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1.
银根-额济纳旗盆地原油的发现及其主要地球化学特征 总被引：9，自引：1，他引：9
在银根－额济纳旗盆地东部查干凹陷和西部路井凹陷首次发现了轻质低硫成熟原油，其饱和烃含量在80％以上，非烃和沥青质含量低；饱和烃和芳烃成熟度参数表明它们均为成熟原油，其成熟度相当于镜质相反射率Ro0.8%-1.1%阶段，是生油高峰阶段的产物。原油全油碳同位素δ^13C值小于－31‰。生物标志物中类异戊二烯含量较高，植烷与姥鲛烷均势；查干凹陷原油三环萜烷含量高于五环萜烷，而路井凹陷原油三环萜烷含量相对较低；两原油中均含有较高的Ts,C29Ts,C30重排藿烷和伽马蜡烷，藿烷为主，C32以上升藿烷含量极低；孕甾烷含量较高，尤其是查干凹陷原油；甾烷中以C29甾烷为主，约占50％，C27和C28甾烷基本均势，异胆甾烷含量高于胆甾烷；重排甾烷含量低，甾烷的含量与萜烷含量相当，这些特征表明原油是典型的湖相原油，其主要的烃源岩是下白垩统湖相源岩而非侏罗系煤系烃源岩。 相似文献
2.
综合应用有机碳丰度、岩石热解、碳同位素、生物标志物和有机显微组分等多项指标,对松辽盆地双城凹陷下白垩统营四段烃源岩进行了分析,以揭示该套烃源岩地球化学特征及形成环境,并探讨该凹陷内原油的可能来源.结果显示,营四段烃源岩有机碳(TOC)含量平均为2.97％,有机质类型为Ⅱ型,有机质来源主要为高等植物,其次为层状藻等水生生物,镜质组反射率(Ro)为0.83％～1.10％,处于生油窗内.烃源岩甾烷分布以C27、C29重排甾烷为主,规则甾烷以C29占优势,具有高丰度重排藿烷,伴有早洗脱重排藿烷(C30D/C30H比值平均为0.68,C30E/C30H比值平均为0.32),反映沉积环境为弱氧化-弱还原的淡水半深湖-浅湖.双城凹陷原油为高蜡低硫轻质油,碳同位素平均为?29.69‰,来源于营四段烃源岩,其中登三段原油重排藿烷相对丰度较低,为烃源岩成熟度较低时生成的原油运移成藏;营四段原油重排藿烷相对丰度较高,且其与深度的变化规律与烃源岩基本一致,反映为近源成藏. 相似文献
3.
盐城凹陷凝析油地球化学特征 总被引：3，自引：0，他引：3
运用碳同位素、气相色谱、色谱—质谱、流体包裹体技术，研究了盐城凹陷凝析油地球化学特征，并与永安凹陷永7井凝析油、下扬子海相原油进行了对比。该凝析油碳同位素为-28．8‰—30．5‰，全油色谱中含有一定的长使正构烷烃，Pr/Ph为1．56，三环菇烷含量高，伽玛蜡烷含量低，重排甾烷含量高，C29甾烷＞＞C27甾烷＞C28甾烷。石蜡指数、庚烷值表明原油为高成熟凝析油，甲基菲指数MPI表明原油为未熟—低藏原油，C29甾烷20S／(20S 20R)值表明原油为成熟原油。这种成熟度的差异可能与不同成熟度原油的混合作用有关。油气主要充注时间为6—15Ma。凝析油的主体可能源于泰州组烃源岩，凝析油的形成与蒸发分信作用密不可分。 相似文献
4.
银额盆地查干凹陷原油地化特征及油源对比 总被引：11，自引：1，他引：11
银额盆地东部查干凹陷首次发现轻质低硫成熟原油，其饱和径含量在90％以上，成熟度相当于镜煤反射率Ro1．0％左右，是生油高峰阶段的产物；原油全碳同位素δ^13C值－31．1‰。原油生物标志物中类异戊二烯含量较高，植烷与姥皖烷均势；三环萜烷含量高于五环萜烷；含有较高的TS C29、Ts、C30重排藿烷、伽马蜡烷；藿烷中以C50藿烷为主，C32以上升藿烷含量极低；孕甾烷含量高；甾烷中以C29甾烷为主，C27甾烷含量也较高，异胆甾烷含量高于胆甾烷；重排甾烷含量低；甾烷的含量与萜烷含量相当，是典型的湖相原油。已发现的天然气中甲烷含量达80％，为湿气。原油和源岩生物标志物组成特征分析对比表明下白垩统巴音戈壁组源岩是主要油源岩。生物标志物特征示原油具有一定的运移效应。 相似文献
5.
从普光气田及邻近地区二叠系和下三叠统15个含沥青碳酸盐储集岩样品分步提取了自由态油气组分和油气包裹体组分,并且应用限定体系(金管)热解实验获取了固体沥青热解组分.各组分进一步做色谱和色谱-质谱分析获取了生物标志物组成.分析结果表明,从油气包裹体组分、自由态油气组分至固体沥青热解组分,伽马蜡烷/C31升藿烷比值依次增高.同时油气包裹体组分 C23三环萜烷/(C23三环萜烷+C30藿烷)、C21/(C21+ΣC29)甾烷、C27重排甾烷/(C27重排甾烷+C27规则甾烷)、20S/(20R+20S) C29甾烷和αββ/(ααα+αββ) C29甾烷等成熟度指标与自由态组分相近,而明显高于固体沥青热解组分.根据分子指标,可以推断古油藏的原油来源于不同的烃源岩,早期充注的原油来源于下志留统烃源岩,具有较低的伽马蜡烷含量和较高的成熟度;晚期充注的原油来源于上二叠统烃源岩,具有较高的伽马蜡烷含量和较低的成熟度.固体沥青主要为晚期充注、来源于上二叠统烃源岩的原油裂解生气的产物 相似文献
6.
准噶尔盆地是中国西部典型的多旋回叠合盆地,发育有石炭系、二叠系、三叠系、侏罗系、白垩系和古近系6套烃源岩,同时存在6大类原油和3大类天然气,广泛分布于盆地不同地区。西北缘原油总体相似,碳同位素组成轻(δ~(13)C-29‰),胡萝卜烷、类异戊二烯烷烃、三环萜烷、伽马蜡烷丰富,甾烷以C_(28)、C_(29)为主,基本没有重排甾烷,为第二类原油,来源于二叠系湖相烃源岩。腹部绝大多数原油与西北缘原油相似,但胡萝卜烷、类异戊二烯烷烃、伽马蜡烷等有差异,来源于不同凹陷的二叠系湖相烃源岩;少量原油碳同位素组成重(δ~(13)C-28‰~-26‰),Pr/Ph大于2.5,三环萜烷以C_(19)、C_(20)为主,藿烷丰富而伽马蜡烷极低,以C_(29)规则甾烷及重排甾烷为主,为第四类原油,来源于侏罗系煤系烃源岩。东部存在5种类型原油,第一类原油碳同位素组成特别重(δ~(13)C-26‰),来源于石炭系烃源岩;第二类原油与腹部地区绝大多数原油十分相似,来源于二叠系湖相烃源岩;第三类原油碳同位索组成轻,重排甾烷、Ts、C_(29)Ts及C_(30)重排藿烷异常丰富,来源于中上三叠统湖相烃源岩;第四类原油源于侏罗系煤系烃源岩;混合类原油为二叠系、三叠系、侏罗系原油的混合,各自贡献平均分别为20%、15%和65%。南缘存在4类典型原油,为第二、第四、第五和第六类原油,其中第二、第四类分别源于二叠系和侏罗系;第五类原油碳同位素组成轻(δ~(13)C-29‰)、Pr/Ph1.0、伽马蜡烷丰富且有两个异构体、Ts、C_(29)Ts、C_(30)重排藿烷、C_(27)~C_(29)异胆甾烷及C_(30)甲基甾烷丰富,来源于白垩系湖相烃源岩;第六类原油主要为中低成熟原油,碳同位素组成δ~(13)C~28‰~-26‰,C_(27)、C_(28)、C_(29)甾烷呈"V"型分布,甲藻甾烷异常丰富,来源于古近系湖相烃源岩。准噶尔盆地天然气有油型气、混合气和煤型气,前两类主要来源于二叠系湖相烃源岩和石炭系海相烃源岩,煤型气主要来源于石炭系和侏罗系煤系烃源岩。不同类型油气分布与不同时代烃源灶具有良好对应关系:石炭系油气主要分布于陆东-五彩湾;二叠系油气主要分布于西北缘、腹部与东部;三叠系原油仅分布于东部;侏罗系原油主要分布于东部与南部;白垩系原油仅分布于南缘中部;古近系原油仅分布于南缘西部。按照盆地构造特征及不同时代烃源灶与油气关系,将准噶尔盆地划分为西部、中部、东部、南部及乌伦古5个油气系统及15个子油气系统。 相似文献
7.
塔里木阿瓦提凹陷乌鲁桥油苗地化特征及来源 总被引：1，自引：0，他引：1
阿瓦提凹陷乌鲁桥油苗全油碳同位素较重(-29.4‰)。在甲基菲分布分数图版上落在高成熟油区;甲基菲比值为2.03,高于塔里木盆地现已发现的高成熟凝析油和成熟度较高的原油,表明该油苗的成熟度高。萜烷、甾烷分布具有C29Ts、重排藿烷含量低,伽玛蜡烷丰度较高,中等—高丰度C28甾烷,低重排甾烷等分布特征。这与凹陷及其周缘的石炭系—二叠系、三叠系及中—上奥陶统这三套烃源岩的明显不同,而与寒武系烃源岩相似。综合分析认为乌鲁桥油苗来源于寒武系烃源岩成熟晚期阶段生成的烃类。 相似文献
8.
利用原油与岩样抽提物的族组成分离与定量分析、饱和烃色谱色质、芳烃色谱色质等分析测试资料,系统分析了陇东地区延长组原油的地球化学特征,并研究了原油的成因类型。研究表明,陇东地区延长组原油均为正常油,组分以饱和烃馏分为主;原油的母质来源为低等水生生物与陆源高等植物的双重贡献;形成环境为淡水微咸水的水体环境、弱氧化还原的沉积环境;原油为成熟油,属于烃源岩生烃高峰时期的产物。根据C30重排藿烷的相对含量,可将原油划分为3类,第Ⅰ类原油C30重排藿烷含量最低,第Ⅱ类原油C30重排藿烷含量中等,第Ⅲ类原油C30重排藿烷含量最高。其中第Ⅰ类原油最多,来自于长7油页岩,该类原油分布广泛,白豹、西峰、合水、华庆以及姬塬地区均以该类原油为主;第Ⅱ、Ⅲ类原油样品较少,与暗色泥岩关系密切,零星分布于镇北以北,西峰以东地区。 相似文献
9.
珠江口盆地番禺低隆起轻质原油地球化学特征及其对比研究 总被引：4，自引：1，他引：4
珠江口盆地番禺低隆起轻质原油的密度小于0.83 g/cm3,饱和烃质量分数高(71%～93%),不含沥青质等.从原油族组成、轻烃特征、碳同位素、生物标记化合物等方面综合分析了原油的地球化学特征.轻质原油的姥鲛烷/植烷峰面积比值高(6.1～7.4),碳同位素较重(-27.09‰～-26.48‰)、重排甾烷相对含量较高、重排甾烷/规则甾烷峰面积比值为0.65～0.95,C304-甲基甾烷相对含量较低,双环倍半萜烷相对含量较高,双环倍半萜烷/五环三萜烷峰面积比值为3.33～18.09.研究表明轻质原油的成熟度较高(镜质体反射率Ro＞1.0%),原油母岩的沉积环境为弱氧化条件,母质以陆源高等植物输入为主,细菌和藻类也有少量贡献;运用轻烃参数,金刚烷化合物、生物标记化合物的相对含量和碳同位素值及系列指标进行的油油和油源对比研究表明,轻质原油具有相同母源和成因,油源可能主要为珠江口盆地白云凹陷渐新统恩平组煤系烃源岩. 相似文献
10.
太平洋海底富钴结壳中的烃类有机质及其成因意义 总被引：1，自引：0，他引：1
用气相色谱-质谱(GC-MS)联测方法测定了中西太平洋海底海山富钴结壳中的可溶有机质,对其丰度、生源构成、沉积环境、成熟度等方面进行了初步的探讨.富钴结壳的烃类生物标志化合物大多具成熟烃特征,个别具低成熟烃特点.“A“/C高达9.81～21.15,显示出运移烃的特征;藿烷C31-R(S JR)为0.43～0.46,Tm/(Tm Ts)为0.40～0.59,C30αβ藿烷/(αβ藿烷 βα莫烷)为0.85～0.89,C29αβ藿烷/(αβ藿烷 βα莫烷)为0.81～0.85,c29甾烷20S/(20S 20R)为0.45～0.60,从而计算出Rsc(%)为0.73%～0.81%,个别达到1.06%;C29αββ/(αββ ααα)为0.35～0.42.甾烷丰度顺序为C29甾烷＞C27甾烷＞C28甾烷,同时检出了孕甾烷和4-甲基甾烷,重排甾烷三角图显示该有机质为Ⅱ型.Pr/Ph值介于0.35～0.82,显示植烷优势.说明烃类形成于强还原环境.链状烷烃、类异戊二烯烷烃、萜烷、甾烷化合物的组成和分布都说明茵藻类低等水生生物和陆源高等植物混合生源输入.洋底热液活动是富钴结壳中有机质热演化的重要热源.有机质在特定的海底条件下生成,并被运移到海山上,通过扩散和浸粢由外层进入结壳. 相似文献
11.
马岭油田是鄂尔多斯盆地发现最早的油田之一,也是大陆河流相油气藏的典型代表,可是以往对马岭油田原油及其烃源岩地球化学研究很少,原油的成因更多的依靠于地质推测。本文对采集于马岭油田的21个原油和鄂尔多斯盆地14个烃源岩的烃类生物标志化合物进行了系统的分析,研究了它们的地球化学特征。生物标志化合物的分布和组成特征,指示了原油形成于弱还原环境淡水湖相;原油的母质除了菌藻类外陆源高等植物作出了重要贡献;原油均为成熟原油;油源对比表明,马岭油田原油的源岩为延长组烃源岩,特别是长7油层组烃源岩。 相似文献
12.
Junping Huang Xiangbo Li Qilin Chen Zhanlong Yang Yanrong Wan Lihua Wei Liwen Long Xiaoguang Liu 《中国地球化学学报》2012,31(3):327-339
In the lower parts of oil reservoirs Chang 9 and Chang 10 of the Yanchang Formation are oil-bearing layers newly found in oil exploration in the Ordos Basin.Based on GC,GC-MS analyses of saturated hydrocarbons from crude oils and source rocks,reservoir fluid inclusions and BasinMod,the origin of crude oils,accumulation period and accumulation models are discussed in combination with other petroleum geology data in this paper.The result shows that(1) there are two different types of crude oils in oil reservoir Chang 9 in the Longdong and Jiyuan regions:crude oils of typeⅠ(Well D86,Well A44,Well A75,Well B227,Well X62 and Well Z150) are mainly de-rived from the Chang 7 source rocks(including mudstones and shales) and distributed in the Jiyuan and Longdong regions;those of typeⅡ(Well Z14 and Well Y427),are distributed in the Longdong region,which are derived from the Chang 9 source rocks.Crude oils from oil reservoir Chang 10 in the Shanbei region are mainly derived from the Chang-9 source rocks;(2) there are two phases of hydrocarbon filling in oil reservoir Chang 9 in the Jiyuan and Longdong regions and oil reservoir Chang 10 in the Shanbei region:The first phase started at the early stage of J2z.The process of hydrocarbon filling was discontinuous in the Late Jurassic,because of the tectonic-thermal event in the Ordos Basin.The second phase was the main accumulation period,and hydrocarbons began to accumulate from the late stage of J2a to the middle-late of K1,mainly at the middle-late stage of K1;(3) there exist two types of accu-mulation models in oil reservoirs Chang 9 and Chang 10 of the Yanchang Formation:source rocks of the reservoirs in oil reservoir Chang 9 in the Jiyuan region and oil reservoir Chang 10 in the Shanbei region,the mixed type of reservoirs on the lateral side of source rocks and source rocks of the reservoirs in oil reservoir Chang 9 in the Long-dong region. 相似文献
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14.
Maling oilfield is one of the earliest discovered oilfields in the Ordos Basin. It is also a typical representative of oil reservoirs in fluvial deposits. However, due to the deficiency of geochemical study on the crude oils and source rocks, the interpretation of the oil origin is largely based on the geological situation. Maling crude oils (21) and source rocks (14) from the basin have been systematically analyzed. The distribution of the biomarkers indicates that the crude oils mainly originated from source rocks deposited under a weakly reducing to sub-oxic, freshwater lacustrine environment. Besides algae, higher land plants have also made an important contribution to the source organic matter. Comparison of the distributions of the biomarkers suggests that there is a correlation between the Maling oilfield oils and the source rocks of the Yanchang Formation. 相似文献
15.
The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields. 相似文献
16.
17.
PAUL Philp 《中国地球化学学报》2012,31(3):264-275
Based on the systematic analyses of fifteen typical crude oils and ten typical potential source rocks col-lected from the Qaidam,Tarim and Turpan basins,Northwest China,the geochemical characteristics of the oils and source rocks were investigated and oil-source rock correlations undertaken.The oils and source rocks deposited in saline lacustrine environment from the western Qaidam Basin were characterized by n-alkanes with even car-bon-number preference in the C20-C28 range,low pristane/phytane(Pr/Ph) ratios(less than 0.5),and high abundances of C27 steranes,gammacerane and C35 hopanes.The oils and source rocks deposited in marine environment from the Tarim Basin were characterized by n-alkanes with even carbon-number preference in the C14-C18 range,relatively low Pr/Ph ratios(near to 1),high abundance of C28 steranes,and relatively high gammacerane.In contrast,the oils and source rocks deposited in terrigenous bog environment from the Turpan Basin were characterized by relatively high Pr/Ph ratios(oil samples greater than 6) high abundance of C29 steranes,and relatively low gammacerane and C31-35 hopanes.The higher amounts of C37 and C38 n-alkanes of source rocks from the western Qaidam Basin and the Tarim Basin suggest an origin of these alkanes from functionalized C37 and C38 n-alkadienes and alkenones in prymnesiophytes living in lacustrine and marine environments.Oil-source rock correlations suggest oils in the west-ern Qaidam Basin were derived from the Oligocene Lower Ganchaigou Formation(E3),oils in the Tabei and Tazhong uplifts from the Tarim Basin have a genetic relationship with the Middle-Upper Ordovician source beds.Oils in the Turpan Basin generally fall into two genetic types.Most oils in the Taibei depression from the Turpan Basin were derived from the Lower-Middle Jurassic coal measures,but the fewer oils in this region are a mixed source derived from the Lower-Middle Jurassic coal measure and the Upper Permian source rocks. 相似文献
18.
系统采集鄂尔多斯盆地南部中生界的烃源岩、原油及油砂样品,对其饱和烃和芳烃馏分进行气相色谱-质谱分析,通过 对生物标志物组成特征的研究,分析和探讨中生界原油的油源。结果表明:根据 8β(H)-补身烷和 C3017α(H)-重排藿烷含量, 鄂尔多斯盆地南部中生界原油可划分为I,II,III类。第I类原油 8β(H)-补身烷含量高, C3017α(H)-重排藿烷含量低,来自 深湖相沉积相带的长 7 油页岩 (A1 类),第II类原油 8β(H)-补身烷含量较高, C3017α(H)-重排藿烷含量中等,来自深湖—半深 湖沉积相带的长 7 暗色泥岩 (A2 类),第III类原油 8β(H)-补身烷含量低, C3017α(H)-重排藿烷含量高,来自半深湖沉积相带的 长 7 暗色泥岩 (A3 类),由于采集样品数量限制,第III类原油不排除来自长 8 或长 9 暗色泥岩 (A3 类) 的可能,目前发现的原油 主要是第I类,即各油层组的原油主要是由长 7 油页岩提供的,它是鄂多斯盆地南部中生界的主力烃源岩。 相似文献
19.
各类生物标志物的组成特征表明:柴达木盆地北缘的冷湖油田原油具有姥植比高（Pr/Ph>2.0）,重排甾烷（C27重排甾烷/规则甾烷=0.5~0.7）、重排藿烷（diaC30H/C30H=0.2~0.4）和新藿烷（C29Ts/C29H=0.4~0.7）含量中等,伽马蜡烷含量低（伽马蜡烷指数<0.05）的特征,它们源于该地区发育的下侏罗统淡水湖沼相烃源岩;而柴西北区咸水湖相原油的姥植比低（Pr/Ph<0.8）,重排甾烷（C27重排甾烷/规则甾烷<0.1）、重排藿烷（diaC30H/C30H<0.05）和新藿烷（C29Ts/C29H=0.2~0.4）含量低和伽马蜡烷含量高（伽马蜡烷指数=0.4~0.8）,这一系列特征与柴西地区发育的古近系-新近系咸水湖相烃源岩一致。但是,东坪地区原油呈现完全不同的生物标志物组合,主要表现为丰富的伽马蜡烷（伽马蜡烷指数=1.2~3.0）与高含量的新藿烷（C29Ts/C29H>1.5）、重排藿烷（diaC30H/C30H>0.7）和重排甾烷（C27重排甾烷/规则甾烷>0.4）并存,这与地质样品中伽马蜡烷和重排类标志物的分布特征相矛盾,因为依据现有的认识无法解释这一特殊地球化学现象。生物标志物组成特征表明东坪地区原油所具有的特殊生物标志物组合并非源于不同类型原油之间的混合,而是一种客观存在,尽管其确切的地球化学意义和形成条件目前并不清楚。由此可见,东坪地区原油为柴达木盆地一个新的原油类型,推测其烃源岩可能形成于偏酸性的咸水环境。 相似文献