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1.
江西省横迳温泉区地热气体地球化学   总被引：2，自引：0，他引：2  
孙占学  高柏  刘金辉 《现代地质》2004,18(1):116-120
从赣南横迳温泉区采集10个水样并分析了温泉及冷泉的水化学成分,认为热水起源于大气降水补给。在此基础上,还在温泉区采集了4个气样,测定了气体组分的含量及氦同位素．以及CO2和CH4的碳同位素。研究结果表明：横迳地区温泉气中CO2的含量很高(>96％),δCCO2较重(-4.43‰～-5.50‰),属幔源CO2;He同位素特征值(R/Ra)变化于1.36～2.11之问．均大于1,有幔源He的加入;本区温泉气的的组合类型为二氧化碳幔源温泉气,从整体上来说属于幔源无机成因气,是地幔脱气的产物。  相似文献   

2.
深部物质运动的气体地球化学特征   总被引：10，自引：0，他引：10  
根据氦同位素地球化学资料讨论了中国东部和云南腾冲地区上地幔的脱气。尽管地球脱气作用主要发生在地球形成时的十亿年间，但是后期的脱气作用仍是影响大气圈演化的主要因素。在两种力学性质不同的构造带──中国东部大陆裂谷和位于欧亚板块与印度板块缝合带的腾冲火山区，采集了天然气样，并分析了气体组分和氦同位素组成，较高的３Ｈｅ／４Ｈｅ值和地质、地球物理资料表明天然气和温泉气中的氦相当一部分是来自上地幔。来自上地幔的氦和其他气体自第三纪以来不断在气藏中聚集或向大气中逃逸。伴有源于上地幔的岩浆活动的地幔脱气是深部物质运动的具体表现形式，它对新生代气候演变可能有直接影响。  相似文献   

3.
腾冲火山区的现代幔源氦释放:构造和岩浆活动意义   总被引：6，自引：3，他引：3  
赵慈平  冉华  王云 《岩石学报》2012,28(4):1189-1204
深地震测深(DSS)和大地电磁测深(MT)都表明腾冲火山区现今仍存在壳内岩浆囊,但对其数量和空间分布还存在分歧并缺乏全貌性认识。MT探测认为腾冲火山区是一个软流圈上涌和岩石圈减薄区,但对这一减薄区的空间范围还缺乏充分的约束。通过对腾冲火山区及外围大范围温泉逸出气体的分析测试,我们共获得了75个温泉逸出气体的氦同位素3He/4He比值数据(部分为前人资料)。利用氦同位素示踪原理,我们研究了腾冲火山区幔源氦释放强度空间分布和时间变化特征,结果发现:腾冲火山区的幔源挥发份释放呈1带3区分布。以3He/4He≥1 Ra,幔源氦比例≥15%为界,腾冲火山区的幔源挥发份释放异常区呈整片分布,为一南北走向的条带,南北长100km,东西宽50km。在整片异常区的内部,腾冲火山区的幔源挥发份释放又有强度不同的3个区域:① 中部腾冲县城-热海一带,3He/4He比值达到5.5 Ra以上,幔源氦比例达到70%以上,释放强度最强。② 北部曲石一带,3He/4He比值达4.5 Ra以上,幔源氦比例达到50%以上,释放强度次之。③ 南部五合-蒲川-新华一带,3He/4He比值达2Ra以上,幔源氦比例达到25%以上,释放强度最弱;腾冲火山区幔源挥发份释放强度在不断升高,其中第3个释放区的3He/4He比值(Ra)升高速率比前两者明显要大。我们认为:腾冲火山区现今幔源挥发份释放强度的空间分布图象就是该地区软流圈上涌和岩石圈减薄区空间尺度和上涌强度的最直接反映,上涌区(减薄区)的大小大致为南北长100km,东西宽50km;腾冲火山区现今存在3个壳内岩浆囊。第1个岩浆囊位于腾冲县城-热海一带,第2个岩浆囊位于马站-曲石一带,第3个岩浆囊位于五合-龙江-团田-蒲川-新华一带;腾冲火山区3个岩浆囊都在不断受到幔源岩浆的持续补充;第1个岩浆囊集幔源挥发份释放、相对地热梯度、地壳形变和地震活动等异常于一身,活动性最强,是未来腾冲火山最可能喷发的地点,需重点监视。第2个岩浆囊的幔源挥发份释放强度也引人注目,需加强监测。第3个岩浆囊规模大,埋深较浅,幔源挥发份释放增加较快,需引起注意。  相似文献   

4.
江西相山铀矿田西部地区实施的铀矿科学深钻3号孔在深部–700 m发现大量铅锌银多金属矿化脉,垂向上呈"上铀下多金属"的分布特征。本文对深部多金属矿化主成矿阶段的黄铁矿、闪锌矿、方铅矿进行了流体包裹体He和Ar同位素组成测定,结果表明,相山深部多金属矿化主成矿阶段的黄铁矿、闪锌矿和方铅矿具有较一致的He、Ar同位素组成,矿物内流体包裹体的~3He含量范围为4.55×10–14～1560×10–14 cm^3·STP/g,~4He含量范围为1.05×10–7～525×10–7 cm^3·STP/g,~3 He/~4He为2.98×10–7～4.96×10–7,即0.21～0.35 Ra,介于地壳(0.01～0.05 Ra)和饱和大气水(1 Ra)之间,明显低于地幔的~3 He/~4He值(6～9 Ra),40Ar浓度为0.969×10–7～157×10–7 cm^3·STP/g,40Ar/36Ar值为303.7～573.9,略高于饱和大气水的Ar同位素组成,结合矿石和蚀变岩石中Li元素富集特征,本文认为相山西部地区深部多金属成矿流体以地壳流体和大气降水为主,成矿流体富Li元素是He同位素明显高于地壳的原因,可能存在少量幔源流体的加入。另外,通过对比前人研究的该地区铀矿化矿石中黄铁矿He-Ar同位素组成,并结合前人对该地区幔源组分明显参与铀成矿的认识,本文认为多金属矿化和铀矿化成矿流体可能并非同一来源。  相似文献   

5.
《Applied Geochemistry》2004,19(5):665-673
Here, a new technique for the determination of dissolved He isotope ratios in ground-waters is presented. This method is based on the extraction and subsequent equilibrium of dissolved gases in an added “host” gas phase. Ultra pure N2 is placed in glass flasks (250 cc), containing water samples, that were hermetically sealed after their collection. After shaking in an ultrasonic bath for 10 min, an aliquot of the separated gas phase was removed from the flask for MS analysis. 3He/4He ratios are measured by using a modified double collector mass spectrometer (VG 5400-TFT). Helium and Ne concentrations are calculated by comparing the partial pressures of masses 4 and 20 of the samples with those of the air-standard measured by a quadrupole mass spectrometer (QMS;VG Quartz). Using He and Ne equilibrium partitioning coefficients, it is possible to calculate the amount of gas originally dissolved in the water. The technique was tested on both air-saturated waters (ASW) and thermal waters from Stromboli (Aeolian Islands, South Italy), the results of which confirmed good reproducibility (≌5%) and accuracy (≌3%) of the data. The method was then applied to three thermal water samples collected from the same volcanic area and the results compared with those of a fumarolic and a soil gas. The isotope ratios for dissolved He gave values of 4.06–4.23 Ra, which are significantly higher than those previously reported in the literature (3.0, 3.5 and 2.9 Ra) and that measured at the fumarole (3.09 Ra), suggesting a newer and higher isotopic signature for the volcanic system. The proposed method appears to be a useful tool in the determination of 3He/4He ratios in ground-water systems, especially when free gases are not available or are dangerous to collect.  相似文献   

6.
In recent years big strides have been made in the exploration of ores in the central-south segment of the Da Hinggan Ling Range, though some debates still exist on the metallogenesis and sources of ore-forming materials. Pyrite and other sulfides in direct relation to the Pb-Zn-Ag ore deposits were chosen for the He and Ar isotopic analysis of ore-forming fluids, and the first He and Ar isotope data have been obtained from the study region. ^3He/^4He ratios in 14 samples collected from 7 mining districts are 2.17×10^-6-12.52×10^-6, averaging 6.86×10^-6 and their R/Ra ratios are 1.56-9.01 Ra, averaging 4.37 Ra. By projecting the data points onto the ^3He-^4He concentrations diagram, all the points fall near the mantle helium area. The calculated mantle-source helium ratios are within the range of 19.58%-76.96%, with an average of 49.52%. Argon isotopic characteristics are close to those of mantle source, indicating that the ore-forming material was transport upwards via the multi-stage evolution of mantle plume and concentrated as ores in the favorable loci of mantle branch structures.  相似文献   

7.
We present He, Ne, Ar, and C isotope analyses of hydrothermal brines and gases from fumaroles, hot springs, mofettes and hydrothermal exploration drillings on the major islands of the Lesser Antilles Arc. The origin of hydrothermal brines, which have been analyzed also for O and H isotopes, is essentially meteoric-hydrothermal. Air-corrected isotope compositions of helium (2.2 Rc/Ra < 3He/4He < 8.6 Rc/Ra) and carbon (−20 < δ13CPDB < +0.5) are variable and require a variety of crustal and magmatic sources. The diversity of δ13CPDB and 3He/CO2 ratios within individual volcanic centres suggests that crustal sources (e.g., limestone) contaminate magmatic CO2 en route from high-level magma reservoirs (depth < 15 km) to the surface. A similar contamination may be found for magmatic helium on distal springs. The 3He/4He signature of summit fumaroles, thought to reflect the 3He/4He signature of high-level magmas, shows a remarkable systematic variation along the arc. In addition, there is a correlation throughout the arc between published Sr, Pb, and Nd isotope signatures of lavas and the 3He/4He signatures of summit fumaroles. On the northern islands (Nevis, Montserrat, Guadeloupe, and Dominica) summit fumaroles have the N-MORB signature (3He/4He = 8 ± 1 R/Ra), and the isotope signature of lavas is not dissimilar from comparable intra-oceanic arc tholeiites elsewhere. Variable enrichments in radiogenic Sr and Pb have been reported for lavas of individual volcanic centres of the Southern Islands (Martinique, St.Lucia, and Grenada), and summit fumaroles on these centres match these variations by variable radiogenic He-enrichments, i.e., lower 3He/4He ratios. This correlation suggests that radiogenic Sr and Pb enrichments of lavas and low 3He/4He signatures on summit fumaroles have a common origin, i.e., a terrigenous contaminant derived from the Orinoco depositionary fan. Crustal assimilation is thought to decouple the He isotope system from any other radiogenic isotope system and, therefore, we argue that the observed correlation of He, Sr, Pb, and Nd isotope systems is related to a terrigenous contaminant derived from subducted sediments. Support for this scenario also comes from the matching of low 3He/4He ratios and tectonic features of the forearc thought to favor the subduction of forearc sediments.The present study offers a first clue that, under suitable conditions, crustal helium from oceanic sediments might be subducted to the depth of arc magma sources and, possibly, even recycled into the deeper mantle.  相似文献   

8.
Previousworkshavenotonlywellestablishedtheiso topiccriteriaforrecognizingdifferentsourcesofnoblegases(ref.PintiandMarty ,2 0 0 0 ;Sardaetal.,1985 ) ,butalsoadvocatedtheintegrationofC/ 3Heratioswithstableisotoperatiostoprovideaninsightintotheoriginsofmantle derivedCO2 (Ballentineetal.,2 0 0 1,2 0 0 0 ;Lollaretal.,1997;Pedronietal.,1996 ;Trulletal.,1993;MartyandJam bon ,1987;DesMarais ,1985 ) .Inmanycases,however,thenoble gassignatureandC/3Heratiocannotbesimplyusedtoindicatetheoriginsofsuc…  相似文献   

9.
Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that： （1） up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; （2） high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; （3） in gas reservoirs of such abiotic methane （〉80%） and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; （4） a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.  相似文献   

10.
Thirty-three groups of thermal mineral springs in the Chukchi Peninsula are studied. The thermal fluids of the Kolyuchino-Mechigmen Zone (KMZ) show specific characteristics. The zone corresponds to recent depression with occurrences of basic volcanism and high seismicity. Characteristic features of the gases in the springs of the KMZ include the predominance of carbon dioxide, high percentage of mantle-derived helium, enrichment of CO2 in 13C, admixture of nonatmospheric nitrogen, excess in 40Ar and 15N relative to the atmosphere, maximal depletion of thermal water in deuterium and heavy oxygen isotope, and the highest estimates of deep temperature in reservoirs of hydrothermal fluid. All these features indicate the contemporary ascent of a mantle diapir that supplied helium enriched in 3He and thermal energy to the crust, thus provoking thermal metamorphism of rocks and degradation of permafrost.  相似文献   

11.
济阳坳陷高青-平南发育多个CO_2气藏,对气藏组分、同位素以及组分同位索相关组合进行分析,认为气藏中CO_2主要是幔源-岩浆成因.气藏同时具有高~(40)Ar/~(36)Ar和高~3He/~4He值表明:气藏中稀有气体主要来自幔源,同时有部分壳源混入;气藏中~4He/~(40)Ar~*平均值为2.15,说明该地区气藏形成主要以岩浆缓慢脱气为主,大规模CO_2及稀有气体是岩浆冷却结晶阶段所释放.其形成机理为:在随岩浆上升的过程中,随着压力和温度不断下降以及岩浆成分的变化,岩浆中CO_2及稀有气体溶解度也随之降低并析出,产生的大量CO_2及稀有气体沿着深大断裂及一些二、三级断裂交汇处输送至地层的各类圈闭中,并在适当的位置聚集成藏.  相似文献   

12.
喷珠池位于康滇构造带西南侧的石屏 异龙湖坝区 ,它所排放的大量气体以无机成因CO2 为主 (达91 5 9% )。3 He/ 4He值R =7 78× 10 8,R/Ra =0 0 6 ,4 He/ 2 0 Ne =417,表明其中大气成分少 ,属壳源CO2 泉气。喷珠池气体地球化学特征的研究对于该地区地热资源的开发利用和地震活动监测具有十分重要的意义。  相似文献   

13.
中国东部幔源气体同位素地球化学   总被引：11，自引：0，他引：11  
中国东部地幔岩包体及其单矿物中发育有大量的流体包裹体，采用阶段加热真空热爆的 方法脱出幔源包裹体中的气体，测试了气体的碳、氧、氦、氮等同位素组成。ＣＯ２的σ１３℃普遍较低， 主峰值为（－１８～－２２）×１０－3 ，多数样品在高温下的 σ１３℃普遍小于低温下的对应值。氧同位素变 化也很大，从－３．４×１０－３至２５．５×１０－３（ＳＭＯＷ），并呈现多峰的特征。σ１８Ｏ与σ１Ｃ３具有很好的相 关性，可能受控于同种分馏机制。Ｃ、Ｏ同位素组成特征表明，中国东部大陆地幔具有很大的化学不 均一性，可能是由地幔碳的多样性、源区的不均一性或地幔交代作用所致。氧同位素的变化可能是 结晶作用、去气作用或地壳物质混染所至。４Ｈｅ含量变化范围为（０．２４～２５．００）×１０－８，３Ｈｅ／４Ｈｅ变 化范围为（０．４６～１２．８０）×１０－６，４０Ａｒ含量从０．９７×１０－６到３４．１８×１０－６，４０Ａｒ／３６Ａｒ变化范围为 ２５０．５８～１２０２。３Ｈｅ／４Ｈｅ的变化反映了亏损地幔和富集地幔的存在。不同地区４０Ａｒ／３６Ａｒ的巨大差 异显示了地幔脱气程度的不同，也说明在地幔演化中Ａｒ、Ｈｅ同位素地球化学行为的差异。  相似文献   

14.
Heat flow and the origin of helium in natural gases from fault basins of the continental rift-valley in eastern China are discussed in terms of helium isotope geochemistry.3He/4He ratios in natural gases from the rift-valley range from 2.23 × 10−7 to 7.21 × 10−6, which are directly proportional to the concentration of helium and ΣNHC/ΣHC ratio in natural gases. Geological and isotope geochemical data suggest that helium in natural gases consists predominantly of crustal radio-genic and upper mantle-derived helium. In a simple mixing pattern between crustal He and mantle-derived He, mantle-derived helium in natural gases would account for 10–60%. Calculated values for heat flow (Q) range from 59.7 to 82.4mWm−2, of which about 60 percent in the rift-valley is derived from the upper mantle. Natural helium reservoirs would be found in the areas where the upper mantle uplifted greatly and heat flow is large in the continental rift-valley. The project is financially supported by the National Natural Science Foundation of China.  相似文献   

15.
The chemical and isotopic characteristics (oxygen, hydrogen, and strontium) of spring waters and isotopic compositions of helium (He) and neon (Ne) in gases escaping from spring waters in the Lanping–Simao Basin are studied. A total of twenty-one spring water samples (twelve hot springs, four cold springs, and five saline springs) and eleven gas samples were collected from the study area, including one spring and one gas sample from northern Laos. It is found that saline spring waters in the study area are of chloride type, cold spring waters are of carbonate type or sulfate type, and hot spring waters are of various types. High total dissolved solids levels in saline springs are significantly related to Upper Cretaceous–Paleocene salt-bearing strata. On the basis of hydrochemical geothermometry, the reservoir temperatures (Tr) for hot springs, cold springs, and saline springs are 65.5–144.1, 37.8–64.4, and 65.1–109.0 °C, respectively, and the circulation depths of saline springs are much larger than those of hot and cold springs. The oxygen and hydrogen isotopic compositions of springs in the Lanping–Simao Basin and northern Laos are primarily controlled by meteoric waters with obvious latitude and altitude effects, and are also influenced by δ18O exchange to some extent. Most Sr2+ in spring waters of the study area is derived from varied sources (carbonate, evaporite, and silicate mineral dissolution), and the Sr isotopic compositions are greatly influenced by volcanic rocks. Wide distribution of crust-derived He in the Lanping–Simao Basin and northern Laos reveal that faults in these areas may not descend to the upper mantle. It is concluded that water circulation in the study area may be limited above the upper mantle, while saline springs may originate from the Upper Cretaceous–Paleocene evaporites. Hydrochemical characteristics demonstrate affinities among the Lanping–Simao Basin, northern Laos, and Yanjing, eastern Tibet, while disaffinities are observed between these areas and Tengchong on the basis of the hydrochemical characteristics and noble gas isotopic compositions.  相似文献   

16.
广东三水盆地天然气非烃组分同位素地球化学   总被引：1，自引：0，他引：1  
根据广东省三水盆地天然气中氦、氩、二氧化碳和氮等非烃组分的稳定同位素地球化学特征,探讨了该区天然气的来源以及大地热流。测得天然气中3He/4He（R）值为（1.60-6.36）×10-6,比大气的3Ne/4He（Ra）值(1.4×10-6)大:氩的稳定同位素组成(40Ar/36Ar=450-841)较大气氩富40Ar;二氧化碳的δ13C（PDB）值在-20-2‰的范围内,δ13N（Air）值在-57-+95‰之间:根据（?）He,4He值求得研究区的大地热流值（Q）为72-82mWm-2。大地热流和非烃组分同位素组成的高值以及研究区特别发育的火山岩等地质资料表明三水盆地有较强的地球深部流体（物质的和热的）向上溢出。一些油气藏中相当一部分氦、氩和氮来自地幔,各种天然气中均混有地壳来源的非烃气体。贫13C的二氧化碳气主要为地层中有机质分解的产物;富13C的二氧化碳则主要来自岩石化学反应的产物,并混有深部来源的二氧化碳。相当一部分大地热流源于上地幔。  相似文献   

17.
The noble gas isotopic composition and content data of 2 alkali basalts, 3 Iherzolite xenoliths and one clinopyroxene megacryst from the Kuandian region have confirmed the occurrence of a fractionation of noble gases during magmatism. Light noble gases such as He and Ne are high in mobility and appear to be incompatible as compared with heavy ones ( such as Kr and Xe). Therefore, light noble gases are abundant in volcanics, especially in the volcanics with bubbles; lherzolite xenoliths have relatively high heavy noble gases. The clinopyroxene megacryst has the lowest abundance of noble gases, probably due to its high P-T origin. Noble gas isotopic composition of the clinopyroxene megacryst reveals that the mantle source beneath the Kuandian area has an MORB-like reservoir with^3 He/^4He ratio of—10 Ra(Ra: atmospheric^3 He/^4He ratio) and^40 Ar/^36 Ar ratio of 345.6. The Iherzolite xenoliths possess moderate^3 He/^4He ratios of 2.59 -4.53 Ra, reflecting the loss of primary helium during rock deformation or metasomatism caused by enriched mantle fluids during the up-lifting. The alkali volcanics have very low^3 He/^4 He ratios(0.47—0.61 Ra),indicating a contribution of radiogenic^4 He, probably having resulted from crust contamination. Most of the samples have excess^21 Ne and^22 Ne as compared with atmospheric neon, but Kr and Xe isotopic compositions are indistinguishable from atmospheric values within uncertainties with only individual samples having excess^129Xe,^134Xeand^136 Xe.  相似文献   

18.
同位素示踪技术在地质研究中的某些应用   总被引：7，自引：0，他引：7  
李延河 《地学前缘》1998,5(2):275-281
文中介绍了同位素示踪技术的基本原理,回顾了利用氢氧同位素示踪成矿溶液来源,研究水岩反应所取得的重要成果和最新进展;提出水岩相互作用是一个连续的演化过程,可分三个阶段,不同阶段的交换温度、水／岩比及体系的平衡、封闭情况是不一样的。以太古宙条带状硅铁建造为例,介绍了硅同位素示踪技术的新进展,证明了太古宙条带状硅铁建造为海底喷气成因,条带状构造与海底热液的周期性喷发有关。文中还介绍了氦同位素在示踪幔源组份方面的最新进展,指出我国东部油气区天然气中的氦、氩、二氧化碳等有相当一部分来自地幔;根据太平洋中部多金属结核的氦同位素组成和分布特征,提出成矿物质主要来源于海底热液活动,结核的一个圈层可能代表了一次大的海底热液活动。  相似文献   

19.
《Geochimica et cosmochimica acta》1999,63(19-20):3357-3372
Lac Pavin is a volcanic crater lake in the Massif Central (France), characterized by a permanent vertical density stratification resulting from a strong and persistent chemocline between about 60 and 70 m depth. The deep water below the chemocline forms the monimolimnion, in which most dissolved ions as well as helium, carbon dioxide, and methane are strongly enriched. The 3He/4He isotope ratio of the excess helium is (9.09 ± 0.01) · 10−6, or (6.57 ± 0.01) Ra. These findings clearly indicate a flux of mantle-derived magmatic gases into the monimolimnion.In order to derive the fluxes of magmatic volatiles into Lac Pavin, it is essential to understand the hydrologic characteristics of the lake. Previously published two-box models have assumed groundwater input at the lake bottom, a short residence time in the monimolimnion, and biogenic origin of the CO2. We propose an alternative model with a flux of magmatic gases, but not of water, into the monimolimnion, and a weak diffusive coupling between the monimolimnion and the overlying mixolimnion which leads to a long deep-water residence time (≈ 70 yr). We reassess the carbon budget of the lake and conclude that the major part of the accumulated CO2 in the monimolimnion is of magmatic origin. From the model-derived water exchange rates, we calculated a mantle 4He flux of (6 ± 2) · 1011 atoms m−2 s−1. This value lies near the lower end of the range found in comparable volcanic lakes. The flux of magmatic CO2 is estimated as (1.2 ± 0.4) · 10−7 mol m−2 s−1, which is also comparatively low. The monimolimnion appears to be in steady state with respect to these fluxes, therefore no further, potentially hazardous, accumulation of CO2 takes place.  相似文献   

20.
The paper presents data on the composition of a gas phase of underground fluids in the East Carpathian region, including 3He/4He, 40Ar/36Ar, and 4He/20Ne ratios. The argon isotope composition of these gases was used to estimate the fractions of atmospheric Aratm and radiogenic 40Arrad formed in the rocks, N2/Aratm ratio, and to reveal the admixture of nonatmogenic (“excess”) nitrogen in most samples. The CO2 content in gases positively correlates with the fraction of mantle component in fluid helium. At the same time, the CO2 content shows a negative correlation with the total helium (and light 3He enriching mantle derivatives), thus excluding the simultaneous influx of CO2 and helium from a common mantle source in the fluids. A wide spectrum of 3He/4He = R in gases of the region spanning three orders of magnitude confirms the concept of mixing of the crustal and mantle components in the helium. However, even gases with similar R values show a wide scatter of He concentrations. This is mainly caused by the additional influx of other gases: CH4 formed during OM transformation or CO2 released during the thermal metamorphism of carbonate sequences. Correlation of the CH4/3He ratio and the helium isotope composition in the Carpathian gases indicates the crustal origin of hydrocarbons, which formed economic gas pools in the Ciscarpathian Trough and the adjacent part of the Folded Carpathians. Lateral chemical and isotope variations revealed in the underground fluids are related to the tectonic zoning of the region. The helium isotope variations are also consistent with the geodynamic setting of the region (thinning of the crust and lithosphere towards the Pannonian Basin, growth of the background conductive heat flow and corresponding ascent of isotherms). In combination with geothermal data, they reflect specifics of the mantle heat-and-mass flow discharge.  相似文献   

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