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太行山北段王安镇岩基超镁铁质岩中角闪石成因意义 总被引：1，自引：0，他引：1
太行山北段中生代岩基中发育有基性-超基性岩体。本文以太行山北段王安镇岩基中的窑沟岩体为研究对象,对橄榄辉石角闪石岩中角闪石的矿物学特征以及形成条件进行初步研究,探讨其成因意义。结果表明,窑沟岩体橄榄辉石角闪石岩中的角闪石属于岩浆成因,并且角闪石环带发育,核部呈棕色,边缘为绿色,两者具有共同的特征,其(Ca+Na)B≥1.00,NaB0.50,均属于钙质角闪石。它们的Si/(Si+Ti+A1)值的范围为0.704 2~0.788 5,属幔源角闪石。Na、K、Ti、Al和Fe3+的相对含量存在差异,其棕色部分为镁绿钙闪石,绿色部分为镁绿钙闪石质普通角闪石以及浅闪石质普通角闪石。角闪石的环带特征反映出同一期岩浆结晶的不同阶段,体现出压力和温度等生成条件的变化。角闪石环带中核部的镁绿钙闪石结晶时温度和压力较高,深度较大,属于下地壳环境;而边缘角闪石在较低压地壳环境生成。角闪石所体现的岩浆来源于上地幔,并且在燕山运动前期的晚三叠世开始集聚,先其周围的中酸性岩体侵位,暗示在晚三叠世华北克拉通岩石圈就已发生部分熔融和华北克拉通破坏的开始。 相似文献
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根据赣南会昌地区中基性火山岩高碱、富钾、低钛、贫铁,岩石中斜长石斑晶具钾长石环边,基质中存在大量钾长石微晶,以及富集轻稀土元素和大离子亲石元素等矿物岩石地球化学特征,确切厘定会昌地区的中基性火山岩为橄榄玄粗岩安粗岩组合,属典型的大陆板内橄榄玄粗岩系列火山岩。对会昌橄榄玄粗岩进行了RbSr同位素定年研究,确定其全岩RbSr等时线年龄为107.3±2.3Ma。 会昌橄榄玄粗岩系火山岩SrONdPb 同位素组成的特征为: 偏高的 ISr(0.7098~0.7115); 较低的δ18O值(5.3‰~7.0‰);中等的εNd(t)(-0.61~-3.60); 富放射性成因铅((206Pb/204Pb)i=17.32~18.29, (207Pb/204Pb)i=15.34~15.65, (208Pb/204Pb)i =37.51~38.60)。会昌橄榄玄粗岩的Δ7/4Pb值为-7.8~+16.8(平均值为+5.42), Δ8/4Pb值为27.3~97.3 (平均值为68.04), ΔSr值为96.2~114.1 (平均值为104.3),这表明存在典型的Dupal 同位素异常。根据SrO, SrNd, SrPb, NdPb, PbPb同位素相关特征, 判明会昌橄榄玄粗岩是由亏损地幔端元(DM)和岩石圈富集地幔端元(EM)在源区混合形成的。按SrNd双变量二元混合模型计算得出源区物质中亏损地幔端元和富集地幔端元所占份额各占50%左右。会昌早白垩世橄榄玄粗岩系火山岩带的形成反映了华南板块内部在燕山晚期发生的一起重要的伸展构造事件 相似文献
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本文对赣南会昌地区赣州群茅店组底部的中基性火山岩的矿物岩石-地球化学进行了系统研究对比。根据岩石具高K_2O/Na_2O值(>1.0)、Na_2O+K_2O(>5％)含量、氧化系数(O_x>0.5),低TiO_2含量(<1％)、SiO_2饱和度(CIPW标准矿物Q<3％),贫铁,以及富集亲石元素(Rb、Sr、Ba、Th等)和轻稀土元素等特征,结合岩石基质中存在大量钾长石微晶、斜长石斑晶具钾长石环边及偶见橄榄石斑晶等矿物学特点,确定会昌地区火山岩属橄榄安粗岩系,岩石为橄榄玄粗岩-安粗岩-粗面岩组合。采用Rb-Sr等时线法厘定火山岩的同位素年龄为108Ma。首次证实在华南板块内部存在中生代橄榄玄粗岩系。 相似文献
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铜陵地区中酸性侵入岩及其包体的成因和矿物温压计的应用 总被引：4，自引：0，他引：4
铜陵地区中酸性侵入岩可划分为橄榄安粗岩系列和高钾钙碱性系列。前者岩石组合为辉石二长闪长岩+二长岩+石英二长岩,后者为辉长闪长岩+石英二长闪长岩+花岗闪长岩。两个系列岩石的组成矿物种类相似,但在不同岩石中的含量不同,主要造岩矿物为斜长石、辉石、角闪石、黑云母、钾长石、石英。橄榄安粗岩系列岩石中含有大量的深源包体,包括辉石堆积岩包体、角闪石堆积岩包体和角闪石辉长质堆积岩包体,主要矿物为辉石、角闪石,其次为尖晶石、斜长石、磷灰石、金云母;高钾钙碱性系列岩石中含大量的微粒闪长质包体、镁铁质石英二长闪长质包体和富云母包体,主要矿物为斜长石、角闪石、黑云母。在考虑温压计使用条件的前提下,选择合适的温压计计算了两个系列侵入岩及包体形成的温压条件。结果表明,橄榄安粗岩系列侵入岩侵位深度(4～6km)略小于高钾钙碱性系列侵入岩(6～7km),各种堆积包体形成于45～65km的深位岩浆房,微粒闪长质包体形成于12～15km的浅位岩浆房,镁铁质石英二长闪长质包体是早期侵入岩的边缘相,而富云母包体可能为地壳部分熔融的残余相。 相似文献
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河北承德铁马哈叭沁超贫铁矿床的成因与成矿时代 总被引：4，自引：1，他引：3
河北承德一带基性-超基性岩中的超贫铁矿石(全铁TFe含量<20%)资源在河北的铁精矿产量中占有重要地位,其中以铁马哈叭沁超贫铁矿床贡献最大。本研究以铁马哈叭沁岩体中的超贫铁矿石即钒钛磁铁矿化的角闪石岩中的角闪石为研究对象,通过电子探针分析和40Ar/39Ar测年,结合野外地质特征,探讨了超贫铁矿床的成矿时代及矿床成因。野外和岩相学特征表明,铁马哈叭沁超贫铁矿床为岩浆晚期分异型铁矿床。电子探针分析表明,角闪石岩中角闪石主量元素变化范围较小,具有富Ca、富Mg、富Na、贫K的特征,属于韭闪石和镁绿钙闪石。角闪石成因矿物学研究表明,角闪石岩主要为幔源成因,并受到了地壳物质的混染。角闪石岩中角闪石单矿物的40Ar/39Ar年龄为379～401 Ma,表明成岩成矿时代为泥盆纪,形成于白乃庙岛弧与华北克拉通北缘发生弧-陆碰撞后的伸展阶段。 相似文献
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《矿物岩石地球化学通报》2016,(1)
本文旨在探究安徽铜陵鸡冠山辉石闪长岩中角闪石堆积岩的岩相学和矿物学特征及其地质意义。岩相学研究表明,钛铁磁铁矿和磷灰石早于角闪石结晶并被角闪石包裹形成包含结构,钛铁矿与磁铁矿以固溶体分离结构共存。矿物学分析显示角闪石为具幔源特征的镁绿钙闪石和韭闪石,钛铁磁铁矿中磁铁矿Ti含量极低。地质温压计计算得出角闪石的形成压力为0.70~0.76 GPa,相当于23~25km深度,形成温度为890~975℃;钛铁矿与磁铁矿固溶体分离的平衡温度为501~613℃。综合已有研究及本次分析表明,鸡冠山角闪石堆积岩是由下地壳深位岩浆房中由底侵的碱性玄武岩浆与下地壳发生同化混染作用形成的中基性岩浆结晶分异形成,而钛铁磁铁矿的平衡是随上述的中基性岩浆侵位到地表浅部逐渐冷却在固相线下达到的,角闪石堆积岩记录了鸡冠山岩体的形成过程。 相似文献
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文章综合分析研究了中国21个夕卡岩矿床中的130个角闪石的成分分析数据。根据夕卡岩类型及其伴生金属矿化的不同，把角闪石分为4大类：钙夕卡岩中的角闪石多属钙角闪石，包括绿钙闪石、铁角闪石、镁绿钙闪石、铁浅闪石、阳起石、铁阳起石、铁镁钙闪石和铁韭闪石等；镁夕卡岩中的角闪石以透闪石为主，局部有浅闪石或韭闪石；锰质夕卡岩中的角闪石有锰质阳起石、锰质透闪石、锰直闪石和锰镁闪石；碱质夕卡岩中的角闪石属钠-钙角闪石或钠角闪石类，包括钠透闪石、镁亚铁钠闪石、亚铁钠闪石、镁铝钠闪石和镁钠闪石。碳酸盐围岩和有关侵入岩的成分对角闪石的类型、成分及其伴生金属矿化起重要的作用。 相似文献
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Robert J. Stull 《Lithos》1978,11(3):243-249
Mantled feldspars that formed by resorption, development of skeletal plagioclase crystals, and filling with alkali feldspar are common in the Golden Horn batholith, Washington. Subhedral plagioclase mantles have weak normal zoning from An17 to An10. Plagioclase zoning and twinning are crosscut by resorption channels. Resorption cavities and channels are coated with albite (An10). Anhedral, perthitic orthoclase within the plagioclase is optically continuous with orthoclase in channels and on the mantle exterior.This texture resulted from resorption of calcic cores of plagioclase as pressure decreased when water-undersaturated granite magma intruded to a shallow crustal level. At shallow level, only alkali feldspar and quartz crystallized and were available to fill the skeletal plagioclase. 相似文献
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Two types of reaction rims occur between olivine and plagioclase in ultramafic rocks from the Sefuri Mountains, NW Kyushu, Japan, which were metamorphosed under granulite-facies conditions. One occurs as a thin film of orthopyroxene along the boundary between olivine and plagioclase (orthopyroxene zone). The other is composed of two zones: symplectite of calcic amphibole and spinel on the plagioclase-side (symplectite zone) and calcic amphibole with sporadic orthopyroxene on the olivine-side (tremolite zone). In the tremolite zone, calcic amphibole shows a systematic decrease in Al content and increase in Mg/(Fe +Mg) with decreasing distance from olivine. Local equilibria maintained during the diffusion-controlled corona-forming reaction enable us to apply equilibrium thermodynamics to calcic amphibole and adjacent orthopyroxene. An integrated formulation of the Gibbs method for an Fe–Mg exchange reaction constrains the equilibrium temperature recorded in the tremolite zone to be 600–710 °C. It is significantly lower than the temperature of the granulite-facies metamorphism (800–900 °C) estimated using conventional geothermobarometry. Except for H2O, the association of calcic amphibole and spinel in the symplectite zone is chemically equivalent to the association of olivine, plagioclase and orthopyroxene that was stable before the corona formation. This suggests that the following orthopyroxene-consuming reaction describes the paragenetic change taking place between 800–900 °C and 600–710 °C, olivine + plagioclase + orthopyroxene + aqueous fluid = calcic amphibole + spinel. In contrast, the overall reaction inferred from microstructures produces orthopyroxene as well as calcic amphibole and spinel at the expense of olivine and plagioclase. This reaction requires removal mainly of MgO that is also responsible for destabilizing the local association of olivine and plagioclase. These features suggest that the presence of orthopyroxene as a product in the corona is not always indicative of an orthopyroxene-producing reaction being responsible for the change of paragenetic relation. Microstructural features should be carefully applied to infer the reaction describing paragenetic change by which we argue the P–T path of the rocks. 相似文献
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The Petrology of Plutonic Blocks and Inclusions from the Lesser Antilles Island Arc 总被引：20，自引：12，他引：20
Three main groups of plutonic nodules are present in the LesserAntilles arc and are interpreted as (a) phenocryst clusters,(b) metamorphosed wallrock xenoliths and (c) cumulate texturedxenoliths. Large cumulate blocks display felsic-mafic layering,slump structures and auto-intrusive features. The majority ofspecimens are ad- and heteradcumulates with fewer ortho- andcrescumulates. Interstitial scoria and glass are present ina variety of samples. Plagioclase, amphibole, cino- and orthopyroxene,olivine, magnetite, biotite, ilmenite, quartz and apatite arepresent in various proportions in individual blocks. Plagioclaseand amphibole are modally predominant. Significant variationalong the arc is displayed in the rarity of orthopyroxene andabundance of amphibole in the southern islands compared withthe common presence of two pyroxenes in the northern islands. Plagioclase varies from An100–36 with very low orthoclasecomponent, and usually precedes amphibole in a given crystallizationsequence. Only on Grenada are plagioclase-free blocks present.Olivine is restricted to assemblages where coexisting plagioclaseis more calcic than An89 and its composition range is Fo90–59.Clinopyroxene is predominantly calcic augite and cinopyroxene,olivine and plagioclase all coexist stably with amphibole. Ageneral trend of decreasing Ca content in clinopyroxene fromsouth to north in the arc is present. Orthopyroxene ranges from En73–49 and is most common inassemblages where the coexisting plagioclase is more sodic thanAn83 Coexisting pyroxenes define temperatures in the range 800–1050?C. Amphibole compositions include pargasite, magnesiohastingsite,magnesio-hornblende and tschermakitic hornblende. The K contentof the amphiboles increases from north to south in the samesense as the general tholeiitic-calcalkalic-alkalic variationof parental magmas. Magnetite is the dominant spinel phase but ferrian chromiteand chromian magnetite are present in some Grenada cumulatesand pleonaste is found in rare St. Kitts samples. Ilmenite ispresent in blocks from several islands; coexisting Fe-Ti oxidesdefine a temperature range of 710?-950 ?C at of 15.5 to 10.0 bars. Biotite, quartz and apatiteare restricted to evolve cumulate types. Some modification of interstitial scoria/glass compositionsfrom equilibrium melts has occurred in the majority of samples,but general similarity with erupted lava types is importantevidence for the cognate relationship of the cumulate assemblages.The role of H2O is crucial in determining the calcic natureof island arc plutonic plagioclase when compared with relativelydry, layered tholeiitic plutons. Some modal and chemical featuresof cumulate-lava comparisons suggest plagioclase flotation maybe significant. A variety of thermodynamic calculations indicate temperaturesand pressures of crystallization in the range 850–1050?C, 4–10 kb. No evidence exists for systematic along-arcvariations in these parameters. Standard amphibole crystallinesolution models give unsatisfactory results for calculations. Some distinctive contrasts between cumulate and phenocryst modesare present. The abundance of amphibole in equilibrium withbasaltic melts in the plutonic situation compared with its rarityin lavas is striking. Plagioclase coexisting with a given meltis more anorthitic in the plutonic than the phenocryst mode. Least squares fractionation tests demonstrate the possibilityof relating basalt-andesite-dacite suites by fractional crystallizationof the cumulus phases. Trace element systematics of cumulate-lavasuites for individual islands also generally support this hypothesis.The suggestion of sole amphibole fractionation for the generationof andesite from basalt is discarded.
* Present address: CRAE, Box 39598, Darwin, N.T. 5798, Australia. 相似文献
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Thomas Will Martin Okrusch Esther Schmädicke Guoli Chen 《Contributions to Mineralogy and Petrology》1998,132(1):85-102
Calculated phase equilibria among the minerals sodic amphibole, calcic amphibole, garnet, chloritoid, talc, chlorite, paragonite,
margarite, omphacite, plagioclase, carpholite, zoisite/clinozoisite, lawsonite, pyrophyllite, kyanite, sillimanite, quartz
and H2O are presented for the model system Na2O-CaO-FeO-MgO-Al2O3-SiO2-H2O (NCFMASH), which is relevant for many greenschist, blueschist, amphibolite and eclogite facies rocks. Using the activity-composition
relationships for multicomponent amphiboles constrained by Will and Powell (1992), equilibria containing coexisting calcic
and sodic amphiboles could be determined. The blueschist–greenschist transition reaction in the NCFMASH system, for example,
is defined by the univariant reaction sodic amphibole + zoisite = calcic amphibole + chlorite + paragonite + plagioclase (+
quartz + H2O) occurring between approximately 420 and 450 °C at 9.5 to 10 kbar. The calculated petrogenetic grid is a valuable tool for
reconstructing the PT-evolution of metabasic rocks. This is shown for rocks from the island of Samos, Greece. On the basis of mineral and whole
rock analyses, PT-pseudosections were calculated and, together with the observed mineral assemblages and reaction textures, are used to reconstruct
PT-paths. For rocks from northern Samos, pseudomorphs after lawsonite preserved in garnet, the assemblage sodic amphibole-garnet-paragonite-chlorite-zoisite-quartz
and the retrograde appearance of albitic plagioclase and the formation of calcic amphibole around sodic amphibole constrain
a clockwise PT-path that reaches its thermal maximum at some 520 °C and 19 kbar. The derived PT-trajectory indicates cooling during exhumation of the rocks and is similar to paths for rocks from the western part of the
Attic-Cycladic crystalline complex. Rocks from eastern Samos indicate lower pressures and are probably related to high-pressure
rocks from the Menderes Massif in western Turkey.
Received: 8 July 1997 / Accepted: 11 February 1998 相似文献
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The Buck Creek ultramafic body, North Carolina, includes aluminous lenses that have been described as troctolites. These lenses preserve mineral assemblages which record several different stages of metamorphism. The first stage is characterized by anhydrous reactions between olivine and plagioclase to produce coronas of orthopyroxene+ clinopyroxene/spinel symplectite. Thermo barometric results indicate minimum pressures of c. 6 kbar and c. 800 oC. Sapphirine replaces spinel in some clinopyroxene symplectites, and occurs as anhedral grains within amphibole, observations which in combination suggest peak metamorphic conditions of c. 9-10 kbar and c. 850 oC. Sapphirine-bearing hydrous assemblages formed at the expense of the coronas, indicating a second metamorphic episode involving deeper burial, deformation and hydration. Schistose rocks from the margins of the lenses are composed of anorthite+amphibole+margarite+corundum, and probably record a later, lower P-T event. Whole rock analyses for the Buck Creek lenses suggest an accumulate protolith of magnesian olivine and calcic plagioclase. Trace element data for the troctolites are consistent with data for adjacent amphibolites in suggesting that the Buck Creek mafic and ultramafic cumulates crystallized from magmas derived from a mantle source similar to that which produces modern intraplate or rift-related basalts. We propose that the Buck Creek ultramafics represent basal cumulates(± uppermost mantle) from ocean crust formed in a marginal basin in the latest Precambrian. Subduction-induced burial to at least 18 km under dry conditions induced corona formation. Collisional events of the Taconic orogeny thrust the Buck Creek rocks into the orogenic pile to at least 30 km depth and hydrated them along zones of weakness, locally producing P-T -PH2O conditions appropriate for formation of sapphirine and hydrated assemblages, but still preserving some dry symplectites. 相似文献
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《International Geology Review》2012,54(13):1522-1558
The Melrose Stock in the Dolly Varden Mountains of east-central Nevada is one of the many Mesozoic intrusion s in the Basin and Range Province. It consists of monzonites, quartz monzonites, granodiorites, and granites sharply intruding Mississippian to Triassic units. Phenocrysts of plagioclase (An38–An24) with oscillatory zoning and albitic rims, hornblende ± diopside, and biotite are common. Coexisting phases include orthoclase, quartz and accessory magnetite, apatite, titanite, ilmenite, and allanite. Mineral compositions suggest that the intrusion was emplaced at ～720 ± 40°C and 1.8–2.3 kbar. All rocks are metaluminous to slightly peraluminous, defining a calcalkalic trend in which the monzonites and syenites are shoshonitic. Rare earth element patterns indicate that all studied rock types are comagmatic. Harker plots show curvilinear trends with some kinks consistent with fractionation, and mixing/assimilation. Major-element modelling and petrographic evidence suggest three stages of fractionation/mixing: Stage 1 marked by the fractionation of diopside and plagioclase; Stage 2 by fractionation of plagioclase, hornblende ± orthoclase ± biotite, accompanied by mixing through convection; and Stage 3 by fractionation of biotite, hornblende, plagioclase, and orthoclase. Mineralogic, petrographic, and major- and trace-element data demonstrate that all rocks are I-type granitoids, suggesting a significant mantle contribution. Spider diagrams show troughs for Ti, P, and Nb, indicating magma genesis in a subduction-zone setting. Discrimination diagrams classify all rocks as late orogenic. Magma was therefore generated from mantle metasomatized by subduction, differentiated to a monzonitic magma, and emplaced in the thinned continental crust during a period of extension late in the cycle of Elko orogeny. 相似文献
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Richard J. Arculus 《Contributions to Mineralogy and Petrology》1978,65(4):413-424
The mineralogy and petrology of volcanic and plutonic rocks from the island of Grenada are described. The volcanic rocks include basanitoids, alkalic and subalkalic basalts, andesites and dacites. Phenocryst phases in the basanitoids and basalts are olivine (Fo90–71), zoned calcic augite, spinel ranging from ferrian pleonaste through chromite to titaniferous magnetite, and plagioclase. Some of the basalts contain pargasitic amphibole. Andesites and dacites generally contain hypersthene and augite, and one pigeonite-hypersthene-augite-bearing andesite was found. Apatite commonly occurs as a phenocryst in the andesites and dacites and quartz is present in some dacites as well as being a possible xenocryst in both alkalic and subalkalic basalts. Plutonic cumulates found as ejected fragments in tuffs and ashes are composed of variable proportions of olivine, magnetite, calcic augite, amphibole and plagioclase. One peridotitic (ol-cpx-opx) fragment was found but spinel or garnet peridotitis are absent. Despite the alkalic nature of the association, calcalkalic characteristics such as calcic plagioclase, restricted Feenrichment in coexisting pyroxenes and generally low TiO2 content relative to oceanic suites are present in Grenada. Estimates of conditions of equilibration of the basanitoids with potential upper mantle materials using the results of high-pressure experiments are compared with estimates from thermodynamic data. Equating
and
basanitoid with hypothetical garnet peridotite assemblages gives a pressure and temperature of equilibration in the region of 35–38 kbar and 1550–1625 ° K. Experimental results are not supportive of these estimates. 相似文献
19.
福建平潭角闪辉长岩结晶过程的矿物学记录 总被引：10，自引：1，他引：10
福建平潭角闪辉长岩中具成分环带的斜长石由钙质斜长石核和膜状中长石两部分组成，它是钙碱性高铝玄武岩浆结晶过程中岩浆上升和吸回作用的记录。 相似文献
20.
Discovery of Pyrrhotite-Chalcopyrite-Bearing Amphibole Megacrysts in Tongling Area, Anhui Province 总被引：1，自引：0，他引：1
Some pyrrhotite-chalcopyrite-bearing amphibole megacrysts (including pyroxene megacrysts) were discovered in Mesozoic augite diorite-porphyrite at Caoshan in Tongling area, Anhui Province. The amphibole megacrysts, belonging mainly to pargasite and magnesiohastingsite, are characteristic of the amphibole composition derived from mantle and crystallized in lower crust. In general, the aggregates of pyrrhotite-chalcopyrite take the shapes of cylinder and sphere. Three occurrences have been recognized in the amphibole megacrysts: parallel linear, bunchy and scattered. The unique cylinder-like shape of the aggregates and remarkable Ni-poor sulfides in Caoshan are distinctively different from the spherical Ni-rich sulfides in pyroxene megacrysts and any other kinds of megacrysts. In terms of composition, the amphibole megacrysts and their sulfides in Caoshan are similar to those in the pyroxenite xenoliths in Qilin, Guangdong Province. In terms of origin, the pyrrhotite-chalcopyrites as exsolution products resulted from the subsolidus re-equilibration of sulfide solid solution within amphibole megacrysts.amphibole megacrysts were first discovered inside and outside China. This discovery is important for the study of regional magma evolution and its associated mineralizations and ore sources as well. 相似文献