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1.
淤泥是一种工程性质极差且难以快速固化的土体,通过无侧向抗压强度试验、固结排水三轴剪切试验、微观测试和压汞试验等研究了复合型早强土壤固化剂（composite rapid soil stabilizer,CRSS）固化淤泥的强度发展规律和固化剂掺量对强度的影响,初步探讨了强度增长的微观机制。研究结果表明：CRSS固化淤泥强度随养护龄期呈对数发展规律提高,早期强度发展迅速,养护1 h无侧限抗压强度即可达到3 MPa;随固化剂掺量增加,固化淤泥三轴剪切应力-应变曲线由应变硬化型逐渐向应变软化型发展,破坏偏应力和黏聚力呈线性增大。微观结构表明固化剂水化产物可胶结土颗粒、填充土体孔隙,增强土体整体性;压汞试验结果则进一步通过最可几孔径的联系揭示了固化淤泥黏聚力随固化剂掺量增大而线性增大的机制。CRSS固化淤泥具有显著快硬高强优势,可为抢险救灾、应急道路抢通等淤泥快速固化应用提供理论基础。 相似文献
2.
引入活性MgO-粉煤灰固化材料,采用碳化-固化联合技术处理武汉东湖疏浚淤泥,通过无侧限抗压强度、扫描电镜和压汞试验,研究加压碳化模式、碳化时间、MgO-粉煤灰配比和固化剂掺量等因素下CO2碳化作用对固化淤泥力学性质和微观结构的影响。结果表明：活性MgO-粉煤灰固化淤泥碳化后抗压强度进一步增长,应力-应变关系曲线压密阶段应变缩小;不同固化剂配比的东湖淤泥试样具有不同的最佳加压模式,而加压模式决定了相同碳化时间下固化淤泥CO2吸入量,从而影响碳化-固化淤泥试样抗压强度;活性MgO掺量低时试样抗压强度整体较低,强度随碳化时间增加先增大后减小;MgO掺量较高时,碳化试样强度随碳化时间快速达到较高值,随后增长缓慢。微观分析表明：水碳镁石、球碳镁石和碳酸镁石等镁碳酸盐是碳化-固化联合技术增强淤泥强度的主要原因,其膨胀性和胶结作用促使土体中团粒内孔隙向颗粒间孔隙转化,土体更密实,抗压强度增加。 相似文献
3.
《岩土力学》2021,(5)
引入活性MgO-粉煤灰固化材料,采用碳化-固化联合技术处理武汉东湖疏浚淤泥,通过无侧限抗压强度、扫描电镜和压汞试验,研究加压碳化模式、碳化时间、MgO-粉煤灰配比和固化剂掺量等因素下CO_2碳化作用对固化淤泥力学性质和微观结构的影响。结果表明:活性MgO-粉煤灰固化淤泥碳化后抗压强度进一步增长,应力-应变关系曲线压密阶段应变缩小;不同固化剂配比的东湖淤泥试样具有不同的最佳加压模式,而加压模式决定了相同碳化时间下固化淤泥CO_2吸入量,从而影响碳化-固化淤泥试样抗压强度;活性MgO掺量低时试样抗压强度整体较低,强度随碳化时间增加先增大后减小;MgO掺量较高时,碳化试样强度随碳化时间快速达到较高值,随后增长缓慢。微观分析表明:水碳镁石、球碳镁石和碳酸镁石等镁碳酸盐是碳化-固化联合技术增强淤泥强度的主要原因,其膨胀性和胶结作用促使土体中团粒内孔隙向颗粒间孔隙转化,土体更密实,抗压强度增加。 相似文献
4.
《岩土力学》2020,(5)
引入活性MgO-粉煤灰固化材料,采用碳化-固化联合技术处理武汉东湖疏浚淤泥,通过无侧限抗压强度、扫描电镜和压汞试验,研究加压碳化模式、碳化时间、MgO-粉煤灰配比和固化剂掺量等因素下CO_2碳化作用对固化淤泥力学性质和微观结构的影响。结果表明:活性MgO-粉煤灰固化淤泥碳化后抗压强度进一步增长,应力-应变关系曲线压密阶段应变缩小;不同固化剂配比的东湖淤泥试样具有不同的最佳加压模式,而加压模式决定了相同碳化时间下固化淤泥CO_2吸入量,从而影响碳化-固化淤泥试样抗压强度;活性MgO掺量低时试样抗压强度整体较低,强度随碳化时间增加先增大后减小;MgO掺量较高时,碳化试样强度随碳化时间快速达到较高值,随后增长缓慢。微观分析表明:水碳镁石、球碳镁石和碳酸镁石等镁碳酸盐是碳化-固化联合技术增强淤泥强度的主要原因,其膨胀性和胶结作用促使土体中团粒内孔隙向颗粒间孔隙转化,土体更密实,抗压强度增加。 相似文献
5.
采用磷酸镁水泥（MPC）对铅污染土进行固化/稳定化处理。基于无侧限抗压强度试验、渗透试验和浸出试验,研究了养护龄期和铅含量对污染土固稳性能的影响规律。试验结果表明：固化土的强度随养护龄期增加而增大,渗透系数和浸出浓度减小,7 d龄期的固化土强度和浸出浓度分别为0.36 MPa、1.75 mg/L,均满足环境安全标准;铅含量对固化土的强度及渗透特性的影响均存在临界值,为500 mg/kg。铅含量低于临界值时,固化土的强度随着铅含量的增加而增加,渗透系数随着铅含量的增加而减小。浸出浓度随铅含量的增加而增加,但浸出浓度均低于浸出安全标准。压汞试验结果表明,随养护龄期的增大,固化土孔隙体积减小,铅含量不超过临界值时,固化土孔隙体积随着铅含量的增大而减小。扫描电镜试验结果表明：随着养护龄期的增加,土颗粒团聚化越明显,胶结程度加强;铅含量不超过临界值时,土颗粒团聚体增多。镁钾磷酸盐晶体（MKP）主要通过减少孔径大于0.1 ?m的孔隙体积来影响固化土的渗透特性。 相似文献
6.
进行压汞试验和SEM-EDS试验研究复合改性前后水玻璃加固黄土,分析其孔隙分布特征、颗粒和孔隙形态以及胶结物形态和化学元素含量,探讨宏观力学特性与微观特征的联系。压汞测试结果表明,改性前后加固黄土具有相近的孔隙分布特征,入口孔径主要分布在0.06～8 ?m之间,大、中、小和微孔隙分界值分别为8、2、0.06 ?m,加固时生成的凝胶填充作用不显著。SEM-EDS测试结果表明,改性后黄土仍保持其粒状、架空、接触-胶结结构不变,但加入硅酸钾材料后黄土颗粒表面变得粗糙并吸附有絮状物,EDS数据显示K元素含量随着硅酸钾掺入量的增加而增大,且试样无侧限强度与K元素百分含量正相关。研究还表明,土的颗粒联结强度和结构形态特征是导致黄土宏观力学性质差异的本质原因,在复合改性水玻璃加固黄土时在保持黄土架空孔隙基本不变的前提下,生成的含K凝胶在改变颗粒表面形态的同时强化了骨架颗粒之间的连接强度,从而改善了土体的强度。 相似文献
7.
采用磷酸镁水泥（MPC）对铅污染土进行固化/稳定化处理。基于无侧限抗压强度试验和渗透试验,研究了MPC添加量、水土比对固化污染土强度及渗透特性的影响规律。结果表明,固化土的强度随MPC添加量增加而增大,渗透系数减小;水土比对固化土的强度及渗透特性的影响均存在临界值,为0.45。低于临界值时,固化土的强度随着水土比的增加而增加,渗透系数随着水土比的增加而减小。压汞试验（MTP）结果表明,随MPC添加量的增大,固化土孔隙体积减小,水土比不超过临界值时,固化土孔隙体积随着水土比的增大而减小。扫描电镜试验结果表明,随着MPC添加量的增加,土颗粒团聚化越明显,胶结程度加强;水土比不超过临界值时,土颗粒团聚体增多。镁钾磷酸盐晶体（MKP）主要通过减少孔径大于1 ?m的孔隙体积来影响固化土的强度和渗透特性。 相似文献
8.
进行压汞试验和SEM-EDS试验研究复合改性前后水玻璃加固黄土,分析其孔隙分布特征、颗粒和孔隙形态以及胶结物形态和化学元素含量,探讨宏观力学特性与微观特征的联系。压汞测试结果表明,改性前后加固黄土具有相近的孔隙分布特征,入口孔径主要分布在0.06~8μm之间,大、中、小和微孔隙分界值分别为8、2、0.06μm,加固时生成的凝胶填充作用不显著。SEM-EDS测试结果表明,改性后黄土仍保持其粒状、架空、接触-胶结结构不变,但加入硅酸钾材料后黄土颗粒表面变得粗糙并吸附有絮状物,EDS数据显示K元素含量随着硅酸钾掺入量的增加而增大,且试样无侧限强度与K元素百分含量正相关。研究还表明,土的颗粒联结强度和结构形态特征是导致黄土宏观力学性质差异的本质原因,在复合改性水玻璃加固黄土时在保持黄土架空孔隙基本不变的前提下,生成的含K凝胶在改变颗粒表面形态的同时强化了骨架颗粒之间的连接强度,从而改善了土体的强度。 相似文献
9.
天然硅藻土的应力水平与孔隙空间分布的关系 总被引：4，自引：1，他引：3
采用压汞法研究了不同固结压力作用下具有强结构性的天然沉积硅藻土的微观孔隙入口孔径分布与应力水平的关系。研究结果表明：当应力水平小于固结屈服应力时,具有强结构性的天然沉积硅藻土的微观孔隙入口孔径分布几乎与应力水平无关,而当外加应力水平达到固结屈服压力时,虽然总体孔隙空间体积几乎与天然沉积状态时一样,但其微观孔隙入口孔径分布则发生显著变化。在屈服后阶段,随着应力水平的增大硅藻土的孔隙空间体积逐渐减少,最大孔隙变小,整体孔隙空间的孔径趋于均匀。并对微观结构变化与宏观力学特性的内在联系也进行了初步探讨。 相似文献
10.
疏浚淤泥流动固化处理与流动性试验研究 总被引：1，自引：0，他引：1
疏浚淤泥由于含水率高、强度低、渗透性低等特性,在工程上难以直接利用而往往作废弃处理,造成了资源的浪费和土地的占用。针对我国疏浚施工的特点,基于传统固化方法,提出了将高含水率疏浚淤泥进行流动固化处理,并进行了流动性试验研究。结果表明,固化淤泥拌合物的流动值与初始含水率及固化材料掺量之间均具有良好的线性关系,初始含水率2.5wL是能否进行流动固化处理的临界值。基于影响流动性的两个重要因素,即初始含水率和固化材料掺量,提出了广义水灰比的概念,建立了流动值的预测方法,并对预测公式进行了验证 相似文献
11.
Liu Zhang-Rong Ye Wei-Min Cui Yu-Jun Zhu He-Hua Wang Qiong Chen Yong-Gui 《Acta Geotechnica》2021,16(10):3145-3160
Bentonite pellets are recognized as good buffer/backfill materials for sealing technological voids in high-level radioactive waste (HLW) repository. Compared to that of a traditional compacted bentonite block, one of the most important particularities of this material is the initially discrete pellets and the inevitable heterogeneous porosity formed, leading to a distinctive water retention behaviour. In this paper, water retention and mercury intrusion porosimetry (MIP) tests were conducted on pellet mixture (constant volume), single pellet (free swelling) and compacted block (constant volume) of GMZ bentonite, water retention properties and pore structure evolutions of the specimens were comparatively investigated. Results show that the water retention properties of the three specimens are almost similar to each other in the high suction range (>?10 MPa), while the water retention capacity of pellet mixture is lower than those of the compacted block and single pellet in the low suction range (<?10 MPa). Based on the capillary water retention theory (the Young–Laplace equation), a new concept ‘saturated void ratio’ that was positively related to water content and dependent on pore size distribution of the specimen was defined. Then, according to the product of saturated void ratio and water density in saturated void, differences of water retention properties for the three specimens at low suctions were explained. Meanwhile, MIP tests indicate that as suction decreases, the micro- and macrovoid ratios of pellet mixture and compacted block decrease as the mesovoid ratio increases, while all the void ratios of single pellets increase. This could be explained that upon wetting, water is successively adsorbed into the inter-layer, inter-particle and inter-pellet voids, leading to the subdivision of particles and swelling of aggregates and pellets. Under constant volume condition, aggregates and pellets tend to swell and fill into the inter-aggregates or inter-pellets voids. While under free swelling condition, the particles and aggregates in a single pellet tend to swell outward rather than squeezing into the inter-aggregate voids, leading to the expansion of the pores and even formation of cracks. Results including the effects of initial conditions (initial dry density and fabric) and constraint conditions (constant volume or free swelling) on the water retention capacity and pore structure evolution reached in this work are of great importance in designing of engineering barrier systems for the HLW repository.
相似文献12.
R. S. Sautkin 《Moscow University Geology Bulletin》2014,69(4):267-270
The structural peculiarities of voids in Riphean dolomite are considered. Their filtration and capacitive properties are controlled by a system of fractures and caverns, i.e., by secondary voids. The development of caverns results in a significant increase of the effective volume that is available for hydrocarbons. The study was carried out via the method of penetrant testing of 5-cm samples of a cubic shape. 相似文献
13.
膨胀土强度干湿循环试验研究 总被引：17，自引：2，他引：15
通过南宁地区原状膨胀土干湿循环试验,探讨了膨胀土抗剪强度与含水率、循环次数、循环幅度等循环控制参数的关系。研究结果表明：膨胀土抗剪强度随干湿循环次数增加而衰减,最终趋于稳定,强度稳定值与稳定时所需循环次数均随含水率变化幅度的增加而减小。在此基础上,利用压汞试验测定了膨胀土干湿循环过程中的孔径分布,发现干湿循环对土的粒间联结产生不可逆的削弱,使得土体形成更大的孔隙空间,在高含水率时主要表现为集聚体间孔体积增加,在低含水率时集聚体内孔体积增加,从而降低土的抗剪强度。 相似文献
14.
干湿变化是自然界中土体必然经历的过程,对土体工程性质有重要影响。系统掌握干/湿过程中土结构演化特征,对深入认识土体宏观力学性质有重要意义。基于国内外大量文献资料,着重总结了黏性土在干燥过程、湿化过程和干湿循环过程中微观结构的演化特征,得到了以下几点主要认识:（1）含水率是影响土体微观结构的关键因素之一,在最优含水率干侧制备的土样呈典型的团聚体结构,孔隙分布曲线具有双峰特征,而在湿侧则呈相对均匀的基质结构,孔隙分布曲线呈现单峰特征;（2）在干燥过程中（吸力增加）,到达缩限之前,土体积的减小主要由大的宏观孔隙收缩所致。在不同的吸力区间内,主要受影响的孔隙尺寸是不同的;（3）在湿化过程中（吸力减小）,团聚体内的小孔隙和团聚体间的大孔隙都逐渐增大,且以团聚体内的孔隙增大为主,孔隙结构的演化特征与侧限条件密切相关;（4）在干湿循环过程中,土结构变化并不是完全可逆的,土体产生的累积收缩/膨胀形变量主要来自于宏观孔隙,随着干湿循环次数的增加,土体的体变特性会达到一个平衡状态,可用弹性孔隙比进行描述。除此以外,还总结了土结构观测的常规技术方法,包括SEM、ESEM、MIP和CT技术等。最后针对土结构研究现状,提出了今后的研究重点和方向,主要包括制样新方法、观测新技术、湿化过程的微观结构以及微观结构参数与宏观力学模型相结合等。 相似文献
15.
Tomoko Sato Hiroto Takada Takehiko Yagi Hirotada Gotou Taku Okada Daisuke Wakabayashi Nobumasa Funamori 《Physics and Chemistry of Minerals》2013,40(1):3-10
We have investigated the high-pressure behavior of cristobalite in helium by powder X-ray diffraction. Cristobalite transformed to a new phase at about 8 GPa. This phase is supposed to have a molar volume of about 30 % larger than cristobalite, suggesting the dissolution of helium atoms in its interstitial voids. On further compression, the new phase transformed to a different phase which showed an X-ray diffraction pattern similar to cristobalite X-I at about 21 GPa. On the other hand, when the new phase was decompressed, it transformed to another new phase at about 7 GPa, which is also supposed to have a molar volume of about 25 % larger than cristobalite. On further decompression, the second new phase transformed to cristobalite II at about 2 GPa. In contrast to cristobalite, quartz did not show anomalous behavior in helium. The behavior of cristobalite in helium was also consistent with that in other mediums up to about 8 GPa, where the volume of cristobalite became close to that of quartz. These results suggest that dissolution of helium may be controlled not only by the density (amount of voids) but also by the network structure of SiO4 tetrahedra (topology of voids). 相似文献
16.
考虑体积变化影响的岩石应变软硬化损伤本构模型及参数确定方法 总被引：2，自引：0，他引：2
针对现有岩石损伤模型的局限性与不足,将应力作用下的岩石抽象为空隙、损伤与未损伤材料三部分,以空隙率反映岩石体积或空隙的变化,以损伤变量或损伤因子反映岩石力学性态的改变程度,通过对各部分材料的微观受力及其与宏观应力和应变的关系进行分析,建立了可反映岩石变形过程中体积或空隙变化特性的新型岩石损伤模型;从岩石微元强度合理度量方法研究入手,引进统计损伤理论,建立了可考虑损伤阀值影响的岩石统计损伤演化模型,进而建立了能模拟应变软硬化全过程的岩石统计损伤本构模型,并提出了参数确定方法。该模型不仅能反映岩石应变软硬化特性,而且能反映岩石变形的初期压密和后期扩容的特性。通过实例分析与讨论,表明模型合理与可行。 相似文献
17.
以平煤十三矿二1煤层中受岩浆侵入影响前后的贫瘦煤和无烟煤为研究对象,利用压汞法研究了热变质作用对煤中孔隙发育特征的影响。总结了压汞法测定煤中孔隙的实验原理以及煤中比表面积、孔容及其在不同孔径段分布的计算方法与过程,深入分析了不同样品孔容、比表面积的发育特征及其在不同孔径段的分布规律,并探讨了5.5 nm~350 μm孔径范围内煤中孔隙的分形特征。研究表明:岩浆侵入致使煤中出现大量的新生孔隙,孔容和比表面积都显著增大,但中值孔容孔径、平均孔径减小,说明新生孔隙主要集中在小孔径段。而孔隙的空间分形维数变化规律表明岩浆侵入使煤中孔隙粗糙度增加,孔隙吸附能力增强,粒内孔分布范围增大。 相似文献
18.
The lumpy soil is a by product of the open-pit mining. A composite-lumpy material (in which, the lumps are randomly distributed in the reconstituted soil) is being created due to the degradation of the initial granular structure. In the present study, the compression and failure behaviour of an artificial lumpy material with randomly distributed inclusions are investigated using the finite element method. The computation results show that the stress ratio, defined as the ratio of the volume average stress between the lumps and the reconstituted soil within the inter-lump voids, is significantly affected by both the volume fraction and the preconsolidation pressure of the lumps under an isotropic compression path, while the volume fraction of the lumps plays a minor role under a triaxial compression path. Based on the simulation results, a homogenization law was proposed utilizing the secant stiffnesses. 相似文献
19.
Macroscopic criteria for Green type porous materials with spheroidal voids: application to double porous materials 
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下载免费PDF全文 Combined effects of matrix plastic compressibility and void shape are investigated for ductile porous materials. To this end, a spheroidal volume containing a confocal spheroidal (prolate or oblate) void subjected to uniform strain rate boundary conditions has been first studied. A Green type matrix is chosen as a prototype for investigating effects of plastic compressibility. This is carried out by using a kinematics limit analysis theory from which a closed‐form expression of the macroscopic criterion is established for the considered class of materials. These results are then extended to ductile porous materials made up of a green matrix containing randomly oriented spheroidal voids. In the framework of a two‐step homogenization procedure, the obtained results are implemented to describe the macroscopic behavior of double porous materials involving spherical voids at the microscale and randomly oriented and distributed spheroidal voids at the mesoscale. For validation purpose, the new derived criteria are assessed and validated by comparing their predictions to available upper bounds and numerical data from literature. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
20.
Detection and monitoring of water-filled voids using transient electromagnetic method: a case study in Shanxi, China 总被引：1，自引：0，他引：1
G. Q. Xue J. L. Cheng N. N. Zhou W. Y. Chen H. Li 《Environmental Earth Sciences》2013,70(5):2263-2270
Shanxi Province is a major coal base for the rapid development in China, but heavy production of coal resources has left abundant water-filled voids, creating significant geologic hazards around coal mines. It is necessary to quickly investigate the position and distribution of voids with effective geophysical methods. The feasibility of transient electromagnetic (TEM) method in detecting and monitoring water-filled voids is analyzed using 3D finite-element numerical simulation results as well as a case study in this paper. The case study was mainly to analyze and monitor the conditions around the site of a power transfer station under construction in the west of Shanxi province where many water-filled, mined-out voids existed. Central-loop TEM sounding was carried out three times from January 2010 to April 2011 around the building footprint. The low resistivity abnormal area had been repeatedly located and the survey results showed that the area of voids increased with time, which indicated that the ground at the site was in an unstable and dangerous state. The surveys provided more detailed geological information to the government for further safety arrangement and building re-design. 相似文献