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1.
In the coastal aquifers of Kaluvelly （Bengal coast, India）, the over exploitation of the main aquifer （the Vanur sandstone） has created a piezometric depression. Water flows from the sea towards inland. A salinization problem is questioned. The geochemical study was dedicated to major, minor and trace elements as well as isotope ratios （δ^18O, δD, δ^37Cl and ^87Sr/^86Sr）. The catchment comprises a crystalline bedrock hinterland （chamockites） overlaid by sediment. The Vanur and Cuddalore sandstones, the two main layers, are issued from the decay of chamockites upland. The geochemical feature of a water body is linked both to the composition of the hosted rock and the interaction time between water and rock. In the deeper parts of the Vanur aquifer, a mixture with long-residence time groundwaters has been evidenced. These waters can originate from a pocket of water entrapped in the Vanur or from the charnockites downward. No seawater intrusion could be assessed. Piezometric data suggest a possible hydraulic connection between the Cuddalore and the Vanur aquifers. Major, minor element data and isotope ratios do not allow to distinguish between old waters from the different aquifers. Data evidence the heterogeneity of the charnokite formation which is characterized by high Ba contents. On the whole, the two sandstones are depleted compared to charnockites in alkaline and earth-alkaline elements, and enriched in less soluble element such as Th or Zr. Trace elements in groundwaters waters from the chamockite aquifer exhibit a high concentration of Ba as compared to Vanur and Cuddalore waters. As Ba is a soluble element, the concentration of Ba in waters is related to the concentration in the hosted rocks. The Li concentration, slightly higher in Vanur rocks, allows to distinguish waters from the deeper parts of the Vanur aquifer. For insoluble elements such as Ti, the hosted rock signature cannot be seen. The Ti concentration in water samples seems to rely on the reaction progress rather than on the available amount. Trace element data show that waters recovered from chamockites and sandstone aquifers present different geochemical features. The host rock signature can be seen in the chamockite and Vanur aquifers for some alkaline and alkaline-earth elements （mainly Ba and Li）.  相似文献   

2.
In a coastal zone an understanding of the distance of the fresh water–salt water interface and its extension inland is important for prevention of sea water intrusion. In this article estimating methods are described for calculating the distance of a fresh water–salt water interface in a coastal confined aquifer based on the submarine fresh groundwater discharge. This groundwater discharge is controlled not only by the aquifer properties and hydraulic head difference, but also by the position of the fresh water–salt water interface in the coastal zone. A homogeneous and isotropic coastal confined aquifer is considered and fresh groundwater flow in the confined aquifer is thought to be at a steady state. Two observation wells at different distances in a profile perpendicular to the coastline are required in calculation of the distance of the interface toe in the coastal zone. Four coastal confined aquifers with horizontal and sloping confining beds and with varying thickness are also considered. Reasonable results are obtained when examples are used to illustrate the application of the methods. The methods require hydraulic head data at the two wells and thickness of the confined aquifers, but the hydraulic conductivity and fresh groundwater flow rate of the confined aquifers are not needed.  相似文献   

3.
Naturally occurring arsenic （As） in groundwater of sedimentary aquifers has emerged as a global problem, and the Indo-Gangetic Basin of Nepal is no exception. In the sedimentary aquifers of the Indo-Gangetic Basin, arsenic enrichment and mobilization in groundwater by natural processes is considered an issue of major environmental health concern. About 11 million people, 47% of Nepali＇s total population living in the region and approximately 90% of them are relying on groundwater as their major source of drinking water. Moreover, 205555 ha of agricultural land in the basin are irrigated by groundwater through large numbers of deep and shallow irrigation tubewells for extensive cultivation of crops which has lead to creation of other pathways for arsenic ingestion among the people living in the region. It is estimated that around 0.5 million people in the basin are living at risk of arsenic poisoning In addition, some recent research shows the prevalence of dermatosis related to arsenicosis from 1.3% to 5.2 % and the accumulation of arsenic in biological samples like hair and nails much higher than the acceptance level. In these circumstances, the source of the natural arsenic concentration in groundwater of the Indo-Gangetic Basin is quite essential to explore. Therefore, to investigate the source of arsenic and management of arseniferious groundwater used for human consumption and irrigation, along with treatment or avoidance, is clearly an issue of research concern. Present research is carried out to understand the source of natural arsenic and its mobilization in groundwater of the Indo-Gangetic Basin. For this, we have collected bedrock, aquifer sediments and water samples from the study area. Sediment samples were taken from different lithofacies viz. clay, silt, sand and sandy gravels from groundwater aquifer where arsenic concentration is high. Water samples were taken from domestic shallow and deep tubewells in grid pattern. Bedrock samples were collected from source of the aquifer sediment, northern part of the Indo-Gangetic Basin, especially from the Siwalik and Lesser Himalaya. This paper particularly focuses on geology, mineralogy, hydro-geochemistry and sedimentary analysis of the high arsenic affected districts; Rautahat, Sarlahi, Parsa, and Kailali of Nepal.  相似文献   

4.
Groundwater with low total dissolved solids （less than 200 mg/L） occurs in the unconfined and confined aquifers near Beihai in southern Guangxi, China. Under natural conditions the groundwater ranges in pH from 3,33 to 7,0 with an average value of 5.12. The pH in the unconfined aquifer varies from 3.67 to 7.0 with an average value of 5.17 and the pH in the confined aquifer is in the range 3.33-6.97 with an average value of 5.07. The pH in the groundwater does not show significantly increasing or decreasing trends with time. Fluctuations in pH exist at some of the monitoring wells and the pH in groundwater is a bit higher in the rainy season than in the dry season, Monitoring data show that the pH in rainwater is higher than in groundwater in the unconfined aquifer, whereas the pH in the latter is a bit higher than in the confined aquifer. A slightly decreasing trend in the pH was also found from the inland area to the coastal zone. The occurrence of weakly acidic groundwater in this area is attributed to the recharge from low pH precipitation and the multi-aquifer and leaky groundwater system.  相似文献   

5.
TDEM (time domain electromagnetic) traverses in the Dead Sea (DS) coastal aquifer help to delineate the configuration of the interrelated fresh-water and brine bodies and the interface in between. A good linear correlation exists between the logarithm of TDEM resistivity and the chloride concentration of groundwater, mostly in the higher salinity range, close to that of the DS brine. In this range, salinity is the most important factor controlling resistivity. The configuration of the fresh–saline water interface is dictated by the hydraulic gradient, which is controlled by a number of hydrological factors. Three types of irregularities in the configuration of fresh-water and saline-water bodies were observed in the study area: 1. Fresh-water aquifers underlying more saline ones ("Reversal") in a multi-aquifer system. 2. "Reversal" and irregular residual saline-water bodies related to historical, frequently fluctuating DS base level and respective interfaces, which have not undergone complete flushing. A rough estimate of flushing rates may be obtained based on knowledge of the above fluctuations. The occurrence of salt beds is also a factor affecting the interface configuration. 3. The interface steepens towards and adjacent to the DS Rift fault zone. Simulation analysis with a numerical, variable-density flow model, using the US Geological Survey's SUTRA code, indicates that interface steepening may result from a steep water-level gradient across the zone, possibly due to a low hydraulic conductivity in the immediate vicinity of the fault. Electronic Publication  相似文献   

6.
The Denver Basin bedrock aquifer system is an important source of water for municipal and agricultural uses in the Denver and Colorado Springs metropolitan areas. The Denver area is one of the fastest growing areas in the United States with a population of 1.2 million in 1960 that has increased to over 2.4 million by 2000. This rapid population growth has produced a corresponding increase in demand for potable water. Historically, the Denver area has relied on surface water, however, in the past 10 years new housing and recreation developments have begun to rely on groundwater from the bedrock aquifers as the surface water is fully appropriated and in short supply.The Denver Basin bedrock aquifer system consists of Tertiary and Cretaceous age sedimentary rocks known as the Dawson, Denver, Arapahoe and Laramie-Fox Hills Aquifers. The number of bedrock wells has increased from 12,000 in 1985 to 33,700 in 2001 and the withdrawal of groundwater has caused water level declines of 76 m. Water level declines for the past 10 years have ranged from 3 to 12 m per year. The groundwater supplies were once thought to last 100 years but there is concern that the groundwater supplies may be essentially depleted in 10 to 15 years in areas on the west side of the basin.Extensive development of the aquifer system has occurred in the last 25 years especially near the center of the basin in Douglas and El Paso Counties where rapid urban growth continues and surface water is lacking. Groundwater is being mined from the aquifer system because the discharge by wells exceeds the rate of recharge. Concern is mounting that increased groundwater withdrawal will cause water level declines, increased costs to withdraw groundwater, reduced well yield, and reduced groundwater storage. As the long-term sustainability of the groundwater resource is in doubt, water managers believe that the life of the Denver Basin aquifers can be extended with artificial recharge, water reuse, restrictions on lawn watering, well permit restrictions and conservation measures.  相似文献   

7.

Hard rocks or crystalline rocks (i.e., plutonic and metamorphic rocks) constitute the basement of all continents, and are particularly exposed at the surface in the large shields of Africa, India, North and South America, Australia and Europe. They were, and are still in some cases, exposed to deep weathering processes. The storativity and hydraulic conductivity of hard rocks, and thus their groundwater resources, are controlled by these weathering processes, which created weathering profiles. Hard-rock aquifers then develop mainly within the first 100 m below ground surface, within these weathering profiles. Where partially or noneroded, these weathering profiles comprise: (1) a capacitive but generally low-permeability unconsolidated layer (the saprolite), located immediately above (2) the permeable stratiform fractured layer (SFL). The development of the SFL’s fracture network is the consequence of the stress induced by the swelling of some minerals, notably biotite. To a much lesser extent, further weathering, and thus hydraulic conductivity, also develops deeper below the SFL, at the periphery of or within preexisting geological discontinuities (joints, dykes, veins, lithological contacts, etc.). The demonstration and recognition of this conceptual model have enabled understanding of the functioning of such aquifers. Moreover, this conceptual model has facilitated a comprehensive corpus of applied methodologies in hydrogeology and geology, which are described in this review paper such as water-well siting, mapping hydrogeological potentialities from local to country scale, quantitative management, hydrodynamical modeling, protection of hard-rock groundwater resources (even in thermal and mineral aquifers), computing the drainage discharge of tunnels, quarrying, etc.

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8.
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9.
In this study, a groundwater exploration survey was conducted using the DC Resistivity (DCR) method in a hydrogeological setting containing a perched aquifer. DCR data were gathered and an electrical tomography section was recovered using conventional four-electrode instruments with a Schlumberger array and a two-dimensional (2D) inversion scheme. The proposed scheme was tested over a synthetic three-dimensional (3D) subsurface model before deploying it in a field situation. The proposed method indicated that gathering data with simple four-electrode instruments at stations along a line and 2D inversion of datasets at multiple stations can recover depth intervals of the studied aquifer in the hydrogeological setting even if it has a 3D structure. In this study, 2D inversion of parallel profiles formed a pseudo-3D volume of the subsurface resistivity structures and mapped out multiple resistive (>25 ohm·m) bodies at shallow (between 50–100 m) and deep sections (>150 m). In general, the proposed method is convenient to encounter geological units that have limited vertical and spatial extensions in any direction and presents resistivity contrast from groundwater-bearing geologic materials.  相似文献   

10.
The study area is in the southeastern part of the city of Elaz between 38°17–38°43 latitudes and 38°36–39°07 longitudes. Formations of Paleozoic, Mesozoic and Cenozoic age comprise confined and unconfined aquifers. Unconfined aquifers are represented by Na-Cl and Na-HCO3 type waters while confined aquifers are characterized by Ca-HCO3, Mg-HCO3 and Na-HCO3 type waters. Due to sodium pollution, as a result of irrigation from waters of Hazar lake in the plain, as well as intense use of artificial fertilizer and improper storage of animal fertilizers, NH4-N, NO3-N and total PO4-P pollution are detected in waters of the unconfined aquifer. Organic material contents in waters of well nos. S27, S29 and S32 completed in the unconfined aquifer are above 3.5 mg/l of Turkish Standard Institute (TSE), (266) standard. In confined aquifers, total PO4-P pollution in four wells and NH4-N pollution in three wells were observed to be above the TSE (266) standard.  相似文献   

11.
《Applied Geochemistry》2001,16(4):475-488
The usefulness of stable isotopes of dissolved SO4 (δ34S and δ18O) to study recharge processes and to identify areas of significant inter-aquifer mixing was evaluated in a large, semi-arid groundwater basin in south-eastern Australia (the Murray Basin). The distinct isotopic signatures in the oxidizing unconfined Murray Group Aquifer and the deeper reducing Renmark Group confined aquifer may be more sensitive than conventional chemical tracers in establishing aquifer connections. δ34S values in the unconfined Murray Group Aquifer in the south and central part of the study area decrease along the hydraulic gradient from 20.8 to 0.3‰. The concomitant increasing SO4/Cl ratios, as well as relatively low δ18OSO4 values, suggest that vertical input of biogenically derived SO4 via diffuse recharge is the predominant source of dissolved SO4 to the aquifer. Further along the hydraulic gradient towards the discharge area near the River Murray, δ34S values in the unconfined Murray Group Aquifer increase, and SO4/Cl ratios decrease, due to upward leakage of waters from the confined Renmark Group Aquifer which has a distinctly low SO4/Cl and high δ34S (14.9–56.4‰). Relatively positive δ34S and δ18OSO4 values, and low SO4/Cl in the Renmark Group Aquifer is typical of SO4 removal by bacterial reduction. The S isotope fractionation between SO4 and HS− of ∼24‰ estimated for the confined aquifer is similar to the experimentally determined chemical fractionation factor for the reduction process but much lower than the equilibrium fractionation (∼70‰) even though the confined groundwater residence time is >300 Ka years. Mapping the spatial distribution of δ34S and SO4/Cl of the unconfined Murray Group Aquifer provides an indicative tool for identifying the approximate extent of mixing, however the poorly defined end-member isotopic signatures precludes quantitative estimates of mixing fractions.  相似文献   

12.
Chemical and isotopic analyses of groundwater from the carbonated Jurassic aquifers in the Gijón-Villaviciosa basin (Asturias, northern Spain) were carried out. Nine springs were sampled to determine major cations and anions, as well as the stable isotopes of the water molecule (δ2H and δ18O) and sulphate (δ34S) values. Also, δ34S values from gypsum coming both from Triassic rocks and bottom of Jurassic sequence were also determined. The results obtained were used to classify the waters with a genetic criteria in three groups: (1) waters with a high gypsum influence, with sulphate coming from Jurassic gypsum, (2) waters without gypsum influence, where sulphate source could be atmospheric deposition from industrial processes and marine aerosol, and (3) waters with some gypsum influence, in which sulphate origin could be a combination of different sources. In relation to recharge, δ2H and δ18O values were close to those of Global Meteoric Water Line and fit a local line that suggests a meteoric origin. The estimated elevations for spring recharge are in agreement with those obtained from hydrogeological maps.  相似文献   

13.
Groundwater solute transport phenomena typically occur in water-bearing zones with heterogeneous solute dispersive characteristics and/or media hydraulic properties. A radial basis function collocation method (RBFCM)-based numerical method was developed in order to investigate the ability of RBFCM to accurately portray solute transport phenomena under heterogeneous conditions. Simulations were performed for 1-D and 2-D transport scenarios in which scale-dependent dispersivity fields were taken into consideration and compared with available analytical solutions. Different radial basis functions (RBFs) were employed for assessing the sensitivity of the present method on the selected RBFs. The simulation results were also compared with the results of MT3DMS which is a modular three-dimensional transport model with alternative solution schemes including the method of characteristics, the implicit central finite difference and the third order total variation diminishing finite volume. The proposed model was also used to simulate a real case condition where solute transport through a two-layer soil medium had been investigated experimentally. The results showed that RBFCM represented a powerful tool for predicting the solute transport occurrence under heterogeneous conditions with high accuracy.  相似文献   

14.
Analysis of Total Organic Carbon (TOC) and NO3 ? contents in the water at six springs in the province of Malaga (Southern Spain), sampled under different hydrologic conditions, revealed two different hydrochemical behaviour patterns for these natural tracers of infiltration. TOC content increased during every recharge period, following the rapid arrival of water infiltrating through the soil. On the other hand, NO3 ? content only rose during the first flood episodes (normally in autumn), and fell during the winter and spring ones. This difference is consequence of the distinctive biogeochemical kinetics of nitrogen with respect to organic carbon, both in the soil and within the aquifer. Unlike the mineralisation undergone by TOC from the surface to the spring, the NO3 ? ion remains in the aquifer almost unaffected, due to the oxidizing conditions prevailing within the karst medium, which do not allow its denitrification and favour its preservation within the saturated zone. In non-polluted aquifers, TOC and NO3 ? have a common origin in the soil and can be used to determine infiltration processes and the hydrogeological functioning of karst aquifers. Their different hydrochemical evolution provides information about mineralization and degradation processes of organic matter within karst aquifers, which can be used to validate the vulnerability to contamination in this type of medium.  相似文献   

15.
Groundwater, as a precious resource hidden underground, is an important component of the global water system. Transboundary aquifers containing substantial amount of groundwater often carry crucial ecological and social implications. Yet, it is unfortunate that transboundary aquifers have hardly been in the forefront of political and scientific discussions, and have not received due attention by policymakers. This article attempts to summarize the investigation on the eight transboundary aquifers that China shares with the neighboring countries. An overview on the groundwater resources in China, including its distribution, exploitation and challenges is also provided. Hydrogeological condition of the Heilongjiang-Amur River Basin aquifer, which is one of the eight major aquifers, is further elaborated. Cooperative activities carried out by China and Russia on monitoring and management of this aquifer are also presented.  相似文献   

16.
Extensive in-depth research is required for the implementation of natural tracer approaches to hydrogeological investigation to be feasible in mountainous regions. This review considers the application of hydrochemical and biotic parameters in mountain regions over the past few decades with particular reference to the Austrian Alps, as an example for alpine-type mountain belts. A brief introduction to Austria’s hydrogeological arrangement is given to show the significance of fractured hard-rock aquifers for hydrogeological science as well as for water supply purposes. A literature search showed that research concerning fractured hard-rock aquifers in Austria is clearly underrepresented to date, especially when taking the abundance of this aquifer type and the significance of this topic into consideration. The application of abiotic natural tracers (hydrochemical and isotope parameters) is discussed generally and by means of examples from the Austrian Alps. The potential of biotic tracers (microbiota and meiofauna) is elucidated. It is shown that the meiofauna approach to investigating fractured aquifers has not yet been applied in the reviewed region, nor worldwide. Two examples of new approaches in mountainous fractured aquifers are introduced: (1) use of CO2 partial pressure and calcite saturation of spring water to reconstruct catchments and flow dynamics (abiotic approach), and, (2) consideration of hard-rock aquifers as habitats to reconstruct aquifer conditions (biotic approach).  相似文献   

17.
Since industrial revolution, the “greenhouse effect” is one of the most important global environmental issues. Of all the greenhouse gases, CO2 is responsible for about 64% of the enhanced “greenhouse effect”, making it the target for mitigation, so r…  相似文献   

18.
We analyse recent claims of an additional risk of diffusive intrusion by marine organic contamination (OC) into coastal aquifers, and discuss the activity-driven “salt-pump mechanism” which is claimed to accelerate this diffusion. The reported accelerations of transport of OC out of saltwater are far too large to be due to activity effects on simple diffusion. There probably is a small acceleration of diffusion out of saltwater, but there is no direct experimental evidence for this. Possible experimental artefacts are suggested. Larger effects on diffusion in the literature are shown to be not relevant to this problem. Diffusion of suspended OC, present in the experiments, is too slow to be significant; however, this suspended material is shown to have serious implications for the proposed interpretation of the results. Until these results are better understood, no conclusions about any possible environmental implications can be drawn from them.
D. R. LloydEmail: Phone: +353-1-6081726Fax: +353-1-6712826
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19.
Since industrial revolution, the ＂greenhouse effect＂ is one of the most important global environmental issues. Of all the greenhouse gases, CO2 is responsible for about 64% of the enhanced ＂greenhouse effect＂, making it the target for mitigation, so reducing anthropogenic discharge of carbon dioxide attracts more and more attention. Geological sequestration of CO2 in deep saline aquifers is one of the most promising options. But because unknown fractures and faults may exist in the caprock layers which can prevent the leakage of CO2, CO2 will leak upward into upper potable aquifers, and lead to adverse impacts on the shallow potable aquifers. In order to assess the potential effect of CO2 leakage from underground storage reservoirs on fractures and water quality of potable aquifers, this study used the non-isothermal reactive geochemical transport code TOUGHREACT developed by Xu et al to establish a simplified 2-D model of CO2 underground sequestration system, which includes deep saline aquifers, caprock layers, and shallow potable aquifers, and study and analyze the changes of mineral and aqueous components. The simulation results indicated that the minerals of deep saline aquifers and fractures should be mainly composed of aluminosilicate and silicate minerals, which not only enhance the mass of CO2 sequestrated by mineral trapping, but also decrease the porosity and permeability of caprock layers and fractures to prevent and reduce CO2 leakage. The results from deep saline aquifers showed that the mass of carbon dioxide trapped by minerals and solution phases is limited, the rest remained as a supercritical phase, and so once the caprock aquifers have some unknown fractures, the free carbon dioxide phase may leak from CO2 geologic sequestration reservoirs by buoyancy.  相似文献   

20.
In the Jemmel?CZéramdine region, the combined analysis of petroleum well data, seismic reflection profiles, and gravity data show the presence of the Zéramdine fault corridor, which was activated in the Neogene period. Both tectonic activity and fluvio-deltaic sedimentation are the origin of the lithologic and hydrodynamic heterogeneities. Thus, the Zéramdine fault corridor constitutes a limit between two hydraulic systems formed by Miocene sandy reservoir layers. These reservoirs have not been exploited yet and could be new water resources which can extremely benefit the region; only the upper one is exploited in the Jemmel?CBembla and Zéramdine?CBéni Hassen deep aquifers. The wire line logging, seismic reflection, and gravity interpretations show the distribution of the Miocene layers which formed the Sahel Miocene deep aquifers. The Zéramdine fault corridor leads to a spatial variability in number, distribution, depths, and thicknesses of these reservoir layers. In the northern part of the Zéramdine fault corridor, seven layers were highlighted; their thicknesses range between 15 and 105?m. However, in the southern part, only four strata were deposited: their thicknesses vary between 45 and 53?m. The total porosity of the studied aquifers is about 30%.  相似文献   

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