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1.
笔者通过对冈底斯成矿带驱龙、厅宫斑岩铜矿区和甲马、知不拉等矽卡岩型铜多金属矿区的辉钼矿样品进行的Re-0s法同位素定年研究,获得驱龙、厅宫、甲马和知不拉等矿区的精确成矿年龄。4件驱龙斑岩铜矿区辉钼矿样品的Re-Os模式年龄介于(15.75±0.42)Ma~(16.23±0.90)Ma之间,等时线年龄为(15.99±0.32)Ma;7件厅宫斑岩铜矿矿区辉钼矿样品的Re-Os模式年龄介于(15.5±0.3)Ma~(16.3±0.3)Ma之间,等时线年龄为(15.49±0.36)Ma;在矽卡岩型铜多金属矿区中,7件甲马矿区辉钼矿样品的Re-Os模式年龄介于(15.4±0.2)Ma~(15.5±0.2)Ma之间,等时线年龄为(15.18±0.98)Ma;5件知不拉矿区辉钼矿样品的Re-Os模式年龄介于(16.88±0.28)Ma~(17.06±0.27)Ma之间,等时线年龄为(16.90±0.64)Ma。斑岩铜矿区和矽卡岩型铜多金属矿区所获得的年龄数据基本一致,其年龄明显晚于中生代弧间盆地和碰撞型花岗岩的发育时间,同时矽卡岩型铜多金属矿床在空间上亦分布于斑岩铜矿床的外围。因此笔者认为甲马和知不拉等铜铅锌矿床与冈底斯成矿带新生代晚期大规模成矿形成的斑岩铜钼矿床属于统一的斑岩-矽卡岩成矿系统,是由深源花岗质岩浆的岩浆-热液系统在不同的围岩介质条件成矿的产物。  相似文献   

2.
广东锡坪钼铜多金属矿床位于钦杭成矿带的西南端,为一大型的斑岩型矿床。本文利用辉钼矿Re-Os同位素定年方法对锡坪钼铜多金属矿床4件辉钼矿样品进行了成矿年代学测定,获得的模式年龄为85.15~88.34Ma,加权平均值为86.1±2.3Ma,对应的等时线年龄为89.9±3.4Ma,模式年龄和等时线年龄结果在误差范围内基本一致,指示锡坪钼铜多金属矿床的成矿时限为晚白垩世。锡坪钼铜多金属矿辉钼矿样品的Re含量较低,表明其成矿物质可能主要来自于壳源。钦杭成矿带成岩成矿作用以中生代燕山期为主,存在180~150Ma、110~80Ma两个爆发期,两期成岩成矿作用可能均与太平洋板块的俯冲有一定的关系。锡坪钼铜多金属矿床是在岩石圈伸展减薄环境下发生的大规模成矿作用的产物。  相似文献   

3.
张娟  毛景文  程彦博  李肖龙 《矿床地质》2012,31(6):1149-1162
在个旧锡铜多金属矿集区发育有矽卡岩型和热液脉型等锡铜矿化体,其形成时代是晚白垩世,属与花岗岩有关的岩浆热液成因矿床。赋存于三叠纪蚀变玄武岩层中,呈(似)层状的铜矿体的精确年龄尚未有报道,成因仍备受争议。文章选择赋存于卡房矿田蚀变玄武岩层中,呈(似)层状分布的铜矿体中的金云母,及新山岩体接触带云英岩中的白云母为研究对象,利用40Ar-39Ar阶段加热同位素定年方法对它们进行了年代学研究,获得了金云母和白云母的40Ar-39Ar同位素坪年龄分别为(79.55±0.47) Ma和(79.53±0.57) Ma,对应等时线年龄分别为(79.8±1.3) Ma和(79.7±1.0) Ma,反等时线年龄分别为(79.7±2.0) Ma和(79.61±0.75) Ma,两者年龄基本一致。结合矿物共生组合特征和流体包裹体测温资料,认为金云母的坪年龄(79.55±0.47) Ma,可以代表卡房蚀变玄武岩中(似)层状铜矿的形成时代,而白云母的坪年龄(79.53±0.57) Ma,则代表新山岩体形成后期岩浆热液活动的年龄。这2个年龄与个旧锡铜多金属矿床的成矿时代基本一致,应是同一构造-岩浆-流体活动形成的成矿系列产物。  相似文献   

4.
[摘 要]于沟子铁-稀有多金属矿区位于东昆仑祁漫塔格矿集区西段,其中铁铜(钼)多金属矿体主要分布于正长花岗岩与狼牙山组碳酸盐岩的接触带矽卡岩内,属于矽卡岩型铁铜(钼)多金属矿床,而铌(铷)等稀有-稀土矿化带分布于正长花岗岩和二长花岗岩内。通过对于沟子铁铜(钼)多金属矿体内磁铁矿石中的辉钼矿Re-Os定年表明,辉钼矿中含有对Re-Os定年产生较大影响的普通Os,在扣除普通Os后,辉钼矿Re-Os等时线年龄为(210.1±4.8)Ma(n=5,MSWD=0.37),厘定了其成矿年龄为晚三叠世,是东昆仑祁漫塔格印支期大规模成矿的产物。  相似文献   

5.
鄂东南地区(斑岩-)矽卡岩型铜铁金多金属矿床是长江中下游地区金属成矿带的重要组成部分,铜绿山矿田以成矿类型齐全和矿体规模较大为特点,是鄂东南矿集区最重要的矿田.但目前对不同成矿元素的矽卡岩型铜铁金矿床的成矿时代、成岩成矿时差和构造背景的研究相对较少.本文利用Re-Os同位素定年方法对铜绿山矿田两个典型的大型铜绿山矽卡岩铜(铁金)矿床和大型鸡冠嘴矽卡岩(铜)金矿床进行了成矿时代的研究,获得了辉钼矿的Re-Os同位素年龄范围分别为(1368±19)~(1381±18) Ma和(1371±19)~(1388±19) Ma,等时线年龄分别为(1371±19) Ma和(1382±22) Ma,表明铜绿山矿田不同类型的矿床几乎同时形成;与矿田花岗闪长岩锆石SHRIMP U-Pb年龄[(1403±18) Ma]在误差范围内基本一致,存在较短的成岩成矿时差,该成矿时代与鄂东南地区其他矿田的(斑岩-)矽卡岩型铜钼矿床和矽卡岩型铁矿床,以及长江中下游地区铜陵、安庆、九瑞矿集区(斑岩-)矽卡岩铜多金属矿床的形成时代基本一致.铜绿山矿田矽卡岩铜铁金矿床可能是在太平洋板块俯冲的撕裂或开天窗时,由于玄武质岩浆底侵和岩石圈减薄导致中国东部大规模侵入岩和成矿作用产物的形成.  相似文献   

6.
西藏墨竹工卡县哈海岗钨钼多金属矿床是近年来新发现的以钨钼为主的多金属矿床,也是念青唐古拉成矿带发现的第一个钨钼多金属矿床。文章简要地介绍了该矿床基本地质特征,利用Re-Os同位素定年方法对采自哈海岗矽卡岩型钨钼矿体中的2件辉钼矿进行了成矿年代的测定,获得的辉钼矿Re-Os同位素模式年龄分别为(140.1±2.8) Ma和(143.3±5.2) Ma,平均值为(141.7±4) Ma。测年数据表明,矿床成矿时代属于早白垩世,可能系班公湖—怒江洋向南俯冲碰撞阶段成矿作用的产物,早于其东侧亚贵拉、洞中拉石英斑岩的成岩年龄(126 Ma左右)。矿床成矿时代的厘定丰富了冈底斯—念青唐古拉成矿带矿床成矿系列,指示冈底斯成矿带存在早白垩世的成矿作用,该带至少存在四期独立的钼成矿事件;同时对于研究区域岩浆演化与成矿作用以及区域找矿预测也具有十分重要的意义。  相似文献   

7.
云南个旧锡铜多金属矿床是世界级超大型矿床,个旧矿集区内与蚀变玄武岩有关的(似)层状铜矿床是其重要的矿床类型。该类型矿床的围岩玄武岩均发生蚀变,且蚀变强度与矿化关系密切。本文对个旧卡房矿化玄武岩中的金云母进行40Ar-39Ar同位素定年分析,得到其坪年龄为(85.49±0.63)Ma,等时线年龄为(85.62±0.42)Ma,反等时线年龄为(85.59±0.81)Ma,三者基本一致,代表了变玄武岩的蚀变年龄及同期矿化年龄,属于晚白垩世,可与个旧锡铜多金属矿床的成矿时代进行对比。  相似文献   

8.
东秦岭南泥湖钼(钨)矿田Re—Os同位素年龄及其地质意义   总被引:53,自引:2,他引:53  
位于华北克拉通南缘东秦岭钼矿带的南泥湖为一超大型夕卡岩斑岩型钼(钨)矿田,本研究采用电感耦合等离子体质谱仪法对南泥湖钼矿田三个矿床6件辉钼矿进行了Re-Os同位素年龄测定,获得南泥湖矿床的辉钼矿Re-Os模式年龄为141.8±2.1 Ma;三道庄矿床的辉钼矿Re-Os模式年龄为144.5±2.2~145.0±2.2Ma,平均为145.0±2.2 Ma;上房沟矿床的辉钼矿Re-Os模式年龄为143.8士2.1~145.8±2.1 Ma,平均为144.8±2.1 Ma;6件样品的等时线年龄为141.5±7.8 Ma(2σ),准确厘定了成矿时间.Re-Os同位素还表明:南泥湖钼矿的成矿物质来源以下地壳成分为主,但混有少量地幔组分.南泥湖钼矿是在中国东部中生代构造体制大转换中形成,属于中国东部中生代大规模成矿作用的一部分.  相似文献   

9.
黄凡  罗照华  卢欣祥  陈必河  杨宗峰 《地质通报》2010,29(10):1704-1711
位于东秦岭钼成矿带内的河南汝阳钼铅锌多金属矿田是国内近几年发现的大型矿床集中区,区内发育东沟超大型斑岩钼矿床、竹园沟大型钼矿床和老代仗沟、西灶沟、王坪西沟等大型铅锌矿床。介绍了竹园沟大型钼矿床的地质特征,并利用Re-Os同位素定年方法对竹园沟钼矿体中的辉钼矿进行了成矿年代的测定,获得辉钼矿同位素的模式年龄为(122.2±2.3~119.6±2.2)Ma,平均为120.9 Ma±2.3Ma。该成矿年龄显示竹园沟钼矿的成矿时代与汝阳南部其他钼铅锌等多金属矿床的形成时代相近,表明汝阳南部钼铅锌多金属成矿带成岩成矿年龄(120~110Ma)的一致性,均形成于统一的地球动力学背景,即中生代晚期中国东部岩石圈大规模伸展时期的板内拉张环境。  相似文献   

10.
广西德保铜锡矿床为一矽卡岩型矿床。笔者对采自该矿床的7件不同矿化类型的辉钼矿样品,进行了Re-Os同位素定年,获得的模式年龄为(429.5±5.9)~(440.0±6.9)Ma。其中,采自含矿石英脉的6件辉钼矿样品的Re-Os模式年龄加权平均值为(435.0±2.5)Ma,等时线年龄为(445±11)Ma,表明该地区曾于晚奥陶世—早志留世发生过成矿作用,是华南加里东运动的产物。文章提供了关于右江地区加里东期成矿作用的信息,深化了对该地区成矿演化历史的认识,进而强调了对于寻找钦甲式Cu_Sn矿床的意义。  相似文献   

11.
The exposed crust of the Cornubian massif in S.W. England has been systematically sampled, and the rocks analysed for a wide range of major and trace elements. Geochemically this region is highly anomalous, with three elements (boron, lithium, tin) occurring at levels several times higher than the average for other parts of the continental crust. The greatest degree of enrichment is found in the rocks of the Cornubian granite batholith, but it is also present in rocks pre-dating the formation of the batholith. The mineral deposits of Cornubia derive their trace elements from different sources: B and Sn from the granite, and Cu and S from the country rocks.  相似文献   

12.
Boron in the Bolivian tin belt   总被引:1,自引:0,他引:1  
Tourmaline alteration and high boron contents are typical features of the magmatic-hydrothermal systems of the Bolivian tin province. The average boron content in melt inclusions of quartz phenocrysts from tin porphyry systems is 225 ppm (1σ-variation range: 110–420 ppm; n=12) and suggests a magmatic boron input to the hydrothermal tin systems, and not shallow post-magmatic leaching of boron from pelitic country rocks. Boron data from melt inclusions correlate positively with cesium, rubidium and arsenic, and negatively with lithium, titanium and zirconium, and define magmatic fractionation trends. The generally high B, As, Cs and Li contents in melt inclusions suggest involvement of pelitic source lithologies undepleted in these fluid-mobile components, i.e. first-cycle metamorphic rocks. Magmatic fractionation modified the trace-element contents within a one-log-unit range. Bulk-rock Nd isotope data (ɛNd−5 to −10) are in agreement with the dominantly intracrustal geochemical signature of the Bolivian tin porphyry systems, but also imply a variable but minor mantle input. The metallogeny of the tin belt is likely a consequence of intracrustal melting of Lower Paleozoic pelitic and slightly carbonaceous source material, combined with an extended magmatic evolution. The long-lived thermal preparation of the root zones of the silicic systems is provided by mafic magma which also leaves a chemical imprint in the form of the hybrid dacitic bulk composition of the tin porphyry systems. Received: 6 August 1998 / Accepted: 19 August 1999  相似文献   

13.
It remains poorly constrained whether remobilization of Sn from granites and prograde skarns plays an essential role in forming economic (skarn-type) tin mineralization. Using both electron probe microanalysis and laser ablation–inductively coupled plasma–mass spectrometry methods, in-situ Sn contents, as well as major elements, were analyzed for numerous silicates and magnetite from fresh granite, altered granite, and skarn at the large Furong Sn deposit (530,000 t Sn @ 0.8% Sn) in the Nanling Range, South China. Hornblende and biotite in fresh granite are the main Sn-bearing phases (Sn = 44–321 ppm), while plagioclase and K-feldspar are poor in Sn (< 5 ppm). In altered granite, tin is hosted mainly by hydrothermal muscovite (299–583 ppm) replacing plagioclase, but rarely by chlorite (mostly <10 ppm) replacing hornblende and biotite. In contrast, most silicates (garnet, diopside, vesuvianite, pargasite and epidote) and magnetite from tin skarn are Sn-rich (47–44,241 ppm), except for Sn-poor phlogopite and scapolite (< 10 ppm). In particular, garnet, pargasite, and epidote reach tin concentrations in the percent range. Tin generally enters the stannous silicates and magnetite through substitutions for octahedral Alvi and Fe3+. Comparisons of Sn contents between magmatic and hydrothermal minerals in granite, prograde and retrograde minerals related to tin skarn indicate that remobilization of Sn from granite and prograde skarn is not a pre-requisite to form tin mineralization.  相似文献   

14.
15.
芙蓉锡矿田骑田岭复式岩体主要由早阶段角闪石黑云母花岗岩和晚阶段黑云母花岗岩组成.电子探针分析结果表明角闪石黑云母花岗岩中的黑云母属于铁黑云母,黑云母花岗岩中的黑云母属于铁叶云母.相对于黑云母花岗岩,角闪石黑云母花岗岩中黑云母的MgO、TiO2含量偏高,Al2O3含量偏低.矿物化学研究结果显示,角闪石黑云母花岗岩中黑云母的结晶温度、氧逸度(logfO2)分别为680℃~740℃、-16.00~-15.31,黑云母花岗岩中黑云母的结晶温度、氧逸度分别为530℃~650℃、-19.20~-17.50.从角闪石黑云母花岗岩到黑云母花岗岩,岩浆结晶温度和氧逸度逐渐降低.与花岗岩有关的共存流体性质的研究发现,与角闪石黑云母花岗岩共存的热液流体log(fH2O/fHF)fluid,log(fH2O/fHCl)fluid,log(fHF/fHCl)fiuid值分别为4.22~4.39,2.78~3.24,-1.82~-1.73,而与黑云母花岗岩共存的热液流体log(fH2O/fHF)fluid,log(fH2OfHCl)fluid,log(fHF/fHCl)fluid值分别为3.27~3.53,2.85~3.22,-0.75~-0.22,可见与两种岩石类型共存热液流体的性质存在明显差异,且热液中Cl、Sn含量变化与岩浆结晶分异指数呈正相关关系.骑田岭岩体从角闪石黑云母花岗岩到黑云母花岗岩,随着岩浆的演化.岩浆结晶期后分异出的热液流体向富Cl和Sn方向演化.芙蓉锡矿田的成矿流体应主要来源于黑云母花岗岩岩浆结晶期后分异出的岩浆热液.  相似文献   

16.
锡在地质过程中表现出亲氧、亲硫和亲铁三重特性。在地幔岩浆过程中,锡是一种中等不相容的金属元素。锡成矿主要与酸性岩浆活动有关,其地球化学性质决定了其成矿主要受源区性质、氧逸度以及挥发分含量、岩浆结晶分异等因素控制。高度结晶分异可使锡在岩浆中进一步富集,是锡成矿相关花岗岩的普遍特征;锡为变价元素,岩浆体系氧逸度影响源区中锡的迁移能力和分离结晶过程中锡的元素行为,还原性岩浆体系有利于锡富集成矿。富含F、Cl和B等挥发组分对锡元素的迁移和富集起积极的作用。全球锡矿床分布与俯冲带关系密切,特提斯和环太平洋构造域是主要蕴藏区。重要的锡成矿事件表现出区域性和阶段性的特征。结合锡的地球化学特性以及锡矿分布特征,我们认为最有利锡成矿的动力学机制是俯冲板片后撤机制。俯冲板片后撤引发深部软流圈地幔上涌,导致强烈的壳幔相互作用,形成低氧逸度、富F、Cl和B等花岗岩,有利于锡成矿。对于华南晚白垩世锡成矿事件,新特提斯洋俯冲板片发生后撤是其成矿地球动力学背景。  相似文献   

17.
The Rooiberg tin field, also known as the Rooiberg Fragment, is located within the western lobe of the Bushveld Complex. The fragment is triangular-shaped, consists of early Proterozoic Transvaal Sequence volcano-sedimentary rocks, and is surrounded by granitoid intrusives of the Lebowa Granite Suite. Practically all the significant tin deposits are hosted by arkoses, located towards the transition with shaly arkoses at the stratigraphic top of the Boschoffsberg Quartzite Member. This stratabound distribution of individual deposits gave rise to the concept of a regionally developed continuous stanniferous zone. On regional scale, the individual deposits are broadly similar and are collectively classified as replacement and open space-filling type. Particular styles of mineralization such as tourmaline pockets/orbicules, disseminated cassiterite, steep and flat dipping sulphidic fractures and hydrothermal carbonate breccias appear to dominate each mine. Petrological and geochemical investigations of four mineralized centres, indicated the presence of a 500–600 m thick stratified zone of pervasively altered clastic sedimentary rocks of possible arkosic precursor composition. Alteration displays a distinct zonal distribution consisting of a grey-green sodic (albitized) foot wall, an approximately 80 m transitional sericitized-tourmalinized sulphidic tin zone and red hematitic potassic hanging wall. The observed zonal pattern and localization of economically significant cassiterite, is explained by the evolutionary path of magmatic stanniferous hydrothermal fluids genetically related to the surrounding acid phase of the Bushveld Complex. Areas of high fracture density, the tectonic focal points, acted as conduits for the ascending reactive fluids. Factors such as fluid-lithostatic pressure equilibration, limited fracture evolution and/or impermeable shaly arkose retarded this ascent. As a result accumulation, lateral spreading of fluid and pervasive alteration occurred over a broad stratified front. Lateral overlapping of these fronts creates the impression of a continuous tin zone. Abundance of geochemical common denominators between the various focal points (mines) supports a shared composition and source for these contemporaneous fluids.  相似文献   

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陈晓翠  毛凯楠  杨巍  杨梧  闫俊  李朋  姜海 《地质学报》2023,97(11):3846-3860
锡矿床全球空间分布高度不均,成矿与花岗岩密切相关,对花岗岩Sn成矿作用的研究受到学界高度重视。准确示踪岩浆源区和精细刻画岩浆演化过程对理解花岗岩与对Sn成矿之间的关系十分关键。磷灰石作为花岗岩类岩石中常见的副矿物,其化学组成在示踪花岗岩岩浆源区和成岩过程方面有独特优势。本文对滇西腾冲-梁河锡矿带具有代表性的小龙河锡矿床,对矿区内的花岗岩展开磷灰石原位化学成分分析。研究结果表明,小龙河锡矿区的花岗岩为一套高分异花岗岩,显示A型花岗岩特征,主要源于地壳物质熔融,花岗岩形成于相对还原的环境,富F且含有一定量的Cl元素。上述岩石地球化学特征有利于花岗岩浆演化过程中Sn的富集和迁移,说明磷灰石的成分特征可以很好地指示花岗岩浆的成因、演化及其物理化学条件,能有效评价花岗岩的Sn成矿能力。  相似文献   

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大东山锡矿田矿化类型复杂,其中矽卡岩型锡矿规模大,可分含锡矽卡岩型和硫化物矽卡岩型。岩体区有脉状和面状云英岩产出,前者多具锡矿化,后者具钨矿化。燕山第四期花岗岩是锡(钨)成矿母岩,含SiO274.96%~75.28%,K2O+Na2O7.37%~8.54%,K2O>Na2O,与南岭地区钨锡成矿岩体具有相似的岩石化学特征。锡矿成因类型可划分为接触交代型、侵入岩浆热液型和风化矿床。根据成矿地质条件,认为在接触带寻找硫化物矽卡岩、硫化物型锡矿有较大前景,而在岩体区具有寻找云英岩型钨矿的潜力。  相似文献   

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