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河南桐柏老湾金矿床的成矿作用是在变基性火山碎屑沉积岩为矿源层的背景上演化的。本文根据矿床氢氧同位素研究,认为矿床的热液成矿期成矿流体为大气降水和老湾花岗岩岩浆水的混合,成矿Ⅰ阶段和Ⅱ阶段以岩浆水为主,成矿Ⅲ阶段以大气降水为主,但在成矿Ⅱ阶段大气降水已占有很大的比例。氦同位素分析表明,在老湾金矿形成过程中有地幔流体加入,且从成矿Ⅱ阶段至Ⅲ阶段,由于大气降水比例增大,其与地幔流体的混合导致成矿流体的3He/4He比值不断减小。 相似文献
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河南省老湾金矿床地球化学特征及矿床成因 总被引：3，自引：0，他引：3
在详细分析河南省老湾金矿床成矿地质背景、矿床地质特征的基础上,研究该矿床流体包裹体和氢、氧、硫、铅同位素,结果表明该金矿床的成矿流体为中低温、低盐度的富CO2的K+-Na+ -Cl--SO 2-4体系。氧、氢同位素分析显示,成矿流体δ18O值变化于-5.25‰～+5.37‰,δD变化于-67‰～-76‰,表明成矿流体主要来源于岩浆水和大气降水;硫化物的δ34S值变化于-0.1‰～+5.3‰,平均值为+3.98‰,显示深源硫的特征;Pb同位素组成显示铅主要来源于地幔,有少量地壳铅的加入。综合研究表明,老湾金矿床为受韧性剪切带控制的中-低温热液构造蚀变岩型金矿床。
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铲子坪金矿位于雪峰山构造岩浆岩带的白马山复式花岗岩体外接触带附近。本文通过对铲子坪金矿床岩石地球化学以及稳定同位素的研究,探讨其矿床成矿物质来源及矿床成因。研究结果表明:矿石中金属硫化物的δ34S介于-7.58‰~+0.32‰,平均为-2.44‰,富轻硫,表明硫化物中的硫主要来自花岗岩浆,有部分地层硫酸盐中的硫混入;铅同位素组成相对稳定,变化范围很小。根据铅构造模式图解和△γ-△β图解,铅同位素主要来源于地幔,有部分地壳铅的加入;氢、氧同位素表明成矿流体具有变质热液和岩浆热液的双重性,成矿晚期热液有大气水成分加入;碳同位素表明成矿流体与砂质板岩关系密切,与地幔或深部流体有一定的关系,矿床成矿流体中的CO2很可能为壳幔混合;锶同位素研究表明,铲子坪金矿床的(87Sr/86Sr)i组成特征与华南陆壳重熔性花岗岩初始岩浆水的(87Sr/86Sr)i组成特征基本一致,表明其成矿作用可能与岩浆热液有关。铲子坪金矿成因类型为岩浆热液型。 相似文献
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《现代地质》2017,(5)
湾岛金矿是近年来广西东南部大瑶山多金属成矿集中区古袍金矿田内发现的中型矿床,其物质来源及成因尚存在较大分歧。根据详细的坑道及岩矿相学观察,将湾岛金矿成矿分为2期3阶段:钨钼铜金成矿期和金主成矿期(分为金主成矿阶段和金晚成矿阶段)。石英流体包裹体显微测温和激光拉曼光谱分析表明,金主成矿期成矿流体为中高温、低盐度、低密度的含CO_2和CH_4流体。氢氧同位素分析表明,金主成矿期成矿流体中水主要为变质水,钨钼铜金成矿期成矿流体中水可能为岩浆水及变质水的混合。矿石矿物硫同位素数据显示,钨钼铜金成矿期硫同位素值为小的正值,可能为深源硫;金主成矿期湾岛矿区硫同位素组成变化范围大而均值较小,推测钨钼铜金成矿期成矿物质来源以深源硫为主;金主成矿期为岩浆硫与地层硫的混合硫。初步认为湾岛金矿属于变质-岩浆热液叠加改造成矿。 相似文献
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《矿物岩石地球化学通报》2018,(6)
为探讨者桑金矿床的成矿流体特征、Au的沉淀机制及基性岩浆活动与Au成矿的关系,对该矿床热液成矿期的流体包裹体进行了显微测温研究,并对热液矿物进行了H、O、C同位素分析。结果表明,矿床中包裹体有气液H_2O、CO_2-H_2O和纯CO_2包裹体3种类型,成矿流体温度从早阶段到晚阶段逐渐降低、主成矿阶段盐度高于早晚两个阶段;热液成矿期早阶段成矿流体以岩浆水为主,主成矿阶段为岩浆水和大气降水混合,成矿晚阶段以大气降水为主;成矿晚阶段热液方解石中的碳质主要来自幔源碳的低温蚀变。研究认为,者桑金矿床成矿流体为岩浆水和大气降水的混合流体,Au的沉淀与NaCl-H_2O-CO_2流体不混溶作用密切相关,基性岩浆侵入活动为成矿流体提供热源、H_2O、CO_2和Au。 相似文献
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铜陵冬瓜山层控矽卡岩型铜金矿床的成因机制:硫同位素制约 总被引：7，自引：5，他引：2
冬瓜山铜金矿床是铜陵矿集区乃至长江中下游成矿带中的一个重要矿床。矿床上部受石炭系层位控制,发育层状、似层状层控矽卡岩型矿体;下部受岩体及其接触带控制,在岩体及其接触带围岩中发育脉状、细脉浸染状矿体。上部层控矽卡岩型矿体中的矿石类型以含铜(金)石英硫化物为主,矿石硫化物矿物的硫同位素组成显示主要成矿阶段的硫同位素基本达到了平衡。矿石矿物中的硫化物和硫酸盐的硫同位素组成对比表明,冬瓜山矿床与斑岩型矿床相似,而与Sedex型和VHMS型矿床不同。结合矿床成矿物理化学条件和矿石矿物共生组合关系,根据硫同位素储库效应,认为冬瓜山矿床硫化物阶段成矿热液中的含硫物种以H2S为主(XH2S0.99),硫化物的结晶沉淀对成矿热液的δ34S值影响不大。应用大本模式,高温岩浆来源的热液与熔体之间的硫同位素分馏Δ34S为0‰～+5‰,依据岩浆岩全岩硫同位素组成可以确定岩浆来源热液的硫同位素组成为+0.3‰～+12.0‰。在高温(600～350℃)硅酸盐阶段和氧化物阶段,硬石膏与成矿热液之间的硫同位素分馏Δ34S为+5.0‰～+19.0‰,而在高温(450～350℃)氧化物阶段后期及低温(350～200℃)硫化物阶段,黄铁矿与成矿热液之间的硫同位素分馏Δ34S分别为-1.0‰～0‰和0‰～+1.5‰。据此计算的含硫矿物硫同位素组成理论值与冬瓜山矿床实测值基本一致,显示成矿热液流体中的硫源为岩浆来源。综合前人对区域及冬瓜山矿床的研究,本文认为冬瓜山矿床为与燕山期岩浆作用密切相关的层控矽卡岩型铜金矿床。岩浆及其平衡热液中较高的总硫同位素组成暗示岩浆混染了区域沉积地层中广泛发育的膏盐成分。虽然硫同位素组成特征显示区域沉积岩成岩过程中经历了明显的海水沉积作用和细菌硫酸盐还原作用,但冬瓜山矿床矿石没有保存海西期沉积成矿的硫同位素证据。 相似文献
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长江中下游地区是中国重要的铜、金、硫产地,区内分布着一系列喷流沉积及喷流沉积热液叠加改造型层状铜金矿床。本文以冬瓜山层状铜矿床为例,通过热液流体和矿石同位素地球化学研究,探讨层状铜矿床的成矿机制,重点分析了成矿物质的来源。冬瓜山铜矿床热液流体氢、氧、碳和锶同位素分析表明,成矿热液流体主要来自岩浆,混有少量大气降水;CO2可能主要来自被岩浆同化的原始地层中海相沉积碳酸盐;ISr具有地壳物质来源的特征。各种类型矿石的硫、铅同位素研究显示,硫具有海底喷流沉积和后期岩浆热液叠加作用的特征,铅则以上地壳铅为主,混有少量的地幔铅。上述同位素地球化学特征表明冬瓜山层状铜矿床是在原始沉积基础上,经燕山期岩浆热液叠加成矿作用所形成。 相似文献
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西秦岭寨上金矿床地球化学特征
及成因机制研究 总被引：4，自引：0，他引：4
寨上金矿床共发现金矿脉22条,金矿体19条.通过氢、氧同位素分析得出:该区成矿流体水具有多来源特征.δ34S的组成特点可能反映了硫源为岩浆硫和地层硫的混合.碳的来源主要由海相沉积碳酸盐岩经溶解作用和花岗岩岩浆热液提供.矿石稀土元素并没有完全继承围岩的特征.成矿流体具有以下特征:成矿流体为中低温、低盐度、低密度、多期次活动的流体.金矿成矿是在300Ma之后燕山晚期形成的.成矿热液中,金主要以硫化物配合物的形式迁移.成矿流体与围岩发生充分的物质交换后.运移到裂隙发育部位,并因为流体的混合和围压突然降低,成矿流体产生强烈的沸腾作用,使成矿物质沉淀富集成矿. 相似文献
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1ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅＤｕｏｌａｎａｓａｙｉｇｏｌｄｄｅｐｏｓｉｔ,6 0ｋｍＮＷｏｆＨａｂａｈｅＣｏｕｎｔｙｉｎＸｉｎｊｉａｎｇ ,ｉｓｓｉｔｕａｔｅｄｏｎｔｈｅｎｏｒｔｈ ｗｅｓｔｅｒｎｍａｒｇｉｎｏｆｔｈｅＶａｒｉｓｃｉａｎＥｒｔｉｘｏｒｏｇｅｎｉｃｂｅｌｔ.Ｉｔｉｓａｍｅｄｉｕｍ ｌａｒｇｅｓｃａｌｅｇｏｌｄｄｅｐｏｓｉｔｃｏｎｔｒｏｌｌｅｄｂｙｔｈｅｃｏｕｐｌｅｄｏｒｅ ｆｏｒｍｉｎｇｐｒｏｃｅｓｓｅｓｉｎｖｏｌｖｉｎｇｂｒｉｔｔｌｅ ｄｕｃｔｉｌｅｓｈｅａｒｉｎｇ ,ａｌｂｉｔｉｔｅｖｅ… 相似文献
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Yang Liqiang Deng Jun Zhang Jing Guo Chunying Gao Bangfei Gong Qingjie Wang Qingfei Jiang Shaoqing Yu Haijun 《中国地质大学学报(英文版)》2008,19(4):378-390
The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃(2) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO2-4-K type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl--Na /Ca2 type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS- complex in the HTFS, and Au-Cl- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future. 相似文献
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Geochemistry of Ore Fluids and Rb-Sr Isotopic Dating for the Wulong Gold Deposit in Liaoning, China 总被引：3，自引：0，他引：3
WEI Junhao QIU Xiaoping GUO Dazhao TAN Wenjuan Faculty of Earth Resources Chinese University of Geosciences Wuhan Hubei Institute of Geology Chinese Academy of Geological Sciences Beijing 《《地质学报》英文版》2004,78(6):1267-1274
On the basis of detailed geological studies of the Wulong gold deposit, three metallogenic stages can be identified. With quartz fluid inclusions as an object of study, the authors investigated phase characteristics, compositional variations, temperature and pressure changes, fluid evolution, Pb isotope tracing and Rb-Sr isotopic dating of fluid inclusions entrapped in the above three metallogenic stages. The results show that Na+ is decreased obviously with metallogenic evolution, while K+ and other cations and gas compositions (H2, CO, CH4 and CO2) are increased slightly, and that the temperature and salinity vary in a pulsating manner along with the metallogenic evolution. Inverse calculation of hydrogen and oxygen isotopes indicate that at the first metallogenic stage the fluids were magmatic water, at the second stage they were dominated by magmatic water with a minor amount of meteoric water involved, and at the third stage, i.e., the final stage of metallogenesis, the fluids were composed complete 相似文献
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Trace element and REE geochemistry of the Zhewang gold deposit,southeastern Guizhou Province,China 总被引：1，自引：0，他引：1
The quartz vein-type gold deposits are widely hosted by the Neoproterozoic （Xiajiang Group） epimeta- morphic clastic rock series in southeastern Guizhou Province, China. The Zhewang gold deposit studied in this paper occurs in the second lithologieal member of the Pinglue Formation of the Xiajiang Group. Trace element geochemis- try of host rocks, quartz veins and arsenopyrite has revealed that ore-forming fluid was enriched in sulphophile ele- ments such as Au, Ag, As, Sb, Pb and Zn, and simultaneously concentrated some magmaphile elements such as W and Mo, which probably provides some evidence for multi-stage mineralization or overprinting of magmatic hydro- therm. Quartz veins and arsenopyrite were characterized by depletion in HFSE and enrichment in LREE. Hf/Sm, Nb/La and Th/La imply that the ore-forming fluid was probably a NaC1-H20 solution system enriched in more C1 than F; Th/U values reflect the strong reducibility of the ore-forming fluid, coincident with the sulfide assemblages. The values of Co/Ni reflect that magmatic fluids may have partly participated in the ore-forming process and Y/Ho values have proved that the ore-forming fluid was associated with metamorphism and exotic hydrotherm which has reformed former quartz veins during late mineralization. The concentrations of REE, Eu anomalies and Ce anomalies of this deposit display that ore-forming elements mainly were derived from host rocks and possibly from a mixed deep source, and the ore-forming fluid was mixed by dominant metamorphic fluid and minor other sources. The physical-chemical conditions of ore-forming fluid changed from the initial stage to the late stage. The metamorphic fluid is responsible for the mineralization. Therefore, the Zhewang gold deposit is classified as a quartz vein-type gold deposit which may have been reformed by magmatic fluids during the late stage. 相似文献
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阿沙哇义金矿位于中国新疆南天山造山带,属于著名的中亚南天山锑-汞-金成矿带的东延部分。该矿床严格受断裂所控制,以浸染状黄铁矿化、毒砂化为特征。矿化可分为三个阶段:早期无矿或贫矿石英阶段,中期石英多金属硫化物阶段,晚期石英-碳酸盐阶段。其中,中期是主要成矿阶段。成矿流体气相成分以H_2O为主,摩尔含量为75%～93%,其次为CO_2,摩尔含量为6%～25%,其余为CH_4、C_2H_6、H_2S、N_2和Ar;液相成分阳离子以Na~+为主,含少量K~+、Ca~(2+)离子,阴离子以Cl~-为主,SO~(2-)次之;矿石的Au含量与其流体的CO_2含量呈反相关,与K~+含量呈正相关。硫化物成分分析结果表明:(1)围岩地层和矿石中的黄铁矿和毒砂是重要的载金矿物,黄铁矿Au含量为0～0. 09%,平均值0. 03%;毒砂Au含量为0～0. 28%,平均值0. 07%;(2)黄铁矿和毒砂Au含量与其自形程度没有明显的相关性;(3)环带状黄铁矿较均质结构黄铁矿具有更高的Au含量;(4)岩体中的黄铁矿几乎不含Au。在成矿构造环境、成矿流体特征及演化、金矿富集机制、成矿温压条件等方面,该矿床与世界上大多数造山型金矿显示出一致性,成矿类型应属于剥蚀程度较浅的造山型金矿。断层阀作用控制的断层愈合-破裂导致的流体不混溶作用是本区金富集、沉淀的最重要机制,但流体混合机制对金的富集沉淀也发挥了作用。黄铁矿、毒砂发育及较多的含炭物质三者共存是本区寻找富矿的关键标志。 相似文献
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海沟金矿地质-地球化学特征及其成矿机制探讨 总被引：3，自引：0，他引：3
海沟金矿床产于海沟花岗岩体中,受NE-NNE向断裂控制,为大型贫硫化物石英脉型金矿床.微量元素研究表明成矿作用以充填作用为主,矿床主要指示元素为Au、Ag、Hg、Pb、Bi、Mo,由上至下的轴向分带序列为Ba-Hg-Ag-Bi-Au-As-Sb-Pb-Mo.同位素和流体地球化学资料表明成矿物源与色洛河群变质岩系和海沟花岗岩有关,成矿流体由岩浆水和古大气降水组成,流体属CO2-NaCl-Na2SO4-H2O型.在区域地质构造演化背景下,深大断裂的活动导致富金的色洛河群变质岩系发生深熔作用形成海沟花岗岩及富矿质和矿化剂的岩浆热液,同时也产生了以大气降水为主的含矿热液.在143 Ma左右,随区内应力场转变为张性,并在岩体和周边地层中形成大量NE-NNE向次级断裂系统,富矿质和矿化剂的岩浆热液和以大气降水为主的含矿热液的平衡被打破,导致两种流体向NE-NNE向次级断裂系统的扩容带迁移,混合作用、沸腾作用以及物化条件的改变导致金的沉淀,从而造就了海沟金矿床. 相似文献