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1.
广东河台金矿尾矿库金属硫化物环境地球化学效应   总被引:4,自引:0,他引:4  
对河台金矿尾矿库中尾矿、尾水及生长植物进行采样分析,研究了尾矿库剖面中金属硫化物的环境地球化学效应,结果显示金属硫化物的化学风化作用呈规律性变化,从而导致尾水的pH值降低,游离态重金属离子浓度增加。通过对水生植物凤眼莲和尾矿坝上的植物蜈蚣蕨的分析发现,它们对矿山污染环境中的砷和铜有显著富集作用。  相似文献   

2.
粤北大宝山矿尾矿铅污染迁移及生态系统环境响应   总被引:7,自引:6,他引:7  
粤北大宝山铁多金属矿床的开发给环境带来了严重的危害。采选冶产生的废液及固体废弃物堆积的淋滤酸水,携带浸滤出的大量重金属离子随着酸水排入下游河道,严重影响矿区及酸水流域的生态环境。将矿床—土壤(含河流底泥)—水体—生命体视为统一的生态环境系统,从尾砂、水体、河流底泥、土壤以及食用蔬菜等方面探讨整个环境系统对重金属Pb的环境响应。结果表明:河流水中高Pb含量直接源于尾砂,并受水体pH值的显著影响;河流底泥能够大量聚集水体中的Pb,在高pH值时,相对稳定存在,在水体pH值降低时,Pb会被再次从河流底泥中释放出来,形成河流二次污染;土壤中Pb含量受土壤pH值和土壤粒度的影响;食用蔬菜中Pb的高含量受土壤Pb高含量决定,并受土壤pH值的影响,通过改善农业灌溉水质,提高土壤pH值,可以降低蔬菜重金属Pb含量。  相似文献   

3.
淋洗剂乙二胺四乙酸对重金属污染土工程特性的影响   总被引:1,自引:0,他引:1  
王平  李江山  薛强 《岩土力学》2014,35(4):1033-1040
以重金属铅(Pb2+)污染土和淋洗剂乙二胺四乙酸(EDTA)为研究对象,通过批次试验研究了不同浓度EDTA的淋洗对Pb2+污染土的渗透特性、持水特性、压缩特性、抗剪强度等工程特性的影响,为淋洗修复后土壤的二次利用提供参数支持。基于矿物成分、孔隙结构等微观试验,揭示了土壤工程特性变化的内在机制。研究结果表明,当淋洗剂EDTA浓度从0增加到0.15 mol/L,经淋洗修复后的污染土壤pH值从7.94下降到5.12,渗透系数降低超过一个数量级,黏聚力降低50%以上,而内摩擦角增大,持水性能提高,孔隙比从0.81下降到了0.76。微观试验的结果表明,随着淋洗剂浓度的增大,土壤中的蒙脱石、钠长石和伊利石矿物含量减少,石英矿物含量增加,其中蒙脱石含量从7.87%下降到了0.07%,而石英矿物含量增加了11.09%;淋洗后土壤单位质量进汞量由0.22 ml/g降低到0.15 ml/g,土壤总孔隙体积减少。重金属污染土淋洗修复工程在考虑重金属去除率及经济性指标的同时,还应考虑淋洗剂对土壤工程特性的弱化。  相似文献   

4.
粤北大宝山矿酸性排水中铅元素环境地球化学   总被引:2,自引:0,他引:2       下载免费PDF全文
粤北大宝山铁多金属矿床的开发给环境带来了严重的危害。采选冶产生的酸性排水及固体废弃物堆积的淋滤酸水,携带浸滤出的大量重金属离子流入下游河道,严重影响矿区及酸水流域的生态环境。结果表明,河流水中高Pb含量直接源于尾砂,并受水体pH值的显著影响。河流底泥能够大量聚集水体中的Pb,在水体pH值降低时,相对稳定存在的Pb会被再次从河流底泥中释放出来,形成河流二次污染。土壤中Pb含量受土壤pH值和土壤粒度的影响,食用蔬菜中Pb的高含量由土壤Pb高含量决定,并受土壤pH值的影响,通过改善农业灌溉水质,提高土壤pH值,可以降低蔬菜重金属Pb含量。  相似文献   

5.
中国大陆火山活动对气候与环境影响的研究进展   总被引:1,自引:0,他引:1  
本文简要回顾了我国中、新生代典型中酸性火山活动的气候环境效应的研究进展,重点讨论了新生代长白山天池火山喷发和中生代辽西火山活动对气候环境造成的影响。天池火山气体含量呈现两个相同趋势的旋回式变化,从早到晚,卤化物和H2O呈降低趋势,而硫化物气体呈增加趋势。火山旋回早期富含HF气体导致动物窒息、甚至大批集群死亡;晚期喷出的大量硫化物气体可以形成大规模酸雨和剧毒火山灰云幕,对周围的动植物生长有严重影响。辽西火山气体可分为三种组合,形成酸雨,导致地表温度下降,加速臭氧浓度降低,甚至破坏臭氧层,从而对生物的生存环境造成严重危害。  相似文献   

6.
0 前言 一般而言,矿石的开采和选冶导致大量硫化物矿石及尾矿暴露于地表,改变了矿石原有的物理和化学状态,黄铁矿等硫化物矿物经风化淋滤作用将产生大量的酸性矿山废水,致使周围水体pH值降低,重金属和硫酸盐浓度严重超标,破坏矿区生态环境[1].  相似文献   

7.
为评价红层岩土化学特性对工程的影响,对红层岩土pH值、EC值、碳酸钙、芒硝、石膏等关键物质成分的变化规律进行了试验研究,提出了岩土化学稳定性的工程概念与分析思路,初步建立了pH值、EC值、碳酸钙、芒硝、石膏临界含量等指标组成的红层岩土化学稳定性综合判别标准,将红层岩土分为化学稳定性强、化学稳定性中等、化学稳定性差三类,为红层特殊岩土定量化评价与分类治理提供了参考依据。  相似文献   

8.
矿山固体废物中硫化物经微生物作用形成的酸性矿山排水及其引起的重金属污染是备受关注的环境问题,而岩石和矿石中的方解石能够影响酸性矿山排水的生成和迁移。为了考察方解石对硫化物-微生物氧化作用的影响,开展了系统的模拟实验,利用ICP-AES、XRD、XRF等分析手段,测定了实验溶液的pH值、Eh值、离子浓度和次生沉淀成分。结果表明,在无方解石或方解石含量低时,黄铜矿的微生物氧化过程中,pH值下降、Eh值上升,有多种重金属离子进入溶液,并生成大量黄钾铁矾、自然硫等次生沉淀。添加过量方解石能有效中和氧化过程产生的酸并能显著抑制氧化菌的活动。因此通过添加碳酸盐矿物的方法可使溶液pH调节至微碱性,降低微生物的活性、阻滞铜矿石的氧化,能够有效降低重金属的释放。  相似文献   

9.
为了明晰黏土矿物和盐分浓度在沉积过程中所起的作用及物理机制,选取高岭土、膨润土及两者组成的混合土进行粒径分析试验、沉积试验和Zeta电位测试。结果显示,盐分环境下高岭土和膨润土的平均粒径增大,部分黏粒组向粉粒组转化。高岭土在蒸馏水环境下和盐水环境下,最终都形成土-水的稳定分界面,但是絮凝稳定时间在盐分环境下更短。膨润土在蒸馏水环境下处于稳定的分散体系中,在盐水环境下迅速絮凝沉积。混合土在蒸馏水环境下,上部澄清层和下部沉淀层之间存在土颗粒的悬浮层,且该层的高度最终稳定;盐水环境下,混合土则迅速的发生土水分离。随着NaCl浓度增加,膨润土和高岭土的Zeta电位绝对值降低,因此胶粒组的絮凝行为对平均粒径产生影响,进而影响其沉积特性。  相似文献   

10.
三峡库区大型的赵树岭滑坡区滑坡灾害极为发育。三峡工程蓄水后,水位上升导致原先许多非饱水的松散岩土体处于饱水状态,严重破坏了其稳定性。文章针对该滑坡区内广泛分布的松散岩土的基本类型和特点,设计了4种不同的浸泡环境,进行水-松散岩土相互作用的室内控制试验,通过监测阴离子浸出特征来揭示其化学变化规律。试验结果表明:在不同的pH值、不同的搅拌速度、不同的流速、以及同时改变pH值和搅拌速度的试验环境中,水岩化学作用所浸出的阴离子特征各异。研究结果可以为松散岩土-水化学作用机理研究提供资料,也对赵树岭滑坡体的工程治理具有重要指导意义。  相似文献   

11.
This study presents a laboratory study of the following two aspects: (1) the influence of sea laver treatment acid on the geoenvironmental properties of Ariake Sea tidal mud, and (2) the natural remediation effect on the sea laver treatment acid contaminated Ariake Sea tidal mud caused by the upward seepage of pore water liquid in the mud. Firstly, the mechanisms of the transport of sea laver treatment acid in the Ariake Sea tidal mud and the generation mechanisms of the upward seepage flow in the Ariake Sea tidal mud are discussed. Secondly, a series of one-dimensional laboratory infiltration tests were carried out to investigate the deterioration of the Ariake Sea tidal mud caused by the sea laver acid treatment practice. Test results reveal that the acid treatment practice caused considerable change in the geochemical properties of the mud in terms of increase in sulfide content and decrease in pH value. After the treatment by the sea laver treatment acid, the sulfide content of the mud even exceeded the safe limit value for the benthos, which represents undesirable living condition for benthos. Thirdly, series of laboratory fresh seawater infiltration tests for the deteriorated Iida site mud were conducted to illustrate this natural remediation efficiency. It is found that with the infiltration of the fresh seawater, the sulfide content of the Iida site mud was considerably reduced and pH value increased to an acceptable range for benthos living in the tidal flat mud. With the increase in the infiltration time and the hydraulic gradient, the remediation efficiency could be increased.  相似文献   

12.
《Sedimentology》2018,65(5):1631-1666
Detailed logging and analysis of the facies architecture of the upper Tithonian to middle Berriasian Aguilar del Alfambra Formation (Galve sub‐basin, north‐east Spain) have made it possible to characterize a wide variety of clastic, mixed clastic–carbonate and carbonate facies, which were deposited in coastal mudflats to shallow subtidal areas of an open‐coast tidal flat. The sedimentary model proposed improves what is known about mixed coastal systems, both concerning facies and sedimentary processes. This sedimentary system was located in an embayed, non‐protected area of a wide C‐shaped coast that was seasonally dominated by wave storms. Clastic and mixed clastic–carbonate muds accumulated in poorly drained to well‐drained, marine‐influenced coastal mudflat areas, with local fluvial sandstones (tide‐influenced fluvial channels and sheet‐flood deposits) and conglomerate tsunami deposits. Carbonate‐dominated tidal flat areas were the loci of deposition of fenestral‐laminated carbonate muds and grainy (peloidal) sediments with hummocky cross‐stratification. Laterally, the tidal flat was clastic‐dominated and characterized by heterolithic sediments with hummocky cross‐stratification and local tidal sandy bars. Peloidal and heterolithic sediments with hummocky cross‐stratification are the key facies for interpreting the wave (storm) dominance in the tidal flat. Subsidence and high rates of sedimentation controlled the rapid burial of the storm features and thus preserved them from reworking by fair‐weather waves and tides.  相似文献   

13.
苏北弶港现代潮坪沉积   总被引:6,自引:1,他引:6  
对现代砂泥质潮坪研究,不仅有益于弄清潮汐沉积作用,而且为探讨古潮坪沉积,寻找有关矿产提供依据。近年来我们对弶港潮坪调查研究表明,该潮坪是以古长江和旧黄河组成的三角洲为基础,并在两股强潮流以弶港为顶点辐聚辐散控制下所形成的滩面宽阔,潮沟发育,向海开敞的潮坪。本文着重探讨潮坪不同地貌单元沉积物的特点和相标志。不妥之处,望祈指正。  相似文献   

14.
汪寿松  陈昌明  Irion  G 《沉积学报》1988,6(2):78-96
本文目的在于说明有限区域内潮坪小环境沉积物的矿物学和地球化学特点及沉积过程的改造作用。沉积物样品取自汪额诺格岛与联邦德国的德国湾南岸之间的障壁潮坪。粒度分析表明,障壁潮坪由大体平行于大陆的泥坪、混合坪到砂坪三个带组成。粘土矿物以伊利石为主,其次为蒙脱石、高岭石和绿泥石,与北海粘土矿物组合一致。粘土矿物组成和重金属Fe、Mn、Cu、Pb、Zn含量在潮坪不同部位相差无几,说明沉积物受到潮汐水流反覆侵蚀和再沉积作用的混合作用。近潮口附近有机碳含量增高是潮汐水流从北海通过进潮口携入有机物的结果。  相似文献   

15.
Trace metals (Mn, Fe, Mo, U, Cr, V) were studied in pore waters of an intertidal flat located in the German Wadden Sea. The study system is an example of a permeable tidal flat system where pore water exchange is affected by tidal driven pressure gradients besides diffusion. Permanently installed in situ samplers were used to extract pore waters down to 5 m depth throughout one year. The samplers were either located close to the tidal flat margin or in central parts of the tidal flat. Despite dynamic sedimentological and hydrological conditions, the general trends with depth in deep tidal flat pore waters are remarkably similar to those observed in deep sea environments. Rates of trace metal cycling must be comparably large in order to maintain the observed pore water profiles. Trace metals further show similar general trends with depth close to the margin and in central parts of the tidal flat. Seasonal sampling revealed that V and Cr vary concurrent with seasonal changes in dissolved organic carbon (DOC) concentration. This effect is most notable close to the tidal flat margin where sulphate, DOC, and nutrients vary with season down to some metres depth. Seasonal variations of Mn, Fe, Mo, and U are by contrast limited to the upper decimetres of the sediment. Their seasonal patterns depend on organic matter supply, redox stratification, and particulate matter deposited on sediment surfaces. Pore water sampling within one tidal cycle provides evidence for pore water advection in margin sediments. During low tide pore water flow towards the creekbank is generated by a hydraulic gradient suggesting that deep pore waters may be seeping out of creekbank sediments. Owing to the enrichment of specific elements like Mn in pore water compared to sea water, seeping pore waters may have an impact on the chemistry of the open water column. Mass balance calculations reveal that the impact of deep pore waters on the Mn budget in the open water column is below 4%. Mn deep pore water discharge of the whole Wadden Sea is estimated to be about 9% of the total dissolved riverine Mn input into the Southern North Sea.  相似文献   

16.
江苏圆陀角位于长江北支岸线与江苏海岸线的交汇处,发育了粉砂淤泥质海岸典型潮滩地貌,潮滩岩芯沉积物粒度变化记录了潮滩环境变化的信息。2007年在圆陀角附近潮滩采集了192cm长的柱状岩芯,对沉积物的粒度组成进行了分析,分析结果显示,砂质粉砂是主要的沉积类型,岩芯分为三部分,从下部向上,粗颗粒沉积组分减少,反映了采样点附近潮滩环境由潮滩中部向上部转化的过程。根据岩芯沉积物137Cs的1963年和1986年两个蓄积峰值时标推算,1963年以来的平均沉积速率为2.3cm/a,1986年以来的平均沉积速率为1.6cm/a,1963~1986年之间的平均沉积速率达到2.9cm/a。沉积速率变化表明20世纪60年代以来伴随潮滩淤积增高,圆陀角附近潮滩沉积物的沉积速率下降,大体与辐射沙洲南翼淤积型潮滩淤积速率一致,小于长江口外的泥沙沉积速率。泥沙来源主要是苏北沿岸流携带的部分泥沙在圆陀角附近沉积,伴随研究区围垦活动向海推进,在长江北支口门北侧形成了大片的泥质潮滩和水下沙嘴。  相似文献   

17.
从河北秦皇岛采集的用无水乙醇保存的鸭嘴舌形贝(Lingula anatina)样品中提取了DNA,经PCR扩增后进行克隆,得到了2条长度为682 bp的线粒体细胞色素C氧化酶第I亚基(COI)基因片段。调用GenBank中日本有明海和中国香港的鸭嘴舌形贝同源序列,用邻接法和贝叶斯法构建了系统发育树,结果表明:秦皇岛地区的鸭嘴舌形贝与日本有明海的鸭嘴舌形贝形成姊妹群,具有较近的亲缘关系,与香港的鸭嘴舌形贝亲缘关系较远。初步分析认为西太平洋地区鸭嘴舌形贝现有的地理分布并不是由浮游幼虫的扩散引起的,不同地区鸭嘴舌形贝的差异可能跟地理隔离有关。  相似文献   

18.
中国近海沿岸泥的地球化学特征及其指示意义   总被引:12,自引:5,他引:12       下载免费PDF全文
中国海域辽阔,分为渤海、黄海、东海和南海4个海区。各海区沿中国大陆均有呈斑块状或条带状的泥质沉积分布。选取各沿岸泥的代表性样品,采用先进的XRF和ICP-MS等方法,测定了K、Li、Rb、Cs、Mg、Ca、Sr、Ba、Al、Fe、Ti、Be、Nb、Ta、W、Sn、Bi、La、Ce、Th。元素的地球化学研究表明:渤海和黄海、东海、南海沿岸泥的地球化学特征分别与黄河、长江、珠江沉积物的地球化学特征一致,显示了元素的物源效应;从渤海到南海,由于气候的变化使沿岸泥中某些元素有所流失或富集,显示了元素的气候效应;中国沿岸泥元素的丰度相对接近中国大陆沉积物的丰度,而异于西太平洋褐色粘土和深海粘土的丰度,显示了元素的亲陆性。  相似文献   

19.
晚二叠世龙潭组沉积期是湖北省境内一次重要的成煤时期,由于煤层的不稳定性,其煤层层数、厚度、煤质等存在明显差异。通过岩性、煤层及古生物研究对比,查明龙潭组由下向上共出现5个煤层,煤层的形成与沉积特征明显受岩相古地理条件所制约。在龙潭组沉积期,湖北省境内总体为"两陆夹一盆"的基本格局,形成潮坪-泻湖-障壁岛沉积体系,该沉积体系是华南海北部沉积区的一个组成部分,由秦淮古陆、海湾泻湖及江南古陆组成,沉积区主要为泻湖相和潮坪相单元,其中沼泽亚相为煤层的最佳沉积环境。  相似文献   

20.
Along a 2 km NW-SE transect along the energy gradient of an intertidal sand body of the back-barrier tidal flats of Spiekeroog island (German Wadden Sea, southern North Sea), three sets of closely spaced surface sediment samples were taken at different times to investigate whether the effects of progressive size sorting could be identified in the textural parameters and size-frequency curves of the sediments. Grain-sizes analyses were carried out with a high-resolution settling tube having an internal resolution of 1/50-psi intervals. The settling velocity data were subsequently transformed numerically into equivalent settling diameters on the basis of a quartz sphere standard. At this high resolution, it was possible to visualize subtle changes in textural parameters which would not have been resolved by standard 0.25-phi sieve analyses. The first two sample sets of 1992 and 1994 show similar trends of progressive fining in the sediment, combined with a slight decrease in skewness and sorting in the direction of decreasing energy. Ten years later, in 2003, the sediments were slightly coarser but still reflected the hydrodynamic energy gradient by a distinct fining trend along the transect. However, in contrast to the former data sets, the skewness values now remained constant, whereas the sorting values revealed the existence of two overlapping hydrodynamic energy regimes on the tidal flat. The better sorting in the coarser size fractions and the general coarsening trend in the central part of the tidal flat are interpreted to reflect an increase in the hydrodynamic energy level since the first two sample sets were collected. This observation suggests that some of the finer particles in the grain-size spectrum on the tidal flat were winnowed out by wave action without, however, completely obliterating the former trend. This interpretation is supported by an increase in the frequency and duration of strong winds as recorded by the national weather bureau since the early 1990s. The results of the study demonstrate that the intertidal sediments of the Wadden Sea respond rapidly and sensitively to gradual changes in the hydrodynamic energy regime.  相似文献   

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