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黄铁矿是金矿床中重要的载金矿物,对其成分标型进行深入研究可以获得大量矿床成因方面的信息。采用δFe δS、δFe/δS As、(Fe+S) As体系对胶东各类型金矿中的黄铁矿的主微量元素进行了详细研究,得出胶东石英脉型、蚀变岩型和层间滑脱带型金矿成矿期黄铁矿的主微量元素化学成分标型特征。结果表明石英脉型和蚀变岩型金矿成矿期黄铁矿的δFe δS、δFe/δS As、(Fe+S) As体系都具有明显分区特征,这反映了其成矿环境的差异。研究结果证实了该方法适用于胶东各亚类型金矿的研究,并对金矿床中黄铁矿化学成分标型的进一步研究及胶东金矿床的成因和找矿工作具有重要的借鉴意义。 相似文献
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本文讨论了河南小秦岭金矿田寻找金矿的矿物学标志问题,诸如石英、黄铁矿、黄铜矿、方铅矿等主要矿物的化学成分、物理性质、形态特征和晶体构造等方面之标型特征。这些标型特征有助于研究小秦岭金矿田中金矿床的岩浆热液成因。作者对金矿床的变质热液成因观点持反对态度。这些矿物标型特征提供了寻找金矿的指示信息。 相似文献
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四川松潘东北寨金矿黄铁矿标型特征研究 总被引：11，自引：0，他引：11
对东北寨金矿中黄铁矿形态、成分、晶胞参数、物理性质及红外谱学特征５个方面进行了详细研究，分析了黄铁矿的成因和找矿标型特征，认为东北寨金矿床属于浅成低温渗滤热卤水热液成因金矿，指出本区的黄铁矿标型特征是找寻东北寨式金矿的重要找矿标志。 相似文献
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1981—1986年,我们对玲珑金矿、夏甸金矿、栖霞金矿和三山岛金矿的黄铁矿晶体形态进行了野外和室内研究。其中,晶形统计2495粒,晶体测角300粒,用扫描电子显微镜对60粒晶体进行了微形貌研究。对四个金矿床的研究表明,黄铁矿晶体单形以立方体{100}最常见,出现频率为92.47%,其次为五角十二面体{hko}(其形号包括{210}、{310}、{410}、{810}、{830}、{910}及{11,1,0})出现频率为57.27%;其次为八面体{111},出现频率为16.88%,较少见的为偏方复十二面体{hkl}(其形号包括{321}、{421}、{10,6,5),{18,24,25)及{34, 相似文献
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玲珑金矿黄铁矿电阻率特征及含金性研究 总被引：1，自引：1，他引：0
黄铁矿是热液型金矿床中最主要的载金矿物之一,其物性特征在很大程度上指示了金的富集规律。采用BHMR-08型半导体矿粒调温电阻测试分析仪测量了胶东玲珑金矿的黄铁矿电阻率。结果表明,50~60℃测试条件下,所测黄铁矿电阻率值变化幅度最小,说明上述温度是测黄铁矿电阻率的合适温度范围。在此工作基础上,系统测量了玲珑金矿47号脉不同标高的14件黄铁矿样品的电阻率,结合该脉金的富集特点发现,黄铁矿电阻率为0.4~0.8Ωm时含金性最大。 相似文献
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内蒙古乌拉山金矿黄铁矿的标型特征 总被引：3，自引：0，他引：3
系统研究了乌拉山金矿黄铁矿的产状，晶体宏观形态，晶面微形貌，化学成分，热电性方面的标型特征，提出了一系列的重要找矿标志，为矿床的成因研究和深部远景评价提供了矿物学依据。 相似文献
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甘肃省阳山金矿田金的赋存状态和金矿物特征 总被引：1，自引：0，他引：1
甘肃阳山金矿田属于类卡林型金矿床,金矿化类型主要有蚀变千枚岩、蚀变斜长花岗斑岩、蚀变砂岩、蚀变灰岩四种。金多呈独立金矿物形式出现,少许呈分散状,矿石中金矿物以自然金为主,其次是银金矿。金矿物以包体金、裂隙金、粒间金等形式嵌布于毒砂、黄铁矿、辉锑矿、粘土矿物等主要载金矿物中,且毒砂、黄铁矿、辉锑矿较其它金属硫化物中占优势。金矿物形态各样,粒度以微细粒为主。金矿物特征反映出本区金矿床的成矿物质主要来源于变质岩、岩浆岩和地幔,成矿作用与印支晚期中酸性侵入岩有关。这与地质地球化学研究所获得的矿床成因认识相一致。 相似文献
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对胶东西北部望儿山金矿床中的黄铁矿进行了系统的采样和热电系数、热电导型、晶胞参数、化学成分等特征的分析,在此基础上探讨了黄铁矿的找矿意义。研究表明,望儿山金矿床中的黄铁矿化学成分亏S,特征元素为Au、Ag、Cu、Pb、Zn、As、Co、Ni、Se;黄铁矿热电导型P型的出现率为29.4%,热电性各项参数的变化在时间和空间上都与矿石金品位有明显的相关性;黄铁矿热电系数-温度标尺显示成矿温度集中在130.3~339.8℃之间;黄铁矿晶胞参数a0、v0值及X射线衍射峰半高宽都偏低,具有深部黄铁矿特征。黄铁矿δFe-δS图和晶胞参数a0图均显示望儿山金矿床为中低温热液成因,矿体的剥蚀程度较深,向下可能转化为蚀变岩型。 相似文献
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本文在系统总结归纳不同研究者对锆石形态标型特征的研究成果基础上，重点从晶体生长、晶体化学和地球化学理论为重点探讨了锆石形态标型特征的生长机制。研究表明：锆石晶体结构中不同的面网方向，其平面内的原子组成、比例、化学键联结和键力以及面网间距和密度都是有差别的，由此决定了锆石晶体在不同的结晶介质条件下，不同面网的生长速度发生改变，生成相应的晶形。例如，尽管碱性元素并不进入锆石晶格，但它们可以影响Ｚｒ、Ｓｉ、Ｏ离子的扩散速度，但是富钾和富钠的介质对锆石晶形发育的影响是有差别的，表现为：在富钾的介质中，将导致柱面的法向生长速度较锥面快得多，而锥面中，｛１１１｝的法向生长又较｛３１１｝快，由此决定了形成以｛３１１｝锥为主的双锥状晶体；在富钠的介质中，柱面和锥面都有一定程度的发育，但前者弱于后者，而柱面中，｛１００｝的法向生长较｛１１０｝慢，由此决定了形成以｛１００｝柱和｛１１１｝锥为主的短柱锥状晶体。根据类似方法，论证了其它形态标型特征的客观性，从而揭示了标型之间的内在联系和本质，展示了花岗岩研究中锆石形态标型特征应用推广的前景，也可为单颗粒锆石定年研究提供更多的分析应用价值 相似文献
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The morphological theory of Hartman and Perdok (1955, 1956) allows to deduce the character of a growth form {hkl} on the basis of structural data alone. Its application to the structure of whewellite leads to the identification of forms {100}, {010}, {021}, {011}, {12 \(\bar 1\) } and {121} which show during the growth a flat surface profile (flat forms F). These forms occur very frequently in the crystals we grew from pure aqueous solutions at supersaturation β≦1,90. Other forms, {001} and {10 \(\bar 1\) }, possibly show a double character (F or S, where S stays for related faces showing a stepped profile during the growth) according to the bonds assumed within some periodic bond chains (PBCs). Alternative ways of bonding water molecules lead to different structures of the same PBC. The different energy corresponding to these structures may explain the complex morphology of both natural and synthetic crystals grown at high β values. 相似文献
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Concepcion Jimenez-Lopez Jose M Dominguez-Vera 《Geochimica et cosmochimica acta》2003,67(9):1667-1676
Several mechanisms have been proposed to explain the interactions between proteins and mineral surfaces, among them a combination of electrostatic, stereochemical interactions and molecular recognition between the protein and the crystal surface. To identify the mechanisms of interaction in the lysozyme-calcium carbonate model system, the effect of this protein on the precipitation kinetics and morphology of calcite crystals was examined. The solution chemistry and morphology of the solid were monitored over time in a set of time-series free-drift experiments in which CaCO3 was precipitated from solution in a closed system at 25°C and 1 atm total pressure, in the presence and absence of lysozyme. The precipitation of calcite was preceded by the precipitation of a metastable phase that later dissolved and gave rise to calcite as the sole phase. With increasing lysozyme concentration, the nucleation of both the metastable phase and calcite occurred at lower Ωcalcite, indicating that lysozyme favored the nucleation of both phases. Calcite growth rate was not affected by the presence of lysozyme, at least at protein concentrations ranging from 0 mg/mL to 10 mg/mL.Lysozyme modified the habit of calcite crystals. The degree of habit modification changed with protein concentration. At lower concentrations of lysozyme, the typical rhombohedral habit of calcite crystals was modified by the expression of {110} faces, which resulted from the preferential adsorption of protein on these faces. With increasing lysozyme concentration, the growth of {110}, {100}, and finally {001} faces was sequentially inhibited. This adsorption sequence may be explained by an electrostatic interaction between lysozyme and calcite, in which the inhibition of the growth of {110}, {100}, and {001} faces could be explained by a combined effect of the density of carbonate groups in the calcite face and the specific orientation (perpendicular) of these carbonate groups with respect to the calcite surface. Overgrowth of calcite in the presence of lysozyme demonstrated that the protein favored and controlled the nucleation on the calcite substrate. Overgrowth crystals nucleated epitaxially in lines which run diagonal to rhombohedral {104} faces. 相似文献
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Gerhard Vavra 《Contributions to Mineralogy and Petrology》1994,117(4):331-344
The internal morphologies of zircon crystals from different types of granitoids (alkaline, calcalkaline and anatectic) are revealed by cathodoluminescence imaging and are described in terms of growth rates of the crystal faces relative to each other. Zircons in the alkaline granitoids are characterized by high and constant growth rates of {010} relative to the pyramidal forms and by symmetric grwoth of {011}. Zircons in the calcalkaline and anatectic granitoids are characterized by fluctuating or gradually decreasing relative growth rates of {010}, by asymmetric and highly variable growth of {011}, and by a tendency of {110} to become grwoth-inhibited. Corrosion events are interspersed during zircon growth in the calcalkaline magmas. In the calcalkaline and anatectic magmas, a discontinuity breaks the morphological evolution at late stages of crystallization. The discontinuity coincides with a sharp drop in cathodoluminescence. The growth behaviour of each crystal form is analysed and compared with predictions made by the periodic bond chain (PBC) theory. It is argued that the relative growth rate of {010} depends on supersaturation, that the growth rates of {011} faces are changed in response to different ratios of adsorbing cations (Na, K, Al), and that {110} faces become growth-inhibited by the adsorption of H2O or trace elements enriched in the residual liquid. Morphological and chemical discontinuities at late stages of crystallization are reasonably explained by the formation of larger growth units (from smaller ionic entities) in the residual liquid. Important factors controlling the zircon morphology in different types of granitoids are: high cooling rates (alkaline magmas), magma mixing (calcalkaline magmas), enrichment of H2O and trace elements in residual liquids (calcalkaline and anatectic magmas), and the major element chemistry of the magma, possibly the ratio of Na and K to Al (agpaicity). 相似文献
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香炉碗子金矿床产于韧性剪切带内,具有多期成矿的特点。矿床成因属浅成低温热液—蚀变岩型金矿床。黄铁矿形成于两个成矿阶段。早期黄铁矿含金量较少,其晶体形态主要为{hko}、{hko}+{100}。晚期黄铁矿以富含金为特征,主要为它形晶,呈细脉浸染状产出。黄铁矿的热电性特征可作为金矿的找矿标志。利用成矿阶段形成的黄铁矿所求出的产矿系数可以圈定矿体。其产矿系数<4010×10~(-2)者为工业矿体。 相似文献
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主要对黄铁矿及石英的某些标型特征进行研究，并推测成矿的有利部位，研究发现，本区成矿阶段的黄铁矿为ｎ＋ｐ混合型，ｐ型含量愈高，矿化愈好，金品位高值区与热电系数标志值５００～７００部位吻合，主成矿阶段出现（１００）＋（３２１）＋（２１０）＋（３２１）及（１００）＋（２１０）＋（１１１）黄铁矿聚形，石英热发光强度大（大于０．５Ｒ）发光曲线峰多（双峰），总积分强度大于４．３Ｒ是本区主成矿阶段的一个标志。 相似文献