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1.
The Upper Proterozoic volcanism of northwestern Africa is characterized by the predominance of calc-alkaline rocks. Volcanics with tholeiitic affinities and alkali basalts are rare. The geochemistry and the relative proportions of calc-alkaline rocktypes in the Silet zone (Algeria) and the Ouarzazate formation (Morocco) are similar to those of recent island arc suites where basalts are most abundant while in the Tassendjanet and Gara Akofo zones (Algeria) they resemble contintal margin volcanic suites with a predominance of andesites. The volcanic rocks have undergone low-grade metamorphism which strongly affected alkali and alkali-earth elements and also to a smaller degree, the less mobile elements such as REE, Zr, Hf, Nb, and P. The geochemistry of the calc-alkaline rocks point to a complex origin involving low-pressure fractional crystallization, crustal contamination and derivation from a source already enriched in LILE. 相似文献
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内蒙古西乌旗晚石炭世–早二叠世伸展事件——来自大石寨组火山岩的证据 总被引：2，自引：0，他引：2
内蒙古西乌旗地区发育一套中酸性火山岩,空间展布特征显示其为大石寨组火山岩的西延部分。为查明该火山岩的形成时代及构造属性,对其进行了岩石学、年代学和岩石地球化学研究。研究结果表明该火山岩主要由安山岩及流纹岩组成。锆石LA-MC-ICP-MS U-Pb定年结果显示其喷发时代为275~311 Ma,属晚石炭世–早二叠世。岩石地球化学特征表明中性岩富钙贫镁,富集LREE及K、Rb、Ba,亏损Nb、Ta,具有弱Eu异常,安山质岩浆可能是由基性岩浆分离结晶形成的,但在形成过程中受到了陆壳物质混染。酸性岩贫钙镁,富硅碱,具有显著的Eu负异常,亏损Nb、Ta、Sr、P、Ti,反映岩石成因与中下地壳的熔融及其后期的分离作用有关。在构造判别图解中,中性岩具有板内玄武岩特征,而酸性岩具有A2型花岗岩特征。结合区域已发表资料推断,西乌旗大石寨组火山岩形成于造山后伸展环境,暗示古亚洲洋至少在早二叠世之前已经闭合。 相似文献
3.
白银厂矿田早中寒武世火山岩地球化学及成因分析 总被引：16，自引：3，他引：13
白银厂矿田早中寒武世火山岩主要为玄武岩－碱性玄武岩－安山岩－玄武安山岩－玄武粗安岩－英安流纹岩－流纹岩。其中基性和中基性岩类为碱性系列和亚碱性系列,碱性玄武岩主要为钾质玄武岩系列。酸性岩类为钙碱性系列。岩石全碱含量平均为５．７６％,Ｋ２Ｏ／,Ｋ２Ｏ／Ｎａ２〈１,Ｆｅ２Ｏ／ＦｅＯ平殚为０．７４;ＴｉＯ２绝大部分样品含量小于１％（在酸性火山岩中含量较低：０．２％～０．８３％,平均为０．５３％;基性和中 相似文献
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5.
Mahnaz Khodami Moussa Noghreyan Ali Reza Davoudian 《Arabian Journal of Geosciences》2010,3(3):257-266
Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO2 contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts. 相似文献
6.
东昆仑西段夏日哈木地区出露一套鄂拉山组火山岩,其成因对古特提斯洋演化过程具有重要的指示意义。通过对其进行锆石U-Pb年代学、Hf同位素和全岩主、微量元素、Sm-Nd同位素等研究确定其形成时代、岩石成因及其构造意义。安山岩中锆石的^(206)Pb/^(238)U加权平均年龄为223±2Ma,属于晚三叠世。岩石具有较低的SiO_(2)(59.45%~63.10%)和Mg^(#)值(28~51)、较高的Al_(2)O_(3)(16.19%~17.66%)和K_(2)O含量(1.42%~3.50%),表现为弱过铝高钾钙碱性系列。岩石具有富集轻稀土和大离子亲石元素,亏损高场强元素的特征,结合全岩ε_(Nd)(t)值(-4.3~-3.1)和锆石ε_(Hf)(t)值(-3.4~+1.1),表明其可能来源于受富集地幔熔体底侵的古老下地壳部分熔融。结合区域地质资料,认为这些安山岩形成于碰撞后伸展环境,而古特提斯洋在晚三叠世已关闭。本文研究结果也说明在造山带研究中需谨慎利用火成岩的岛弧性质来判断其俯冲环境这一构造属性。 相似文献
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尽管龙木错—双湖结合带经历早古生代—三叠纪的长期演化过程,但已有资料显示羌塘中部沿该带的岩浆活动主要与碰撞作用有关,仍缺乏与俯冲相关火成岩的报道。报道龙木错—双湖结合带西段日湾茶卡东的一套那底岗日组火山岩中安山岩的年龄、岩石及地球化学特征,利用LA-ICP-MS方法测得安山岩锆石U-Pb年龄为330.6±2.8Ma,表明火山活动的时间为早石炭世。该套岩石因遭受硅质流体交代,SiO2含量变化较大（54.84%~72.84%）,在Nb/Y-Zr/TiO2×0.00001图解中全部落入安山岩区,属于低—中钾钙碱性系列;微量元素蛛网图明显富集Rb、Th、U等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,具火山岛弧特征。日湾茶卡安山岩是在羌塘中部发现的早石炭世岛弧型火山岩,为龙木错—双湖古特提斯洋盆晚古生代俯冲作用提供直接的年代学和岩石学证据。 相似文献
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The Bandas belt, one of two prominent Archaean greenstone belts in the Central African Republic (Equatorial Africa), is ca. 250 km long. At the southernmost part of the belt, a metasedimentary—metavolcanic rock suite is preserved only in brachysynclines. The suite can be divided into two lithostratigraphic units. The lower unit is composed predominantly of volcanic rocks, while the upper one contains mainly metasedimentary rocks. The volcanic rocks, which are part of a sequence ca. 3600 m thick, can be sub-divided according to stratigraphic position, lithology and geochemistry into three groups. The lowermost group includes low-K tholeiitic basalts depleted in light REE. The second group consists of tholeiitic basalts with light REE-enriched patterns and the third, uppermost, group includes andesites, which are similar in several respects to Recent calc-alkaline andesites.The tholeiitic basalts of the first two groups are probably related to different upper mantle sources. The andesites of the third group were produced either by fractional crystallization from a basaltic magma enriched in light REE or equilibrium melting of eclogite or garnet amphibolite. 相似文献
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Abstract. This study presents the petrographical, mineralogical, and geochemical characteristics of Late Pliocene‐Pleistocene volcanic rocks distributed in the Hishikari gold mining area of southern Kyushu, Japan, and discusses their origin and evolution. The Hishikari volcanic rocks (HVR), on the basis of age and chemical compositions, are divided into the Kurosonsan (2.4–1.0 Ma) and Shishimano (1.7–0.5 Ma) Groups, which occur in the northern and southern part of the area, respectively. Each group is composed of three andesites and one rhyodacite. HVR are characterized by high concentrations of incompatible elements compared with other volcanic rocks in southern Kyushu, and have low Sr/Nd and high Th/U, Th/Pb, and U/Pb ratios compared with typical subduction‐related arc volcanic rocks. Modal and whole‐rock compositions of the HVR change systematically with the age of the rocks. Mafic mineral and augite/hypersthene ratios of the andesites decrease with decreasing age in the Kurosonsan Group, whereas in the Shishimano Group, these ratios are higher in the youngest andesite. Similarly, major and trace element compositions of the younger andesites in the former group are enriched in felsic components, whereas in the latter group the youngest andesite is more mafic than older andesites. Moreover, the crystallization temperature of phenocryst minerals decreases with younger age in the former group, whereas the opposite trend is seen in the latter group. Another significant feature is that rhyodacite in the Shishimano Group is enriched in felsic minerals and incompatible elements, and exhibits higher crystallization temperatures of phenocryst minerals than the rhyodacite of the Kurosonsan Group. Geochemical attributes of the HVR and other volcanic rocks in southern Kyushu indicate that a lower subcontinental crust, characterized by so‐called EMI‐type Sr‐Nd and DUPAL anomaly‐like Pb isotopic compositions, is distributed beneath the upper to middle crust of the Shimanto Supergroup. The HVR would be more enriched in felsic materials derived from the lower crust by high‐alumina basaltic magma from the mantle than volcanic rocks in other areas of southern Kyushu. The Kurosonsan Group advanced the degree of the lower crust contribution with decreasing age from 51 %, through 61 and 66 % to 77 %. In the Shishimano Group, the younger rhyodacite and andesite are derived from hotter magmas with smaller amounts of lower crust component (58 and 57 %) than the older two andesites (65 % and 68 %). We suggest that the Shishimano rhyodacite, which is considered to be responsible for gold mineralization, was formed by large degree of fractional crystallization of hot basaltic andesite magma with less lower crustal component. 相似文献
10.
The western terranes exposed east of the Pan-African suture in western Hoggar (southwest Algeria), are reexamined in the light of new structural, petrologic and by the 40Ar/39Ar laser probe data on metamorphic micas and amphiboles. To the north, the Tassendjanet nappe includes the Paleoproterozoic basement, its Mesoproterozoic cover and mafic rocks representing the roots of a ca. 680 Ma arc overlain by Late Neoproterozoic andesites and volcanic greywackes. The nappe preserved at rather shallow crustal level in the east was emplaced southward (D1a) to southeastward (D2). In the south, two metamorphic suites are distinguished. The Tideridjaouine–Tileouine high-pressure metamorphic belt (T=550–600 °C, P=1.4–1.8 GPa) represents a slab of subducted continental material exposed along the western edge of the In Ouzzal granulite unit interpreted as a microcontinent. Differential exhumation of tectonic slices from the high-pressure belt occurred around 615–600 Ma through a system of west-directed recumbent folds (D1b). The Egatalis high grade belt in the west was intruded by syn-metamorphic gabbro–norite bodies. It includes unretrogressed low-pressure granulite facies rocks (T around 750–800 °C, P0.45 GPa) cooled at a rate of 15°/m.y. between 600 and 580 Ma, and followed by the emplacement of several late-kinematic granitic plutons. Final exhumation of the low-pressure, high-temperature metamorphic rocks, that are not found as pebbles in the molasse, took place in the Late Cambrian. The early and relatively fast cooling of the high-pressure and high-temperature metamorphic rocks of the southern part of the Tassendjanet terrane is at variance with the slow cooling of central Hoggar where repeated magmatic activity as young as Late Cambrian occurred [Lithos 45 (1998) 245]. 相似文献
11.
汝城地区晚中生代火山岩地球化学特征及其对源区属性的指示 总被引：4，自引：0，他引：4
湘东南汝城地区发育一套由基性玄武岩和中酸性安山质-英安质岩石组成的火山岩建造,属于低钾拉斑系列,该火山岩系中两个玄武岩的K-Ar年龄分别为124.5±2.5Ma和127.6±1.9Ma,属晚侏罗—早白垩世产物。在主、微量元素上两者成分存在明显差异。其中安山质-英安质岩石具有高MgO特征,属高MgO岩石,LILE富集、Nb-Ta、Sr-P亏损强烈,(La/Yb)N=6.7～7.9,Eu*/Eu=0.74～0.85,具岛弧型微量元素配分型式,87Sr/86Sr(t)=0.71079～0.71118,εNd(t)=-7.64～-8.16,与adakites高Mg岩石有着明显的差别,可能是富集岩石圈地幔熔融后直接分异的产物;玄武岩LILE富集,Nb-Ta富集,(La/Yb)cn=4.0～4.3,Eu*/Eu=1.00～1.16,具OIB型微量元素配分型式,87Sr/86Sr(t)=0.70812～0.70832,εNd(t)=0.48～1.03,其源区具二元混合趋势,其源区可能是富集型岩石圈地幔端员与亏损的软流圈地幔端员的混合产物。汝城地区晚中生代玄武岩和高Mg安山质-英安质岩石源区属性的限定及其相互的空间依存关系表明该区晚中生代时有着较薄的岩石圈厚度,处于岩石圈伸展减薄的大地构造背景。 相似文献
12.
Mineralization of pegmatites in parts of the Oban Massif, Southeastern Nigeria： A preliminary analysis 总被引：1，自引：0，他引：1
The Oban Basement Massif of southeastern Nigeria is composed of metamorphosed rocks including phyllites, schists, gneisses and amphibolites cut by pegmatitic dykes of varying length and thickness, which intruded the metamorphic rocks. Preliminary geochemical study and analysis of these pegmatites from western Oban Massif at Uyanga, Akwa Ibami, Iwuru I, Iwuru Ⅱ and Igbofia showed that the pegmatites are highly albitized. This is incon-sistent with earlier postulations that the pegmatites in this part of Nige... 相似文献
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Arfvedsonite granites are most prevalent in the northern sector of the Nigerian anorogenic ring-complex province wherein they form the main granitic rocks at Kudaru and Fagam and are important components of Kila-Warji, Ririwai and Dutsen-Wai ring-complexes. The albitized variety of these rocks hosts pyrochlore to varying extents depending on the degree of albitization and are, therefore, important targets for niobium investigation. Geochemical data of the granites reveal that niobium has a mean concentration of 111 ppm in the arfvedsonite granite, increasing to 168 ppm in the aegirine arfvedsonite granite and reaching 1568 ppm in the albite arfvedsonite granite. Niobium is thus enriched in the albite arfvedsonite granite by a factor of 8-11 relative to its mean value in the aegirine arfvedsonite and arfvedsonite granites, respectively. Uranium contents show a sympathetic trend with niobium, being also enriched in the albite arfvedsonite granite relative to its abundance in both the aegirine arfvedsonite granite and arfvedsonite granite by a factor of 15. The uranium abundance in the albite arfvedsonite granite is more than 48 times higher than the mean background values in low-calcium granite.The REE fractionation patterns in all three arfvedsonite granite varieties are characterized by enrichment of both the light (La-Sm) and heavy (Gd-Lu) rare earth elements and a significant negative Eu anomaly. The albite arfvedsonite granite is, however, preferentially more enriched in the heavy REE relative to the aegirine arfvedsonite and the arfvedsonite granites. A plot of the ∑REE against Na2O and niobium reveals positive correlation in the arfvedsonite granites. There is also a linear relationship and strongly positive correlation between Nb and Na2O because the pyrochlore is most abundant in the most extensively albitized variety of the arfvedsonite granites. 相似文献
14.
南盘江盆地南缘发育大量早—中三叠世岩浆岩和巨厚三叠系,为研究沿中越边界一带是否发生洋盆俯冲消亡过程提供了重要的岩浆-沉积证据。选取中越边界地区出露面积最大的富宁—那坡地区早—中三叠世火山岩及相关沉积作为研究对象,通过系统的地质填图和剖面测量,查明这套火山-沉积组合具有下部玄武安山岩,上覆碳酸盐岩质砾岩、含砾粗砂岩和钙质砂岩的沉积序列,与岛弧环境火山-沉积序列相似。玄武安山岩SHRIMP锆石U-Pb定年结果为247±1 Ma和246±3 Ma,与野外产于中三叠统碎屑岩之下的地质事实相符。结合前人研究成果,确定这套火山岩形成于早—中三叠世(247~242 M a)。全岩地球化学分析结果显示,玄武安山岩富集大离子亲石元素(LILEs,R b、T h和U)和轻稀土元素(LR EE),其具有明显的Nb、Ta和Ti负异常。火山-沉积序列和火山岩地球化学特征表明,富宁—那坡地区早—中三叠世火山-沉积组合形成于与俯冲相关的弧环境。中越边界地区早—中三叠世弧火山岩与蛇绿混杂岩带的时空展布特征表明,该地区晚古生代洋盆发生了向北的俯冲消减。 相似文献
15.
新疆新源县城南石炭纪火山岩岩石学和元素地球化学研究 总被引：14，自引：0，他引：14
新疆新源县南部那拉提山北坡出露的石炭纪火山岩主要由玄武岩、玄武质粗面安山岩、粗面安山岩、安山岩、流纹岩和火山碎屑岩组成。该火山岩中玄武岩属于钙碱性系列，安山质岩石和流纹岩属于高钾钙碱性系列，其中轻稀土轻微富集而重稀土相对亏损，玄武岩富集大离子亲石元素、U、Th和Pb，亏损高场强元素。研究表明，该火山岩岩浆可能是由俯冲板片脱水产生的流体交代地幔楔后，地幔楔发生部分熔融的结果。微量元素模拟计算表明，该玄武岩岩浆可以由石榴石二辉橄榄岩经3％～6％的部分熔融得到；安山质岩浆可由玄武岩岩浆经15％-28％的分离结晶形成。 相似文献
16.
对松辽盆地南部早白垩世火石岭组和营城组火山岩进行的岩石地球化学研究表明,火石岭组火山岩主要以玄武质粗面安山岩和粗安岩为主,存在少量粗面英安岩,其Si O2=53.8%~68.6wt%、K2O+Na2O=7.70%~9.59%、Mg#=26.72~33.89,以富集轻稀土和大离子亲石元素(LILEs,如Rb、Ba、Th、U等),亏损重稀土和高场强元素(HFSEs,如Nb、Ta、Ti、P等)为特征,这些特征与俯冲带火山岩类似。营城组火山岩以流纹岩为主,存在少量的玄武质粗面安山岩、粗面安山岩和英安岩,基性端元具有低硅(Si O2=49.3%~56.6%)、低碱(K2O+Na2O=4.57%~6.60%)、富镁(Mg#=33.49~59.51)的特征,主要属于钙碱性系列,暗示其原始岩浆主要来源于地幔;酸性端元的Si O2=65.4%~74.9%,K2O+Na2O=3.23%~7.75%,低镁(Mg#=21.76~39.18)。营城组火山岩稀土配分型式呈右倾型,富集轻稀土和大离子亲石元素,亏损重稀土和高场强元素,与俯冲环境火山岩相似。其中,营城组流纹岩地球化学特征类似A型花岗岩,暗示形成于伸展环境。结合区域研究成果,认为松辽盆地南部早白垩世火山岩的形成与古太平洋板块向欧亚大陆之下的俯冲作用有关。火石岭组火山岩形成于活动大陆边缘环境,营城组火山岩的形成与岩石圈拆沉作用引发的伸展背景有关。 相似文献
17.
In the calc-alkaline rocks of Peru, the rubidium content and the K/Ba, Rb/Sr ratios increase, while the strontium content and the K/Rb, Ba/Rb ratios decrease according to the distance of the trench. It is suggested that theses variations are related to a fractionation of plagioclase and contamination with differential migration of mobile elements. A comparative study between andesites of various localities shows in Peru an enrichment in Rb, Sr and Ba and a disparition of the Rb-Ba correlation; this last observation looks characteristic of continental margin andesites. The shoshonitic rocks differ from the andesites by a high content of Sr and Ba. The genetic relationships between these two kinds of rocks are discussed. It appears that the shoshonites are originated from a different magmatic source. 相似文献
18.
Major and trace element data on the Archean metavolcanic rocks of the Prince Albert Group (PAG), Northwest Territories. Canada, are reported. The following major groups were found, based on combined field and geochemical evidence: ultramafic flows; basaltic rocks, predominantly tholeiites; andesites; heavy REE depleted dacites; and rhyolites.The ultramafic and basaltic rocks are relatively normal Archean volcanics except for the downward bowed REE patterns of the tholeiitic basalts. The andesites, dacites and rhyolites, however, are not typical of Archean terrains. Comparisons between the andesites of the PAG and other Archean and more recent ones show that those of the PAG are most similar chemically to modern high-K andesites. REE patterns in these rocks suggest that partial melting of assemblages with significant garnet are an unlikely source but it is not possible to ascribe their origin to any simple process. Partial melting of a garnet-poor mafic granulite is an acceptable source for the heavy REE depleted dacites. The geochemical characteristics of the rhyolites cannot be explained by partial melting of a mafic source or by fractional crystallization from the daeites. It is suggested that these rocks originated by partial melting of pre-existing sialic crust. 相似文献
19.
L.J.G. Schermerhorn 《Lithos》1973,6(1):1-11
The rock names keratophyre and quartz keratophyre are beset by confusion and ambiguity. This is due in part to the notion that these sodic rock types originated by albitization of potassic rocks (trachyte and rhyolite) and in part to the existence of two varieties of quartz keratophyre, one with and one without quartz phenocrysts. Though both types of quartz keratophyre are felsic rocks, they are often confused with keratophyre, an intermediate rock. Generally, keratophyre is not albitized trachyte but the sodic-plagioclase counterpart of trachyte. Similarly, quartz keratophyre is not albitized rhyolite but its sodic-plagioclase complement. Keratophyre is less common than quartz keratophyre and the spilite-keratophyre suite is more often a spilite-quartz keratophyre association. Keratophyre and the two types of quartz keratophyre are leucocratic sodic albite-phyric volcanics, the former intermediate and the latter felsic. 相似文献
20.
华北陆块南部元古宙熊耳群火山岩的成因与构造环境：事实与争议 总被引：31，自引：0，他引：31
位于华北陆块南部的熊耳群形成于古元古代1.80~1.75 Ga,以火山熔岩占绝对优势,沉积岩和火山碎屑岩仅占地层总厚度的4.3%。熊耳群火山岩是华北陆块结晶基底形成后规模最大、涉及范围最广的火山活动产物,基岩出露面积约7 000 km2,地层厚度3 000~7 000 m,以玄武安山岩、安山岩为主,次为英安-流纹岩,SiO2=60%±的岩石较少,显示双峰特点。中基性熔岩的主要造岩矿物是斜长石和辉石,几乎没有角闪石和黑云母。其岩石化学成分的突出特点是高Fe,K,而低Al,Ca和Mg,火山岩显示富集大离子亲石元素和轻稀土元素、相对亏损高场强元素的岛弧型地球化学特征。Nd同位素和微量元素特征表明,这种地球化学特征是地幔源区遭受地壳组分改造及少量岩浆上升过程中的地壳混染造成的。熊耳群中的沉积岩主要分布在大古石组及马家河组。沉积岩的岩石学和地球化学特征表明熊耳群形成于被动大陆边缘的构造环境,结合火山岩的结构、构造特征,表明火山喷发的主体环境是海相,经历了陆相到海相再到陆相的演变过程,即：伴随着裂谷的发育、地面沉降和海水的侵入,以及随着火山喷发的进行最后又高出海面暴露于地表的全过程。熊耳群形成后,海侵范围更广、海水逐渐加深,表明地壳逐步向更大的凹陷发展。熊耳群形成于夭折的三叉裂谷环境,其火山岩所具有的岛弧型火山岩的地球化学特征是继承于受俯冲组分改造的陆下岩石圈富集地幔源区。熊耳期岩浆活动在华北陆块广泛分布,除了陕西宝鸡附近及山西吕梁地区的火山岩,还广泛分布1.75 Ga前后的基性岩墙群、A-型花岗岩以及比熊耳群稍晚的斜长岩、奥长环斑花岗岩等（1.75-1.70 Ga）和碱性花岗岩类（~1.65 Ga）。这些岩浆岩和熊耳群火山岩在源区性质、岩石
成因及其形成的构造背景等方面,可能存在必然的联系。上述岩浆岩的发育,说明华北陆块在1.80 Ga后处于地壳拉伸、减薄,很可能沿早先拼合的薄弱部位最先发生破裂,是华北陆块裂解的产物。 相似文献