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1.
《Chemie der Erde / Geochemistry》2023,83(1):125924
Two-mica granite is the most common magmatic rock type in the Himalayan leucogranite belt, which has close relationship with rare metal mineralization. Its genesis is generally attributed to magmatic differentiation. In recent years, the mineral geochemical compositions are increasingly used to study magmatic differentiation, which are significant for deciphering the melt evolution and element migration processes. In this study, in-situ major and trace element and boron isotope compositions for tourmalines from two-mica granites in the Cuona and Cuonadong leucogranites in the Cuona area are conducted to determine microscopic changes in mineral assemblages and geochemical compositions. Analytical results show that the tourmalines in the Cuonadong leucogranite were crystallized earlier relative to the tourmalines in the Cuona leucogranite during magmatic differentiation. The volatile contents have a genetic relationship with incompatible elements in tourmaline, which is possibly responsible for the formation of tourmaline zonation and the enrichment of Sr, Zn, and Pb during magmatic differentiation. The B isotopic composition of tourmaline in the Cuona area suggests that the granitic magma was dominantly derived from the partial melting of the metasedimentary source rocks. Their B isotope variations likely resulted from fluid exsolution during B-rich melt evolution. High rare metal contents in tourmalines indicate that the two-mica granites in the Cuona area may have great mineralization potential. 相似文献
2.
In the eastern Sierras Pampeanas, Central Argentina, tourmalinites and coticules are found in close association with stratabound scheelite deposits in metamorphic terranes. In Sierra Grande (Agua de Ramón and Ambul districts) and Sierra de Altautina, tourmalinites are associated with stratabound scheelite deposits related to orthoamphibolites. In the Pampa del Tamboreo area, tourmalinites are located in biotite schists stratigraphically related to acid to intermediate metavolcanic rocks and scheelite-bearing quartzites.The mineral chemistry and boron isotopic compositions of tourmalinite-hosted and vein-hosted tourmalines are investigated. Overall, the tourmalines belong to the dravite-schorl series and are generally aluminous; Fe/(Fe+Mg) ranges from 0.33 to 0.85, Al/(Al+Fe+Mg) from 0.66 to 0.76 and the amount of X-site vacancy (0.12–0.48) indicates significant foitite components. Their boron isotopic compositions (δ11B) are from −24.0‰ to−15.0‰.Similar mineral chemistries and boron isotopic values for tourmaline in tourmalinites related to stratabound scheelite mineralisation and in tungsten-bearing quartz veins suggest a common source for the boron and probably the tungsten. The field, chemical and isotopic relationships are consistent with tungsten and boron in quartz-vein deposits being remobilised from stratabound scheelite and tourmalinite, dominantly by liquid-state transfer associated with regional shear zones. Tungsten and boron in the original sedimentary sequence (now meta-exhalites) are ascribed to volcanogenic exhalations. 相似文献
3.
The Songqi region, SW Henan, is an important bauxite province in China. The bauxite ore deposits occur unconformably on the top of Middle Ordovician argillaceous carbonates. The bauxite ores from the Songqi region are characterized by unusually high boron contents. In this paper, we report the mineralogical and chemical compositions of selected bauxite ores from the region. These new data, together with existing geochemical data of soils in the region, are used to evaluate the origin of boron enrichment in the bauxite ores. The compositional characteristics of tourmaline in the bauxite ores suggests that this mineral was likely derived from a meta-sedimentary protolith. Mass balance calculation reveals that tourmaline only accounts for a small portion of boron in the bauxite ores; the majority of boron in the ores must occur in other forms, possibly by ion absorption on the surfaces of diaspore and clay minerals. In the Songqi region, the Precambrian meta-sedimentary rocks are known to contain abundant tourmalines whereas the Cambrian–Ordovician argillaceous carbonates and the Upper Proterozoic shales are all enriched in boron in free ion state. We suggest that these rocks provided tourmaline and boron ion to the bauxite deposits in the region. Most known bauxite deposits in the Songqi region occur at the margins of boron-rich soil domains, suggesting that boron in soils is a potential exploration indicator for unknown bauxite deposits in this region. 相似文献
4.
在研究马超营断裂带主要金矿床的流体包裹体组成及成分特征基础上, 综合分析归纳了流体系统地球化学特征, 研究了流体的组成、来源及演化特征, 认为成矿流体具有低盐度、弱碱性及较高矿化度的混合成因特点, 早期成矿流体以深源为主, 晚期则混有大量大气水演化形成, 分析了影响流体演化的控制因素及金等成矿物质在流体中的迁移、沉淀机制, 提出流体活动是成矿作用的核心, 对成矿流体系统的研究, 有助于从本质上揭示马超营断裂带金矿成矿条件和成因, 更好地认识金矿成矿规律与进行成矿预测。 相似文献
5.
A microprobe study has been carried out on the chemical composition of tourmaline from the Yindongzi and Tongmugou stratabound Pb-Zn ore deposits, eastern Qinling, China. Tourmaline was analysed from a variety of rock types representative of its various occurrences associated with the ore bodies. All the tourmalines studied here belong to the schorl-dravite series. Most are of hydrothermal origin with Mg > Fe and Na > Ca. Some detrital cores of tourmaline have been recognized from their geometry and chemistry, with Fe > Mg. The chemical trends from core to rim in zoned grains suggest a multi-stage model for the growth of tourmaline and genesis of the ore bodies. The first stage was represented by a more Mg-rich hydrothermal fluid in the submarine hydrothermal system, producing Mg-rich tourmalines by selective replacement of clay-rich sediments close to the sediment-water interface. The second stage was dominated by Fe-rich hydrothermal fluid and resulted in overgrowth of Fe-rich tourmaline rims. This stage also led to the nucleation and growth of new tourmaline crystals and was responsible for the formation of the main massive sulphide orebodies. Finally, a further period of hydrothermal activity or a metamorphic event led to the formation of an additional rim of Mg-rich tourmaline. 相似文献
6.
矿产勘查地球化学:过去的成就与未来的挑战 总被引：24，自引：0，他引：24
勘查地球化学经过 70年的发展 ,已从矿产勘查从属地位的一种战术手段上升到能左右整个矿产勘查全局的战略地位 ,并且从一门经验或技术 ,发展成为一门地学分支科学。这主要表现在 (1)系统地建立了各种类型的地球化学分散模式 ,并根据这些分散模式所形成的地球化学异常去追踪和发现矿床的理论 ;(2 )发展了各种尺度和各种不同介质的地球化学采样方法 ,多元素高灵敏分析方法和数据处理与图件表达方法 ;(3)发展了不同尺度 (局部、区域、国家和全球 )地球化学填图理论 ,一些国家开始陆续完成和出版了区域性或国家性地球化学图 ;(4 )在全世界发现了一大批新的矿产地 ,包括从 2 0世纪 30年代一直延续到 70年代在前苏联、北美和南美发现的许多斑岩铜矿 ,70年代在北美发现许多铀矿 ,80年代开始在中国发现数百个金矿。勘查地球化学尽管取得了从理论到实践的很大成功 ,但它也面临如下的挑战 :(1)全球各种介质中的地球化学基准与全球地球化学填图 ,(2 )隐伏区三维地球化学分散模式、深穿透地球化学与隐伏区矿产勘查 ,(3)巨量金属的聚集机理、地球化学块体与大型矿集区或巨型矿床的定量评价 ,(4 )难识别矿种或难识别类型的地球化学勘查与评价方法。 相似文献
7.
Sheng Jifu Zhang Dequan Li YanInstitute of Mineral Deposits Chinese Academy of Geological Sciences Beijing Jiang M inxi 《《地质学报》英文版》1995,69(3):289-302
Physicochemical parameters of mineralization such as temperature, pressure, salinity, density, composition and boiling of ore fluids as well as pH, Eh, fo2 and reducing parameter in theprocess of mineralization of major ore deposits in the study district have been obtained by the authors through systematic observation and determination of characteristics and phase changes of fluid inclusions at different temperatures and analysis of gaseous and liquid phase compositions of the inclusions, thus providing a scientific basis for the division of mineralization-alteration stages, types of mineral deposits and minerogenetic series and the deepening of the knowledge about the ore-forming processes and mechanisms of mineral deposits. It is indicated that the deposits of the same type have similar fluid inclusion geochemical features and physicochemical parameters though they belong to different minerogenetic series, while the compositions of inclusions are not conditioned by deposit types but closely related to 相似文献
8.
我国积累的大量高质量、多元素、多尺度的地球化学数据,为矿产勘查与环境评价提供了有效的数据支撑。如何对这些数据进行二次开发和再利用,提取有价值的地球化学异常信息并带动找矿突破,是缓解当前矿产资源短缺的重要途径之一。在覆盖区和深部的找矿实践中,由于矿体埋深和覆盖层的影响,往往在表生介质中形成弱小的地球化学异常,识别和评价弱小地球化学异常是当前勘查地球化学数据处理的重要方向之一。本文围绕地球化学异常信息的提取和评价,主要从以下几个方面讨论了相关的国内外研究进展和发展趋势:勘查地球化学数据处理与异常识别方法和模型,勘查地球化学数据闭合效应的影响及其解决方案,基于大数据和机器学习的勘查地球化学数据处理以及弱小地球化学异常的识别和评价。研究发现,在地质环境的约束下,基于大数据思维和机器学习相结合的方法,注重地球化学空间分布模式与已发现矿床的相关关系,同时使用所有地球化学变量能有效刻画具有非线性特征的地球化学空间分布模式,可识别出传统方法无法识别的异常,为开展地球化学空间模式识别与异常提取提供了新的途径。 相似文献
9.
汪玉琼 《物探化探计算技术》2004,26(1):37-42
地球化学块体制作方法主要是运用地球化学块体的理论与方法技术，利用GeoMDIS2000软件系统制作地球化学块体图及统计与块体相关的参数。并通过对贵州区域化探资料剖析，划分出不同级次的地球化学块体，进行资源潜力评价和矿床规模预测。为矿产资源勘查及新一轮异常查证提供了战略靶区。 相似文献
10.
勘查地球化学的现状与未来展望 总被引：28，自引：2，他引：28
勘查地球化学在过去50年发展迅速,并取得巨大成功。从它近年的发展及在中国北京与澳大利亚Townsville召开的第16届及第17届国际地球化学勘查学术讨论会上所表现的创新与非传统性看来,勘查地球化学正在从经验式阶段向革新技术与加强理论研究的新阶段过渡。其主要标志是由于国际地球化学填图研究的进展及各种宽阔地球化学模式的认识,地球化学勘查将逐步成为能左右矿产勘查部署的战略性方法,各种新技术的出现使隐伏区找矿特别是找巨型矿床正在取得重大突破。高质量的地球化学图还将使今后的环境研究更具全球眼光,中国的工作是这些方 相似文献
11.
地球化学测量成果被广泛而成熟地运用在矿产勘查工作中,为明确张家口崇礼区北部成矿、找矿的地球化学指示信息,对该区水系沉积物测量及异常查证成果进行了综合分析。通过计算元素富集系数和变异系数、开展R型聚类分析、统计化探异常区岩石的地质年代、对比该区化探异常及已知矿床与典型矿床的成矿要素,从而推断了该区找矿主攻元素为Ag、Pb、Zn、Mo、Cd,且Ag、Pb、Zn和Mo、W 2组元素分别具有共伴生关系,指出该区化探异常主要受燕山期岩浆热液控制。综合分析认为,本区找矿模型为蔡家营式次火山-热液型多金属矿床,具有寻找次火山-热液型Ag、Pb、Zn、Mo多金属矿床的潜力。 相似文献
12.
文章总结了20世纪冶金地质化探工作中的10项有创新、并取得显著找矿效果的成果:找金矿盲矿体的构造叠加晕模式、汞气测量和热释汞测量寻找隐伏矿床、典型有色金属矿床地球化学异常模式研究、中国主要类型金矿找矿模型研究、胶东金矿带盲矿预测的原生地球化学专家系统、包裹体气晕、离子晕及其叠加晕找金新方法、脉钨矿床的"三环一帽式"地球化学异常模式、应用卤素找盲矿和土壤热释卤素新方法、建立优质锰矿床的地球化学找矿模型、区带化探找贵金属及有色金属矿产. 相似文献
13.
地球化学岩相学类型及其在沉积盆地分析中应用 总被引：1，自引：0，他引：1
按照流体地球化学动力学-岩石组合系列,地球化学岩相学相系统类型分为氧化-还原相(ORF)、酸碱相(Eh-pH F)、盐度相（SF）、温度相（TF）、压力相（PF）、化学位相（CF）、不等化学位相和不等时不等化学位地球化学岩相等8种。在沉积盆地分析中,地球化学岩相学主要用于沉积盆地物质组成及演化历史研究,恢复重建沉积盆地中流体场类型和成分特征、流体场分布范围及运移规律、流体场大规模运移机制及动力学、盆地改造过程中流体叠加关系等,进行深部找矿预测。 相似文献
14.
15.
大陆块体地球化学边界与成矿——兼论中国东秦岭金属矿集区的构造控制 总被引：9，自引：0，他引：9
地球块体不均一性边界存在地球化学急变带 ,控制大型矿床的分布 ;深部构造或隐性的构造面与地壳浅表形成的矿集区有明显的空间和形成机制耦合关系。地球化学急变带在大陆内部往往沿着一些古大陆边缘展布 ,与地壳下部和上地幔的深部构造或扩展到地幔的不连续面具有相联系的空间组合关系 ,反映壳幔相互作用对深部构造效应和大规模成矿热流体的控制。东秦岭金属矿化集中区的大型或超大型矿床沿古大陆边缘产出 ,并受地球化学急变带与地球物理梯度带交叉效应控制 ,揭示了深部构造对大型矿集区的制约。 相似文献
16.
The Laloki and Federal Flag deposits are two of the many (over 45) polymetallic massive sulfide deposits that occur in the Astrolabe Mineral Field, Papua New Guinea. New data of the mineralogical compositions, mineral textures, and fluid inclusion studies on sphalerite from Laloki and Federal Flag deposits were investigated to clarify physiochemical conditions of the mineralization at both deposits. The two deposits are located about 2 km apart and they are stratigraphically hosted by siliceous to carbonaceous claystone and rare gray chert of Paleocene–Eocene age. Massive sulfide ore and host rock samples were collected from each deposit for mineralogical, geochemical, and fluid inclusion studies. Mineralization at the Laloki deposit consists of early‐stage massive sulfide mineralization (sphalerite‐barite, chalcopyrite, and pyrite–marcasite) and late‐stage brecciation and remobilization of early‐stage massive sulfides that was accompanied by late‐stage sphalerite mineralization. Occurrence of native gold blebs in early‐stage massive pyrite–marcasite‐chalcopyrite ore with the association of pyrrhotite‐hematite and abundant planktonic foraminifera remnants was due to reduction of hydrothermal fluids by the reaction with organic‐rich sediments and seawater mixing. Precipitation of fine‐grained gold blebs in late‐stage Fe‐rich sphalerite resulted from low temperature and higher salinity ore fluids in sulfur reducing conditions. In contrast, the massive sulfide ores from the Federal Flag deposit contain Fe‐rich sphalerite and subordinate sulfarsenides. Native gold blebs occur as inclusions in Fe‐rich sphalerite, along sphalerite grain boundaries, and in the siliceous‐hematitic matrix. Such occurrences of native gold suggest that gold was initially precipitated from high‐temperature, moderate to highly reduced, low‐sulfur ore fluids. Concentrations of Au and Ag from both Laloki and Federal Flag deposits were within the range (<10 ppm Au and <100 ppm Ag) of massive sulfides at a mid‐ocean ridge setting rather than typical arc‐type massive sulfides. The complex relationship between FeS contents in sphalerite and gold grades of both deposits is probably due to the initial deposition of gold on the seafloor that may have been controlled by factors such as Au complexes, pH, and fO2 in combination with temperature and sulfur fugacity. 相似文献
17.
隐伏矿床上方纳米铜颗粒存在形式与成因 总被引：3，自引：0，他引：3
在铜镍矿床覆盖层土壤颗粒中和其下伏原生矿石中同时采集到金属纳米颗粒,颗粒在其粒径大小、形貌、连接和簇聚形式、微粒元素组合等性质上相似,表明两者为同成因物质,是内生成矿作用元素存在形式,土壤颗粒中金属纳米颗粒来自深部矿体。在金矿上方土壤颗粒中采集的纳米金属颗粒,与在铜镍矿床覆盖层土壤颗粒中采集观测到的微粒,在微粒性质可以对比,表明元素的纳米微粒是稳定形式,在其源区形成后可借助多种营力,穿越后期地质作用覆盖层,在近地表被土壤地球化学障捕获滞留,是深部矿化的有效传递物质。深穿透地球化学技术可从土壤中分离富集采集到此纳米微粒,并通过其微粒性质,追踪其源区性质。此研究结果在实用意义上,可为以土壤作为采样介质的深穿透地球化学勘查探测覆盖区隐伏矿方法提供理论依据。 相似文献
18.
东天山中段区域化探异常评价方法研究 总被引：3，自引：0，他引：3
本文利用1/20万区域化探数据,研究了东天山中段地区针对不同类型铜矿化的元素组合异常圈定方法。选择典型（含）铜矿床及其周围地段的化探测量点为建模样本,通过因子分析,查明针对不同矿化类型的指示元素定量组合;以因子得分为综合指标,用泛克里格剩余值圈定化探异常。结果得到3个元素组合：Cu-Co-Ni-Mn-V-Fe-Cr组合... 相似文献
19.
关于亲花岗岩类矿床研究的进展和趋势 总被引：1，自引：0，他引：1
本文试就矿床与花岗岩类侵入体存在成因联系的证据、亲花岗岩类矿床形成的地球化学因素和岩石成因因素三方面的研究进展和趋势作简短概述。矿床和火成岩在地理上的伴生、分带现象、金属与特殊种属花岗岩类之间的关系、岩体微量元素的浓度与其伴生矿床的关系以及相对年代关系,是确定矿床和火成岩之间存在成因联系的依据。元素离子的电子层构造、离子半径和离子势等地球化学性质与矿石沉积地点、母火成岩成分、矿石形成方式、矿物生成顺序、矿石矿物成分、矿质沉淀温度以及矿石形成深度等都有内在联系。花岗岩类岩荣的形成与矿质的富集、岩浆和富水流体之间的关系和造矿元素在岩浆与富水流体之间的分配关系是控制矿床形成的三个关键性因素。 相似文献
20.
流体地质填图是一种全新的地质调查及找矿方法。本次研究选择云南巍山－永平矿集区进行流体地质填图试验，研究了矿集区的控矿地质要素、各种主要的矿床（点）特征、成矿流体子系统及流域、流体的盐度与均一温度、流体的气液相成分、微量元素含量、稳定同位素特征及成矿流体的浓集中心。得到的流体地质图基本反映了本区成矿流体的性质与状态，反映了两个成矿流体子系统的基本特征，圈字了2个成矿流体子系统的流域范围及7个成矿流体浓集中心。这些浓集中心与已知矿化点分布、化探异常及有利的地质条件基本吻合，成为该区进一步找矿预测的重要依据之一。本项目的实践表明，流体地质填图不失为一种有效的找矿手段。 相似文献