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1.
The assemblage paragonite + quartz is encountered frequently in low- to medium-grade metamorphic rocks. With rising grade of metamorphism they react mutually to yield the condensed assemblage albite + Al2SiO5.The univariant curve pertaining to the equilibrium paragonite + quartz=albite + andalusite + H2O has been located experimentally. The reversed P H 2 O-T data are: 1 kb: 470–490° C 2 kb: 510–530° C 3 kb: 540–560° C 4 kb: 560–580° C 5 kb: 590–600° C The univariant curve pertaining to the equilibrium paragonite + quartz=albite + kyanite + H2O runs through the following P H 2 O-T-intervals: 5 kb: 570–625° C 6 kb: 600–630° C 7 kb: 620–640° C Thermodynamic calculations of S 298 0 , H f,298 0 and G f,298 0 of the phase paragonite from the experimental data presented above and those obtained from the equilibria of the reaction paragonite=albite + corundum + H2O (Chatterjee, 1970), agree within the limits of uncertainty. This prompts the idea that Zen's (1969) suggestion of a possible error of approximately 7 kcal in G f,298 0 of the Al2SiO5 polymorphs may in fact be due to an error of similar magnitude in G f,298 0 of corundum.A best estimate of S 298 0 , H f,298 0 and G f,298 0 of paragonite based on these considerations yield: S 298 0 : 67.61±3.9 cal deg–1 gfw–1 H f,298 0 : –1411.4±2.7 kcal gfw–1 G f,298 0 : –1320.9±4.0 kcal gfw–1 These numbers will be subject to change when better thermochemical data on corundum and albite are available.In medium-grade metamorphic rocks the assemblage paragonite + quartz is commonly found in stable coexistence with such other phases as muscovite, staurolite, andalusite, kyanite, but not with cordierite or sillimanite. However, the assemblage paragonite-sillimanite has been reported to be stable in the absence of quartz. All these petrologic observations can be explained on the basis of the stability data of the phases and phase assemblages concerned.  相似文献   

2.
The diffusion rate of 18O tracer atoms in anorthite (An97Ab03) under anhydrous conditions has been measured using SIMS techniques. The tracer source was 18O2 98.4% gas at 1 bar, in the temperature range 1300° C–850° C. The measured diffusion constants are D 0=1 –0.6 +1 ×10–9 m2s–1 Q=236±8 kJ mol–1 Comparison of these values with published data for 18O diffusion in anorthite under hydrothermal conditions shows that dry oxygen diffusivities are orders of magnitude lower than equivalent wet values at similar temperatures. The effect of these differences on oxygen isotope equilibration during cooling is discussed.  相似文献   

3.
Stability of titanian clinohumite: Experiments and thermodynamic analysis   总被引：2，自引：0，他引：2  
Reversed hydrothermal experiments on a natural titanoclinohumite [Ti-Cl; approximate formula Mg7.5FeTi0.5O16(OH)] show that it breaks down at 475°±11° C (3.5 kbar), 620°±11° C (14 kbar) and 675°±8° C (21 kbar) to the assemblage olivine +ilmenite+vapor. An internal-consistency analysis of the data yields r G s /0 (298 K, 1 bar)=36,760±3,326 cal (mole Ti-Cl)–1. r S s /0 (298 K, 1 bar)=34.14±5.91 cal deg–1(mole Ti-Cl)–1. Linear correlation coefficient r G–S 1.0. A solution model that accounts for TiO2-M(OH)2 and F-OH substitution shows that the results for our nearly F-free Ti-Cl are in reasonable agreement with the unreversed breakdown experiments of Mer-rill et al. (1972) on a F-bearing Ti-Cl.Because fluorine is necessary to stabilize Ti-Cl under mantle conditions, we suggest that Ti-Cl is much more likely to be a storage device for fluorine than for water in the mantle.  相似文献   

4.
The behaviour of synthetic Mg-ferrite (MgFe2O4) has been investigated at high pressure (in situ high-pressure synchrotron radiation powder diffraction at ESRF) and at high temperature (in situ high-temperature X-ray powder diffraction) conditions. The elastic properties determined by the third-order Birch–Murnaghan equation of state result in K0=181.5(± 1.3) GPa, K=6.32(± 0.14) and K= –0.0638 GPa–1. The symmetry-independent coordinate of oxygen does not show significant sensitivity to pressure, and the structure shrinking is mainly attributable to the shortening of the cell edge (homogeneous strain). The lattice parameter thermal expansion is described by a0+a1*(T–298)+a2/(T–298)2, where a0=9.1(1) 10–6 K–1, a1=4.9(2) 10–9 K–2 and a2= 5.1(5) 10–2 K. The high-temperature cation-ordering reaction which MgFe-spinel undergoes has been interpreted by the ONeill model, whose parameters are = 22.2(± 1.8) kJ mol–1 and =–17.6(± 1.2) kJ mol–1. The elastic and thermal properties measured have then been used to model the phase diagram of MgFe2O4, which shows that the high-pressure transition from spinel to orthorombic CaMn2O4-like structure at T < 1700 K is preceded by a decomposition into MgO and Fe2O3.  相似文献   

5.
Late Cretaceous, granitic pegmatite-aplite dikes in southern California have been known for gem-quality minerals and as a commercial source of lithium. Minerals, whole-rock samples, and inclusion fluids from nine of these dikes and from associated wall rocks have been analyzed for their oxygen, hydrogen, and carbon isotope compositions to ascertain the origins and thermal histories of the dikes. Oxygen isotope geothermometry used in combination with thermometric data from primary fluid inclusions enabled the determination of the pressure regime during crystallization.Two groups of dikes are evident from their oxygen isotope compositions (18Oqtz+10.5 in Group A, and +8.5 in Group B). Prior to the end of crystallization, Group A pegmatites had already extensively exchanged oxygen with their wall rocks, while Group B dikes may represent a closer approximation to the original isotopic composition of the pegmatite melts. Oxygen isotope fractionations between minerals are similar in all dikes and indicate that the pegmatites were emplaced at temperatures of about 730 ° to 700 ° C. Supersolidus crystallization began with the basal aplite zone and ended with formation of quench aplite in the pocket zone, nearly to 565 ° C. Subsolidus formation of gem-bearing pockets took place over a relatively narrow temperature range of about 40 ° C (approximately 565–525 ° C). Nearly closed-system crystallization is indicated.Hornblende in gabbroic and noritic wall rocks (Dw.r. = –90 to –130) in the Mesa Grande district crystallized in the presence of, or exchanged hydrogen with, meteoric water (D –90) prior to the emplacement of the pegmatite dikes. Magmatic water was subsequently added to the wall rocks adjacent to the pegmatites.Groups A and B pegmatites cannot be distinguished on the basis of their hydrogen isotope compositions. A decrease in D of muscovite inward from the walls of the dikes reflects a decrease in temperature. D values of H2O from fluid inclusions are: –50 to –73 (aplite and pegmatite zones); –62 to –75 (pocket quartz: Tourmaline Queen and Stewart dikes); and –50 ± 4 (pocket quartz from many dikes). The average 13C of juvenile CO2 in fluid inclusions in Group B pegmatites is –7.9. In Group A pegmatities, 13C of CO2 is more negative (–10 to –15.6), due to exchange of C with wall rocks and/or loss of 13C-enriched CO2 to an exsolving vapor phase.Pressures during crystallization of the pockets were on the order of 2,100 bars, and may have increased slightly during pocket growth. A depth of formation of at least 6.8 km (sp. gr. of over burden = 3.0, and P fiuid=P load) is indicated, and a rate of uplift of 0.07 cm/yr. follows from available geochronologic data.  相似文献   

6.
Trajectories of two reversible phase transitions in a low-Na synthetic tridymite have been determined to 6 kbar by differential thermal analysis (DTA) in hydrostatic apparatus using Ar or CO2. The temperature of the lower transition increases from 111 ° C at 1 bar linearly with pressure with slope 15 deg kbar–1. Pressure raises the temperature of the upper transition from 157 ±2 ° or 159 ° C (independently determined) at 1 bar wit a slope of 53 deg kbar–1, up to 0.7 kbar; for the data above that pressure, the initial slope is 64 deg kbar–1. Above 2–1/2 kbar, the variation is linear with slope 70 deg kbar–1. No evidence for other transitions was found at any of the apparent changes of slope. Hystereses for both transitions decreased at high pressures compared to 1-bar. Preferred values for the transition enthalpies, together with these slopes and the Clausius-Clapeyron equation, yield estimates for the volume changes at the transitions of 0.01 (lower) and 0.15 to 0.25 (upper) cm3 gfw–1. These calculated volume changes are not consonant with many of the high temperature volumetric data on tridymites of varying origins.  相似文献   

7.
The oxygen isotope compositions of coesite, sanidine, kyanite, clinopyroxene and garnet were measured in an ultra-high pressure-temperature grospydite from the Roberts Victor kimberlite, South Africa. The 18O values (per mil v. SMOW) of each phase and (1 ) are as follows: coesite, 8.62 (0.31); sanidine, 8.31 (0.02); kyanite, 7.98 (0.08); pyroxene, 7.63 (0.11); garnet, 7.53 (0.03). In situ analyses of the coesite with the laser extraction system are 18O=9.35 (0.08), n=4, demonstrating that the coesite is homogeneous. The coesite has partially inverted to polycrystalline quartz and the pyroxene is extensively altered during uplift. The larger scatter for the mineral separate coesite and pyroxene data may be due to partial reequilibration between the decompression-related breakdown products of these two phases. The anomalously high 18O value of the grospydite (18Owholerock=7.7) is consistent with altered oceanic crust as a source rock. Temperature estimates from a linear regression of all the data to three different published calibrations correspond to an equilibrium temperature of 1310±80°C. The calculated isotopic pressure effect is to lower these estimates by about 40°C at 40 kb. The estimated temperature based on Al–Si disorder in sanidine is 1200±100°C and that from Fe–Mg exchange thermometry between garnet and clinopyroxene is 1100±50°C. Given the large errors associated with thermometry at such high temperatures, it is concluded that the xenolith equilibrated that 1200±100°C. Pressure estimates are 45±5 kb, based on dilution of the univariant equilibria albite = jadeite + coesite and 2 kyanite + 3 diopside = grossular + pyrope + 2coesite. Zoning in the outer 20 m of the feldspar from Ab0.8 to Ab16 indicates rapid decompression to 25 kb or less. The isotopic temperature estimates are the highest ever obtained and combined with the high degree of Al–Si disorder in sanidine require rapid cooling from ultra-high temperatures. It is inferred that the xenolith was sampled at the time of equilibration, providing a point on the upper Cretaceous geotherm in the mantle below South Africa.  相似文献   

8.
A combined analytical and numerical evaluation of the uncertainties in P-T paths is made for three assemblages that propagates errors in the parameters: initial pressure, initial temperature, initial composition, change of composition of monitor parameters, endmember entropy, and endmember volume. Propagated errors along an isobaric heating path (T=77°C) for assemblage 1 (Grt-Bt-Pl-Qtz-Ms-Chl-H2O), using as monitor parameters the mole fractions of almandine, spessartine, grossular, and anorthite, and ignoring uncertainties in thermodynamic properties, are approximately ±320 bars (1) and ±8.3°C (1) if rim compositional uncertainties of 5% in major cations are assumed, or ±2.5°C (1) and ±50 bars (1) if electron microprobe analytical uncertainties are assumed for compositions. The largest source of uncertainty is from the errors in the monitor parameters, and P-T path uncertainties can depend critically on which monitor parameters are used. If the mole fraction of annite is used as a monitor parameter in place of the anorthite content of plagioclase, then propagated uncertainties are worse than ±29°C (1) and ±5800 bars (1). P-T path uncertainties also depend on assemblage. 1 precisions in assemblages 2 (Grt–Bt–Pl–Qtz–Ms–Sil–H2O) and 3 (Grt–Bt–Qtz–Kfs–Sil–H2O) using as monitor parameters the mole fractions of almandine, spessartine, grossular, and anorthite are calculated to be ±267 bars and ±43.4°C and ±372 bars and ±8.2°C respectively. Estimates of the accuracies in P-T paths that include potential errors in endmember entropy of ±1 J/mol·K and in endmember volume of ±1 cm3/mol are: ±324 bars and ±8.5°C (assemblage 1), ±341 bars and ±48.6°C (assemblage 2), and ±388 bars and ±9.7°C (assemblage 3). Use of different garnet, plagioclase, and muscovite activity models can change the length of a P-T path by as much as 15%, but does not typically change directions in P-T space significantly. Models that incorporate changes of fluid composition shorten P-T paths in assemblages 1 and 3 but do not change trajectories significantly. Assemblage 2 is virtually unaffected by fluid phase models. For the mineral assemblages considered here and using appropriate monitor parameters, propagated errors are small compared to the total path length, suggesting that the differential thermodynamic approach is a precise and accurate method for determining amounts of heating or thickening during metamorphism, and hence for interpreting orogenic processes.  相似文献   

9.
Recent low temperature, adiabatic calorimetric heat capacity measurements for grossular have been combined with DSC measurements to give entropies up to 1000 K. In conjunction with enthalpy of solution values for grossular, these data have yielded H f o (298.15K) and G f o (298.15K) values of –1583.2 ± 3.5 and –1496.74 ± 3.7 kcal mol–1 respectively. For 15 reactions in the CaO-Al2O3-SiO2-H2O system, thermodynamically calculated P-T curves have been compared with experimental reversals and have shown good agreement in most cases. Calculations indicate that gehlenite is probably totally disordered. Estimates of zoisite and lawsonite entropies are consistent with the phase equilibrium and grossular data, but estimates of the entropies of pyrope and andradite show large discrepancies when compared with experimental reversals.Contribution no. 600 from the Mineralogical Laboratory, The Department of Geology and Mineralogy, The University of Michigan, Ann Arbor, Michigan 48109, USA  相似文献   

10.
Mo mineralization within the Galway Granite at Mace Head and Murvey, Connemara, western Ireland, has many features of classic porphyry Mo deposits including a chemically evolved I-type granite host, associated K- and Si-rich alteration, quartz vein(Mace Head) and granite-hosted (Murvey) molybdenite, chalcopyrite, pyrite and magnetite mineralization and a gangue assemblage which includes quartz, muscovite and K-feldspar. Most fluid inclusions in quartz veins homogenize in the range 100–350°C and have a salinity of 1–13 eq. wt.% NaCl. They display Th-salinity covariation consistent with a hypothesis of dilution of magmatic water by influx of meteoric water. CO2-bearing inclusions in an intensely mineralized vein at Mace Head provide an estimated minimum trapping temperature and pressure for the mineralizing fluid of 355°C and 1.2 kb and are interpreted to represent a H2O-CO2 fluid, weakly enriched in Mo, produced in a magma chamber by decompression-activated unmixing from a dense Mo-bearing NaCl-H2O-CO2 fluid. 34S values of most sulphides range from c. 0 at Murvey to 3–4 at Mace Head and are consistent with a magmatic origin. Most quartz vein samples have 18O of 9–10.3 and were precipitated from a hydrothermal fluid with 18O of 4.6–6.7. Some have 18O of 6–7 and reflect introduction of meteoric water along vein margins. Quartz-muscovite oxygen isotope geothermometry combined with fluid inclusion data indicate precipitation of mineralized veins in the temperature range 360–450°C and between 1 and 2 kb. Whole rock granite samples display a clear 18O-D trend towards the composition of Connemara meteoric waters. The mineralization is interpreted as having been produced by highlyfractionated granite magma; meteoric water interaction postdates the main mineralizing event. The differences between the Mace Head and Murvey mineralizations reflect trapping of migrating mineralizing fluid in structural traps at Mace Head and precipitation of mineralization in the granite itself at Murvey.  相似文献   

11.
Summary High-grade gneisses from the Pulur complex in NE Turkey bear evidence for biotite-dehydration melting at 820°C and 0.7–0.8GPa, melt segregation and near-isothermal decompression to 0.4–0.5GPa. During further exhumation, the rocks underwent secondary pervasive rehydration at temperatures between 400 and 230°C and fluid pressures between 0.3 and 0.1GPa. Metamorphic peak conditions are dated at 331–327Ma, while hydrothermal retrogression occurred significantly later at 315–310Ma under static conditions. During the rehydration event, primary high-grade mineral assemblages including garnet, cordierite, sillimanite, spinel, biotite, plagioclase and ilmenite were extensively replaced by muscovite, paragonite, margarite, corundum, diaspore, chlorite, kaolinite, pumpellyite, prehnite, epidote, titanite, anatase, pyrite and chalcopyrite. Secondary mineral assemblages indicate that the infiltrating fluids were characterized by low fO2, very low XCO2 (<0.002), variable activities of Ca2+, K+, Na+ and H+ and relatively high activities of H2S and CH4. Quartz veins that might have acted as pathways for the fluids are rare. Ubiquitous veinlets consisting of (i) albite, (ii) chlorite+calcite+quartz or (iii) K-feldspar+calcite+quartz were formed after the pervasive rehydraton event by precipitation from aqueous solutions that were somewhat richer in CO2.  相似文献   

12.
The pre-Cenozoic geology at Candelaria, Nevada comprises four main lithologic units: the basement consists of Ordovician cherts of the Palmetto complex; this is overlain unconformably by Permo-Triassic marine clastic sediments (Diablo and Candelaria Formations); these are structurally overlain by a serpentinitehosted tectonic mélange (Pickhandle/Golconda allochthon); all these units are cut by three Mesozoic felsic dike systems. Bulk-mineable silver-base metal ores occur as stratabound sheets of vein stockwork/disseminated sulphide mineralisation within structurally favourable zones along the base of the Pickhandle allochthon (i.e. Pickhandle thrust and overlying ultramafics/mafics) and within the fissile, calcareous and phosphatic black shales at the base of the Candelaria Formation (lower Candelaria shear). The most prominent felsic dike system — a suite of Early Jurassic granodiorite porphyries — exhibits close spatial, alteration and geochemical associations with the silver mineralisation. Disseminated pyrites from the bulk-mineable ores exhibit a 34S range from — 0.3 to + 12.1 (mean 34S = +6.4 ± 3.5, 1, n = 17) and two sphalerites have 34S of + 5.9 and + 8.7 These data support a felsic magmatic source for sulphur in the ores, consistent with their proximal position in relation to the porphyries. However, a minor contribution of sulphur from diagenetic pyrite in the host Candelaria sediments (mean 34S = — 14.0) cannot be ruled out. Sulphur in late, localised barite veins ( 34S = + 17.3 and + 17.7) probably originated from a sedimentary/seawater source, in the form of bedded barite within the Palmetto basement ( 34S = + 18.9). Quartz veins from the ores have mean 18O = + 15.9 ± 0.8 (1, n = 10), which is consistent, over the best estimate temperature range of the mineralisation (360°–460°C), with deposition from 18O-enriched magmatic-hydrothermal fluids (calculated 18O fluid = + 9.4 to + 13.9). Such enrichment probably occurred through isotopic exchange with the basement cherts during fluid ascent from a source pluton. Whole rock data for a propylitised porphyry ( 18O = + 14.2, D = — 65) support a magmatic fluid source. However, D results for fluid inclusions from several vein samples (mean = — 108 ± 14, 1, n = 6) and for other dike and sediment whole rocks (mean = — 110 ± 13, 1, n = 5) reveal the influence of meteoric waters. The timing of meteoric fluid incursion is unresolved, but possibilities include late-mineralisation groundwater flooding during cooling of the Early Jurassic progenitor porphyry system and/or meteoric fluid circulation driven by Late Cretaceous plutonism.  相似文献   

13.
Mean and turbulent velocity measurements of supersonic mixing layers   总被引：1，自引：0，他引：1  
The behavior of supersonic mixing layers under three conditions has been examined by schlieren photography and laser Doppler velocimetry. In the schlieren photographs, some largescale, repetitive patterns were observed within the mixing layer; however, these structures do not appear to dominate the mixing layer character under the present flow conditions. It was found that higher levels of secondary freestream turbulence did not increase the peak turbulence intensity observed within the mixing layer, but slightly increased the growth rate. Higher levels of freestream turbulence also reduced the axial distance required for development of the mean velocity. At higher convective Mach numbers, the mixing layer growth rate was found to be smaller than that of an incompressible mixing layer at the same velocity and freestream density ratio. The increase in convective Mach number also caused a decrease in the turbulence intensity ( u /U).List of Symbols a speed of sound - b total mixing layer thickness betweenU 1 – 0.1U andU 2 + 0.1U - f normalized third moment ofu-velocity,f u 3/(U)3 - g normalized triple product ofu 2 v,g u 2 v/(U)3 - h normalized triple product ofu v 2, h uv' 2/(U)3 - l u axial distance for similarity in the mean velocity - l u axial distance for similarity in the turbulence intensity - M Mach number - M c convective Mach number (for 1=2),M c (U 1–U 2)/(a 1+a 2) - P static pressure - r freestream velocity ratio,rU 2/U 1 - Re unit Reynolds number,Re U/ - s freestream density ratio,s 2/ 1 - T t total temperature - u instantaneous streamwise velocity - u deviation ofu-velocity,u u–U - U local mean streamwise velocity - U 1 primary freestream velocity - U 2 secondary freestream velocity - U average of freestream velocities, ¯U (U 1 +U 2)/2 - U freestream velocity difference,U U 1 –U 2 - v instantaneous transverse velocity - v deviation ofv-velocity,v v – V - V local mean transverse velocity - x streamwise coordinate - y transverse coordinate - y 0 transverse location of the mixing layer centerline - ensemble average - ratio of specific heats - boundary layer thickness (y-location at 99.5% of free-stream velocity) - similarity coordinate, (y –y 0)/b - compressible boundary layer momentum thickness - viscosity - density - standard deviation - dimensionless velocity, (U –U 2)/U - 1 primary stream - 2 secondary stream A version of this paper was presented at the 11th Symposium on Turbulence, October 17–19, 1988, University of Missouri-Rolla  相似文献   

14.
The positions of the liquidi and the near-liquidus phases of olivine-melilitite+CO2 have been determined under MH-buffered and furnace-buffered conditions up to 40 kb. It is found that CO2 alone lowers the liquidus compared to dry conditions, yet its influence is minor compared to H2O. The major role of CO2 is to favour the growth of orthopyroxene and garnet over that of olivine at least at high pressures. CO2-contents of glasses from experiments just above the liquidus (MH-buffered) were determined as 5.1 % at 10kb; 7.5 % at 20kb, 9.3 % at 30kb and 10–11 % (estimated) at 40 kb. Experiments on (pyrolite –40 % olivine)+H2O+CO2 show that CO2 occurs under mantle conditions as carbonate under subsolidus conditions and dissolved in a melt above the solidus. At 30kb, the solidus lies between 1,000 ° C and 1,050 ° C for vapour-saturated conditions, at and at .  相似文献   

15.
Temperatures of the formation of mud-volcanic waters are determined based on concentrations of some temperature-dependent components (Na–Li, Mg–Li). Estimates obtained for the Taman and Kakhetia regions are similar and range from 45 to 170°, which correspond to depths of 1–4.5 km. The calculated temperatures correlate with the chemical (Li, Rb, Cs, Sr, Ba, B, I, and HCO3) composition of water and 13 (2) and 13 (CH4) values in spontaneous gases. The isotope values indicate that mechanisms of the formation of 13-rich gases, i.e., gases with high 13 values (up to +16.0 in 2 and –23.4 in CH4) in mud-volcanic systems of Taman and Kakhetia are governed by fluid-generation temperatures rather than the supply of abyssal gases. The 11 value was determined for the first time in mud-volcanic products of the Caucasus region. This value ranges from +22.5 to +39.4 in the volcanic water of Georgia, from –1.2 to +7.4 in the clayey pulp of Georgia, and from –7.6 to +13.2 in the clayey pulp of Taman. It is shown that the 11 value in clay correlates with the fluid-generation temperature and 11 correlates with 13 in carbon-bearing gases. These correlations probably testify to the formation of different phases of mud-volcanic emanations in a single geochemical system and suggest the crucial role of temperature in the development of isotope-geochemical features.  相似文献   

16.
The transformation from blueschist to greenschist facies forms a major part of the Alpine regional geodynamic evolution of the Cyclades. The transition in metabasic rocks on Sifnos involves the retrogression of eclogites, blueschists and actinolite-bearing rocks from high-pressure conditions which have been estimated at 460±30° C and 15±3 kb. Petrographically observed parageneses are interpreted by a sequence of hydration and carbonation reactions involving the breakdown of omphacite and glaucophane-bearing assemblages to albite+chlorite±actinolite±calcite assemblages. The retrograde processes are calculated to occur at pressures of 10 to 8 kb during the isothermal uplift of the Sifnos units. Oxygen isotope analyses of different rock types show that interlayered lithologies have experienced a large degree of isotopic equilibration during both metamorphic phases. However, chemically equivalent rocks show systematic increases in 18O from lowest values (8 to 11 in metabasics) in the unaltered blueschists in the upper stratigraphic levels to higher values (>15 in metabasics) associated with greenschists in the deepest stratigraphic levels. Relict eclogites enclosed within greenschists have the lower 18O values typical of unaltered blueschist facies rocks. These isotopic gradients and the 13C and 18O compositions of carbonates demonstrate an infiltration mechanism involving the upward movement of 18O-enriched fluids whose compositions were buffered by exchange with marble units. Calculated minimum fluid/rock ratios for the blueschist-to-greenschist transition decrease from 0.4 in the deepest studied level (Central Sifnos) and 0.2 in the intermediate level (Kamares Bay samples) to an assumed value of zero in unaltered blueschists. These ratios may be lower if recycling of fluids occurred between schists and marbles. Infiltration of fluids became inhibited as the transformation advanced as a consequence of sealing effect of the hydration and carbonation reactions. Although infiltration most probably was a pre-requisite for the regional occurrence of the blueschist-to-greenschist transformation in the Cyclades, the evidence on Sifnos does not suggest the introduction of large quantities of fluid.  相似文献   

17.
Giester  G. 《Mineralogy and Petrology》1995,53(1-3):165-171
Summary The crystal structure of synthetic KMn[SeO4]2 was determined by single crystal X-ray diffraction methods in space group , a = 4.827(2) Å, b = 4.988(2) Å, c = 7.981(3) Å, = 83.18(1)°, = 85.32(2)°, = 67.92(1)°, V = 176.66 Å3, Z = 1; 1564 unique data, measured up to 2 = 70° (MoK-radiation); R, R(I)w = 0.034, 0.074.KMn[SeO4]2 is closely related to monoclinic yavapaiite, KFe[SO4]2, and isotypic compounds. Jahn-Teller distorted MnO6 octahedra are alternately linked with KO10 polyhedra along [001]. The mean values of the Mn-O and Se-O distances are 2.007 Å and 1.637 Å, respectively.
Die Kristallstruktur vonKMn 3+[SeO4]-einem triklin verzerrten Vertreter der Yavapaiite-Familie
Zusammenfassung Die Kristallstruktur von synthetisch dargestelltem KMn[SeO4]2 wurde mittels Einkristallröntgenmethoden in der Raumgruppe bestimmt: a = 4.827(2) Å, b = 4.988(2) Å, c = 7.981(3) Å, = 83.18(1)°, = 85.32(2)°, = 67.92(1)°, V = 176.66 Å3, Z = 1; 1564 unabhängige Daten bis 2 = 70° (MoK-Strahlung); R, R(I)w = 0.034, 0.074.KMn[SeO4]2 ist eng mit dem monoklinen Mineral Yavapaiit, KFe[SO4]2 und einer Reihe damit isotyper Verbindungen verwandt. Jahn-Teller verzerrte MnO6 Oktaeder sind alternierend mit KO10 Polyedern parallel [001] verbunden. Die Mittelwerte der Mn-O und Se-O Abstände sind 2.007 Å bzw. 1.637 Å.

With 1 Figure  相似文献   

18.
Mesothermal gold mineralization at the Samdong mine (5.5–13.5 g/ton Au), Youngdong mining district, is situated in massive quartz veins up to 1.2 m wide which fill fault fractures within upper amphibolite to epidote-amphibolite facies, Precambrian-banded biotite gneiss. The veins are mineralogically simple, consisting of iron- and base-metal sulfides and electrum, and are associated with weak hydrothermal alteration zones (<0.5 m wide) characterized by silicification and sericitization. Fluid inclusion data and equilibrium thermodynamic interpretation of mineral assemblages indicate that the quartz veins were formed at temperatures between 425 and 190°C from relatively dilute aqueous fluids (4.5–13.8 wt. % equiv NaCl) containing variable amounts of CO2 and CH4. Evidence of fluid unmixing (CO2 effervescence) during the early vein formation indicates approximate pressures of 1.3–1.9 kbars, corresponding to minimum depths of 5–7 km under a purely lithostatic pressure regime. Gold deposition occurred mainly at temperatures between 345 and 240 °C, likely due to decreases in sulfur activity accompanying fluid unmixing. The 34S values of sulfide minerals (-3.0 to 5.3 ), and the measured and calculated O-H isotope compositions of ore fluids (18O = 5.7 to 7.6; = –74 to –80) indicate that mesothermal gold mineralization at the Samdong mine may have formed from dominantly magmatic hydrothermal fluids, possibly related to intrusion of the nearby ilmenite-series, Kimcheon Granite of Late Jurassic age.  相似文献   

19.
Sub-potassic nephelines in the system NaAlSiO4(Ne)-KAlSiO4(Ks) were synthesized under a variety of conditions and studied at room temperature and up to 1000 °C using an X-ray powder diffractometer. At low temperatures they do not have the hexagonal structure determined by Hahn and Buerger (1955) for natural nepheline. Samples with 0.7 to 2.5 mole % Ks have an orthorhombic supercell with parameters equivalent to a, 3a, 3c where a and c are Hahn and Buerger structure cell parameters. Nephelines with 0 to 0.7% Ks consist of two phases with different c axes; one of these phases has the orthorhombic supercell.Pure-Na nephelines (NaAlSiO4) invert to a hexagonal phase with the Hahn and Buerger structure at 190 °±10 °C; this inversion temperature decreases with increasing Ks and a sample with 0.5% Ks inverts at 170 °±5 °C. The inversion is reversible and is displacive. Another reversible inversion begins at 875 °±10 °C in pure-Na nepheline; this inversion increases in temperature with increasing Ks and a sample with 1.8% Ks begins to invert at 960 °±10 °C.Superstructures with anomalous low-temperature cell parameters in sub-potassic nephelines are attributed to reversible collapse of the framework about the larger cation sites which must be occupied by small Na in subpotassic nephelines. Superstructures in natural nephelines are also related to framework collapse at a displacive inversion.  相似文献   

20.
A thermodynamic analysis of the intermediate solid solution (Iss) of near-cubanite composition has been attempted by considering an Fe–Zn exchange equilibrium between Iss and sphalerite. The interchange free-energy parameter of Fe–Zn mixing in Iss (WIss) and the free energy of the exchange equilibrium (G1,T ) have been deduced at 500, 600, 700 and 723° C using the compositional data of sphalerite and Iss from phase equilibrium experiments and by the standard method of linear regression analysis. For sphalerite, two independent activity-composition models have been chosen. The extracted values of G1,T and WIss, using both models, are compared. Although the values match, the errors in the extracted parameters are relatively larger when Hutcheon's model is used. Both G1,T and WIss show linear variations with temperature, as given by the following relations: G1,T = –35.41 + 0.033 T in kcal (SE=0.229)WISS= 48.451 – 0.041 T in kcal (SE=0.565) Activity-composition relations and different mixing parameters have been calculated for the Iss phase. A large positive deviation from ideality is observed in Iss on the join CuFe2S3–CuZn2S3. No geothermometric application has been attempted in this study, even though Iss of cubanite composition (isocubanite) in association with sphalerite, pyrite and pyrrhotite is reported from seafloor hydrothermal deposits. This is due to the fact that: (a) the temperatures of formation of these deposits are significantly lower than 500° C, the lower limit of appropriate experimental data base; (b) microprobe data of the coexisting isocubanite and sphalerite in the relevant natural assemblages are not available.Symbols a J i activity of component i in phase J - G1, T standard free energy change of reaction (cal) - GIM free energy of ideal mixing (cal) - GEM free energy of excess mixing (cal) - G M ex free energy of mixing (cal) - G i excess free energy of mixing at infinite dilution (cal) - i J activity coefficient of component i in phase J - i J, 0 standard chemical potential of component i in phase J (cal) - ; i J chemical potential of component i in phase J (cal) - R universal gas constant (1.98717 cal/K·mol) - T temperature in degree (K) - WJ interchange free energy of phase J in (cal) - X J i mole fraction of component i in phase J  相似文献   

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