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1.
A FEM model for analysis of fully coupled multiphase flow, thermal transport and stress/deformation in geological porous media was developed based on the momentum, mass and energy conservation laws of the continuum mechanics and the averaging approach of the mixture theory over a three phase (solid–liquid–gas) system. Six processes (i.e. stress–strain, water flow, gas flow, vapor flow, heat transport and porosity evolution processes) and their coupling effects are considered, which not only makes the problem well-defined, but renders the governing PDEs closed, complete, compact and compatible. Displacements, pore water pressure, pore gas pressure, pore vapor pressure, temperature and porosity are selected as basic unknowns. The physical phenomena such as phase transition, gas solubility in liquid, thermo-osmosis, moisture transfer and moisture swelling are modeled. As a result, the relative humidity and other related variables in porous media can be evaluated on a sounder physical basis. A three dimensional computer code, THYME3D, was developed, with eight degrees of freedom at each node. The laboratory CEA Mock-up test and the field scale FEBEX benchmark test on bentonite performance assessment for underground nuclear waste repositories were used to validate the numerical model and the software. The coupled THM behaviors of the bentonite barriers were satisfactorily simulated, and the effects and impacts of the governing equations, constitutive relations and property parameters on the coupled THM processes were understood in terms of more straightforward interpretation of physical processes at microscopic scale of the porous media. The work developed enables further in-depth research on fully coupled THM or THMC processes in porous media.  相似文献   

2.
微/纳米孔隙内甲烷的运移研究是进行页岩气藏开发预测及评价的前提和基础.页岩中分布大量的微/纳米孔隙,其中干酪根中的纳米级孔隙分布广泛.由于气体在不同尺度孔隙中的运移机理大不相同,且在有机孔中存在明显的吸附/解吸现象.因而,甲烷在页岩中的运移机理仍需完善.本研究综合物理模拟及数学分析方法,对甲烷渗流规律进行研究.研究结果表明:(1)温度升高,单位质量页岩的产量减少,达到平衡的时间缩短,总体体现在甲烷在高温下的吸附/解吸-扩散速率大.(2)相同生产压力下,随入口压力升高,甲烷运移速率增大,达到产量平衡的时间增长.(3)数学模型充分考虑干酪根中甲烷扩散对气体运移过程的影响,并与实验结果及不考虑干酪根影响的模型进行对比分析,结果显示,本文建立的数学模型能更准确地描述甲烷在页岩基质中的运移动态.   相似文献   

3.
杨勇  薛强  李国敏 《岩土力学》2010,31(9):2973-2977
基于流固耦合机制和多孔介质流体动力学理论,根据Landgem产气方程、气体状态方程,结合达西定律、有效应力原理,建立了渗流场-应力场耦合填埋气体运移模型。利用伽辽金方法对模型进行了离散,通过有限元方法对耦合作用下填埋气体压力分布规律进行了数值仿真分析,同时对垃圾填埋变形介质参数以及垃圾降解系数对填埋气体产气量影响进行了定量评价,表明耦合作用下抽气时孔隙结构发生改变,阻滞气体的运移,导致耦合作用较未考虑耦合作用的气体压力低。垃圾填埋气体的产气量小,对变形介质参数和降解系数的定量评价结果表明,垃圾填埋气体的产气量随着渗透系数和降解系数的增大而增加,因此耦合作用不能忽略。这不仅为准确控制气体的挥发与扩散以及气体资源的再利用提供可靠的理论依据,而且对于生态环境的保护和垃圾资源化利用具有重要的理论意义和实际应用价值。  相似文献   

4.
有效开发富油煤提取石油对缓解我国油气紧张具有重要的现实意义,地下原位开采对流加热技术是富油煤有效开发的主要技术之一。以黄陵矿区延安组富油煤层为例,将高温蒸汽和氮气作为加热介质,采用地下原位转化开采对流加热的技术手段,分别研究2种加热介质在不同注入压力下的开采效果与能量回报率。结果表明:当注入气体的温度为400℃时,注蒸汽开采的加热效率更高,相同注入压力下注蒸汽开采将地层干酪根开采完所需要的时间小于注入高温氮气,二者比例为0.52~0.68,节省时间效果明显,注蒸汽开采与注氮气开采的天然气总产量比例为1.07~1.11,油总产量比例为0.82~0.85,二者差值随注入压力的增加而逐渐减小。注蒸汽开采与注氮气开采的能量回报率比例为1.754~2.363,注蒸汽开采注入压力为6 MPa时能量回报率在4.99 a达到峰值1.796,注氮气开采均未达到能量正收益。无论哪种加热介质,增加注入压力都能够缩短加热反应时间,有利于提高注蒸汽能量回报率。注氮气开采的地层流体有效渗透率较高,利于油气在地层中流动。注蒸汽开采在富油煤清洁开采方面具有优越性,为富油煤清洁开采的具体生产过程提供一定的数据参考依据。  相似文献   

5.
In this research, the hydraulic conductivity changes in uniformly graded sands, due to injection pressure increase, were experimentally evaluated using a cell-type radial model. Conducted tests, simulating variation of media permeability at different depths along a recharge well, were monitoring variations of the samples’ hydraulic conductivity at predetermined three different overburden pressures. The startup low pressure inflow was afterward altered by increasing the injection pressure up to the point at which hydraulic conductivity started to change at each run; we called it the threshold injection pressure. The corresponding hydraulic conductivity at such pressure was measured. As the increased permeability was a function of distance to the simulated recharge, it was deemed too beneficial to develop an equation to enable predicting this new hydraulic conductivity at different distances. Findings indicate that in uniformly graded sands under overburden pressure up to 68.64 kPa, the hydraulic conductivity in the threshold injection pressure—compared to its primary amount up to 45 cm from borehole wall—show a remarkable growth. However, this growth rate for greater distances up to 60 cm is negligible. Furthermore, in the threshold injection pressure, the hydraulic conductivity seems not to be time dependent. But, in constant injection pressures above the threshold injection pressure, the hydraulic conductivity shows some sort of time dependency.  相似文献   

6.
非常规油气资源的孔隙结构及其连通性非常复杂,其孔隙尺度从毫米到纳米跨越多个量级.多孔介质中气体的输运过程不仅依赖于介质的多尺度微观结构特征,还依赖于气体的相关属性.气体在多尺度多孔介质中的输运过程包括无滑流、滑脱流和过渡流,涉及分子扩散和努森扩散等多种机制,因此很难用唯一的连续介质理论来描述气体的输运特征.大量的数据表明真实多孔介质中的内部孔隙具有分形标度特征,因此采用分形几何表征多尺度多孔介质的孔隙结构,引入孔隙分形维数和迂曲度分形维数定量表征多孔介质的微结构和弯曲流道,建立多尺度多孔介质气体输运过程的细观模型;推导了多尺度多孔介质中气体的有效渗透率和有效扩散系数,并讨论了多尺度多孔介质微结构参数和气体属性对于气体等效输运特性的定量影响.该研究不仅可以丰富渗流理论,且有利于深入理解非常规油气藏的产出机制.   相似文献   

7.
天然气水合物储量巨大且富含甲烷,被视为21世纪最重要的潜在新型清洁能源之一。天然气水合物大多赋存在海底沉积物的孔隙介质中(少部分赋存于永久冻土层中),对其相变过程受孔隙介质影响规律的系统梳理和总结对未来的勘探开发具有重要意义。本文综合分析前人研究成果,将孔隙介质中天然气水合物的相变过程概化为水合物形成分解时的温压平衡条件变化、速率、稳定性、转化效率以及生长形态、分布状态等;将影响因素分为孔隙介质特性如孔径及粒径、润湿性、导热性能,以及孔隙介质中的物理化学因素如温压和水气条件,并总结了其影响规律和影响机理:(1)孔径及粒径能影响水合物温压平衡条件,较小粒径还能加快水合物相变速率,降低其转化效率。(2)润湿性能够决定水合物的微观生长形态及其与孔隙介质间的接触形式,亲水性强的介质表面能加快水合物的相变速率。(3)孔隙介质导热性能越强,水合物的相变速率越大。(4)温压条件控制下的温压驱动力越大,水合物的相变速率越大,但这种趋势不适用于温压驱动力过大的情形。(5)水气条件影响着水合物相变过程的温压平衡条件、相变速率、稳定性及分布状态。另外,本文分析了目前研究中的不足,并给出了未来的重点研究方向。  相似文献   

8.
Water in the subsurface of the Earth’s cold regions—and possibly the subsurface of Mars—resides in the liquid, vapor, and ice phases. However, relatively few simulations addressing full three-phase, nonisothermal water dynamics in below-freezing porous media have been undertaken. This paper presents a nonisothermal, three-phase approach to modeling water migration in partially frozen porous media. Conservation equations for water (as ice, liquid, and vapor) and a single gas species (in the gas phase and dissolved in water) are coupled to a heat transport equation and solved by a finite-volume method with fully implicit time stepping. Particular attention is given to the method of spatial differencing when the pore space is partially filled with ice. The numerical model is able to reproduce freezing-induced water redistribution observed in laboratory experiments. Simulations of Earth permafrost dynamics and of the formation and evolution of a planetary-scale cryosphere on Mars demonstrate the new capabilities.  相似文献   

9.
Interpretation of carbon dioxide diffusion behavior in coals   总被引:3,自引:1,他引:3  
Storage of carbon dioxide in geological formations is for many countries one of the options to reduce greenhouse gas emissions and thus to satisfy the Kyoto agreements. The CO2 storage in unminable coal seams has the advantage that it stores CO2 emissions from industrial processes and can be used to enhance coalbed methane recovery (CO2-ECBM). For this purpose, the storage capacity of coal is an important reservoir parameter. While the amount of CO2 sorption data on various natural coals has increased in recent years, only few measurements have been performed to estimate the rate of CO2 sorption under reservoir conditions. An understanding of gas transport is crucial for processes associated with CO2 injection, storage and enhanced coalbed methane (ECBM) production.A volumetric experimental set-up has been used to determine the rate of sorption of carbon dioxide in coal particles at various pressures and various grain size fractions. The pressure history during each pressure step was measured. The measurements are interpreted in terms of temperature relaxation and transport/sorption processes within the coal particles. The characteristic times of sorption increase with increasing pressure. No clear dependence of the characteristic time with respect to the particle size was found. At low pressures (below 1 MPa) fast gas diffusion is the prevailing mechanism for sorption, whereas at higher pressures, the slow diffusion process controls the gas uptake by the coal.  相似文献   

10.
光纤位移传感器在盐岩地下储气库群模型试验中的应用   总被引:3,自引:0,他引:3  
段抗  张强勇  朱鸿鹄  向文  蔡兵  许孝滨 《岩土力学》2013,34(Z2):471-476
为了研究盐岩地下储气库群运行过程中注采气压变化对洞周围岩变形的影响,设计开发了一种基于光纤布拉格光栅技术的棒式光纤位移传感器,并将其成功应用在盐岩地下储气库群模型试验的位移监测中。试验结果表明,注采气压速率是影响盐岩储气库运营安全的重要因素。采气过程中洞周出现径向收敛位移,该位移随采气速率和时间的增加而增加;注气过程中洞周出现扩张位移,该位移随注气速率和时间的增加而增加。空间上,气压变化对洞腔腰部位移影响最大。为了保证储气库运行安全,应控制注采气速率。针对所研究工程原型,建议储气库的最大采气速率应小于0.65 MPa/d,最大注气速率应小于0.75 MPa/d。  相似文献   

11.
In the development of oil and gas reservoirs, the transport of miscible fluids in porous rocks is a key issue for oil and gas recovery. The simplified unidirectional flow model is employed to investigate the effects of the viscosity ratio on dispersion in semi-infinite homogenous media. The viscosity is supposed to be unsteady due to changing component concentration over time. In cases of both a viscosity ratio larger and less than 1, the pollutant concentration and flow velocity are computed at different initial conditions and viscosity ratios. The analytical solutions are then developed by introducing new variables and transforming the equation governing advection–diffusion equation in semi-infinite homogeneous media with a continuous source. A comparison of the numerical solution with the analytical solution revealed a similarity over 98%, highlighting the usability of the analytical solution. If the viscosity ratio is larger than 1, flow velocity declines exponentially and concentration attenuates with transporting time. In addition, the timescale plays a significant role and the effects become more prominent in long-term transport. In the case of a viscosity ratio less than 1, both the timescale and viscosity ratio variables have little influence on the changing speed of the concentration profile. This work helps to predict the position and the time required to reach the harmless pollutant concentration when monitoring fracturing fluids transportation into groundwater system and would be especially useful in designing and interpreting laboratory experiments studying the miscible flow.  相似文献   

12.
冰点下水合物在多孔介质的生成是一个复杂的多相转化过程,为了研究冰点下多孔介质中水合物生成过程的水相转化率、气体消耗量与稳定压力等生成特性,在定容条件下,进行不同孔径与粒径的多孔介质中甲烷水合物在冰点下的生成实验。所使用的多孔介质平均孔径为1295 nm、1796 nm和3320 nm。研究结果表明:水合物生成结束时水的转化率随着初始生成压力的增大而增大,随着温度的升高而降低,随着孔径的增大而增大;在相同的孔径下,多孔介质粒径的增大降低了水合物的生成速率但对最终气体消耗量没有影响;在相同的温度下,随着初始生成压力的增大,实验最终压力、气体消耗量与最终水的转化率均随之升高;温度越高,不同的生成初始生成压力下体系的最终稳定压力与水的转化率相差越大;在多孔介质的毛细管作用力与结合水的共同作用下,冰点下水合物生成的水的转化率会大大地降低。在本实验条件下,水相转化为水合物的比例最高为32.39%。  相似文献   

13.
Conventional and non-conventional flotation for mineral processing and for water (and wastewaters) treatment and reuse (or recycling) is rapidly broadening their applications in the mining field. Conventional flotation assisted with microbubbles (30–100 μm) finds application in the recovery of fine mineral particles (< 13 μm) and flotation with these fine bubbles is being used as a solid/liquid separation to remove pollutants. The injection of small bubbles to conventional coarse bubbles flotation cells usually leads to general improvements of the separation parameters, especially for the ultrafines (< 5 μm) ore particles. Results obtained are believed to occur by enhancing the capture of particles by bubbles, one of the main drawbacks in fine ore flotation. It is believed that by decreasing the bubble size distribution (through the injection of small bubbles), increases the bubble surface flux and the fines capture. DAF or dissolved air flotation with microbubbles, treating water, wastewater and domestic sewage is known for a number of years and is now gradually entering in the mining environmental area. This technology offers, in most cases, advantages over settling, filtration, precipitation, or adsorption onto natural and synthetic adsorbents. The targets are the removal of oils (emulsified or not), ions (heavy metals and anions) and the reuse or recirculation of the process waters. Advantages include better treated water quality, rapid start up, high rate operation, and a thicker sludge. New applications are found in the mining vehicles washing water treatment and reuse, AMD (acid mining drainage) neutralization and high rate solids/water separation by flotation with microbubbles. This work reviews some recent applications of the use of microbubbles to assist the recovery of very small mineral particles and for the removal of pollutants from mining wastewaters. Emphasis is given to the design features of innovative devices showing the potential of conventional and unconventional DAF flotation.  相似文献   

14.
盐穴具有良好的稳定性和密闭性,是储存天然气、石油、氢气等的理想场所。传统水溶造腔采用的油垫阻溶存在阻溶效果差、卤水油污重等问题,无法满足绿色矿山建设要求。气垫作为一种替代品备受关注,但因其起步较晚、控制难度大,加之我国复杂的盐层地质条件,阻碍着其推广应用。为此,首先分析了不同造腔阶段气垫控制特点,然后在对气-液界面处压力平衡分析的基础上提出了不同阶段气垫厚度预测及注气量计算方法,结合某井建槽期实例给出了建议气垫厚度及其波动范围,探明了气垫厚度和注气量随造腔推进的变化规律,最后探讨了气垫阻溶应用相关的关键问题。研究结果表明:建槽期及收顶期以气垫厚度控制为主,建腔期及腔体修复阶段则以气-液界面位置控制为主。建议建槽期平均气垫厚度不低于0.3 m,建槽期初期气垫厚度波动迅速,应设置较大的气垫厚度并及时补注氮气,随后气垫厚度波动趋于稳定,补气时间间隔可逐渐拉长。随造腔时间增加,单次补气量越来越大,累计补气量整体呈线性增长。造腔过程中井口气压及气-液界面处气垫压力先增加后线性减小,应实时监测井口气压变化。气垫阻溶与油垫阻溶成本相近但环境效益显著,可重复利用排出氮气及井口注气设施以节约成本。现场应...  相似文献   

15.
To tackle the problem that wells that are deployed in a specific pattern based on the requirements of gas reservoir development are not suitable for gas storage,we have conducted concentrically circular injection and production simulation experiments for gas storage,discovered the existence of a threshold radius,denoted by Rt, and derived the expression for Rt.Based on the analysis and discussion results,we propose a strategy for deploying gas storage wells in specific patterns.The expression for Rt shows that it is affected by factors such as the gas storage gas production/injection time,the upper pressure limit,the lower pressure limit,the bottomhole flow pressure at the ends of injection and production,the and permeability. The analysis and discussion results show that the Rt of a gas storage facility is much smaller than the Rt for gas reservoir development.In the gas storage facilities in China,the Rt for gas production is less than the Rt for the gas injection, and Rt increases with the difference in the operating pressure and with permeability K.Based on the characteristics of Rt,we propose three suggestions for gas storage well pattern deployment:(1)calculate Rt according to the designed functions of the gas storage facility and deploy the well pattern according to Rt;(2) deploy sparser,large-wellbore patterns in high-permeability areas and denser,small-wellbore patterns in high-permeability areas;and (3)achieve the gas injection well pattern by new drilling,and the gas production well pattern through a combination of the gas injection well pattern and old wells.By assessing a gas storage facility with a perfect well pattern after a number of adjustments,we found that the Rt of the 12 wells calculated in this paper is basically close to the corresponding actual radius,which validates our method.The results of this study provide a methodological basis for well pattern deployment in new gas storage construction.  相似文献   

16.
松辽盆地十屋断陷区油气分布复杂,勘探程度高,油田外排污水规模巨大,常规技术处理污水效果不理想。区内4 km以下部分地层呈负压态,若容储介质参数达到相应地质填埋标准,则可在工程实践中尝试应用。结合该区水文及地质资料,建立地下水流及污水污染物迁移数值模拟模型,模拟研究区低压系统入注污水时地下水流动特征及污染物的迁移规律,同时估算了系统空间污水容储量。在预测过程中,分析了断陷区负压形成机制及分布特点,同时结合虚拟粒子示踪及注水过程,对污水的环境影响度进行了预测。研究结果表明,十屋断陷异常低压区是一个天然污水封闭储藏区,系统地层压力梯度仅为0.005~0.008 MPa/m,容储量高达1.241×108 m3,且污染物逃逸概率极小,非常适合油田污水的处置。  相似文献   

17.
High-pressure air injection (HPAI) is a significant enhanced oil recovery (EOR) technology of light oils especially in deep, thin, low-permeability reservoirs. The flow and heat transfer behaviors of compressed air in wellbore is essential to maximize performance of air in EOR. Due to strong compressibility of air and high injection pressure, wellbore temperature and pressure are greatly affected by friction and gas compression. However, the available models of wellbore flow and heat transfer are only accurate for thermal fluid, such as saturated steam and superheated steam, injected at relatively low pressure and high temperature. In this paper, a novel model is proposed to characterize wellbore pressure and temperature distribution for HPAI wells with consideration of dynamic behaviors of injected air. Flow and heat transfer in depth direction are coupled with air properties by iterative technique, and heat transfer in radial direction is treated as steady state in wellbore and transient state in formation. The mathematical model is solved by employing finite difference method and it is validated by field data. Then, integrated analyses of flowing pressure, heat transfer mechanism, and interaction between pressure and temperature are conducted. Results indicate that (1) as well depth increases, temperature difference between formation and air tends to become constant, and the radial heat transfer tends to reach an equilibrium state. The higher the flow rate is, the deeper the equilibrium depth is. (2) Air temperature is dominated by heat transmission from formation at low flow rates and dominated by frictional heat and gas compression effect at high flow rates. Fictional heat begins to affect air temperature at an injection rate beyond the critical value, while gas compression effect can increase air temperature in the whole calculated injection rate range. (3) Interaction between wellbore temperature and pressure is mainly achieved by altering air density. The effect of injection pressure on air temperature can be negligible, while the influence of injection temperature shows strong dependency on injection rate.  相似文献   

18.
煤层CH4解吸效率低、扩散慢的特点严重制约着煤层瓦斯抽采的效率,为解决低透气性煤层瓦斯抽采困难的问题,选取晋城赵庄煤矿煤样,研究不同注气压力对驱替CH4过程的影响以及驱替过程中CH4扩散系数的变化规律,利用自主研发的CO2驱替CH4试验平台,在0.6、0.8、1.0 MPa等不同注气压力条件下分别进行CO2驱替CH4实验。结果表明:驱替压力越大,达到最大CH4排放量的时间越短,CO2突破时间越快,置换效率越大,驱替效果越好;CH4气体驱替过程分为3个阶段,先急剧增加再缓慢增加最后保持平稳;在同一注气压力下,瓦斯扩散系数随时间呈先增大后减小的变化规律,注气压力为0.6、0.8、1.0 MPa时,瓦斯扩散系数的最大值分别为2.27×10-5、3.36×10-5、4.62×10-5 cm2/s。从实验结果可知,不同注气压力下,CO2对CH4主要起到驱替作用、置换吸附-解吸作用及稀释驱替作用;每个阶段的CH4气体运移情况不同,根据实验阶段合理调整注气流量、压力等参数,使注驱技术搭配更高效。研究结果对CO2深埋与瓦斯(煤层气)高效抽采具有理论指导意义。   相似文献   

19.
The feasibility of CO2 storage and enhanced gas recovery (EGR) effects in the mature Altmark natural gas field in Central Germany has been studied in this paper. The investigations were comprehensive and comprise the characterization of the litho- and diagenetic facies, mineral content, geochemical composition, the petrophysical properties of the reservoir rocks with respect to their potential reactivity to CO2 as well as reservoir simulation studies to evaluate the CO2 wellbore injectivity and displacement efficiency of the residual gas by the injected CO2. The Rotliegend sediments of the Altmark pilot injection area exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. The reservoir rock reactivity to CO2 has been studied in autoclave experiments and associated effects on two-phase transport properties have been examined by means of routine and special core analysis before and after the laboratory runs. Dissolution of calcite and anhydrite during the short-term treatments leading to the enhancements of permeability and porosity as well as stabilization of the water saturation relevant for CO2 injection have been observed. Numerical simulation of the injection process and EGR effects in a sector of the Altmark field coupled with a wellbore model revealed the possibility of injecting the CO2 gas at temperatures as low as 10 °C and pressures around 40 bar achieving effective inflow in the reservoir without phase transition in the wellbore. The small ratio of injected CO2 volume versus reservoir volume indicated no significant EGR effects. However, the retention and storage capacity of CO2 will be maximized. The migration/extension of CO2 varies as a function of heterogeneity both in the layers and in the reservoir. The investigation of CO2 extension and pressure propagation suggested no breakthrough of CO2 at the prospective production well during the 3-year injection period studied.  相似文献   

20.
深入探究孔隙尺度下的流体流动特性和溶质运移规律对石油开采、农田养分管理、地下水污染修复有着重要意义。以人工构建的多孔介质结构和同步辐射X射线显微CT扫描的土壤团聚体(分辨率3.7μm)为研究对象,在空间节点数多达64 000 000的情况下,基于格子Boltzmann模型和GPU并行技术计算得到多孔介质流体运动和溶质运移过程的关键参数,并据此探究多孔介质空间异质性对水力学特性的影响。通过对3组不同结构的多孔介质比较发现,结构复杂程度最高的土壤样品和不规则堆叠的圆球结构的渗透率在100 mD(即10^-13m^2)量级,远低于规则堆叠的圆球结构(>20 000 mD);土壤的迂曲度为1.40~1.60,明显高于规则堆叠的圆球结构。研究结果表明,渗透率大的样品具有较小的迂曲度,这与结构的空间异质性有较强的关系;土壤的渗透率和迂曲度呈现各向异性;在水力梯度一定的前提下,渗透率较大的样品,纵向弥散系数也较大;同时,结构的异质性也会影响溶质的穿透曲线。本研究提出的模拟方法可在土壤结构中进行高效的水流运动和溶质运移模拟,可用于土壤多孔介质在孔隙尺度下的水力学特性研究。  相似文献   

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