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1.
LA-MC-ICP-MS锆石Hf同位素的分析方法及地质应用   总被引：68，自引：111，他引：68  
本研究利用Thermo Finngan Neptune型多接收等离子质谱和Newwave UP213 激光剥蚀系统对两个国际锆石标准和一个实验室锆石标准进行了系统的测定.测得的TEMORA、GJ1和FM02锆石标准的176Hf/177Hf比值分别为0.282700±64(2SD,N=22),0.282008±25(2SD,N=26)和0.282967±44(2SD,N=27),该结果在误差范围内与文献报道值完全一致.采用不同的剥蚀直径对FM02锆石标准进行了对比测定,结果在误差范围内是一致的.从分析结果来看,GJ1和FM02的Hf同位素比值变化范围较小,是Hf同位素LA-MC-ICP-MS测试的理想标准锆石.文中还对四个不同地区的锆石Hf同位素进行了测定,结合前人研究,对其成因和物质来源进行了初步探讨.  相似文献   

2.
10 μm尺度锆石U-Pb年龄的LA-MC-ICP-MS测定   总被引：13，自引：0，他引：13  
利用激光烧蚀多接收器等离子质谱系统, 采用离子计数器与法拉第接收器同时接收U-Pb同位素的技术, 对4个标准锆石GJ-1, 91500, M257和TEMORA采用10 μm剥蚀斑直径、单点剥蚀模式测定, 得到了(602±3) Ma (n=32)、(1058±3) Ma (n=29)、(561.9±2.5) Ma (n=32)和(414.7±2.3) Ma (n=36)的结果; 对GJ-1和TEMORA采用5 μm剥蚀斑直径、曲线扫描模式测定, 得到(596.9±4.5) Ma (n=22)、(417.9±2.5) Ma (n=32)的年龄, 均与文献参考值在误差范围内一致。10 μm斑径单点剥蚀得到I9801、05SD07-01两个典型变质锆石年龄分别为(426±2) Ma (n=30)、(1815±10) Ma (n=16), 5 μm斑径曲线扫描得到I9801、05SD07-01年龄分别为(427±3) Ma (n=32)、(1789±32) Ma (n=15), 均为其可信年龄结果。利用LA-MC-ICP-MS系统对小颗粒锆石、锆石变质增生边或其他成因增生边进行10 μm尺度内U-Pb定年是可行的。  相似文献   

3.
对同一地区但Re、Os含量不同的一组辉钼矿样品,分别采用电感耦合等离子体质谱(ICP-MS)和负离子热表面电离质谱(NTIMS)对其Re-Os年龄进行了测定比较。结果表明,该组样品的平均Re-Os模式年龄分别为(138.3±4.0)Ma和(141.0±3.6)Ma(2σ,n=9),采用ISOPLOT软件的模式1进行等时线计算,得到等时线年龄分别为(138.6±2.9)Ma(2σ,n=9)和(141.6±1.9)Ma(2σ,n=9),两者在目前水平下的误差范围内基本一致。另外,分别采用ICP-MS和NTIMS对辉钼矿Re-Os年龄国家一级标准物质GBW04435和GBW04436进行了测定,所得的结果吻合也较好。  相似文献   

4.
磷灰石微区原位LA-MC-ICP-MS U-Pb同位素定年   总被引：5，自引：0，他引：5  
利用激光剥蚀多接收器电感耦合等离子体质谱法(LA-MC-ICP-MS), 建立了磷灰石微区原位U-Pb同位素定年新方法, 本文给出了这一新方法的分析流程, 报道了利用这一新方法对5个磷灰石样品的分析结果, 并应用同位素稀释-热电离质谱法(ID-TIMS)对一些样品定年结果进行了验证。磷灰石工作标样SDG的U-Pb同位素年龄: (1596±15) Ma (MSWD=1.5, n=7, LA-MC-ICP-MS), (1602±13) Ma (MSWD=0.578, n=5, ID-TIMS); 某铁矿石中磷灰石的LA-MC-ICP-MS U-Pb同位素年龄: (125±14) Ma (MSWD=0.68, n=25), (124.2±3.5) Ma (MSWD=1.5, n=37); 新疆阿尔金地区片麻岩中磷灰石的LA-MC-ICP-MS U-Pb同位素年龄: (250.8±3.9) Ma (MSWD=8.6, n=26), (245.4±2.9) Ma (MSWD=2.1, n=39)。  相似文献   

5.
报道了赣南安远县路迳金伯利质煌斑岩筒的 Rb-Sr等时线地质年龄 :t=( 3 7.6± 2 .2 ) Ma,初始值 [n( 87Sr) / n( 86Sr) ] i=0 .70 5 17± 0 .0 0 0 12。  相似文献   

6.
宁芜盆地火山作用峰期锆石U-Pb定年和Lu-Hf同位素研究   总被引：1，自引：0，他引：1  
宁芜盆地是长江中下游重要的火山岩盆地之一,发育龙王山、大王山、姑山和娘娘山4期火山喷发旋回。盆地内火山作用峰期的大王山期和姑山期火山喷发旋回的安山岩样品的锆石定年和Hf同位素分析研究表明,大王山组2个安山岩年龄分别为(130.6±1.6) Ma和(132.6±1.8) Ma,姑山组安山岩年龄为(131.7±1.1) Ma,均为早白垩世。锆石176Hf/177Hf比值为0.282 468～0.282 607,εHf(t)集中在-3～-6之间,结合前人的岩石地球化学数据,认为宁芜盆地火山岩源区可能主要为富集地幔,有少量地壳物质的混染。宁芜盆地火山作用峰期岩浆活动是太平洋板块俯冲作用减弱、发生后撤拉张背景下的产物。  相似文献   

7.
广东莲花山岩体位于莲花山断裂带北部, 由规模巨大的侏罗—白垩纪花岗岩组成。本文对莲花山岩体中部进行了系统的岩石学、地球化学、锆石U-Pb同位素和Lu-Hf同位素研究, 获得片麻状花岗岩、细粒黑云母花岗岩和细-中粒黑云母花岗岩的锆石206Pb/238U年龄分别为(142.5±1.5) Ma(MWSD=3.5, N=30)、(138.9±0.6) Ma(MWSD=1.4, N=30)和(145.5±0.7) Ma(MWSD=1.2, N=28), 表明岩体为晚侏罗至早白垩世岩浆活动的产物。地球化学特征显示岩体为偏铝质-弱过铝质(A/CNK=0.97~1.1)、富碱(K2O+Na2O=6.1 wt%~ 8.1 wt%)、富钾(K2O/Na2O=1.4~1.8), 富集Rb、Th、U、K、Pb, 亏损Ba、Ta、Nb、Sr、P、Ti, 与壳源岩浆特征类似。岩体SiO2含量差异较大(69.5 wt%~80.1 wt%), 高硅样品明显经历一定程度的结晶分异, 属于分异的I型花岗岩。所有样品锆石εHf(t)值均为负值(–4.5 ~ –2.0), 在年龄-εHf(t)图中, 均落入球粒陨石演化线和华夏基底演化线之间, 暗示源岩主要为古老壳源基底物质。在此基础上, 结合区域构造-岩浆记录, 本文认为莲花山花岗岩体的形成与古太平洋板片俯冲后撤(roll back)诱发的弧后扩张作用相关。  相似文献   

8.
大兴安岭地区发育大量的玄武安山岩-流纹岩双峰式火山岩。本文通过扎兰屯地区辉绿岩和斑岩脉的研究发现,它们具有明显的岩浆混合作用特征,表明它们是基本同时形成的。锆石原位U-Pb定年结果显示,其中花岗斑岩的锆石有非常一致的早白垩世U-Pb年龄(130±1Ma),而辉绿岩中虽然含有一定的捕获锆石,但岩浆结晶锆石的年龄(124±2Ma)也为早白垩世,表明早白垩世是大兴安岭中生代火山岩形成的重要时期。花岗斑岩的锆石具有正的εHf值(10.3±0.5),其亏损地幔模式年龄为349～568Ma;而辉绿岩中岩浆结晶锆石的εHf值(11.0±1.4)以及亏损地幔Hf模式年龄(…  相似文献   

9.
徐通  张晓团  焦建刚  张红强  贾力 《地质学报》2020,94(12):3607-3624
纸房沟岩片位于勉略构造带略阳地区。通过细致的岩石学和地球化学研究，将纸房沟岩片内的火山岩分为拉斑玄武岩系列（Ⅰ类）和钙碱性火山岩系列（Ⅱ类）。Ⅰ类火山岩稀土配分曲线左倾，富Na贫P，整体具有N- MORB特点，形成于洋脊构造环境。相比Ⅰ类火山岩，Ⅱ类火山岩具有更高的SiO2(49.02％~61.86％)和K2O(0.32％~1.55％)含量，相对亏损Nb、Ta、P和Ti，形成于陆缘弧构造环境。Ⅱ类火山岩锆石Lu- Hf同位素测试结果显示，εHf(t)值主体为负值，介于-8.01~+0.77，表明其主要为古老地壳物质熔融成因。Ⅱ类火山岩LA- ICP- MS锆石U- Pb测年结果为854±3Ma(MSWD=0.12, n=30)、844±4Ma (MSWD=0.03, n=15)，表明纸房沟岩片火山岩结晶时代为新元古代早中期。综合前人成果认为，纸房沟岩片火山岩为新元古代勉略洋盆俯冲的产物，俯冲作用一直持续到800Ma左右，该俯冲过程很可能是对全球性Rodinia超大陆聚合事件的响应。  相似文献   

10.
采用SHRIMP锆石微区U-Pb测年技术,对冈底斯成矿带东段工布江达县亚贵拉铅锌、钼矿区的容矿石英斑岩岩体进行年代学研究，通过对3件含矿石英斑岩样品中单颗粒锆石56个样品点的分析，其206Pb/238U 年龄范围在（110.2±6.8～140.9±1.9）Ma之间，三件样品206Pb/238U 年龄加权平均值分别为128±1.0Ma (n = 20 ,MSWD = 1.3)，129.3±1.3Ma (n = 14 ,MSWD = 1.12)，127.8±1.1Ma (n = 22 ,MSWD = 1.4)。结合前人研究以及本次测年结果认为：(1)含矿石英斑岩岩体侵位年龄在126.7～130.6Ma之间，属于燕山晚期。(2)辉钼矿成矿年龄约为60Ma左右，钼矿矿化发生在岩体侵位之后。(3)亚贵拉铅锌、钼矿矿床属于斑岩型钼矿夕卡岩型-热液脉型铅锌铜银多金属矿床，而非晚石炭世-早二叠世的海底喷流沉积成因矿床。(4)亚贵拉-沙让矿集区矿床的形成得益于燕山晚期和喜山早期的岩体侵位，并与碰撞前（180～65Ma ）及主碰撞期（65Ma-41Ma）的岩浆活动关系密切，属于碰撞前和主碰撞期早期成矿。这一认识对冈底斯的区域找矿具有极其重要的意义。  相似文献   

11.
We describe an in situ method for simultaneous measurement of U–Pb–Hf isotopes and trace element compositions of zircons using a quadrupole and multiple-collector inductively-coupled-plasma mass spectrometer (Q-ICP-MS and MC-ICP-MS, respectively) connected to a single excimer laser-ablation system. A laser-generated zircon aerosol was split behind the ablation cell into two transport tubes via a Y-shaped connector and simultaneously introduced into the two mass spectrometers. Hafnium isotopes were measured on the MC-ICP-MS instrument, while U–Pb ages and trace element compositions were determined using the Q-ICP-MS. The precision and accuracy of this method was evaluated using six well-known and widely used zircon standards (91500, Temora-2, GJ-1, Mud Tank, BR266 and Monastery). Analyses were carried out using spot sizes of 32, 44 and 60 μm. For the 44 and 60 μm spot, the resulting U–Pb ages, Hf isotopic and rare earth element (REE) compositions of these six zircons agree with recommended/reported values within 2σ error. The difference in relative standard deviations (RSD) of 206Pb/238U ages between split-flow measurements and those obtained separately on the Q-ICP-MS is within ～ 20% for 91500, Temora-2 and GJ-1, and ～ 60% for Mud Tank (due to its lower U and Pb concentrations). Our method provides a precise approach for determining the U–Pb age and the Hf isotopic and trace element compositions of zircon within a single ablation event. This is in particular important for analysis of zircons that are small or contain complicated zoning patterns. Finally, the REE composition of zircon BR266 is more homogeneous than other zircons and could be a suitable standard by which to benchmark new standards for microprobe analyses of zircons.  相似文献   

12.
Zircon geochemistry can vary over micrometre scales; therefore, natural reference materials need to be well characterised before being used to calculate trace element mass fractions in unmeasured samples. Moreover, reference material homogeneity needs to be ensured with the accelerating rate of geoanalytical developments to map mineral chemistry at increasingly finer scales. Here, we investigate trace element zoning in four widely used zircon reference materials: 91500, Mud Tank, Temora and Plešovice, as well as zircon crystals from the Mount Dromedary/Gulaga Igneous Complex, Australia. Sub-micrometre resolution focused ion beam scanning electron microscope (FIB-SEM) based time-of-flight secondary ion mass spectrometry (ToF-SIMS) and 5 μm resolution LA-ICP-MS mapping show that trace elements are zoned in all reference materials, though 91500 exhibited the least zonation. We demonstrate that FIB-SEM-based ToF-SIMS can rapidly resolve variations in trace elements (e.g., U, Th, Sc, Y, Gd, Dy, Yb and Li) at sensitivities down to the μg g-1 level with a spatial resolution of 195 nm for areas 100 × 85 μm to 959 × 828 μm. Zircon 91500 is recommended for future quantitative analyses provided that (1) the spatial distribution of elements is imaged before analysis of unknown samples and (2) it is used in conjunction with a doped glass as the primary reference material.  相似文献   

13.
Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ18O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ18O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ18O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ18O values associated with low‐U zircon grains.  相似文献   

14.
Zircon megacrysts from the Mud Tank carbonatite, Australia, are being used in many laboratories as a reference material for LA‐ICP‐MS U‐Pb dating and trace element measurement, and LA‐MC‐ICP‐MS determination of Hf isotopes. We summarise a database of > 10000 analyses of Mud Tank zircon (MTZ), collected from 2000 to 2018 during its use as a secondary reference material for simultaneous U‐Pb and trace element analysis, and for Hf‐isotope analysis. Trace element mass fractions are highest in dark red‐brown stones and lowest in colourless and gem‐quality ones. Individual unzoned grains can be chemically homogeneous, while significant variations in trace element mass fraction are associated with oscillatory zoning. Chondrite‐normalised trace element patterns are essentially parallel over large mass fraction ranges. A Concordia age of 731.0 ± 0.2 Ma (2s, n = 2272) is taken as the age of crystallisation. Some grains show lower concordant to mildly discordant ages, probably reflecting minor Pb loss associated with cooling and the Alice Springs Orogeny (450–300 Ma). Our weighted mean 176Hf/177Hf is 0.282523 ± 10 (2s, n = 9350); the uncertainties on this ratio reflect some heterogeneity, mainly between grains. A few analyses suggest that colourless grains have generally lower 176Hf/177Hf. MTZ is a useful secondary reference material for U‐Pb and Hf‐isotope analysis, but individual grains need to be carefully selected using CL imaging and tested for homogeneity, and ideally should be standardised by solution analysis.  相似文献   

15.
There is a growing need for new zircon reference materials for in situ Hf-isotope analysis by laser ablation-multicollector inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS). In this contribution we document the results of a preliminary investigation of seven natural zircons, conducted in order to test their suitability in this regard. Solution MC-ICP-MS data on separated Lu and Hf fractions provided reference compositional data while the results of ca. 750 in situ LA-MC-ICP-MS analyses allowed assessment of potential micrometre-scale heterogeneity. On the basis of these analyses and additional relevant considerations such as availability, size and (Lu)Yb/Hf ratio, we suggest that, of the currently available zircons, Temora-2 and Mud Tank are most likely to provide robust reference materials for Hf isotope determinations both at the present time and into the future. The former has the advantage of also being well-characterised for U-Th-Pb systematics and suitable for in situ age determination, while the latter is the most readily available and is of very large grain size. Additional materials such as BR266, and 91500, although limited in supply, show more consistent Lu/Hf ratios and are thus of use in monitoring elemental fractionation during ICP-MS analysis.  相似文献   

16.
Three samples from the Mud Tank Carbonatite have very similar isotopic ratios, averaging δ13C=‐4.3 and δ18O=+7.5(SMOW). These isotope values are distinct from those of nearby highly metamorphosed Carpentarian marbles, which have marine limestone values of δ13C=‐1.3±0.5, and δ18O=+17.6+0.7 with n=11. Minor variations in the values for the normal marbles show no correlation with stratigraphy or geographic location; however, somewhat lighter oxygen is found in some other marbles known to be affected by low‐temperature fluids within the Woolanga Lineament. Isotopes of C and O, if discretely used in conjunction with other geochemical features, not only may discriminate between deep‐seated carbona‐tites and marbles, but may also help to identify zones of carbonate metasomatism and define the isotopic characters of the fluids.  相似文献   

17.
LA-ICP-MS工作参数优化及在锆石U-Pb定年分析中的应用   总被引：6，自引：4，他引：2       下载免费PDF全文
将激光器(LA)和电感耦合等离子体质谱仪(ICP-MS)联用避免了溶液分析繁琐、耗时的前处理操作,减少了样品制备过程中可能带来的污染,同时又具备分析成本低、测试速度快、分析数据精度高等优势。本文将LA与ICP-MS联接使用,通过激光能量密度和剥蚀频率组合来讨论较低的元素分馏效应,同时匹配RF功率、采样深度、载气及He气流速等主要工作参数以获得较高的元素信号灵敏度和稳定性,从而得到仪器最优工作参数组合,建立了可靠的锆石U-Pb定年方法。通过对锆石标样91500、GJ-1及Ple2ovic互测结果表明,其206Pb/238U加权平均年龄分别为1063.9±6.0 Ma(2σ,n=20)、600.3±2.6 Ma(2σ,n=27)及337.6±1.7 Ma(2σ,n=20),测试结果准确度和精度均在1%范围内,与前人报道的误差范围一致。使用优化后的仪器参数对来自鄂东南铜绿山矿区石英正长闪长玢岩岩体中的实际锆石样品进行测试,获得其206Pb/238U年龄与前人研究结果基本一致,表明本法能准确地对锆石进行定年分析。  相似文献   

18.
In this study, we established a rapid acid digestion for determining Hf–Sr–Nd isotopic ratios of geological samples by using MC-ICP-MS. Conditions of 1600 °C for 1 min and 1400 °C for 1 min were adopted for fusing intrusive rocks and extrusive rocks, respectively. The rapid acid digestion technique is superior in digestion time compared with high-pressure PTFE bomb method. The procedural blanks of the method were also lower than that flux fusion. Replicate analyses of international certified reference materials (CRMs) indicate that isotopic ratios of 176Hf/177Hf, 87Sr/86Sr and 143Nd/144Nd agree well with previously published data. The external reproducibility (2SD, n = 5) of ten CRMs are ±0.000030 for 87Sr/86Sr, ±0.000030 for 143Nd/144Nd, and ±0.000018 for 176Hf/177Hf.  相似文献   

19.
桃溪群混合岩位于南岭东段武夷山褶皱带南段.本文通过采自桃溪附近帽村-田园两个代表性花岗片麻岩样品进行LA-ICP-MS锆石U-Pb 测年获得494～496Ma的结晶年龄,641～657Ma和799Ma两组继承锆石的206Pb/238U 表观年龄.同时对样品FJ-137进行的Hf同位素测定表明其εHf(t)变化于-2.3...  相似文献   

20.
The Hf isotopic composition of zircon reference material 91500   总被引：2，自引：0，他引：2  
Janne Blichert-Toft   《Chemical Geology》2008,253(3-4):252-257
Ten new single zircon fragments, analyzed by solution chemistry and MC-ICP-MS, of the 91500 zircon standard show no evidence to support a recent claim based on in situ data that this reference material is heterogeneous in terms of its radiogenic Hf isotope composition and as a consequence should be abandoned as a reliable interlaboratory standard. Rather, the larger spread in 176Hf/177Hf among in situ data compared with solution chemistry data may reflect the uncertainties resulting from prominent isobaric interference corrections inherent to the in situ analytical protocol. The unweighted mean values of 176Hf/177Hf and 176Lu/177Hf measured for the ten zircon fragments of this study are 0.282313 ± 0.000008 (2σ) and 0.000311 ± 0.000136 (2σ), respectively. Pooling the mean 176Hf/177Hf of this work with those of published solution chemistry studies results in a value of 0.282308 ± 0.000006 (2σ; relative to 176Hf/177Hf = 0.282163 for JMC-475), which is recommended here as the currently best estimate of the Hf isotopic composition of this standard. All published studies agree on a value of ~ 0.0003 for the corresponding 176Lu/177Hf ratio.  相似文献   

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