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不同类型黄铁矿对金的吸附实验 总被引:16,自引:1,他引:16
在稀溶液状态下的Au的吸附实验,较好地体现了地质热液过程中吸附作用在金矿成矿方面的重要性。黄铁矿与金的硫氢配合物的作用结果截然不同于黄铁矿与金的氯配合物的作用结果。黄铁矿对金的硫氢配合物的吸附是通过表面络合和静电吸附完成的,且不同类型黄铁矿有明显的吸附差异。矿物表面特性及非均匀催化可能在吸附过程中起了重要作用。金矿中常见的Au、As和p型黄铁矿三位一体的现象可能与As对吸附作用的影响有较大关系。而 相似文献
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次显微金在毒砂,黄铁矿等矿物中富集的成因研究 总被引:7,自引:0,他引:7
本文详细探讨了次显微金在毒砂、黄铁矿等矿物中富集的成因机制,指出这些矿物生长时生长面附近出现的氧化还原电位局部降低和(或)(AsS)3-,S2-等组分的局部负异常会导致金的络合物变得不稳定和易于分解,从而引起次显微金在这些矿物中富集。由此笔者解释了次显微金龙富集于小颗粒的毒砂、黄铁矿中及特别富集于这些矿物边缘的原因。同时笔者认为普遍呈小圆球形态出现于载金矿物中的金颗粒可能是金胶体沉聚下来形成的。文中还对黄铁矿含Au量与含As量之间具正相关关系以及黄铁矿和黄铜矿的含Au量在不同矿床中互有高低的原因予以了解释 相似文献
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留龙金矿床中,大部分金以显微金的形式赋存于黄铁矿和毒砂中,银主要以独立矿形式存在。方铅矿是银的最主要载体矿物。不同矿化阶段的矿石中,金银含量高低与载体矿物的生成世、晶形、粒度和微量隙发育程度有关。Ag和Sb元素有关,与As无明显关系。As是Au的标型指示元素。 相似文献
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江西银山矿田伴生金银综合回收利用研究 总被引:2,自引:0,他引:2
叙述了银山铜铅锌多金属矿田铅锌成矿系列和铜硫成矿系列6个成矿带中伴生金银的赋存状态、富集特征和成矿规律,并进行伴生金银相关性分析。认为伴生金银是以独立矿物存在为主,主要载体矿物有黄铜矿,含砷铜矿物、黄铁矿、方铅矿和闪锌矿。Au、Ag与Pb、Zn、Cu、S密切相关。同时分析了金银生产中存在的具体问题,提出综合回收金银的措施和建议。 相似文献
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秦岭卡林型金矿床金、砷地球化学探讨 总被引:16,自引:0,他引:16
讨论了秦岭卡林型金矿床中Au 、As 的元素地球化学、矿物学特征。在含矿岩系中获得的Au、As 等成矿元素初始含量较高,且主要集中在成岩黄铁矿中。在矿石样品中对含砷硫化物矿物的研究表明,Au 、As 在矿物显微结构中具有强的正相关性。在大量金进入到硫化物结构之前,就已有[AsS]3 - 的存在。在含砷硫化物矿物中,金多半以一种带电类型(Au3 +) 存在, 它很可能替代铁位置上的过剩砷, 以固溶体方式沉淀于硫化物矿物中。此时, 黄铁矿构成(Au3 + ,Fe2 +)([AsS]3 - [S2]2 - ),毒砂构成(Au3 + ,Fe2 +)([AsS]3 - [AsS]3 -) 。通过电子探针(EMP) 和透射电镜(TEM) 对秦岭卡林型金矿含砷硫化物矿物中金的赋存状态的研究表明,在金的成矿作用早期阶段, 金主要以固溶体形式优先富集于含砷黄铁矿和毒砂及砷黝铜矿之中,并且认为是以金的氧化和砷的还原的共沉淀方式发生的。在此之后的金成矿作用晚期阶段,由于热液蚀变和结晶作用程度的增高,寄主矿物耐熔性质相对降低,加之金本身的聚集能力,和因过量砷加入而造成的含砷硫化物矿物的晶格缺陷,致使已形成的固溶体金以“出溶”形式发生再分布,赋存于硫化物矿物晶粒 相似文献
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石柱子花岗闪长岩体形成于晚株罗-早白垩世,岩石属钙碱系列,形成于造山带或岛弧构造环境。岩体的副矿物组合及矿物组合标型研究表明,锆石-磷灰石-锐钛矿(金红石),锆石-锐钛矿(金红石),锆石-磷灰石-榍石-金红石(锐钛矿)等3种副矿物组合类型;黄铁矿-黄铜矿-斑铜矿(黝铜矿)-重晶石,黄铁矿-黄铜矿,黄铜矿-方铅矿-重晶石,黄铁矿-黄铜矿-重晶石,黄铁矿-黄铜矿-辉钼矿,黄铁矿-白钨矿,黄铁矿-重晶石 相似文献
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本文重点研究了除黄铁矿(另文介绍)以外的石英、方铅矿、黄铜矿、闪锌矿、菱铁矿、褐铁矿等载金矿物的矿物学特征及其找矿意义。研究结果表明,石英的颜色和其中的Pb、Cu含量,方铅矿中的Ag、黄铜矿的晶胞参数等具有找金和评价的标型意义。石英的红外光谱和包体研究可以揭示其形成温度和后期变形情况,方铅矿的空间分布极不均匀,可能与金矿形成时代有关。另外,本文纠正了前人把菱铁矿误认成铁白云石的作法。 相似文献
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含金矿物中金及微量元素的质子探针分析 总被引:3,自引:0,他引:3
利用质子探针对黄铁矿、毒砂、人工合成矿物中的Au、Cr、Mn、Cu、As、Pb微量元素进行了分析,实验表明,质子探针微区分析技术可测定痕量金及其它微量元素;不同矿物中金的检出限不同,黄铁矿中Au的检出限3μg/g,毒砂中Au的检出限为30μg/g。 相似文献
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Gold Mineralization of the Gatsuurt Deposit in the North Khentei Gold Belt,Central Northern Mongolia
Mineral assemblages, chemical compositions of ore minerals, wall rock alteration and fluid inclusions of the Gatsuurt gold deposit in the North Khentei gold belt of Mongolia were investigated to characterize the gold mineralization, and to clarify the genetic processes of the ore minerals. The gold mineralization of the deposit occurs in separate Central and Main zones, and is characterized by three ore types: (i) low‐grade disseminated and stockwork ores; (ii) moderate‐grade quartz vein ores; and (iii) high‐grade silicified ores, with average Au contents of approximately 1, 3 and 5 g t?1 Au, respectively. The Au‐rich quartz vein and silicified ore mineralization is surrounded by, or is included within, the disseminated and stockwork Au‐mineralization region. The main ore minerals are pyrite (pyrite‐I and pyrite‐II) and arsenopyrite (arsenopyrite‐I and arsenopyrite‐II). Moderate amounts of galena, tetrahedrite‐tennantite, sphalerite and chalcopyrite, and minor jamesonite, bournonite, boulangerite, geocronite, scheelite, geerite, native gold and zircon are associated. Abundances and grain sizes of the ore minerals are variable in ores with different host rocks. Small grains of native gold occur as fillings or at grain boundaries of pyrite, arsenopyrite, sphalerite, galena and tetrahedrite in the disseminated and stockwork ores and silicified ores, whereas visible native gold of variable size occurs in the quartz vein ores. The ore mineralization is associated with sericitic and siliceous alteration. The disseminated and stockwork mineralization is composed of four distinct stages characterized by crystallization of (i) pyrite‐I + arsenopyrite‐I, (ii) pyrite‐II + arsenopyrite‐II, (iii) galena + tetrahedrite + sphalerite + chalcopyrite + jamesonite + bournonite + scheelite, and iv) boulangerite + native gold, respectively. In the quartz vein ores, four crystallization stages are also recognized: (i) pyrite‐I, (ii) pyrite‐II + arsenopyrite + galena + Ag‐rich tetrahedrite‐tennantite + sphalerite + chalcopyrite + bournonite, (iii) geocronite + geerite + native gold, and (iv) native gold. Two mineralization stages in the silicified ores are characterized by (i) pyrite + arsenopyrite + tetrahedrite + chalcopyrite, and (ii) galena + sphalerite + native gold. Quartz in the disseminated and stockwork ores of the Main zone contains CO2‐rich, halite‐bearing aqueous fluid inclusions with homogenization temperatures ranging from 194 to 327°C, whereas quartz in the disseminated and stockwork ores of the Central zone contains CO2‐rich and aqueous fluid inclusions with homogenization temperatures ranging from 254 to 355°C. The textures of the ores, the mineral assemblages present, the mineralization sequences and the fluid inclusion data are consistent with orogenic classification for the Gatsuurt deposit. 相似文献
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大背坞金矿床属贫硫化物(糜棱岩)石英脉型,该矿床有用组分唯有Au,自然金是Au最主要的赋存形式,几乎集中富集了全部Au组分.虽然矿石中有极微量的银金矿,并在方铅矿中发现可能还存在次显微金,但含金量却微不足道.石英、黄铁矿、毒砂是自然金的主要载体.自然金成色高,多以中粗粒裂隙金形式产出,粒间金次之,包裹金较少.本矿床中黄铜矿、方铅矿、闪锌矿不发育,含量少,但它们与自然金关系密切,镜下常常发现与自然金共生赋存于较粗粒的黄铁矿、毒砂等载金矿物中.这3种硫化物是发现富矿化的标志.铅同位素结果表明本金矿成矿物质来源于前震旦纪变质沉积岩,中元古界双桥山群是矿源层.金以络合物的形式迁移.当温度降低(低于300℃),含矿溶液进入容矿空间压力降低,金发生沉淀.矿化早期石英脉包裹体pH值4.91,Eh值164.52,到矿化主期pH升高到6.38~6.72,Eh降低到57.44,从而使金在溶液中的溶解度大大降低,促使金发生沉淀. 相似文献
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Kotaro Yonezu Takushi Yokoyama Yoshihiro Okaue Akira Imai Koichiro Watanabe 《Resource Geology》2007,57(4):400-408
In order to elucidate the formation mechanism of low‐sulfidation epithermal gold deposit, the adsorption of [Au(S2O3)2]3? (a model compound for gold(I) complex ion) on alumina gel (a model compound for the aluminum‐bearing minerals) and change in chemical state of [Au(S2O3)2]3? after adsorption on the surface of alumina gel were investigated as a basic model experiment. In the pH range from 4 to 6, the amount of [Au(S2O3)2]3? adsorbed on alumina gel decreased with increasing pH and decreased drastically between pH 6 and 7, and then approached zero above pH 8 at 30°C. At 60°C, the amount of gold adsorbed above pH 7 was enhanced compared with that at 30°C. This adsorption tendency indicates that [Au(S2O3)2]3? is mainly adsorbed by electrostatic interaction between negative charges of [Au(S2O3)2]3? and positive charges of alumina gel because of its isoelectric point around pH 9. The chemical state of gold after adsorption of [Au(S2O3)2]3? on alumina gel was examined using X‐ray absorption near edge structure (XANES). The result showed that [Au(S2O3)2]3? was spontaneously reduced to elemental gold even in the absence of specific reducing agents after adsorption on alumina gel. This reduction reaction might occur by two steps: (i) disproportionation of the adsorbed [Au(S2O3)2]3? at the surface of alumina gel, and (ii) spontaneous reduction of the resulting gold(III) complex ions on the surface of alumina gel. The experimental results suggest that aluminum plays an important role in the concentration of gold(I) complex ions and subsequent reduction of gold during the formation of low‐sulfidation epithermal gold deposits. 相似文献
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新疆红山糜棱岩型金矿床地质特征及成矿条件 总被引:2,自引:0,他引:2
红山金矿区属天山地槽北天山地向斜褶皱带,位于康古尔与苦水断裂之间狭长的含金韧性剪切带东段北缘;出露地层为中下石炭统;华力西中晚期的多期次岩浆活动、韧性剪切作用和构造活动叠加形成了一系列金及多金属矿床,已成为新疆东部主要的产金基地。通过对红山金矿床地质特征的研究,并从宏观及微观尺度进行成矿条件分析发现金的富集与多金属硫化物,尤其是与方铅矿关系密切。主要特征是贫黄铁矿,少多金属硫化物,局部富含方铅矿,金的分布极不均匀。金具多源性,主要来自岩浆,少量来自围岩。剪切作用多次叠加及强烈糜棱岩化,使金矿物与多金属硫化物沿裂隙及糜棱面理分布,形成糜棱岩型或超糜棱岩型金矿床。 相似文献
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An XPS and SEM study of gold deposition at low temperatures on sulphide mineral surfaces: Concentration of gold by adsorption/reduction 总被引:1,自引:0,他引:1
Gilles E. Jean 《Geochimica et cosmochimica acta》1985,49(4):979-987
Using X-ray photoelectron spectroscopy (XPS or ESCA) and scanning electron microscopy (SEM), we have examined the mechanism of adsorption and reduction of gold solutions on sulphides. KAuIIICl4 solutions are quickly adsorbed on the sulphide surfaces, and the Au(III) is quickly reduced to Au(0). Monolayer Au coverage is attained within one minute. The reduction is auto-catalyzed and Au metal grows on the surface. SEM photographs clearly show agglomerates of gold unevenly distributed on the surface. Specific sites of abnormally high Au concentration are found. We propose possible mechanisms for the adsorption and reduction. Our results suggest that adsorption of Au(III) and Au(I) by sulphide minerals, followed by reduction, could play an important role in the deposition of gold in natural systems especially at low temperature and low gold solution concentrations. 相似文献