudosections calculated for specific grain boundaries considered as chemical domains. The sequence of microstructures preserved in the rocks constrains a two‐stage isothermal decompression–isobaric cooling path. The stability of cordierite along the retrograde path is examined using a domainal approach and pseudosections for orthopyroxene–quartz and garnet–quartz grain boundaries. This analysis indicates that the presence or absence of cordierite may be explained by local variation in aH2O. This study has important implications for thermobarometric studies of UHT granulites, mainly through showing that traditional FMAS petrogenetic grids based on experiments alone may overestimate P–T conditions. Such grids are effectively constant aH2O sections in FMAS‐H2O (FMASH), for which the corresponding aH2O is commonly higher than that experienced by UHT granulites. A corollary of this dependence of mineral equilibria on aH2O is that local variations in aH2O may explain the formation of cordierite without significant changes in P–T conditions, particularly without marked decompression.  相似文献   

16.
High‐MgAl rocks occur as xenoliths (up to 2 m in diameter) in mafic granulites at a newly discovered locality near Anakapalle. Following an early phase of deformation, ultrahigh‐temperature (UHT) metamorphism and near‐isothermal decompression, the rocks were intruded in a lit‐par‐lit manner by felsic melts (charnockite), which caused local‐scale metasomatism. A subsequent deformation produced isoclinal folds and the distinct gneissic foliation of the charnockite still at granulite facies conditions. The sequence of multiphase reaction textures in the high‐MgAl xenoliths reflects the changes of physico‐chemical conditions during the polyphase evolution of the terrane; UHT metamorphism (stage 1, > 1000°C, c. 10 kbar) is documented by relics of extremely coarse grained domains with the assemblage orthopyroxene (opx)1 + garnet (grt)1 + sapphirine (spr)1 + spinel (spl)1 + rutile (rt). A subsequent phase of near‐isothermal decompression in the order of 1–2 kbar (stage 2) resulted in extensive replacement of grt1 and opx1 megacrysts by lamellar (opx2 + spr2) symplectites. The intrusion of felsic melt (stage 3) led to the development of a narrow metasomatic black wall reaction zone (bt + sil + plg3 + opx2,3 + rt) at the immediate contact of the xenoliths and in melt infiltration zones to the partial replacement of (opx2 + spr2) symplectites by biotite and sillimanite and/or plg3, mainly at the expense of orthopyroxene, with concomitant coarsening of the intergrowth texture. The subsequent deformation (stage 4) further modified the symplectite textures through polygonization, recrystallization and grain‐size coarsening. The deformation was followed by a period of cooling and decompression (stage 5, c. 800°C, 4–7 kbar) as indicated by local growth of late garnet (grt5) at the expense of (opx + spr + plg) domains at static conditions. Recently published isotope data suggest that the multistage evolution of the high‐MgAl granulites at Anakapalle followed a discontinuous P–T trajectory that may be related to heating of the crust through magmatic accretion culminating in deep‐crustal UHT metamorphism at 1.4 Ga (stage 1), fast uplift of the UHT granulites into mid‐crustal levels as a consequence of extensional tectonics (stage 2), emplacement of felsic magmas in the Grenvillian (at c. 1 Ga, stage 3) resulting in reheating of the crust to high–T conditions followed by a phase of compressional tectonics (stage 4) and a period of cooling to the stable geotherm (stage 5) still in the Grenvillian.  相似文献   

17.
The Fuping Complex and the adjoining Wutai and Hengshan Complexes are located in the central zone of the North China craton. The dominant rock types in the Fuping Complex are high‐grade tonalitic–trondhjemitic–granodioritic (TTG) gneisses, with minor amounts of mafic granulites, syntectonic granitic rocks and supracrustal rocks. The petrological evidence from the mafic granulites indicates three stages of metamorphic evolution. The M1 stage is represented by garnet porphyroblasts and matrix plagioclase, quartz, orthopyroxene, clinopyroxene and hornblende. Orthopyroxene+plagioclase symplectites and clinopyroxene+plagioclase±orthopyroxene coronas formed in response to decompression during M2 following the peak metamorphism at M1. Hornblende+plagioclase symplectites formed as a result of further isobaric cooling and retrograde metamorphism during M3. The P–T estimates using TWQ thermobarometry are: 900–950 °C and 8.0–8.5 kbar for the peak assemblage (M1), based on the core compositions of garnet, matrix pyroxene and plagioclase; 700–800 °C and 6.0–7.0 kbar for the pyroxene+plagioclase symplectites or coronas (M2); and 550–650 °C and 5.3–6.3 kbar for the hornblende+plagioclase symplectites (M3), based on garnet rim and corresponding symplectic mineral compositions. These P–T estimates define a clockwise P–T path involving near‐isothermal decompression for the Fuping Complex, similar to the P–T path estimated for the metapelitic gneisses. The inferred P–T path suggests that the Fuping Complex underwent initial crustal thickening, subsequent exhumation, and finally cooling and retrogression. This tectonothermal path is similar to P–T paths inferred for the Wutai and Hengshan Complexes and other tectonic units in the central zone of the North China craton, but different from anti‐clockwise P–T paths estimated for the basement rocks in the eastern and western zones of the craton. Based on lithological, structural, metamorphic and geochronological data, the eastern and western zones of the craton are considered to represent two different Archean to Paleoproterozoic continental blocks that amalgamated along the central zone at the end of Paleoproterozoic. The P–T paths of the Fuping Complex and other tectonic units in the central zone record the collision between the eastern and western zones that led to the final assembly of the North China craton at c. 1800 Ma.  相似文献   

18.
Meta‐anorthosite bodies are typical constituents of the Neoproterozoic Eastern Granulites in Tanzania. The mineral assemblage (and accessory components) is made up of clinopyroxene, garnet, amphibole; scapolite, epidote, biotite, rutile, titanite, ilmenite and quartz. Within the feldspar‐rich matrix (70–90% plagioclase), mafic domains with metamorphic corona textures were used for P–T calculations. Central parts of these textures constitute high‐Al clinopyroxene – which is a common magmatic mineral in anorthosites – and is therefore assumed to be a magmatic relict. The clinopyroxene rims have a diopsidic composition and are surrounded by a garnet corona. Locally the pyroxene is surrounded by amphibole and scapolite suggesting that a mixed CO2–H2O fluid was present during their formation. Thermobarometric calculations give the following conditions for the metamorphic peak of the individual meta‐anorthosite bodies: Mwega: 11–13 kbar, 850–900 °C; Pare Mountains: 12–14 kbar, 850–900 °C; Uluguru Mountains: 12–14 kbar, 850–900 °C. The P–T evolution of these bodies was modelled using pseudosections. The amount and composition of the metamorphic fluid and <0.5 mol.% fluid in the bulk composition is sufficient to produce fluid‐saturated assemblages at 10 kbar and 800 °C. Pseudosection analysis shows that the corona textures most likely formed under fluid undersaturated conditions or close to the boundary of fluid saturation. The stabilities of garnet and amphibole are dependent on the amount of fluid present during their formation. Mode isopleths of these minerals change their geometry drastically between fluid‐saturated and fluid‐undersaturated assemblages. The garnet coronae developed during isobaric cooling following the metamorphic peak. The cooling segment is followed by decompression as indicated by the growth of amphibole and plagioclase. The estimated of the metamorphic fluid is ～0.3–0.5. Although the meta‐anorthosites have different formation ages (Archean and Proterozoic) they experienced the same Pan‐African metamorphic overprint with a retrograde isobaric cooling path. Similar P–T evolutionary paths are known from the hosting granulites. The presented data are best explained by a tectonic model of hot fold nappes that brought the different aged anorthosites and surrounding rocks together in the deep crust followed by an isobaric cooling history.  相似文献   

19.
The partitioning of rare earth elements (REE) between zircon, garnet and silicate melt was determined using synthetic compositions designed to represent partial melts formed in the lower crust during anatexis. The experiments, performed using internally heated gas pressure vessels at 7 kbar and 900–1000 °C, represent equilibrium partitioning of the middle to heavy REE between zircon and garnet during high‐grade metamorphism in the mid to lower crust. The DREE (zircon/garnet) values show a clear partitioning signature close to unity from Gd to Lu. Because the light REE have low concentrations in both minerals, values are calculated from strain modelling of the middle to heavy REE experimental data; these results show that zircon is favoured over garnet by up to two orders of magnitude. The resulting general concave‐up shape to the partitioning pattern across the REE reflects the preferential incorporation of middle REE into garnet, with DGd (zircon/garnet) ranging from 0.7 to 1.1, DHo (zircon/garnet) from 0.4 to 0.7 and DLu (zircon/garnet) from 0.6 to 1.3. There is no significant temperature dependence in the zircon–garnet REE partitioning at 7 kbar and 900–1000 °C, suggesting that these values can be applied to the interpretation of zircon–garnet equilibrium and timing relationships in the ultrahigh‐T metamorphism of low‐Ca pelitic and aluminous granulites.  相似文献   

20.
Some granulites from the Amessmessa area (south In Ouzzal unit, Hoggar) contain the peak assemblage gedrite+garnet+sillimanite+quartz that was used to estimate the P–T conditions of metamorphism. The rocks developed symplectites and corona textures by the breakdown of the primary paragenesis to orthopyroxene, cordierite and spinel. The successive parageneses formed in separate microdomains according to a clockwise P–T path. Geothermometry, geobarometry and phase diagram calculations indicate that the textures formed by decompression and cooling from 7–9 kbar and 850–900°C to 3.5–4.5 kbar and 700–800°C. This P–T evolution is consistent with low to medium aH2O, between 0.4 and 0.7, and is similar to the metamorphic conditions deduced in Al–Mg granulites from the north of In Ouzzal.  相似文献   

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