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1.
TAMURA  Y.; NAKAMURA  E. 《Journal of Petrology》1996,37(6):1307-1319
New Sr and Nd isotopic data are presented and integrated withprevious data for the Shirahama Group Mio-Pliocene medium-Kvolcanic are suite of south-central Honshu, Japan. Main resultsare: (1) The Shirahama lavas range in 87Sr/86Sr from 0.70315to 0.70337 and in 143Nd/144Nd from 0.51298 to 0.51306; the Srand Nd isotopic data cluster tightly within the mantle array,and all lie within an overlapping field of mid-ocean ridge basaltand ocean island basalt; (2) small differences exist among theShirahama tholeiitic series, calc-alkaline series and mixedlavas. The present isotopic data are consistent with a previouslypublished model, which proposes that chemical variations inmagmas of coexisting tholeiitic and calc-alkaline series areproduced through crystal fractionation from mantle-derived magmasof basalt and magnesian andesite, respectively. Moreover, thetholeiitic series and the calc-alkaline series are isotopicallyidentical. Thus, both magma series can be derived from a sourcemantle with the same isotopic composition, supporting the hypothesisof simultaneous generation of basalt and magnesian andesitemagmas from a single diapir rising through the mantle wedgeabove the subduction zone. The differences of water contentand temperature within the diapir are again thought to havebeen produced through dehydration and heating of an isotopicallyhomogeneous hydrous diapir. The isotopic data show that thehigh-SiO2 lavas have the same isotopic compositions as moremafic lavas. These data and liquid lines of descent of the Shirahamamagmas suggest that even rhyolites can be produced by differentiationfrom mantle-derived magmas without crustal contamination. Analysesfrom 38 other arc volcanoes have been compiled to investigatethe intravolcano variability of 87Sr/86Sr. Twelve of these displayno intravolcano strontium isotopic variability, as is the casewith the Shirahama Group, but others show greater variationof 87Sr/86Sr from individual volcanic centers, presumably reflectingcrustal contamination. Most of the latter volcanoes are underlainby thick continental crust. It is noteworthy, however, thatthe greater variations of 87Sr/86Sr correlate with SiO2 content;andesites or dacites, not basalts, from the same volcano havethe lowest 87Sr/86Sr, and these rocks are calc-alkaline in termsof FeO*/MgO and SiO2 Theoretically, assimilation of continentalcrust by the isotopically uniform Shirahama magmas could producethese relationships. Given that mantle-derived basalt and magnesianandesite both encounter continental crust on their ascent tothe surface, the hotter basalt magma would assimilate more crustalwallrocks than the cooler andesite, resulting in the basaltbeing more radiogenic. Fractional crystallization, magma mixing,and/or assimilation-fractional crystallization of these magmasin crustal magma chambers could produce large compositionalvariations, but the derivatives of the hotter basaltic magmas(tholeiitic series in the broad sense) would display greatercontamination than those derived from the cooler andesitic magmas(calc-alkaline series). *Telephone: 81-858-43-1215. Fax: 81-858-43-2184. e-mail: tamura{at}misasa.okayam-u.ac.jp  相似文献   

2.
Calbuco volcano is a Late Pleistocene-Holocene composite stratovolcano located at 41°20 S, in the southern region of the Southern Volcanic Zone of the Andes (SSVZ; 37°–46° S). In contrast to basalt and basaltic andesite, which are the dominant lava types on the volcanic front from 37° to 42° S, Calbuco lavas are porphyritic andesites which contain a wide variety of crustal xenoliths. They have SiO2 contents in the 55–60% range, and have comparatively low K2O, Rb, Ba, Th and LREF abundances relative to other SSVZ centers. Incompatible element abundance ratios are similar to those of most SSVZ volcanics, but 87Sr/86Sr and 143Nd/144Nd are respectively higher and lower than those of adjacent volcanic centers. Basalts from nearby Osorno stratovolcano, 25 km to the northeast, are similar to other basaltic SSVZ volcanoes. However, basalts from several minor eruptive centers (MEC), located east of Calbuco and Osorno volcano along the Liquiñe-Ofqui fault zone (LOFZ), are enriched in Ba, Nb, Th and LREE, and have higher La/Yb and lower Ba/La, K/La and Rb/La. 87Sr/86Sr and 143Nd/144Nd in MEC basalts are respectively lower and higher than those of Osorno and Calbuco lavas. We suggest that MEC basalts were produced by lower extents of mantle melting than basalts from Osorno and other SSVZ stratovolcanoes, probably as a result of lower water content in the source of MEC basalts. Calbuco andesites formed from basaltic parents similar to Osorno basalts, by moderate pressure crystallization of a hornblende-bearing assemblage accompanied by crustal assimilation. Hornblende stability in the Calbuco andesites was promoted by the assimilation of hydrous metasedimentary crustal rocks, which are also an appropriate endmember for isotopic trends, together with magma storage at mid-crustal depths. The unique characteristics of Calbuco volcano, i.e. the stability of hornblende at andesitic SiO2 contents, low 143Nd/144Nd and high 87Sr/86Sr, and abundant crustal xenoliths, provide evidence for crustal assimilation that is not apparent at more northerly volcanoes in the SSVZ.  相似文献   

3.
New Rb-Sr and trace element data are reported for the GreatDyke and Bushveld Mafic Phase layered intrusions. It is arguedthat geochemical characteristics, such as 87Sr/86Sr ratios andR.E.E. distribution patterns have been little modified by crustalcontamination. Rb-Sr data for whole-rocks of the Great Dyke yield an age of2514±16 m.y. and an initial 87Sr/86Sr ratio of 0.70261±4.Mineral data are consistent with these results. The low errorson the results indicate no significant variation of 87Sr/86Srratios of successive magmatic influxes emplaced in differentmagma chambers. Earlier Great Dyke magmas were highly Mg-richand represent extensive partial melts of the source material.One such influx is shown to have a high Rb/Sr ratio (0.25) anda fractionated R.E.E. pattern (CeN/YBN 12). These ratios areconsidered to approximate those of the source region. The Bushveld Mafic Phase has been dated accurately for the firsttime and has a Rb-Sr age of 2095±24 m.y. Initial 87Sr/86Srratios increase in a stepwise manner upwards in the intrusionfrom 0.70563±2 to 0.70769±6. Each increase isabrupt and occurs at a horizon also characterized by a suddenirregularity in cryptic variation. The Mafic Phase was emplacedas a succession of magmatic influxes each of which had higher87Sr/86Sr ratio than its predecessor. The first magma was both Mg-rich (MgO 21.5 per cent) and SiO2-rich(50–55 per cent SiO2) and was derived by extensive partialmelting of a shallow level upper mantle source. This sourcewas characterized by trace element abundance ratios (e.g. Rb/Sr 0.25; K/Rb 90; CeN/YbN 11), similar to those of kimberlitesand some potassic lavas and comparable with those deduced forthe Great Dyke source region. It is postulated that when the Rhodesian and Kaapvaal cratonsstabilized, underlying refractory mantle became fixed theretoto form a proto-lithosphere. Shortly afterwards, at about 2800m.y. ago, this proto-lithospheric mantle was enriched by passagethrough it of fluids with kimberlitic trace element chemistry.This sub-cratonic mantle thereafter evolved with a relativelyhigh Rb/Sr ratio. Magmas derived from it have anomalous chemicalcharacteristics with respect to those of ocean-floor basalts,reflecting major differences in the evolution of their respectivesource regions.  相似文献   

4.
The Younger Andesites and Dacites of Iztacc?huatl volcano, Mexico,constitute a medium-K calcalkaline rock suite (58–66 wt.per cent SiO2) characterized by high Mg-numbers (100Mg/(Mg+0?85Fe2+=55–66) and relatively high abundances of MgO (2?5–6?6wt. per cent), Ni(17–158 p.p.m.), and Cr (42–224p.p.m.). Chemical stratigraphy plots of eruptive sequences indicatethe existence of a plexus of long-lived dacite magma chambersperiodically replenished by influxes of basaltic magma ascendingfrom depth. Short-term geochemical evolution after batch influxwas dictated by magma mixing and eventual dilution of the basalticcomponent by ‘quasi-steady state’ hornblende dacitemagma. The chemical data support textural and mineralogicalevidence for rapid homogenization of originally diverse magmasby convective blending of residual liquids accompanied by dynamicfractional crystallization (Nixon, 1988). Internally-consistent mixing calculations used to derive thecomposition of basaltic magma influx incorporate analyticaluncertainties and the observed range of salic end-member compositions.Mafic end-members are basalts to basaltic andesites (52–54wt. per cent SiO2) with Mg-numbers (73–76), MgO (9–11wt. per cent), Ni (250 p.p.m.), and Cr (340–510 p.p.m.)concentrations, and liquidus olivine compositions (Fo90–88),appropriate for unfractionated partial melts of mantle peridotite.The majority of model compositions are Ol-Hy-normative, similarto those of primitive basaltic lavas on the flanks of Iztacc?huatland in the Valley of Mexico. However, calculated magma batchesrange from weakly Qz-normative to strongly Ne-normative. Bothcalculated and analyzed basaltic compositions are distinguishedby highly variable abundances of alkalies and incompatible traceelements, notably Rb, Ba, Sr, P, Zr, and Y. Initial 87Sr/86Sr ratios for Iztacc?huatl lavas (0?7040–0?7046;n=24) are comparable to those for primitive basaltic rocks (0?7037–0?7045;?=4) and indicate that (1) mantle source regions are isotopicallyheterogeneous; and (2) contamination of iztacc?huatl magma chambersby radiogenic crustal rocks was not a significant factor inthe evolution of calc-alkaline andesites and dacites. The replenishment of Iztacc?huatl dacite reservoirs by Ne-normativemagmas late in the history of cone growth precludes exhaustionof mantle source regions by progressive partial melting. Thewaning stages of volcanic activity at Iztacc?huatl appear toreflect the inability of dense basaltic influxes to successfullypenetrate a large high-level chamber of low density hornblendedacite magma.  相似文献   

5.
Most of the flows in the Palaeocene lava pile remnant of Skyeare members of the Skye Main Lava Series (SMLS), comprisingtransitional basalts and two associated suites of evolved lavas.The first suite evolves through Fe-rich hawaiites and mugearitesto benmoreites, and the second suite evolves through Fe-poorintermediates to trachytes. Ca-rich, alkali-poor olivine tholeiites(the Preshal Mhor magma type) occur as sparse flows in the stratigraphicallyhighest parts of the lava pile remnant and are abundant in thedyke swarm transecting it. Initial 87Sr/86Sr ratios rangingfrom 0.70308 to 0.70571 in 45 SMLS samples show no significantcorrelation with degree of zeolitization (H2O+), silica saturation,or 87Rb/86Sr. A moderately good negative correlation with totalSr confirms published Pb-isotope evidence of interaction withancient, sialic crust. Details of the (87Sr/86Sr)l versus Srpattern are consistent with previous hypotheses that the SMLSbasalt-benmoreite suite evolved at a depth near the Moho, whilstthe low-Fe trend to trachyte resulted from near-surface basaltfractionation. (87Sr/86Sr)l values ranging from 0.70307 to 0.70621 for PreshalMhor basalts show a strong positive correlation with total Sr,consistent with a model of extensive fractionation within theupper crust of a mantle-derived low 87Sr/86Sr-low Sr magma,which became progressively contaminated with comparatively radiogeniccrustal Sr. The lowest measured (87Sr/86Sr)l values of 0.70307and 0.70308, for a Preshal Mhor basalt and for an SMLS basaltrespectively, are consistent with the hypothesis that thesetwo magma types were produced by successive phases of partialmelting from a single volume of upper mantle. (87Sr/86Sr)l values for additional miscellaneous basaltic lavas,dykes and major intrusives from Skye and from nearby Isle ofMull exhibit considerable variability within the range 0.7038to 0.7072, whilst three basaltic dykes from Northern Englandare in the range 0.7089 to 0.7123. The latter values overlapwith published (87Sr/86Sr)l values for some of the granitesin the Tertiary Province of northwest Scotland and indirectlyremove objections based on Sr-isotopic arguments to the genesisof the granites by fractionation of basalt contaminated withcrustal Sr, but neither prove this nor disprove large-scalecrustal partial fusion.  相似文献   

6.
Continental flood basalts from the Parana plateau are of LowerCretaceous age and are represented by abundant (c. 45 per centby volume) two-pyroxene tholeiites characterized by relativelylow-TiO2 (< 2 wt. percent) and incompatible (e.g., P, Ba,Sr, La, Ce, Zr) element contents. Low-Ti basalts are distributedthroughout the Parana Basin and predominate in the southernregions, where they represent over 90 per cent by volume ofthe basic activity. Major and trace elements and Sr-Nd isotope ratios were analysedin 43 low-Ti basalts selected so as to cover the entire Paranabasin. In general, low-Ti basalts with initial 87Sr86Sr ratios (R0)lower than O7060 may be divided into two groups: (A) those relativelyenriched in incompatible elements (e.g., average K2O = O.85and P2O5 = 0.27 wt. per cent, and Ba = 346, Sr =289, Rb=16;La =18; Zr=132 p.p.m.) and SiO2 (average 51.1 wt. per cent);and (B) depleted in incompatible elements (e.g., average K2O= 0.31, P2O5 =0.17 wt. per cent, and Ba=178, Sr= 179, Rb= 11,La = 9, Zr = 93 p.p.m.) and SiO2 (average 49.7 wt. per cent).Low-Ti basalts of Group A are typical of northern Paran? {Ro= O70550–O70596), but a few are also present in centralParan? (Ro = 070577–0–70591), while those of GroupB are exclusive to central Paran– {Ro = 070463–0–70580) Low-Ti basalts with R0> O7060 are typical of southern Paran?(R0 = O7O639 –O71137), but are also present in centralParana (Ro = 070620–070890). These low-Ti basalts havechemical similarity (e.g., Ti, P, Sr) with low-Ti basalts depletedin incompatible elements (Group B) from which, however, theydiffer-in possessing significantly higher concentrations ofSiO2, K2O, Rb, and Ba. Such chemical diversity, accompaniedby important Ro variations (070463–071137) suggests thatthe low-Ti basalts from southern and part of central Paranamay result from crustal contamination. On the contrary, low-Ti basalts from northern, and part of central, Parana (GroupA) may be considered virtually uncontaminated. Results indicate that crustal contamination by granitic material(s)may be in the range 7–17 per cent. Such contaminationin central Paran? appears compatible with an assimilation-fractionalcrystallization process (AFC), while in southern Parana, othercontamination processes (e.g., mixing of magmasfrom crustaland mantle sources, assimilation of wall rock while magmas flowthrough dykes, etc.) were probably superimposed on AFC. Thedegree of crustal contamination generally decreases from southernto northern Parana. Sr and Nd isotope ratios suggest that mantle source materialfor low-Ti basalts depleted in incompatible elements (GroupB: southern and part of central Parana) had a lower R0 value(c. O.7046) and a higher l43Nd/144Nd ratio (Nd + c. 0.51274)than that for low-Ti basalts enriched in incompatible elements(Group A: northern and part of central Parana), namely R0 c.O.7059 and Nd+ c. 0.51242. These Sr-isotopic differences alsoapply to the northern (incompatible-element rich, R0 c. O.7053)and southern (incompatible-element poor R0 c. 0.7046) basaltprovinces of Karoo, suggesting that both Parana and Karoo basaltmagmas, differing by about 70 m.y. in age, probably originatedin a similar batch of subcontinental lithospheric mantle inpredrift times (cf. Cox, 1986). The extension of the Dupal Sr-anomaly (i.e. Rio Grande Rise+ Wai vis Ridge + Gough and Tristan da Cunha islands: Sr = 46=53;Hart, 1984) inside the Brazilian continent (Sr = 46–59)suggests that the lithospheric mantle of the Parana (and Karoo)provinces was possibly also the local source of oceanic volcanismup to advanced stages of the opening of the South Atlantic. *Reprint requests to E. M. Piccirillo.  相似文献   

7.
The isotopic compositions of strontium in 25 basalts and relatedvolcanic rocks from both oceanic and continental localitieshave been determined. The isotopic abundance of Sr87, convenientlyexpressed as the Sr87/Sr86 ratio, was found to vary from 0?7047to 0?7101. The range of variation is outside experimental errorsand is considered to be significant. No consistent differencein the value of the Sr87/Sr86 ratio was observed for basaltsfrom continental and oceanic localities. The average Sr87/Sr86ratio for eleven oceanic basalts was found to be 0?7072?0?0003,whereas fourteen continental basalts and related volcanic rocksaveraged Sr87/Sr86=0?7082?0?0003. The errors are the standarddeviations of the mean. The average Sr87/Sr86 ratio for all25 basalts is 0?7078 with limits of variation of +0?002 and–0?003. The concentrations of rubidium and strontium in a representativenumber of the basalts were determined by isotope dilution. Fiveolivine basalts averaged Rb=17?6 p.p.m., Sr=390?55 p.p.m., Rb/Sr=0?044?0?018;whereas six tholeiitic basalts were found to contain 30?7 p.p.m.Rb, 504?167 p.p.m. Sr, Rb/Sr=0?060?0?024. On the basis of the most reliable rubidium and strontium analysesof igneous and sedimentary rocks available in the literaturethe Rb/Sr ratio of the near-surface part of the continentalcrust is estimated to be 0?25. If its average age is approximately2 billion years and its initial Sr87/Sr86 ratio was 0?704, thepresent average value would be 0?725. This estimate is compatiblewith results obtained for two composites of Palaeozoic shalewhich averaged Sr87/Sr86=0?7215?0?001. The hypothesis is advanced that there is sufficient enrichmentof Sr87 in crustal materials so that the value of the Sr87/Sr86ratio of igneous rocks at the time of crystallization can beused as a criterion for the origin of the material. The initialSr87/Sr86 ratio of an igneous rock formed by assimilation, remelting,or granitization of old crustal material enriched in rubidiumis expected to be measurably higher than that of igneous rockswhich are products of fractional crystallization of basalt magmaor were derived from undifferentiated basaltic material at depthin the crust. The initial Sr87/Sr86 ratio, time of crystallization, and possibleco-magmatic relationships of differentiated intrusive igneousrocks or series of lava flows of different compositions canbe indicated by the convergence of the whole-rock strontiumdevelopment lines. This method is illustrated by the intrusivealkaline rocks of the Monteregian hills, Quebec.  相似文献   

8.
Mt. Jefferson is an andesite-dacite composite volcano in the Cascade Range, the locus of andesite and dacite-dominated volcanism for at least 1 million years. A large trace element data set for Mt. Jefferson and its surrounding mafic volcanic platform effectively rules out any fractionation based model (FC or AFC) for the generation of Mt. Jefferson andesites. Several incompatible element (Zr, Nb, Y) concentrations decrease in the range from basalt to andesite, and then increase in the range from andesite to rhyodacite. Others (Ba, Rb, La, Th) remain constant or show a slight increase in the basalt to andesite range, with modest increases from andesite to rhyodacite. Systematic variations in highly incompatible element ratios such as Ba/La and Rb/Th suggest magma mixing dominates the trace element signatures. Rhyodacites are isotopically uniform (87Sr/86Sr=0.70325-0.70343; 206Pb/204Pb=18.75-18.85; ‘18O=6.3ǂ.3), whereas andesite and dacite are more variable (87Sr/86Sr=0.70291-0.70353; 206Pb/204Pb=18.59-18.86; ‘18O=6.0ǂ.6). Typical basaltic andesite has 87Sr/86Sr=0.70326-0.70358, 206Pb/204Pb=18.78-18.85, and ‘18O=5.9ǂ.4. Sr-rich (>1,000 ppm) basaltic andesite is more variable (87Sr/86Sr=0.70300-0.70360; 206Pb/204Pb=18.70-18.89; ‘18O=5.9ǂ.4). The data define mixing arrays with one end member at 87Sr/86Sr=0.7029; 206Pb/204Pb=18.59, another at rhyodacite, and a third at 87Sr/86Sr=0.7036; 206Pb/204Pb=18.89. The first end member is defined by Sr-rich (800-1,200 ppm) andesite with high Al2O3, and low K2O, Ba, and Rb/Th; the third one by K2O- and very Sr-rich (>2,000 ppm) shoshonite. Isotopic data for basalts in northern Oregon preclude any fractionation relationship between basalt and either rhyodacite or Sr-rich andesite (e.g., the minimum 206Pb/204Pb ratio in basalt is 18.83). Considered in light of geophysical models for the Cascades, these data suggest two types of crustal melting beneath the arc. Rhyodacite may be generated at 25-30 km depth by partial melting of arc basalt-like amphibolite at 850-900 °C. Sr-rich andesite may be formed by partial melting of depleted MORB-like mafic granulite at 35-45 km depth at 1,000-1,100 °C. Experimental and REE evidence supports these interpretations as does the restriction of Sr-rich andesite in the Cascades to the area south of the 100 mW/m2 heat flow contour between Mt. Jefferson and Mt. Hood. Thick crust and high heat flow are necessary to produce such andesite.  相似文献   

9.
Twelve new Sr-isotope analyses and seventeen new rare earthelement distribution patterns are reported for basalts fromIceland and the Reykjanes Ridge, together with Rb, Sr, Na2O,K2O, TiO2, and P2O5 contents. The samples were chosen to representthe widest range of basalt types known from the Iceland-ReykjanesRidge system. 87Sr/86Sr ratios range from 0.70291 ?4 to 0.70325?5 for tholeiitesand up to 0.70341 ?7 for alkali basalt. Rare earth elementsalso show a wide range of both total abundance and degree oflight-REE fractionation (chondrite-normalised Ce/Yb ratios of0.30 to 3.36 for tholeiites and up to 7.07 for alkali basalt).As found in previous studies of either Sr-isotope compositionor REE distribution, the ocean floor basalts from the southernportion of the Reykjanes Ridge have lower 87Sr/86Sr and CeN/YbNratios than most of the Icelandic basalts. However, some highlyMg-rich tholeiites from Theistareykir in northern Iceland andKj?lur in central Iceland also have among the lowest valuesfor these parameters and are indistinguishable in this respectfrom the ridge basalts. There is a very strong positive, linear,correlation between 87Sr/86Sr and CeN/YbN for all the tholeiitesincluding some up to 16 m.y. old, but this relationship doesnot hold for the alkali basalts which have proportionately farhigher CeN/YbN ratios. There is also a positive, linear, correlationbetween 87Sr/86Sr and Sr content, but not between 87Sr/86Srand 1/Sr. These relationships are found to be incompatible with disequilibriummelting of a single mantle source region, whether by variabledegrees of partial melting with different mineral stabilityconditions, or by removal of successive incremental melts. Itis certain that the data reflect relatively gross chemical heterogeneityin the upper mantle beneath Iceland, but the correlation withSr content apparently rules out simple binary mixing models(mantle-plume hypothesis). It is proposed that the heterogeneities result from establishmentof a lithophile element gradient during a single chemical fractionationevent in the upper mantle at least 100–200 m.y. ago. Itis not possible at present to relate this geochemical gradientto known mantle structure.  相似文献   

10.
The gabbro-diorite-quartz diorite-tonalite (GDT) suite representsthe oldest crustal component in northeastern Egypt; it was emplacedat 881?58 Ma during the early stage of the Pan-African orogeny.Renewed tectono-magmatic processes at the post-orogenic stageproduced the 516?7 Ma trondhjemite (TR) suite that was emplacedinto GDT host rocks. The GDT suite is compositionally broad,with a wide range of SiO2 contents (50–64 wt.%), and isdepleted in K, Rb, Y, Nb, Hf, and REE. The suite shows a smoothvariation in both major and trace elements from gabbro to tonaliteand has a very low Rb/Sr ratio (0?05) and a low initial 87Sr/86Srratio (0?7042). It is calc-alkaline and shows the petrologicalcharacteristics of M-type granites and the trace-element characteristicsof arc-lavas. The GDT suite exhibits REE profiles typical ofisland-arc basalt (IAB), with an (La/Yb)N ratio of 5?5. The trondhjemite is a relatively homogeneous felsic unit (71–75wt. % SiO2) and belongs to the high- Al2O3 continental trondhjemitetype. The TR has a low Rb/Sr ratio (0?16), a low Sr-initialratio (0?7047) and trace-element characteristics of volcanic-arcgranites. It is relatively enriched in Al, Sr, and Ba, depletedin K and Rb, and highly depleted in Y, Nb, Zr, Hf, Ta, and REE,with LREE-depleted, less fractionated patterns [(La/Yb)N=5?3].These features suggest that the TR was derived from a geochemicallyprimitive source. The GDT suite resulted first by the emplacement of a gabbroicmagma, derived possibly from a mantle wedge above an early Pan-Africansubduction zone, and fractionated (48?8% plagioclase, 12?4%augite, 22% amphibole, and 2?9% magnetite, as documented byfractionation modelling) to give the more felsic varieties.Petrogenetic modelling, combined with petrographic and geochemicalfeatures, suggests that the TR magma was produced by non-modalpartial melting of GDT rocks at depth; fractional crystallizationof plagioclase and amphibole controlled the evolution of thisTR magma. This and other studies suggest that post-Archean trondhjemitesare similar to Archean trondhjemites in that they were mostlyproduced via multi-stage development and crustal recycling whichinvolved partial melting of a mafic crustal source.  相似文献   

11.
The results of experimental studies and examination of variations in major elements, trace elements and Sr isotopes indicate that fractionation, assimilation and magma mixing combined to produce the lavas at Medicine Lake Highland. Some characteristics of the compositional differences among the members of the calc-alkalic association (basalt-andesite-dacite-rhyolite) can be produced by fractional crystallization, and a fractionation model reproduces the major element trends. Other variations are inconsistent with a fractionation origin. Elevated incompatible element abundances (K and Rb) observed in lavas intermediate between basalt and rhyolite can be produced through assimilation of a crustal component. An accompanying increase in 87Sr/86Sr from ∼ 0.07030 in basalt to ∼0.7040 in rhyolite is also consistent with crustal assimilation. The compatible trace element contents (Ni and Sr) of intermediate lavas can not be produced by fractional crystallization, and suggest a magma-mixing origin for some lavas. Unusual phenocryst assemblages and textural criteria in these lavas provide additional evidence for magma mixing. A phase diagram constructed from the low pressure melting experiments identifies a distributary reaction point, where olivine+augite react to pigeonite. Parental basalts reach this point at low pressures and undergo iron-enrichment at constant SiO2 content. The resulting liquid line of descent is characteristic of the tholeiitic trend. Calc-alkalic differentiation trends circumvent the distributary reaction point by three processes: fractionation at elevated pH2O, assimilation and magma mixing.  相似文献   

12.
Quartz-rich xenoliths in lavas and pyroclastic rocks from VulcanoIsland, part of the Aeolian arc, Italy, contain silicic meltinclusions with high SiO2 (73–80 wt %) and K2O (3–6wt %) contents. Two types of inclusions can be distinguishedbased on their time of entrapment and incompatible trace element(ITE) concentrations. One type (late, ITE-enriched inclusions)has trace element characteristics that resemble those of themetamorphic rocks of the Calabro-Peloritano basement of theadjacent mainland. Other inclusions (early, ITE-depleted) havevariable Ba, Rb, Sr and Cs, and low Nb, Zr and rare earth element(REE) contents. Their REE patterns are unfractionated, witha marked positive Eu anomaly. Geochemical modelling suggeststhat the ITE-depleted inclusions cannot be derived from equilibriummelting of Calabro-Peloritano metamorphic rocks. ITE-enrichedinclusions can be modelled by large degrees (>80%) of meltingof basement gneisses and schists, leaving a quartz-rich residuerepresented by the quartz-rich xenoliths. Glass inclusions inquartz-rich xenoliths represent potential contaminants of Aeolianarc magmas. Interaction between calc-alkaline magmas and crustalanatectic melts with a composition similar to the analysed inclusionsmay generate significant enrichment in potassium in the magmas.However, ITE contents of the melt inclusions are comparablewith or lower than those of Vulcano calc-alkaline and potassicrocks. This precludes the possibility that potassic magmas inthe Aeolian arc may originate from calc-alkaline parents throughdifferent degrees of incorporation of crustal melts. KEY WORDS: melt inclusions; crustal anatexis; magma assimilation; xenoliths; Vulcano Island  相似文献   

13.
K-feldspar megacrysts (Kfm) are used to investigate the magmaticevolution of the 7 Ma Monte Capanne (MC) monzogranite (Elba,Italy). Dissolution and regrowth of Kfm during magma mixingor mingling events produce indented resorption surfaces associatedwith high Ba contents. Diffusion calculations demonstrate thatKfm chemical zoning is primary. Core-to-rim variations in Ba,Rb, Sr, Li and P support magma mixing (i.e. high Ba and P andlow Rb/Sr at rims), but more complex variations require othermechanisms. In particular, we show that disequilibrium growth(related to variations in diffusion rates in the melt) may haveoccurred as a result of thermal disturbance following influxof mafic magma in the magma chamber. Initial 87Sr/86Sr ratios(ISr) (obtained by microdrilling) decrease from core to rim.Inner core analyses define a mixing trend extending towardsa high ISr–Rb/Sr melt component, whereas the outer coresand rims display a more restricted range of ISr, but a largerrange of Rb/Sr. Lower ISr at the rim of one megacryst suggestsmixing with high-K calc-alkaline mantle-derived volcanics ofsimilar age on Capraia. Trace element and isotopic profilessuggest (1) early megacryst growth in magmas contaminated bycrust and refreshed by high ISr silicic melts (as seen in theinner cores) and (2) later recharge with mafic magmas (as seenin the outer cores) followed by (3) crystal fractionation, withpossible interaction with hydrothermal fluids (as seen in therim). The model is compatible with the field occurrence of maficenclaves and xenoliths. KEY WORDS: Elba; monzogranite; K-feldspar megacrysts; zoning; magma mixing; trace element; Sr isotopes; petrogenesis  相似文献   

14.
Recent basaltic andesite lavas from Merapi volcano contain abundant,complexly zoned, plagioclase phenocrysts, analysed here fortheir petrographic textures, major element composition and Srisotope composition. Anorthite (An) content in individual crystalscan vary by as much as 55 mol% (An40–95) across internalresorption surfaces with a negative correlation between highAn mol% (>70), MgO wt% and FeO wt%. In situ Sr isotope analysesof zoned plagioclase phenocrysts show that the 87Sr/86Sr ratiosof individual zones range from 0·70568 to 0·70627.The upper end of this range is notably more radiogenic thanthe host basaltic andesite whole-rocks (< 0·70574).Crystal zones with the highest An content have the highest 87Sr/86Srvalues, requiring a source or melt with elevated radiogenicSr, rich in Ca and with lower Mg and Fe. Recent Merapi eruptiverocks contain abundant xenoliths, including metamorphosed volcanoclasticsediment and carbonate country rock (calc-silicate skarns) analysedhere for petrographic textures, mineralogy, major element compositionand Sr isotope composition. The xenoliths contain extremelycalcic plagioclase (up to An100) and have whole-rock 87Sr/86Srratios of 0·70584 to 0·70786. The presence ofthese xenoliths and their mineralogy and geochemistry, coupledwith the 87Sr/86Sr ratios observed in different zones of individualphenocrysts, indicate that magma–crust interaction atMerapi is potentially more significant than previously thought,as numerous crystal cores in the phenocrysts appear to be inheritedfrom a metamorphosed sedimentary crustal source. This has potentiallysignificant consequences for geochemical mass-balance calculations,volatile saturation and flux and eruptive behaviour at Merapiand similar island arc volcanic systems elsewhere. KEY WORDS: assimilation; isotopes; Merapi; xenolith; calc-silicate  相似文献   

15.
EWART  A. 《Journal of Petrology》1982,23(3):344-382
The magmas of the Tertiary volcanic province of S. Queenslandare chemically bimodal, and occur in numerous volcanic centres,at least three representing original shield volcanoes. The maficlavas are dominantly hawaiites and tholeiitic andesites, whereasthe silicic magmas comprise mainly trachytes, rhyolites, andcomendites. The silicic rocks exhibit variable trace element abundance patterns.There is a progressive depletion of Sr, Ba, V, Mg, Ni, Cr, Mn,and P, through the trachytes to the rhyolites and comenditeswhile the behaviour of Zr, Nb, LREE, Y and Zn is very variable.Rb, Th, and to a lesser extent Pb exhibit a more regular behaviour,becoming most generally concentrated in the comendites and rhyolites.These trace element patterns are modelled by application ofthe Rayleigh distillation model, using partition coefficientsbased on analysed phenocrysts from the S. Queensland siliciclavas. Trace mineral phases, namely zircon, chevkinite, andallanite, are shown to be important in the probable controlof LREE, Zr, and Th abundances, while Nb and Zn are probablycontrolled during fractionation by magnetite. Trace elementdata for the hawaiites and tholeiitic andesites also indicateextensive although variable levels of fractional crystallizationof these magmas. The Sr and O isotopic compositions of the mafic lavas, trachytes,comendites and rhyolites are as follows: initial 87Sr/86Sr ratios;0.70357–0.70456, 0.70432–0.70589, 0.70495–0.70917,and 0.70708–0.70863 respectively. 18O range between 5.6–7.0(mafic lavas), 4.9–8.7 (trachytes), 5.0–7.6 (comendites)and 8.1–10.4 per mil (rhyolites). Pb isotopic compositionsare variable, showing a variation of 6.7 per cent for 206Pb/204Pbratios through the range of volcanic compositions. The rhyolitesexhibit a much greater divergence in their O, Sr, and Pb isotopiccompositions compared with those of associated mafic lavas,than is found in the trachytes and comendites. Within the silicicvolcanics, positive correlations exist between 18O and initialSr ratios, and between Pb isotopic compositions and initialSr ratios (with one group of trachytes providing a noteworthyexception). These correlations are not so clearly defined forthe mafic lavas, although these do exhibit positive correlationsbetween differentiation index, 18O, and initial Sr isotope ratios. The development of the silicic magmas, excepting two groups,is interpreted in terms of a model in which assimilation andfractional crystallization occur concurrently, involving a basaltor hawaiite magma component and a crustal component (modelledon the analysed Carboniferous basement greywackes outeroppingin the region); the data indicate, however, that differentiationcontinued in isotopically closed systems (i. e. isolated fromthe wallrocks). The highly depleted Sr and Ba abundances ofthe rhyolites and comendites suggest that contamination didnot occur after differentiation had ceased. The rhyolites havethe highest isotopic input of the crustal components and areinterpreted as crustal anatectic melts, produced locally withinthe crust in response to basalt/hawaiite magma intrusion, whereasmost of the trachytes and comendites are interpreted as primarilythe differentiated products from original mafic parental magmas,with variable assimilation of crustal wallrock components. Theisotopic data suggest that only the Minerva Hills trachyticlavas, and a Glass House comendite, have not been significantlymodified by wallrock assimilation processes. The erpted maficmagmas were also evidently modified by isotopic crustal wallrockinteractions, which independent petrological data suggest hasoccurred at intermediate to lower crustal depths.  相似文献   

16.
Lower Crustal Xenoliths, Chinese Peak Lava Flow, Central Sierra Nevada   总被引：1，自引：0，他引：1  
An assemblage of pyroxenite, peridotite, and mafic granulitexenoliths contained in the toe of a 10 Ma trachybasalt flowremnant overlying Late Cretaceous granitoids indicates the presenceof a mafic-ultramafic complex beneath the Sierra Nevada batholith.Olivine-free pyroxenites that include orthopyroxenites, websterites,and clinopyroxenites are dominant. Primary igneous texturesare displayed by some pyroxenites, but commonly are masked byrecrystallization. Fe-rich harzburgites and lherzolites arerare. A few of the ultramafic xenoliths contain ovoid opaquepatches that are apparently pseudomorphs after garnet and havepyralspite garnet compositions. A pressure corresponding toa lower crustal depth of approximately 40 km has been determinedfrom two of these xenoliths using a garnet-orthopyroxene geobarometer.Abundant mafic granulites can be subdivided into those containing12 per cent or less A12O3 and chemically gradational with pyroxenitesand others containing more than 15 per cent A12O3 and showingconsiderable scatter on oxide variation diagrams. The high-aluminagranulite xenoliths have relatively low 87Rb/86Sr but high 87Sr/86Sr,whereas low-alumina and ultramafic xenoliths have a wide rangeof 87Rb/86Sr, but lower 87Sr/86Sr; the isotopic data indicatean age for the complex roughly the same as that of overlyinggranitoid plutons. However, the granitoids have initial 87Sr/86Srratios intermediate between the high-alumina and ultramaficxenoliths, suggesting that they may have resulted from mixingof basaltic magma, represented by the ultramafics, and crustalmaterials, with subsequent crystal fractionation. The trachybasaltmay represent a partial melt of the ultramafic rocks.Rocks analogousto the Chinese Peak xenoliths are exposed in the Giles complexof central Australia, a series of several deformed layered maficand ultramafic intrusions, emplaced in a granulite facies terrain.Contemporaneous development of mafic-ultramafic complexes andthe Sierra Nevada batholith may explain the present day thick({small tilde} 50 km) crust in this region  相似文献   

17.
Compositionally heterogeneous basaltic centers from a varietyof tectonic environments, including Pisgah Crater in the MojaveDesert region of California, exhibit secular changes in theirchemistry that might be explained by the sequential meltingof ultramafic to mafic mantle sources. We have analyzed phenocrystsfrom alkali basalts and hawaiites erupted at Pisgah Crater toinvestigate the effects of open-system modifications imposedon basaltic systems. We present 87Sr/86Sr data for individualphenocrysts of amphibole and clinopyroxene and the first publishedresults of single olivine grains, in addition to plagioclase.Each mineral phase exhibits a range in Sr isotope compositionthat may only partially overlap the isotopic composition ofthe other mineral phases, suggesting an interplay between twomagmatic end-members that continued up to the time of eruption.Limited 87Sr/86Sr variability in minerals from early and intermediatelavas indicates only moderate syn-crystallization open-systemmodification, whereas minerals in late-erupted lavas have muchhigher 87Sr/86Sr, consistent with extensive open-system modification.Rimward increases in 87Sr/86Sr of plagioclase confirm that thesechanges occurred within the stability field of plagioclase and,therefore, at crustal or near-crustal depths. The major elementcompositions of olivine-hosted melt inclusions indicate thatan Al-rich component of andesitic composition (87Sr/86Sr 0·7056),possibly derived from plagioclase-rich cumulates or pelites,was assimilated by magma generated from asthenosphere or younglithosphere with 87Sr/86Sr 0·7038. The results clearlydemonstrate the utility of measuring the 87Sr/86Sr of individualminerals and indicate that Pisgah Crater basalts probably acquiredisotopically enriched geochemical signatures from crustal contamination,rather than from mixing of heterogeneous mantle melts. KEY WORDS: assimilation; basalts; melt inclusions; minerals; Sr isotopes  相似文献   

18.
The Early Cretaceous volcanic rocks of southern Uruguay comprisemafic and felsic volcanics. The position of these outcrops atthe southern edge of the Paraná–Etendeka continentalflood basalt province provides an opportunity to investigatepossible lateral variations in both mafic and more evolved rocktypes towards the margins of such an area of plume-related magmatism.The mafic lavas are divided into two compositionally distinctmagma types. The more voluminous Treinte Y Trés magmatype is similar to the low-Ti basalts of the Paraná floodbasalt province. The Santa Lucía magma type is a distinctand rare basalt type with ocean-island basalt type asthenosphericaffinities (high Nb/La, low 87Sr/86Sri). The felsic volcanicsare divided into two series, the Lavalleja Series and the AigüaSeries. The Lavalleja Series are chemically and isotopicallysimilar to the Paraná–Etendeka low-Ti rhyolites,and are considered to be related to the Treinte Y Tréslavas by extensive fractionation and crustal assimilation. TheAigüa Series have low 143Nd/144Ndi and low 87Sr/86Sri andunlike the rhyolites of the Paraná, are interpreted asmelts of pre-existing mafic lower crust that subsequently underwentextreme fractionation. The differences observed in the felsicsuites may be linked to differences in the volumes of the associatedbasalts and the amounts of extension. KEY WORDS: South America; flood basalts; felsic volcanics; crustal melts; plume  相似文献   

19.
The volcanic rocks of the Bearpaw Mountains are part of theMontana high-potassium province, emplaced through Archaean rocksof the Wyoming Craton between 54 and 50 Ma ago. Extrusive rocks,dominated by minettes and latites, have a volume of 825 km3.The minettes range in composition from 20 to 6% MgO. The moremagnesian varieties contain the phenocryst assemblage forsterite+ Cr-spinel + diopside phlogopite. More evolved rocks areolivine-free, with an assemblage of either salite + phlogopite+ pseudoleucite or salite + phlogopite + analcime. The analcimeis thought to be secondary after leucite, produced by loss ofpotassium from the minettes. Mineral chemistry and textures,especially of clinopyroxenes, indicate that mixing between minettemagmas of varying degrees of evolution was commonplace. Compositionalvariation was further extended by accumulation of olivine +spinel + clinopyroxene phenocrysts, and by the preservationof mantle xenocrysts in the minettes. The primary minette magmasare inferred to have had 12–14% MgO and to have been generatedat 30 kb from an olivine + diopside + phlogopite-bearing source.The primary magmas evolved dominantly by fractionation of olivine+ diopside. The minettes have high contents of large ion lithophile elements(LILE) and light rare earth elements (LREE), with K2O up to6.18%, Ba 5491 ppm, Sr 2291 ppm, and Ce 99 ppm. (87Sr/86Sr)0ranges from 0.707 to 0.710 and Nd varies from –10 to–16. These data, plus high LILE/HFSE (high field strengthelements) values, are interpreted to show that the minettescontain at least three different mantle components. The lithospherewas initially depleted in Archaean times, but was metasomaticallyenriched in the Proterozoic and in the late Cretaceous and earlyTertiary. The latites have many chemical features in common with the minettes,such as potassic character and high LILE/HFSE values. They formedby fractional crystallization of minette magma in combinationwith assimilation of crustal rocks; this process enriched themagmas in SiO2 and raised Na2O/K2O and 87Sr/86Sr values. Chemicaldata for phenocrysts and bulk rocks in minettes suggest mixingbetween minette and latite magmas.  相似文献   

20.
Sediment mixing and recycling through a subduction zone canbe detected in lead isotopes and trace elements from basaltsand sediments from the Kermadec-Hikurangi Margin volcanic arcsystem and their coupled back-arc basins. Sr, Nd and Pb isotopesfrom the basalts delineate relatively simple, almost overlapping,arrays between back-arc basin basalts of the Havre Trough-NgatoroBasin (87Sr/86Sr = 0.70255; Nd=+9.3; 206Pb/204Pb = 18.52; 208Pb/204Pb= 38.18), island arc basalts from the Kermadec Arc togetherwith basalts from Taupo Volcanic Zone (87Sr/86Sr 0.7042; Nd= +5; 206Pb/204Pb= 18.81; 208Pb/204Pb = 38.61), and sedimentsderived from New Zealand's Mesozoic (Torlesse) basement (87Sr/86Sr 0.715; Nd —4; 206Pb/204Pb 18.86; 208Pb/204Pb 38.8).Basalts from the arc front volcanoes have high Cs, Rb, Ba, Th,U and K, and generally high but variable Ba/La, Ba/Nb ratios,characteristic of subduction-related magmas, relative to typicaloceanic basalts. These signatures are diluted in the back-arcbasins, which are more like mid-ocean ridge basalts. Strongchemical correlations in plots of SiO2 vs CaO and loss on ignitionfor the sediments (finegrained muds) are consistent with mixingbetween detrital and biogenic (carbonate-rich) components. Otherdata, such as Zr vs CaO, are consistent with the detrital componentcomprising a mixture of arc- and continent-derived fractions.In chondrite-normalized diagrams, most of the sediments havelight rare earth element enriched patterns, and all have negativeEu anomalies. The multielement diagrams have negative spikesat Nb, P and Ti and distinctive enrichments in the large ionlithophile elements and Pb relative to mantle. Isotopic measurementsof Pb, Sr and Nd reveal restricted fields of Pb isotopes butwide variation in Nd and Sr relative to other sediments fromthe Pacific Basin. Rare K-rich basalts from Clark Volcano towardthe southern end of the oceanic Kermadec Island Arc show unusualand primitive characteristics ( 2% K2O at 50% SiO2, Ba 600p.p.m., 9–10% MgO and Ni > 100 p.p.m.) but have highlyradiogenic Sr, Nd and Pb isotopes, similar to those of basaltsfrom the continental Taupo Volcanic Zone. These oceanic islandarc basalts cannot have inherited their isotope signatures throughcrustal contamination or assimilation—fractional crystallizationtype processes, and this leads us to conclude that source processesvia bulk sediment mixing, fluid and/or melt transfer or somecombination of these are responsible. Although our results showclear chemical gradients from oceanic island arc to continentalmargin arc settings (Kermadec Arc to Taupo Volcanic Zone), overlapbetween the data from the oceanic and continental sectors suggeststhat the lithospheric (crustal contamination) effect may beminimal relative to that of sediment subduction. Indeed, itis possible to account for the chemical changes by a decreasenorthward in the sediment flux into the zone of magma genesis.This model receives support from recent sediment dispersal studiesin the Southern Ocean which indicate that a strong bottom current(Deep Western Boundary Current) flows northward along the easterncontinental margin of New Zealand and sweeps continental derivedsediment into the sediment-starved oceanic trench system. Thetrace element and isotopic signatures of the continental derivedcomponent of this sediment are readily distinguished, but alsodiluted in a south to north direction along the plate boundary. KEY WORDS: subduction zone basalts; sediments; Sr-, Nd-, Pb-isotopes; trace elements *Present address: School of Earth Sciences, University of Melbourne, Parkville, Vic. 3052, Australia.  相似文献   

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