共查询到20条相似文献，搜索用时 78 毫秒
1.
通过高温X射线衍射(XRD)、差热-热重分析、偏振红外光谱和高压拉曼光谱研究了江西大余的蓝柱石的热膨胀行为、稳定性、羟基峰在(010)面上的强度变化及其常温高压拉曼光谱特征。结果表明,蓝柱石在1273K完全非晶化,其热膨胀系数αV为1.2(1)×10-5+0.16(1)T×10-9/K。蓝柱石在750K开始发生分解反应,最大的反应速率发生在1266K。在蓝柱石的(010)面上,羟基吸收峰在光的偏振方向与c轴夹角为70°和250°时最强,在光的偏振方向与c轴夹角为160°和340°时最弱。在常压至12.3GPa的压力范围内,蓝柱石没有发生相变。通过高压拉曼光谱计算得到了蓝柱石的mode Grüneisen参数的算术平均值为0.52(2)、thermal Grüneisen参数为0.64(2)。另外,根据Grüneisen关系式可以求得thermal Grüneisen参数,其值为0.70(6)。 相似文献
2.
The structural stability of manganese titanate MnTiO3 at high pressure was investigated by X-ray diffraction and Raman spectroscopy with diamond anvil cells. Ilmenite-type MnTiO3 is stable at least to 26.6 GPa, and lithium niobate type MnTiO3 reversibly transforms at room temperature to perovskite at 2.0 GPa. Bulk moduli (K300) of ilmenite, lithium niobate and perovskite are 174(4) GPa, 179(8) GPa, and 208(5) GPa, respectively (at fixed first pressure derivative K′ = 4). The Grüneisen parameter γ has been estimated to be 1.28 for ilmenite and 1.75 for perovskite. In ilmenite phase, TiO6 octahedra become more regular with increasing pressure. In perovskite phase structural distortion increases with pressure increase. 相似文献
3.
Bo Li Jingui Xu Dongzhou Zhang Zhilin Ye Shijie Huang Dawei Fan Wenge Zhou Hongsen Xie 《地学前缘(英文版)》2021,12(2)
Epidote is a typical hydrous mineral in subduction zones.Here,we report a synchrotron-based single-crystal X-ray diffraction(XRD)study of natural epidote[Ca1.97Al2.15Fe0.84(SiO4)(Si2O7)O(OH)]under simultaneously high pressure-temperature(high P-T)conditions to~17.7 GPa and 700 K.No phase transition occurs over this P-T range.Using the third-order Birch-Murnaghan equation of state(EoS),we fitted the pressure-volume-temperature(P-V-T)data and obtained the zero-pressure bulk modulus K0=138(2)GPa,its pressure derivative K'0=3.0(3),the temperature derivative of the bulk modulus((?K/?T)P=-0.004(1)GPa/K),and the thermal expansion coefficient at 300 K(α0=3.8(5)×10-5K-1),as the zero-pressure unit-cell volume V0was fixed at 465.2(2)?3(obtained by a single-crystal XRD experiment at ambient conditions).This study reveals that the bulk moduli of epidote show nonlinear compositional dependence.By discussing the stabilization of epidote and comparing its density with those of other hydrous minerals,we find that epidote,as a significant water transporter in subduction zones,may maintain a metastable state to~14 GPa along the coldest subducting slab geotherm and promote slab subduction into the upper mantle while favoring slab stagnation above the 410 km discontinuity.Furthermore,the water released from epidote near 410 km may potentially affect the properties of the 410 km seismic discontinuity. 相似文献
4.
Thermal expansion of kyanite at ambient pressure： An X-ray powder diffraction study up to 1000 ℃ 总被引：3，自引：0，他引：3
The thermal expansion coefficients of kyanite at ambient pressure have been investigated by an X-ray powder diffraction technique with temperatures up to 1000 °C. No phase transition was observed in the experimental temperature range. Data for the unit-cell parameters and temperatures were fitted empirically resulting in the following thermal expansion coefficients: αa = 5.8(3) × 10?5, αb = 5.8(1) × 10?5, αc = 5.2(1) × 10?5, and αV = 7.4(1) × 10?3 °C?1, in good agreement with a recent neutron powder diffraction study. On the other hand, the variation of the unit-cell angles α, β and γ of kyanite with increase in temperature is very complicated, and the agreement among all studies is poor. The thermal expansion data at ambient pressure reported here and the compression data at ambient temperature from the literature suggest that, for the kyanite lattice, the most and least thermally expandable directions correspond to the most and least compressible directions, respectively. 相似文献
5.
Yin Xiulan China Institute of Geo-environmental Monitoring Beijing China Hu Ping Faculty of Earth Sciences China University of Geosciences Wuhan China Northeastern Illinois University Chicago IL USA Li Dien Division of Earth Environmental Sciences Los Alamos National Laboratory Los Alamos NM USA 《中国地质大学学报(英文版)》2004,15(4):355-360
The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献
6.
Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed. 相似文献
7.
MENG Dawei WU Xiuling FAN Xiaoyu ZHANG Zhengjie CHEN Hong MENG Xin ZHENG Jianping 《《地质学报》英文版》2008,82(2):371-376
α-PbO2-type TiO2 （TiO2-Ⅱ） is an important index mineral for ultrahigh-pressure metamorphism. After the discovery of a natural high-pressure phase of titanium oxide with α-PbO2- structure in omphacite from coesite-bearing eclogite at Shima in the Dabie Mountains, China, a nanoscale （〈2 nm） α-PbO2-type TiO2 has been identified through electron diffraction and high-resolution transmission electron microscopy in coesite-bearing jadeite quartzite at Shuanghe in the Dabie Mountains. The crystal structure is orthorhombic with lattice parameters a = 4.58×10-1 nm, b = 5.42×10-1 nm, c = 4.96×10-1 nm and space group Pbcn. The analysis results reveal that ruffle {011}R twin interface is a basic structural unit of α-PbO2-type TiO2. Nucleation of α-PbO2-type TiO2 lamellae is caused by the displacement of one half of the titanium cations within the {011}R twin slab. This displacement reduces the Ti-O-Ti distance and is favored by high pressure. The identification of α- PbO2-type TiO2 in coesite-bearing jadeite quartzite from Shuanghe, Dabie Mountains, provides a new and powerful evidence of ultrahigh-pressure metamorphism at 4--7 GPa, 850℃-900℃, and implies a burial of continental crustal rocks to 130-200 kilometers depth or deeper. The α-PbO2-type TiO2 may be a useful indicator of the pressure and temperature in the diamond stability field. 相似文献
8.
The sphalerite oxidative kinetics under hypergene condition was simulated and studied by means of a mixed flow reactor over a pH range of 1.0 7.8,and at dissolution temperatures from 20 to 55℃,ferric ion concentrations from 1.0×10-5 to 1.0×10-2 mol/L,O 2 flux of 0.5 L/min,and oxidants of ferric ion and O 2.It is indicated that with ferric ion as oxidant,the oxidation rate of sphalerite increases with increasing ferric ion concentration,temperature and decreasing pH value,and under the studied conditions,the dissolution rates of Zn and Cd are approximately identical,with the values of activation energy being 41.75 and 42.51 kJ·mol-1,respectively,suggesting that the oxidation rate of sphalerite is controlled by chemical reactions on mineral surface.However,with O 2 as oxidant,the oxidation mechanism of sphalerite varies with pH value.Oxidation rate decreases with increasing pH value when pH is lower than 5.95,whereas the increase of pH value results in an increase in oxidation rate when pH value is higher than 7.The oxidation rate of sphalerite can be expressed as:R Zn =10 1.1663 [Fe3+] 0 0.154 ·[H+] 0.2659 ·e-41.75/RT or R Cd =10 1.7292 [Fe3+] 0 0.170 ·[H+] 0.2637 ·e-42.51/RT 相似文献
9.
The powder XRD analysis of ringwoodite(γ-Fe2SiO4),which was synthesized in a II-stage anvil high-pressure capsule,was made,Its unit-cell parameter was calculated:a=8.219A,After the refinements,for several cycles,of the oxygen parameter x and the occupancy rate of Si in octahedron site,i.e.,the iversion degree u,the final result is R=0.077,when x=0.379A and u=27.5%,with the structural formula (Fe1.725 Si0.275)VI(Si0.725Fe0.275)IV O4 and atomic distances(Fe,Si)VI-O=2.022 A and (Si,Fe)IV-O=1.836A,Meanwhile,the Moessbauer spectroscopic analysis of the sample was conducted and the results obtained are in good agreement with those of X-ray structural analysis ,This paper focuses on the phase transformation and the properties of bonds of α－Fe2SiO4→γ-Fe2SiO4. 相似文献
10.
LIU Fulai ZHANG Zeming XU Zhiqin YANG Jingsui XU HuifenInstitute of Geology Chinese Academy of Geological Sciences Beijing China 《《地质学报》英文版》2000,74(2):183-189
Study of micro-area chemical compositions indicates that phengite in albite gneiss from hole ZK2304 of the Donghai region has evident compositional zoning. SiO2 and tetrahedrally coordinated Si contents decrease, and Al2O3, AlIV and AlVI contents increase gradually from core to rim. However, K2O, MgO and FeO contents basically remain unchanged from core to rim. According to P-T estimates obtained from geothermometers and barometers, combined with previous experimental data, the core belt (micro-area I) of phengite was formed at T=637-672℃ and P=1.55-1.73 GPa, and the transitional belt (micro-area II) of the phengite were formed at r=594-654℃ and P=1.35-1.45 GPa. Towards the rim belt (micro-area III), the temperature decreased slightly, but the pressure decreased rapidly with r=542-630℃ and P=1.12-1.19 GPa. The P-T evolution path recorded by the compositional zoning of phengite is characterized by significant near-isothermal decompression, revealing that the gneiss has. undergone high-pressure-ultrahi 相似文献
11.
康永尚 《水文地质工程地质》2000,27(2):54-55
流体动力系统是控制油气藏形成和分布的基本单元,在含油气盆地分析中,划分流体动力系统,确定流体动力系统的类型,进而按类型研究不同系统的成藏作用和没气藏分布规律,是指导油气勘探的一条有效途径。而在盆地内进行纵、横向上流体动力系统的划分,是一个基于构造、地层、温度、流体动力和流体化学等方面以及温度－压力关系综合分析的一个十分复杂的资料整理、信息加工和逻辑推理过程,其目的主要是在纵向上把控制油气成藏的不同 相似文献
12.
刘长明 《水文地质工程地质》2000,27(1):36-39
本文通过对洞庭湖地区历年钻孔资料的统计整理,将该区地面以上２０ｍ内地层岩性归类,并依据其在防洪抗洪中的作用,结合防洪工程基础历年险情特征及野外实地调查考证,对洞庭湖地区防洪工程基础稳定性分区评价。针对各分区险情特点,担子了相应的治理对策和整治措施。 相似文献
13.
IGCP 379“岩溶作用与碳循环”在中国的研究进展 总被引：24，自引：1，他引：23
ＩＧＣＰ３７９项“岩溶作用与碳循环”是中国建议并组织实施的,于１９９５～１９９９年执行。作者对１９９５年以来项目的实施情况及其研究进展作了总结,并对每一科学的研究进展作了综述：（１）表夺溶系统碳循环与大气ＣＯ２源汇的主要进展有３方面：扩展了研究地区;揭示了秀层岩溶系统碳循环的运动机制;对表层岩溶作用回收大气ＣＯ２量进行了估算;（２）深部ＣＯ２释放问题的主要进展有;发现了更多的深部ＣＯ２释放带;揭示 相似文献
14.
地下水非线性流动模拟 总被引：9，自引：0，他引：9
代群力 《水文地质工程地质》2000,27(2):50-51,55
本文探讨了非线性地下水流动的规律,对比了两种常用的公式模型,Ｆｏｒｃｈｈｉｍｅｒ及指数型公式,并通过实验证实了Ｆｏｒｃｈｈｉｍｅｒ公式具有更广的适用性。深入探讨了利用达西流有限元及边界元模型进行非线性地下水流动模拟的方法及步骤并提出了一种简便的边界元模拟方法。 相似文献
15.
昆明王大桥房屋地基开裂变形是在脆弱的地质环境条件下,未经工程勘察,盲目大兴土木,破坏生态环境而造成工程危害的典型实例。本文根据该地特殊的环境、破坏性的工程活动及房屋建筑开裂变形后进行勘察所获得的丰富翔实的工程地质资料,对该处房屋建筑变形机理进行了综合性分析研究,并对其发展趋势作出预测。 相似文献
16.
试论华北型煤田立体充水地质结构理论 总被引：4，自引：0，他引：4
根据对华北型煤田剖面、平面和水力内边界的水文地质特征的系统综合分析,本文首次提出了煤矿吉立体充水地质结构的新理论。同时,依据风边界在空间展布的几何形态特征,将其划分为四种基本类型,即点状岩溶陷落柱型内边界,线状断裂（带）、裂隙型内边界,窄条状隐伏露头型内边界和面状裂隙网络（局部面状隔水层变薄区）型内边界。根据四种基本类型的不同形式,介绍了煤矿井不同的复合内边界类型和它们的矿井水文地质特征。文章最后 相似文献
17.
煤炭开发对水土资源的影响及其保护技术 总被引：3，自引：0，他引：3
在分析煤炭开发对水土环境影响和破坏基础上,探讨了产生这些影响的形成机制,进而对保护水土环境的技术途径、工艺流程和技术关键进行了研究。 相似文献
18.
基坑工程井点降水分析计算 总被引：5，自引：0，他引：5
针对目前应用广泛的解析计算方法,本文分析了基坑工程井点降水的特点,按照有限元理论,在考虑不同边界条件、坑内外是否有水力联系等的基础上分析了降水中潜水、承压水地下水水位随时间的下降过程。因这种分析方法可考虑不同的基坑形状、计算边佃条件、井类型、含水层类型等,故具有较强的适用性。 相似文献
19.
复打法沉管灌注桩在长江河漫滩地区的应用 总被引：1，自引：0，他引：1
朱绍卿 《水文地质工程地质》2000,27(4):55-55,58
本文根据工程实例,对复打法管灌注桩在长江河漫滩厚软土地区的应用了介绍,具体介绍了施工工艺和如何保证成桩质量。 相似文献
20.
张高宁 《水文地质工程地质》2000,27(1):26-28
本文分析了常规定值设计法的不足,指出了可靠度设计方法在工程结构设计中的科学性、合理性和经济性,简单论述了可靠度的计算方法,对岩土工程的特点和不确定性的来源进行了分析;最后简要介绍了可靠度分析方法在岩土工程中的应用前景。 相似文献