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1.
The Campanian-Maastrichtian Agbaja Ironstone Formation of the Nupe basin, Nigeria, forms a major part of the about 2 billion
tons of iron ore reserves of the Middle Niger Embayment. The ironstone deposits were previously reported to be similar to
the Minette-type ironstones because of their depositional patterns, composition and inferred origin. Four rock-types are recognized
within the Agbaja Ironstone Formation: ooidal pack-ironstone, pisoidal pack-ironstone, mud-ironstone and bog iron ore. In
the ironstones, kaolinite of both the groundmass and the ooids/pisoids is of lateritic origin, whereas the associated quartz,
mica and heavy minerals are of detrital origin. Ooids and pisoids were formed by mechanical accretion of platy kaolinite crystals
by rolling on the sea floor in a near-shore environment, and were subsequently transported and deposited together with a fine-grained
kaolinitic groundmass. Pyrite (mainly framboidal) and siderite (both exclusively occurring as pseudomorphs of goethite and/or
hematite) are diagenetic whereas goethite is post-diagenetic in origin, resulting from the ferruginization of the kaolinitic
precursor. Crandallite-gorxeicite-goyazite, bolivarite and boehmite are also post-diagenetic in origin. Hematite was formed
from the dehydration of goethite, whereas gibbsite (restricted to the upper part of the deposit) is of recent and in situ lateritic origin. The presence of newly formed authigenic pyrite and siderite (now replaced by hematite and goethite) are
indicators of a reducing environment during diagenesis. The absence of diagenetic chamositic clay minerals, evidently caused
by a low Mg concentration, suggests that fully marine conditions were not established during sedimentation. This is supported
by the lack of fossils, brecciated shell materials and bioturbation features in the deposit. Reworking and redeposition of
the primary constituents are inferred from broken pisoids, nuclei of pisoidal/ooidal fragments in pisoids and high iron concentrations
present in the pisoids and ooids compared to that of the groundmass. These observations indicate that the Agbaja ironstone
deposits of the Lokoja study area exhibit some environmental and mineralogical characteristics that are markedly different
from other known deposits of Minette-type, where primary chamositic clay minerals generally form the protore for the ironstones.
The recognition of kaolinite as the precursor constituent and the occurrence of similar deposits of the same age (Late Cretaceous)
in Nigeria, Sudan and Egypt have implications for the paleoenvironmental interpretations of Phanerozoic ironstone deposits.
Received: 16 February 1998 / Accepted: 8 July 1998 相似文献
2.
R. J. Taj 《Arabian Journal of Geosciences》2013,6(4):1011-1031
The studied carbonates are present within the middle part of the Tertiary siliciclastic dominated succession in Haddat Ash Sham area. This succession consists of conglomerates, sandstones, siltstones, mudstones, and ironstones arranged in upward coarsening and fining cycles of intermittent depositional environments ranging from fluvial coastal plain to shallow marine. The carbonates represent deposition in slightly restricted depositional environments during periods of very low clastic input. The studied two carbonate sections show a pronounced lateral and vertical changes from predominantly dolostones in the west to mixed dolostones and limestones in the east. Both sections began by egg yellow dolomitic lime mudstones and fine crystalline dolomite which indicate the formation of dolomite by late depositional to early diagenetic recrystallization of precursor Fe and Mg lime mud. During this time period, the western part of the study area continues in the deposition of Fe and Mg lime mud in slightly restricted depositional environments and formation of interbedded fine and coarse crystalline dolostones in coarsening-upward cycles. In the eastern part, the depositional environments become deeper and more circulated with short-lived periods of fluctuation in sea level and hence the deposition of foraminiferal wackestone, bioclastic packstones, and bioclastic rudstone in coarsening and shallowing-upward cycles. Both the western and eastern parts of the study area are terminated by characteristic yellow coarse crystalline phosphatic dolomite which indicate ultimate stages of shoaling and increasing the level and concentration of phosphorous in the restricted water and hence the formation of in situ and reworked phosphatic components. The diagenetic processes affected the dolostones and limestones microfacies associations include: dolomitization of Fe and Mg-rich lime mud, hematitization, calcitization, gypsification, and phosphatization of dolomite. Neophormation and recrystallization of micritic matrix and micritic intraclasts as well as shell fragments are the main diagenetic processes affected the limestones. 相似文献
3.
Glauconitic minerals constitute a family ranging from green smectite to a 10Ådioctahedral mica (glauconite). Chamositic minerals include a 7Åtrioctahedral serpentine (berthierine) and a 14Åtrioctahedral chlorite (chamosite). These green iron-rich, neoformed or transformed clay minerals are most commonly concentrated in sand-size granules.Recent berthierine and Recent and ancient glauconitic minerals occur mainly in structureless peloids, most of which are believed to have been fecal pellets. In contrast, most of the ancient chamositic minerals are in multi-coated ooids generally assumed to have been made by gentle rolling on the sea floor.Glauconitic and chamositic granules accumulated most commonly in marine shelf environments during episodes of reduced influx of sediment. In modern deposits chamositic peloids predominate on the inner shelf, whereas glauconitic peloids are most abundant on the middle and outer shelf. In general, ancient glauconitic and chamositic deposits had a rather similar environmental distribution; in detail, however, they reflect more varied and overlapping marine habitats.Glauconitic greensands and chamositic ironstones commonly occur above a coarsening- or shoaling-upward facies sequence. Many of them are cross-bedded and burrowed, and some are interbedded with a ferruginized or phosphatized hardground. Although differing in detail, their temporal distributions throughout Phanerozoic time were rather similar. Both attained a maximum when cratonic blocks were widely dispersed and sea level was high in Early Paleozoic and Late Mesozoic time. In addition, recurring development of chamositic ooids commonly coincided with repeated regional transgressions.This review of current information and differing interpretations leads to significant questions that are essential subjects for future research. Moreover, some of these relate to unsolved problems of phosphorite genesis. 相似文献
4.
Peter Turner 《Sedimentary Geology》1974,12(3):215-235
The Ringerike Group is a meandering fluviatile succession which is about 60% red. Most of the red zones are formed of mudrocks and siltstones and correspond to the fine members of fining-upwards cyclothems. The majority of coarse members are drab coloured.Textural studies of thin and polished sections show that the red colour is caused by finely crystalline hematite as matrix and grain-coatings. This hematite apparently crystallized post-depositionally. Hematite also occurs in other textural sites: within altered phyllosilicates, as detrital grains and as totally pseudomorphed phyllosilicates. This, and the lack of consistency between colour and clay mineralogy, suggests that the red beds have had a long and complex diagenetic history.Iron analyses indicate that the red beds are enriched in Fe3+ and total iron (FeO) by about 1%. This is thought to have been derived from the pre-depositional weathering of iron minerals and introduced into the sediments as amorphous iron hydroxide or iron-bearing clays. Crystallization of iron hydroxide under oxidizing conditions and the post-depositional alteration of iron-silicates and oxides is thought to be responsible for the formation of the red beds. 相似文献
5.
RETO M. BURKHALTER 《Sedimentology》1995,42(1):57-74
Aalenian and lower Bajocian rocks in the central and northern Swiss Jura mountains comprise a series of parasequences that mainly reflect a shallowing-upward trend in a shallow, mixed carbonate/siliciclastic depositional environment. Within a parasequence, ooidal ironstones may occur at three specific types of horizons. These are: regressional discontinuities and transgressional discontinuities formed by sediment bypassing, and omissional discontinuities formed by starvation. Ooidal ironstones, which principally are autochthonous, accumulated during both sea-level rises and falls in a relatively broad bathymetric and hydrodynamic spectrum. The key physical factor for ferruginous ooid genesis is non-deposition. Ferruginous ooids and microbialites consist of goethite, chamosite and mixtures thereof, with subordinate amounts of apatite and silica. Ferruginous ooids grew stepwise on the sediment surface in an oxygenated marine environment. Ferruginous microbialites, being the product of benthic microbial communities, grew ? partly in cavities ? in aerated moderate- to high-energy environments. Thus, chamosite evolved from a precursor substance stable under oxidizing conditions. The close mineralogical and micromorphological resemblance of ferruginous microbialites and ooids suggests a common biogenic origin. Structural rearrangement of a biologically accreted gel-like precursor substance consisting of various amorphous hydroxides is considered a probable mode of mineral genesis in both ferruginous ooids and microbialites. 相似文献
6.
Asma A. Ghaznavi Mohammad Masroor Alam Zuhi Khan A. H. M. Ahmad 《Arabian Journal of Geosciences》2018,11(14):387
The detrital mineralogy as well as diagenetic characters of the Dhosa Sandstone Member of Chari Formation exposed at the Lerdome, south of Bhuj was studied. In order to assess the potential of the Dhosa Sandstone as a reservoir, it is substantial to understand the diagenetic processes that are controlled largely by post-depositional cementation and compaction in addition to framework composition and original depositional textures. The petrologic analysis of 33 thin sections was carried out to discern primary composition and diagenetic features including primary and secondary porosity patterns. Monocrystalline quartz dominates the detrital mineralogy followed by polycrystalline quartz. Among the polycrystalline variety recrystallized metamorphic quartz surpasses stretched metamorphic quartz in terms of abundance. Feldspars comprise microcline and plagioclase where the former is dominant over the latter. Orthoclase too comprises a very small percentage. Mica, chert, rock fragments, and heavies form the remaining detrital constituent in descending order of their constituent percentage. The diagenetic precipitates are mainly carbonate (8.30%) and iron (7.80%) followed by clay (0.66%) and silica (0.88%) that are minor constituent of the total cementing material. The main paragenetic events identified are early cementation, mechanical compaction, late cementation, dissolution, and authigenesis of clays. The overall reservoir quality seems to be controlled by compaction and authigenic carbonate cementation. The minus cement porosity average 29.4%. The porosity loss due to compaction is 21.92% and by cementation is 29.71%. The loss of original porosity was due to early cementation followed by moderate mechanical compaction during shallow burial. Preservation of available miniscule primary porosity was ascribed to dissolution of carbonates and quartz overgrowth which resisted chemical compaction during deep burial. The studied sandstones may have low reservoir quality owing to existing porosity of less than 9%. More carbonate dissolution and its transformation in dolomite in sub-surface condition and macro-fracture porosity may result in enhanced secondary porosity and good diagenetic traps. 相似文献
7.
Mike J. Pearson 《Geochimica et cosmochimica acta》1979,43(6):927-941
The major element geochemistry of a mudstone sequence of Westphalian age has been studied in detail and mineralogical distributions calculated. Quartz and zircon trends indicate the energy of the depositional environment and this is closely reflected in the clay mineralogical composition. Of the detrital clays kaolinite is concentrated in the finer-grained sediments relative to illite. Chlorite and interstratified illite-smectite probably underwent diagenetic modification and small amounts of authigenic clays may have formed.Siderite, which occurs in both concretionary and disseminated form, and pyrite developed during diagenesis under reducing conditions and account for most of the iron present. Pyrite grew first deriving its iron partly from detrital clays. Carbon isotopic evidence suggests that early siderite precipitated in pore space as nodules and later in dispersed form. A second concretionary phase, pistomesite, grew during late dewatering. Siderite iron was derived mainly from Mn-rich oxidate phases.Titanium occurs as anatase uniformly distributed through the sequence. Phosphorus is mainly in diagenetic apatite and the ratio is controlled by the micas. Adsorbed water is closely related to grain size and clay content. 相似文献
8.
A set of samples from the Camarillas Formation (Barremian, Weald facies) in the Galve Sub-basin (Central Iberian Chain, north-east Spain) was studied to determine the origin of the abundant kaolinitic clays and their relationship to the sedimentary environment, palaeoclimate and diagenetic processes. The samples were examined by X-ray diffraction and scanning and transmission electron microscopy, with special emphasis on clay-mineral characterization. The analysed materials are a mixture of detrital (quartz, micas, and K-feldspars) and authigenic phases (kaolinite, Fe-oxides, gibbsite, dickite, and calcite). Therefore, the mineralogy of the rocks reflects the source area, the sedimentary conditions, and the diagenetic evolution. The most abundant authigenic phases are kaolinites. The combination of XRD and electron microscopy shows that the kaolinites are well crystallized and have as high a degree of ordering as those formed by weathering in palaeosols; this clay formed the rock matrix, intergrowths with muscovite, and vermicular booklets that replaced detrital silicates as a consequence of intense dissolution processes. The diagenetic processes have recrystallized kaolinites in the sandstones, producing larger crystallinity indices and dickite. In contrast, kaolinites from the claystones and siltstones probably reflect formation by weathering. The kaolinitization process described, associated with the crystallization of gibbsite and iron oxides, is in agreement with the relatively warm and humid conditions described for the Iberian Range basin in the early Barremian. 相似文献
9.
The geochemistry of the non-carbonate fraction of sediments from the continental shelf and slope off northwest Africa has been investigated using R-mode factor analysis. The geochemistry is governed by a small number of factors controlled quantiatively by glauconite, phosphorite, quartz, clay minerals and secondary iron oxides. The distributions of the factors and of their controls are governed by mineral provenance and by depositional processes. Clay mineral factors predominate in fine grained sediments. Phosphorite, glauconite and oxide factors and quartz predominate in sands. Provenance controls the relative abundances of the minerals of the sand fraction all of which, except a proportion of the glauconite which is clearly recent, are relict and detrital. The recent glauconite is concentrated in poorly oxidised sediments off the southern Sahara. Provenance differences are detected between Saharan and Moroccan clays, and also exist between the clays of north and south Morocco. 相似文献
10.
The late (?) Miocene non-marine to paralic Guayabo Group in northeastern Colombia and adjacent Venezuela contains as many as thirty-four thin (to 15 cm) goethitic and chamositic oolites and ooid-bearing sandstones in 1080 m of section. This eastward prograding deltaic complex consists mainly of chert-rich litharenite in fluvial, distributary channel, and shoreline facies, and of montmorillonite mudstone in floodplain and interdistributary embayment facies. Within this framework the oolites are restricted to a paralic association that developed during episodes of waning detrital sedimentation when distributary abandonment was followed by minor transgression across mudflats. Most of the multilayered and symmetrical ooids are composed of goethite, rarely with a small amount of chamosite. These are essentially spherical; many of the chamosite-rich ones have been plastically deformed. Goethitic ooids resemble those in a thin layer accumulating in brackish Lake Chad, central Africa. Chamositic ooids have affinities with those accumulating in a sea loch in western Scotland. Each of these examples is associated with detrital (silicate) sedimentation, apparently developed directly from colloidal ferric oxide and silicate precursors, and affords no evidence that primary aragonitic ooids were later placed by ironbearing oxide and clay. 相似文献
11.
《Journal of African Earth Sciences》2000,30(1):25-46
Two types of ooidal ironstone deposits, all of Late Cretaceous age, were recognised in an area trending from Nigeria in a northeasterly direction via Sudan to Egypt. The two types of ironstones are of the kaolinite-type deposits (Agbaja area, Bida area, Sokoto and Potiskum, Nigeria; Shendi and Wadi Haifa, Sudan; and Kalabscha, Egypt) and of the chamosite-type deposits (Aswan, Egypt and Okigwe, Nigeria). Post-diagenetic ferruginisation of these deposits is reflected in only small variations in the chemical composition of the two types. Obvious differences include the varying MgO concentrations, which are considerably higher in the chamosite-type (in the range from ∼0.5–6.75 wt%). In the kaolinite-type, MgO varies from 0.0 to ∼0.4 wt%.One of the principal characteristics of the chamosite-type deposits is the occurrence of fossils, especially of brecciated shell material and bioturbation. These features are unknown in the kaolinite-type. In both types, pyrite and siderite are common constituents. These minerals are of diagenetic origin and were formed under reducing conditions in the presence of either chamositic clay minerals or kaolinite. The protoliths of both the kaolinite and the chamositic types were lateritic weathered rocks of the hinterland, transported via fluvial drainage systems and deposited in marine basins. The differences of the two types have been explained by the attendant environmental conditions. The environment of the chamosite-type is compatible with fully marine conditions and normal salinity, resulting in the availability of Mg leading to the formation of chamositic clay during diagenesis. The environment of the kaolinite-type is thought to be a marginal basin with high river discharge and thus lower salinity with zero or negligibly low Mg concentration. In this environment, a diagenetic transformation of the sedimentary kaolinite precorsur into chamositic clay failed to occur. The model is supported by the distribution patterns of the two ironstone types. Within the study area, the chamositic-types are located at the extreme positions and are thus closest to the open sea where fully marine conditions are most likely to have occurred. 相似文献
12.
13.
Carbonate platforms across Western Europe were superseded at the Middle–Upper Jurassic (Callovian–Oxfordian) boundary either by alternating marl–limestone and widespread marl deposits or by condensed sections containing iron ooids. The characteristics of marine condensed sections in the south-eastern part of the Paris Basin (France) and their distribution pattern are examined here, and a model of iron ooid formation is developed. Iron ooids are found from the shoreface to the offshore zone. They are most abundant in the median-to-distal offshore transition zone, where they originally formed. They also occur commonly, albeit often as reworked grains, in the proximal offshore zone, to which they were transported. The contemporaneous, thick, predominantly marl sections that occur laterally are devoid of iron ooids and were deposited in deeper settings (distal offshore zone). The iron ooids are composed of goethite. Typically, they have a nucleus made up of a clump of goethite crystals and a laminated cortex. Three distinctive nanostructures are identified in the cortex laminae: (i) a nanograined crystalline structure typical of primary goethite; (ii) a secondary nanoflaked structure thought to have formed mechanically by reorientation of the goethite crystals; and (iii) a coalesced structure acquired by subsequent diagenetic recrystallization. The iron ooids formed successively (i) by lamina growth when goethite precipitated in the surface layer of the sediment (nanograined structure) and (ii) by interruption of growth when the ooids were remobilized by hydrodynamic agents, as reflected by the flaked nanostructure; (iii) these two nanostructures were sometimes transformed into a coalesced structure by recrystallization when ooids were buried. 相似文献
14.
Ardiansyah Koeshidayatullah Khalid Al‐Ramadan Geraint Wyn Hughes 《Geological Journal》2016,51(5):704-721
The Al‐Jawf area of northern Saudi Arabia provides spectacular outcrops of Early Devonian carbonate bioherms in the Wadi Murayr and Dumat Al‐Jandal areas. These carbonate bioherms belong to the Qasr Member of the Late Pragian–Early Emsian Jauf Formation (~405 Ma) and are surrounded by a bioclastic carbonate succession. The Qasr Member is the first major carbonate unit of the Palaeozoic succession in Saudi Arabia that mainly consists of microbialite carbonates and metazoan reefs exhibiting distinct mound features. These bioherm complexes and their associated carbonate facies are pervasively dolomitized. Stratigraphic, petrographic and geochemical analyses were conducted to determine the facies distribution and interpret their depositional and diagenetic processes. A total of 11 facies are identified from a range of depositional environments within a carbonate platform system, ranging from tidal flats, lagoon, shoal, patch reefs to reef front. The main diagenetic processes are carbonate cementation and dolomitization. Dolomitization occurred as both fabric preserved (mostly in grain‐dominated facies) and fabric destructive (mud‐dominated facies). The microbialites and coralline sponges facies show poor reservoir with visual porosity less than 5%, but this succession may have a potential to serve as a good source for the underlying and overlying facies. Ooid and peloidal grainstone facies show fair to good visual porosity that locally exceeds 10% with intergranular porosity as the dominant type. However, in the most studied samples, vuggy and intraparticle porosities are observed as the dominant type. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
15.
西藏北部西雅尔岗地区白垩-第三系红层的成岩作用及成岩环境 总被引：1，自引：0，他引：1
西雅尔岗地区位于羌塘高原腹地，地理范围为东经88°00′至89°00′，北纬32°40′至33°40′.大地构造位置从属于羌塘地块的玛依岗日一阿木冈基底隆断带.在晚白坚一第三纪时期，受青藏高原整沐抬升的影响，沉积了一套巨厚的红色陆屑建造，其基本特征为沉积厚度大、粗粒沉积所占比例高、沉积类型复杂、横向及纵向上相变快、岩石的颜色多为红色及紫色.沉积相类型主要为冲积扇、扇三角洲及湖泊.化石类型卖要为植物〔柏型枝)，孢粉和鸟足印化石.反映了在干操气候条件下，快速堆积的沉积特征. 根据对该区岩石学的研究，发现岩石的矿物组合和结构类型皆因成岩作用的影响而发生了很大的变化.矿物组合的变化是由于沉积后附加的陆源机械渗人粘土，在地表条件下不稳定矿物及岩屑的溶解作用以及在成岩过程中自生矿物的形成作用所造成的.导致结构类型改变的原因是(1)机械渗人的碎屑粘土及自生的粘土矿物形成孔隙间的粘土质“成岩杂基”.而这些孔隙在最初沉积时则没有杂基存在;(2)松散沉积物在成岩过程中，结构颖粒的溶解作用;(3)由于压实及压溶作用而形成粉砂级及其它细小的颗粒;(4)交代作用及重结晶作用.这些成岩过程明显地反映了整个区域岩石的演化历史. 显微镜、扫描电镜的观察以及红外光谱的侧定结果表明该区红层的形成是由于在成岩过程中赤铁矿的沉淀而造成的.在扫描电镜下可清楚地识别出赤铁矿的自生晶形.由此可以断定赤铁矿在其形成过程中显然是起了染色剂的作用.它的形成主要受孔隙水的氧化还原条件所控制，似乎于气候的关系不大，尽管它是产于干旱条件的沉积物中. 基于对该区岩石的成岩作用及成岩历史演化序列的研究，建立了该区沉积后的成岩环境模式，亦即(l)早期的表生成岩浅埋藏环境，该环境明显受到沉积环境、沉积作用控制以及气候因素的影响;(2)晚期的成岩深埋藏环境，该环境则主要受地温梯度、压力、温度和孔隙水的地球化学条件的控制. 相似文献
16.
Eric E. Hiatt Kurt Kyser Robert W. Dalrymple 《Journal of Geochemical Exploration》2003,80(2-3):221-240
The Thelon Basin, Nunavut, Canada, is host to unconformity-type uranium mineralisation and has the potential to host other economic deposits. The Thelon Formation (ca. 1750 Ma) is composed of thick (meters to tens of meters), poorly sorted, trough cross-bedded conglomerate and coarse-grained lithic arenite beds, and to a lesser extent, well-sorted, medium- to coarse-grained quartz arenite beds. Relatively rare, 1–12 cm thick, clay-rich siltstones to fine-grained sandstone layers punctuate the coarser lithofacies. Based on regional analysis of drill cores and outcrops, multiple unconformity-bounded sequences are defined in this fluvial-dominated sedimentary succession. Stratigraphic correlations are based on detailed lithofacies analysis, distinct changes in fining-upward cycle thickness, and intraformational surfaces (unconformities, transgressive surfaces, and paleosols).Diagenetic and paragenetic relationships vary systematically with sedimentology and stratigraphy of the Thelon and provide a framework for understanding the evolution of fluid-flow systems in the context of basin hydrostratigraphy. Stratigraphic units with well-sorted textures, which lacked clay and unstable framework grains, originally were aquifers (depositional aquifers) during early basin evolution. However, pervasive, early quartz cementation radically reduced the porosity and permeability of these units, occluding pore throats and transforming them into aquitards. Proximal fluvial and alluvial fan lithofacies that contained detrital, mechanically infiltrated, and diagenetic clay minerals and/or unstable detrital grains originally had low permeabilities and only experienced minor quartz cementation. In the deep burial setting (2–7 km), these units retained sufficient permeability to allow diagenetic fluid flow (diagenetic aquifers) as suggested by feldspar dissolution, quartz dissolution, and formation and recrystallization of illite and other diagenetic reactions. Tracing potential diagenetic aquifer and aquitard units across the study area allowed development of a hydrostratigraphic model. In this model, diagenetic aquifers onlap onto, and focused basinal fluids into basement rocks to the east in the Thelon Basin (in the vicinity of the Kiggavik uranium deposit). 相似文献
17.
T. A. L. TEYSSEN 《Sedimentology》1984,31(2):195-211
The oolitic ironstones of the Minette were deposited during Toarcian/Aalenian times in a nearshore environment of the Paris Basin. The sedimentary sequence comprises up to 13 coarsening upward depositional cycles. The development of the cycles and different facies types are described. The iron ooids accumulated in a subtidal environment under the effects of tidal currents. Sand waves, which form an important part of the Minette sediments, were deposited under both time-velocity symmetrical and time-velocity asymmetrical tides. From the study of their internal structures the time-velocity patterns of the currents, current speeds (up to 0±9m s?1) and net transport rates have been estimated (29 g m?1 s?1 in the case of large-scale sand waves controlled by time-velocity symmetrical tides). Sand wave heights and calculated near-bed current speeds suggest a mesotidal regime. Sedimentary facies include large-scale and waves, subtidal shoals with channels and an offshore muddy shelf. Conclusions as to bathymetry are drawn from ichnofaunal associations and from the study of wave ripple marks. Finally a depositional model of the Minette iron formation is proposed which may be applicable to other oolitic ironstones. 相似文献
18.
鞍本地区大孤山条带状铁建造含铁矿物和相分带特征及形成环境分析 总被引：1，自引：1，他引：0
鞍山-本溪条带状铁建造(Banded Iron Formation,简称BIF)位于华北克拉通东北缘,是世界上典型BIF之一,也是我国最重要的铁矿资源基地。大孤山位于鞍山地区南部矿带,为新太古代典型的Algoma型BIF,与华北克拉通其它大多数BIF相比,具有较低变质程度(绿片岩相-低角闪岩相)和较完整的沉积相分布特征。因此,通过大孤山BIF的研究有利于追踪Algoma型BIF的原生矿物组成及其后期成岩-变质过程,进而通过分析原生矿物形成的物理化学条件探讨古海洋环境。依据原生矿物共生组合及产出特征,可将大孤山BIF沉积相划分为氧化物相(30%)、硅酸盐相(50%)和碳酸盐相(20%)。氧化物相主要分布于主矿体南部,主要矿物组成为磁铁矿和石英;硅酸盐相分布于主矿体中部,主要矿物组成除了石英和磁铁矿之外,还有黑硬绿泥石、绿泥石、镁铁闪石等;碳酸盐相分布于矿体北部,主要矿物组成为菱铁矿、磁铁矿和石英等。本文通过大孤山BIF岩相学观察和含铁矿物化学成分研究,推测原生沉积物的组成为无定形硅胶、三价铁氢氧化物和富铝粘土碎屑,在经历了成岩和低级变质作用后转变为具不同相带的条带状铁建造。通过分析磁铁矿、菱铁矿和黑硬绿泥石等矿物在不同P_(O_2)-P_(CO_2)和pH-Eh条件下的共生相图可知,这些矿物均是在较低氧逸度、中到弱碱性环境下形成。综合考虑矿物成分、共生组合及受变质作用较弱等信息,本文推测制约原生矿物形成的控制因素主要是古海水氧化还原状态、酸碱度、CO_2含量和硫逸度。 相似文献
19.
S. FLINT 《Sedimentology》1987,34(1):11-29
The Oligo-Miocene Pacencia Group of Antofagasta Province, northern Chile consists of over 2 km of molassic sediments deposited in a series of alluvial fan and playa sub-environments. Sandstones of the Artolla Member, exposed around San Bartolo, represent playa-marginal sandflat deposits and locally host stratiform copper mineralization. A detailed study of these sediments has revealed a complex sequence of diagenetic modifications to the arkosic detrital mineral assemblage. Early dissolution of unstable ferro-magnesian minerals and calcic feldspar resulted in the release of ions into intra-stratal solution and the subsequent formation of a suite of eogenetic authigenic minerals. These include early hematite coatings on framework grains, pore-lining zeolite and pore-filling calcite, gypsum and celestite cements. Syntaxial overgrowths of albite, quartz and less common K-feldspar are well developed. Following early oxidative intrastratal conditions, the influx of acidic fluids derived from mudrocks during mesogenesis resulted in an important secondary porosity generation and the establishment of an acidic, reducing intrastratal environment. This facilitated the subsequent introduction of low temperature mineralizing solutions and formation of the San Bartolo copper deposit. A return to oxidative diagenetic conditions is recorded by late stage overgrowths of K-feldspar and quartz and the oxidation of native copper/chalcopyrite cements to cuprite/tenorite and chalcocite/covellite assemblages. This final telogenetic modification to the mineral assemblage is related to flushing by meteoric waters and provides independent evidence for an important phase of Andean deformation and uplift in the middle to upper Miocene. 相似文献
20.
Mohamed A.K. El-ghali Karima G. Tajori Howri Mansurbeg 《Journal of Geochemical Exploration》2006,89(1-3):87
Linking diagenesis to depositional facies and sequence stratigraphy can provide a better understanding of some of the parameters that control the spatial and temporal distribution of diagenetic alterations and of their impact on reservoir quality. A study of the paralic, glaciogenic sandstones of the Melaz Shuqran and Mamunyiat formations (Late Ordovician) of the Murzuq Basin, SW Libya, reveals that the distribution of diagenetic kaolin can be constrained within depositional facies and sequence stratigraphy. Eogenetic kaolinite was formed by the dissolution of unstable detrital grains as a result of influx of meteoric waters into: (i) glacial, fluvial incised-valley lowstand systems tract (LST), glacial, tide-dominated estuarine transgressive systems tract (TST) during formation of overlying sequence boundary, (ii) paraglacial, tide-dominated deltaìc highstand systems tract (HST), paraglacial, foreshore to shoreface HST during progradation and basinward shift of the shoreline and/or formation of overlying sequence boundary, (iii) postglacial, Gilbert-type deltaic LST sandstones during relative sea level fall. On the other hand, formation of kaolinite immediately below maximum flooding surfaces is attributed to dissolution of unstable detrital grains by organic acids that were presumably derived from thermal alterations of organic matter, possibly during mesodiagenesis. The transformation of eogenetic kaolinite into dickite during mesodiagenesis is probably a consequence of low αK+ / αH+ ratio in the pore waters due to the scarcity of detrital K-feldspars. 相似文献