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1.
内蒙古西乌旗地区大石寨组火山岩时代及地球化学特征 总被引：4，自引：1，他引：3
西乌旗地区大石寨组火山岩以流纹岩为主,LA-ICP-MS锆石U-Pb同位素测定结果及全岩主量、微量和稀土元素分析结果表明,本区流纹岩的年龄为280.3Ma±1.4Ma,形成于早二叠世;大石寨组火山岩属高钾过铝质钙碱性火山岩,其中SiO2、K2O、Al2O3含量均较高。稀土元素配分曲线总体向右缓倾斜,轻稀土元素相对于重稀土元素富集,Eu呈明显的负异常,重稀土元素亏损不明显。Rb、Th、U、K等大离子亲石元素富集明显,Ba表现为弱亏损,高场强元素具有明显的Ta、Sr、P及Ti亏损,Zr、Hf相对富集。研究认为,该地区流纹岩可能是由玄武岩、安山岩等中基性火山岩分离结晶作用形成的,且形成的构造环境为大陆边缘弧。 相似文献
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西天山备战铁矿火山岩地球化学特征、锆石U-Pb年代学及Hf同位素组成研究 总被引：3，自引：0，他引：3
备战铁矿是西天山阿吾拉勒成矿带新近发现的大型铁矿之一,矿区广泛发育下石炭统火山岩。本文对矿区火山岩进行了主量元素、微量元素、稀土元素地球化学特征分析、LA-ICP-MS锆石U-Pb测年以及锆石Lu-Hf同位素组成研究,以探讨矿区大哈拉军山组火山岩产出的构造环境、备战铁矿的成岩成矿时代和火山岩的来源。矿区火山岩主要由玄武岩、玄武安山岩、安山岩、流纹岩组成,以中基性岩为主,大多为高钾钙碱性系列;微量元素和稀土元素表明矿区火山岩产出构造环境为活动陆缘火山岛弧;锆石U-Pb测试结果显示矿区南部斜长花岗斑岩的形成时代为晚石炭世早期(301±0.93Ma),成矿时代为早石炭世晚期。结合地质背景认为该铁矿至少有两期成矿期,在成因上为火山沉积后期叠加矽卡岩化的磁铁矿矿床。锆石Lu-Hf同位素组成特征表明备战铁矿的岩石来源于元古代、太古代地壳物质的部分熔融,并且源区物质在地壳中存在较长的时间。 相似文献
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沙泉子铁铜矿床是东天山地区赋存于火山岩中的矿床之一。矿体产于底坎尔组玄武岩与英安岩接触部位,在闪长玢岩与围岩接触带上也可见不规则铁矿化。对火山岩的形成时代以及构造地质背景的研究是重建成矿过程的关键。LA-ICP-MS锆石U-Pb定年结果表明,沙泉子铁铜矿区底坎尔组流纹岩和闪长玢岩的206Pb/238U加权平均年龄分别为(321.7±1.7)Ma和(322.2±1.7)Ma,是早石炭世末岩浆活动的产物。元素地球化学和Hf同位素特征表明,底坎尔组火山岩属钙碱性系列,富集轻稀土元素(LREE)和大离子亲石元素(LILE),亏损高场强元素(Nb、Ta、Ti),具有岛弧火山岩地球化学特征。基性岩来源于受俯冲板片流体交代的亏损地幔,中性岩为基性岩分离结晶的产物,流纹岩是新生地壳物质部分熔融形成。综合前人研究成果表明,沙泉子铁铜矿床形成于早石炭世末陆缘弧环境,铁矿化不早于322 Ma。 相似文献
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西天山查岗诺尔和智博铁矿区火山岩地球化学特征、锆石U-Pb年龄及地质意义 总被引：18，自引：4，他引：14
西天山东段的查岗诺尔铁矿和智博铁矿赋存于以玄武岩、玄武安山岩、粗面岩以及安山质凝灰岩为主的晚石炭世火山岩中, 对火山岩的形成时代以及构造地质背景的研究是重建成矿过程的关键。本文通过对两个矿区的火山岩进行岩石地球化学和LA-ICP-MS锆石U-Pb测年分析来探讨火山岩形成的构造环境与时代。地球化学分析表明大多数火山岩化学成分从钙碱性、高钾钙碱性变化到钾玄岩系列,富集轻稀土元素(LREE)和大离子亲石元素(LILE; 如Rb、Th、K),重稀土元素(HREE)配分平坦,同时具有Nb、Ta、Ti的强烈亏损,类似于岛弧火山岩的地球化学特征。大多数玄武质火山岩在构造环境判别图中位于火山弧环境。LA-ICP-MS锆石U-Pb测年显示流纹岩和英安岩的206Pb/238U加权平均年龄分别为301.8±0.9Ma和300.3±1.1Ma。此外,对两件闪长岩样品测年获得206Pb/238U加权平均年龄介于303.8～305Ma之间。火山岩与闪长岩样品具有类似的地球化学特征以及形成时代,表明它们可能来源于同一母岩浆,形成于相同的构造背景下。结合区域地质资料,本文认为矿区内出露的高钾钙碱性到钾玄岩系列火山岩可能属于俯冲过程末期阶段大陆岛弧岩浆作用的产物。 相似文献
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式可布台铁矿位于西天山阿吾拉勒铁矿成矿带西段,是此矿带极具代表性的铁矿床。主要赋存于以凝灰岩为主的石炭系上统伊什基里克组火山岩中。本文通过对式可布台矿区的火山岩进行岩石地球化学和LA-ICPMS锆石U-Pb测年分析来探讨火山岩形成的构造环境与成岩时代。地球化学分析表明大多数火山岩样品显示为高钾钙碱性系列;主量元素表明矿区火山岩主要由安山岩、英安岩、流纹英安岩组成,为钙碱性系列;微量元素和稀土元素表明矿区火山岩产出的构造环境为火山岛弧;LA-ICPMS锆石U-Pb测年显示火山岩的206Pb/238U加权平均年龄分别为(301±1)Ma和(313±2)Ma,表明该区的火山岩为晚石炭世早期。结合区域地质资料,认为矿区内出露的高钾钙碱性系列火山岩可能属于俯冲过程末期大陆岛弧岩浆作用的产物,其岩石的形成与构造岛弧环境有关,主体与下石炭统大哈拉军山组火山岩岩石化学特征相似。 相似文献
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西天山乌孙山地区大哈拉军山组火山岩LA-ICP-MS锆石U-Pb年龄及其构造环境 总被引：5，自引：0，他引：5
西天山乌孙山地区大哈拉军山组由玄武岩、安山岩、英安岩、流纹岩及相应的火山碎屑岩组成,安山岩和流纹岩分布最广。LA-ICP-MS锆石U-Pb定年结果表明,火山活动喷发的安山岩与安山质晶屑凝灰熔岩分别形成于353.9Ma±6.5Ma和356.3Ma±4.4Ma,属于早石炭世早期。通过区域对比,西天山大哈拉军山组的火山岩浆作用显示从伊犁中天山板块南北缘向伊犁盆地内部逐渐变年轻的特点,且火山岩喷发时代差别不大(约40Ma)。岩石地球化学研究表明,火山岩属钙碱性系列,富集轻稀土元素,相对亏损重稀土元素。中性火山岩富集大离子亲石元素(如Cs、Rb、Th、U),而相对亏损高场强元素,具有明显的Nb、Ta、Ti负异常,显示出岛弧火山岩的特征;酸性火山岩相对富集Rb、Th、U、Ta等元素,具有明显的Ba、Sr、P、Eu、Ti等元素的负异常。综合伊犁-中天山板块南缘的构造演化特征,认为大哈拉军山组形成于活动大陆边缘环境,产在板块俯冲-碰撞的最后阶段。 相似文献
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阿吾拉勒成矿带位于新疆西天山伊犁地块东北缘,是一条极其重要的铁、铜、金多金属成矿带。松湖铁矿床位于该成矿带西段,矿区出露的地层主要为一套钙碱性系列的火山岩,岩石类型有安山岩、安山质火山碎屑、少量英安岩、流纹岩及等质的火山碎屑岩。铁矿体赋存于安山岩及安山质火山碎屑岩中。安山岩中锆石U-Pb谐和年龄为(343.2±2)Ma,属早石炭世维宪期。该组火山岩具有相似的稀土元素及微量元素地球化学特征,暗示它们应为同源岩浆演化的产物。其微量元素组成具有富集大离子亲石元素(Rb、Ba、Th、K等)和轻稀土元素、亏损高场强元素(Nb、Ta和Ti)的特点,显示活动大陆边缘火山岩特征。矿区安山岩的Nd同位素组成具有亏损型特征(εNd(t)=+2.09~+3.39,平均值为+2.59),而Sr同位素组成为富集型((87Sr/86Sr)i=0.7056~0.7060),显示其岩浆源区应为莫霍面附近的岛弧型地壳根部。 相似文献
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拉萨地块南缘日多地区叶巴组火山岩地球化学、年代学、锆石Lu-Hf同位素特征及其地质意义 总被引：2，自引：1，他引：1
拉萨地块南缘日多地区叶巴组火山岩以中酸性熔岩及火山碎屑岩占绝对优势为特征。以墨竹工卡县以东日多地区叶巴组火山岩代表性岩石组合为对象进行了地球化学、LA-ICP-MS锆石U-Pb年龄及锆石Lu-Hf同位素研究。研究结果表明,叶巴组火山岩具有轻稀土元素富集,富集大离子亲石元素Rb、Th、K,亏损高场强元素Nb、Ta、Ti(P、Hf)的地球化学特征。其中,基性火山岩具低钾、低钛和富钠、富铝的特征,Nb、Zr含量和Th/Y、Th/Yb、Ta/Yb值较高,而La/Nb值较低,呈现出大陆地壳组分增加的趋势。中酸性火山岩属中钾-高钾钙碱性系列,具有低钛、低镁和高铝的特征,微量元素含量及比值与大陆岛弧安山岩接近。叶巴组火山岩总体地球化学特征与陆缘弧火山岩相似。LA-ICP-MS锆石U-Pb测年获得英安岩和流纹质晶屑凝灰岩~(206)Pb/~(238)U年龄加权平均值分别为176.9±2.3Ma和162.2±3.3Ma,表明研究区叶巴组酸性火山岩形成于中侏罗世。锆石Hf同位素测试结果显示,εHf(t)值为2.43~11.42,二阶段模式年龄(t_(DM)~C)为482~1065Ma,暗示叶巴组酸性火山岩源区除新生地壳物质的部分熔融外,还明显受到古老结晶基底的影响。结合前人研究成果,认为叶巴组形成于早中侏罗世雅鲁藏布江洋北向俯冲于拉萨地块南缘之下的陆缘弧环境。 相似文献
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西天山查岗诺尔铁矿区石炭纪火山岩地球化学特征及岩石成因 总被引：9，自引：0，他引：9
对伊犁地块东北缘查岗诺尔铁矿区石炭纪火山岩进行了系统的岩石学,锆石U-Pb年代学,岩石地球化学,Nd、Sr同位素地球化学研究.该区火山岩包括玄武岩(少量)、粗面岩、安山岩、流纹岩以及火山碎屑岩,它们的化学组成绝大多数属于钾玄岩系列和高钾钙碱性系列,少数玄武岩和安山岩属于钙碱性和低钾拉斑玄武岩系列.微量元素方面,它们相对... 相似文献
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Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献
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Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world. 相似文献
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《Geoforum》2017
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South. 相似文献
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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
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I. Bejarano-Ramirez Jose M. Jurado R. Muñiz-Valencia Á. Alcázar Silvia G. Ceballos-Magaña A. Olivos-Ortiz O. Rangel 《International Journal of Environmental Science and Technology》2017,14(6):1333-1342
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments). 相似文献
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Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability. 相似文献
18.
Hirokazu Fujimaki 《Contributions to Mineralogy and Petrology》1986,94(1):42-45
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite. 相似文献
19.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification
(e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes
of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application
inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen
constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter
are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system,
our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro
and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically
applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect
to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics
can be extracted from the new statistics; however, substantial additional information is also available. From the practical
point of view, E-classification is substantially faster than the Zingg method. 相似文献
20.
Pools,riffles, and channelization 总被引：2，自引：0，他引：2
Edward A. Keller 《Environmental Geology》1978,2(2):119-127
The addition of regularly spaced deeps (pools) and shallows (riffles) that provide a variety of flow conditions, areal sorting
of stream-bed material, cover for wildlife, and a positive aesthetic experience, may be desirable in many channel projects.
Such designs will reduce adverse environmental impacts of stream channel modifications.
Analysis of variance for pool-to-pool spacing data suggests that there is no significant difference with respect to channel
width between pools that form in natural streams and those in streams affected by a variety of human uses. Short of channelization,
which changes the channel width, pools and riffles, within limits, are not particularly sensitive to environmental stress.
Experiments in Gum Branch near Charlotte, North Carolina, support the hypothesis that channel form and process evolve in harmony
and that manipulation of cross-channel morphology can influence the development of desired channel processes. Planned manipulation
of its channel form induced Gum Branch to develop as desired. Morphologic stability consisting of incipient point bars, pools,
and riffles was maintained over a period of high magnitude flood events, only to be degraded later by a wave of sediment derived
from upstream construction and stream-bank failures. Thus, environmentally desirable channel morphology in urban streams cannot
remain stable if changes in the sediment load or storm-water runoff exceed the limits of the stream's ability to make internal
adjustments while maintaining morphologic stability. 相似文献