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1.
Impact of internal waves on the acoustic field at a coastal station off Paradeep,east coast of India
Internal Wave (IW) characteristics and the impact of IW on acoustic field have been studied utilizing the hourly time series
of temperature and salinity data collected at a coastal site off Paradeep (north Bay of Bengal) during 24–25 October 2008.
The IW characteristics, viz. period (t
per
), velocity (C
vel
), wavelength (L), and wave numbers (k), are found to be 2.133–34.72 h, 0.135 km h−1, 0.37–6.2 km and 2.70–0.16 cycles km−1, respectively. The semi-diurnal tidal forces are predominant than diurnal as well as at other frequencies and its contribution
is about 64% towards the total potential energy (E
0 = 3.34 J m−2). Sound velocity perturbations with space and time in the presence of IW field are examined from Garrettt-Munk (GM) model.
Transmission loss anomaly for optimized source-receiver configuration at the depth of 53 m and range of 9 km has been computed
from acoustic modelling. The loss in the acoustic transmission is found to be 38.4 dB in the presence of low-frequency IW
field. 相似文献
2.
Arnoldo Valle-Levinson Nandita Sarkar Rosario Sanay Doris Soto Jorge León 《Estuaries and Coasts》2007,30(1):113-126
Underway current velocity profiles were combined with temperature and salinity profiles at fixed stations to describe tidal
and subtidal flow patterns in the middle of the northernmost Chilean fjord, Estuario Reloncaví. This is the first study involving
current velocity measurements in this fjord. Reloncaví fjord is 55 km long, 2 km wide, and on average is 170 m deep. Measurements
concentrated around a marked bend of the coastline, where an 8-km along-fjord transect was sampled during a semidiurnal tidal
cycle in March 2002 and a 2-km cross-fjord transect was occupied, also during a semidiurnal cycle, in May 2004. The fjord
hydrography showed a relatively thin (<5 m deep), continuously stratified, buoyant layer with stratification values >4 kg
m−3 per meter of depth. Below this thin layer, the water was relatively homogeneous. Semidiurnal tidal currents had low amplitudes
(<10 cm s−1) that allowed the persistence of a surface front throughout the tidal cycle. The front oscillated with a period of ca. 2.5
h and showed excursions of 2 km. The front oscillations could have been produced by a lateral seiche that corresponds to the
natural period of oscillation across the fjord. This front could have also caused large (2 h) phase lags in the semidiurnal
tidal currents, from one end of the transect to the other, within the buoyant layer. Tidal phases were relatively uniform
underneath this buoyant layer. Subtidal flows showed a 3-layer pattern consisting of a surface layer (8 m thick, of 5 cm s−1 surface outflow), an intermediate layer (70 m thick, of 3 cm s−1 net inflow), and a bottom layer (below 80 m depth, of 3 cm s−1 net outflow). The surface outflow and, to a certain extent, the inflow layer were related to the buoyant water interacting
with the ambient oceanic water. The inflowing layer and the bottom outflow were attributed to nonlinear effects associated
with a tidal wave that reflects at the fjord's head. The weak subtidal currents followed the morphology of the bend and caused
downwelling on the inside and upwelling on the outside part of the bend. 相似文献
3.
Using both the photosynthetically active chlorophylla (chla) content of the organic carbon fraction of suspended particulate matter (chla/POC) and the percentage of photosynthetically, active chla in fluorometrically measured chla plus pheophytina (% chla), we determined that under specified hydrodynamic conditions, neap-spring tidal differentiation in particle dynamics could
be observed in the Columbia River estuary. During summer time neap tides, when river discharge was moderate, bottom chla/POC remained relatively unchanged from riverine chla/POC over the full 0–30 psu salinity range, suggesting a benign trapping environment. During summertime spring tides, bottom
chla/POC decreased at mid range salinities indicating resuspension of chla-poor POC during flood-ebb transitions. Bottom % chla during neap tides tended to average higher than that during spring tides, suggesting that neap particles were more recently
hydrodynamically trapped than those on the spring tides. Such differentiation supported the possibility of operation of a
particle conveyor belt process, a process in which low-amplitude neap tides favor selective particle trapping in estuarine
turbidity maxima (ETM)., while high-amplitude spring tides favor particle resuspension from the ETM. Untrapped river-derived
particles at the surface would continue through the estuary to the coastal ocean on the neap tide; during spring tide some
particles eroded from the ETM would combine with unsettled riverine particles in transit toward the ocean. Because in tensified
biogeochemical activity is associated with ETM, these neap-spring differences may be critical to maintenance and renewal of
populations and processes in the estuary. Very high river discharge (15, 000 m3 s−1) tended to overwhelm neap-spring differences, and significant oceanic input during very low river discharge (5,000 m3 s−1) tended to do the same in the estuarine channel most exposed to ocean input. During heavy springtime phytoplankton blooms,
development of a thick bottom fluff layer rich in chla also appeared to negate neapspring differentiation because spring tides apparently acted to resuspend the same rich bottom
material that was laid down during neap tides. When photosynthetic assimilation numbers [μgC (μgchl,a)−1h−1] were measured across, the full salinity range, no neap-spring differences and no river discharge effects occurred, indicating
that within our suite of measurements the compositional distinction of suspended particulate material was mainly a function
of chla/POC, and to a lesser extent % chla. Even though these measurements suggest the existence of a conveyor belt process, proof of actual operation of this phenomenon
requires scalar flux measurements of chla properties in and out of the ETM on both neap and spring tides. 相似文献
4.
The mummichog,Fundulus heteroclitus, is one of the most important macrofaunal components of salt marsh surfaces and an important link to subtidal areas of the
adjacent estuary along the east coast of the U.S. We estimated growth, population size, and production of the mummichog in
a restored marsh in order to improve our understanding of the role of this resident fish and to evaluate the success of the
restoration. The restored marsh, covering 234 ha, was a former salt hay farm located in the mesohaline portion of Delaware
Bay that was restored to tidal influence in August 1996. We separated the mummichog population into two components based on
life history stage and summer habitat use patterns. One component, consisting of adults and large young-of-the-year (YOY),
exhibited tidal movements to and from the marsh surface and the subtidal creeks. These were examined with an intensive mark
and recapture program using coded wire tags. Another component, consisting of small YOY, remained on the marsh surface throughout
the tidal cycle. Throw traps were used to sample these small YOY. The mean annual population density of adults and large YOY
for the entire marsh was approximately 1.2 fish m−2 and mean monthly density peaked at 2.9 fish m−2. The mean annual density of small YOY on the marsh surface was 15.1 fish m−2 and mean monthly density peaked at 41.4 fish m−2. Size and season influenced the growth rate of individual fish and instantaneous growth rates ranged from 0.03 to 2.26 mo−1. Total annual mummichog production was estimated to be 8.37 g dw m−2 yr−1, with adults and large YOY contributing 28.4% (2.38 g dw m−2 yr−1) and small YOY on the marsh surface contributing 71.6% (5.99 g dw m−2 yr−1). The seasonal use and population densities were comparable to previous studies in natural marshes while growth and production
of mummichog in this restored marsh appeared to be higher. Coupled with the results of other studies on the feeding, movement,
and habitat use of this species in this restored marsh, the species has responded well to the restoration. 相似文献
5.
Alexander W. Karlsen Thomas M. Cronin Scott E. Ishman Debra A. Willard Randy Kerhin Charles W. Holmes Marci Marot 《Estuaries and Coasts》2000,23(4):488-508
Environmentally sensitive benthic foraminifera (protists) from Chesapeake Bay were used as bioindicators to estimate the timing
and degree of changes in dissolved oxygen (DO) over the past five centuries. Living foraminifers from 19 surface samples and
fossil assemblages from 11 sediment cores dated by210Pb,137Cs,14C, and pollen stratigraphy were analyzed from the tidal portions of the Patuxent, Potomac, and Choptank Rivers and the main
channel of the Chesapeake Bay.Ammonia parkinsoniana, a facultative anaerobe tolerant of periodic anoxic conditions, comprises an average of 74% of modern Chesapeake foraminiferal
assemblages (DO-0.47 and 1.72 ml l−1) compared to 0% to 15% of assemblages collected in the 1960s. Paleoecological analyses show thatA. parkinsoniana was absent prior to the late 17th century, increased to 10–25% relative frequency between approximately 1670–1720 and 1810–1900,
and became the dominant (60–90%) benthic formaniferal species in channel environments beginning in the early 1970s. Since
the 1970s, deformed tests ofA. parkinsoniana occur in all cores (10–20% ofAmmonia), suggesting unprecedented stressful benthic conditions. These cores indicate that prior to the late 17th century, there
was limited oxygen depletion. During the past 200 years, decadal scale variability in oxygen depletion has occurred, as dysoxic
(DO=0.1–1.0 ml l−1), perhaps short-term anoxic (DO<0.1 ml l−1) conditions developed. The most extensive (spatially and temporally) anoxic conditions were reached during the 1970s. Over
decadal timescales, DO variability seems to be linked closely to climatological factors influencing river discharge; the unprecedented
anoxia since the early 1970s is attributed mainly to high freshwater flow and to an increase in nutrient concentrations from
the watershed. 相似文献
6.
Frances P. Gelwick Senol Akin D. Albrey Arrington Kirk O. Winemiller 《Estuaries and Coasts》2001,24(2):285-296
We described seasonal fish-assemblages in an estuarine marsh fringing Matagorda Bay, Gulf of Mexico. Habitat zones were identified by patterns of fish species abundance and indicator species optima along gradients in salinity, dissolved oxygen (DO), and depth in our samples. Indicators of the lower brackish zone (lower lake and tidal bayou closest to the bay) were gulf menhaden (Brevoortia patronus), bay anchovy (Anchoa mitchilli), silver perch (Bairdiella chrysoura), and spotted seatrout (Cynoscion nebulosus) at salinity >15‰, DO 7–10 mg l−1, and depth <0.5 m. Indicators of the upper brackish zone (lake and fringing salt marsh) were pinfish (Lagodon rhomboides) and spot (Leiostomus xanthurus) at salinity 10–20‰, DO >10 mg l−1, and depth <0.5 m. In the freshwater wetland zone (diked wetland, ephemeral pool, and perennial scour pool), indicators were sheepshed minnow (Cyprinod on variegatus), rainwater killifish (Lucania parva), mosquitofish (Gambusia affinis), and sailfin molly (Poecilia latipinna) at salinity <5‰, DO <5 mg l−1, and depth ≥1 m. In the freshwater channelized zone (slough and irrigation canal), indicators were three sunfish species (Lepomis), white crappie (Pomoxis annularis), and gizzard shad (Dorosoma cepedianum) at salinity <5‰, DO <5 mg l−1, and depth >1.5 m. In brackish zones, seasonal variation in species diversity among sites was positively correlated with temperature, but assemblage structure also was influenced by depth and DO. In the freshwater zones, seasonal variation in species diversity among sites was positively correlated with depth, DO, and salinity, but assemblage structure was weakly associated with temperature. Species diversity and assemblage structure were strongly affected by the connectivity between freshwater wetland and brackish zones. Uncommon species in diked wetlands, such as tarpon (Megalops atlanticus) and fat sleeper (Dormitator maculatus), indicated movement of fishes from the brackish zone as the water level rose during natural flooding and scheduled (July) releases from the diked wetland. From September to July, diversity in the freshwater wetland zone decreased as receding waters left small isolated pools, and fish movement became blocked by a water-control structure. Subsequently, diversity was reduced to a few species with opportunistic life histories and tolerance to anoxic conditions that developed as flooded vegetation decayed. 相似文献
7.
Bruce A. Warren 《Journal of Earth System Science》1994,103(2):301-314
The setting of the Arabian Sea is reviewed in order to examine which of the circumstances causing large oxygen depletion in
the ocean are responsible for the suboxic layer (concentrations < 0.1 ml 1−1) in the northern thermocline there. The wind field forces circulations that restrict but do not exclude exchange with the
south, and a recent box-model interpretation of trichlorofluoromethane measurements indicates a modest throughflow for the
layer of about 5 × 106m3s
−1.The associated oxygen-flux divergence is roughly consistent with biochemical determinations of local oxygen-consumption rates,
both approaches giving values (3–6 pl 1−1 sτ-1) that are modest in comparison with estimates elsewhere in the world ocean. Despite the high mean-annual surface productivity
in the region (nearly 1gCm−2 day−1), it seems plausible that too little of this particulate matter is consumed at thermocline depths to cause an inflated oxygen
demand there. Since the layer is neither an isolated pool, nor a sluggish backwater, nor a conspicuous oxygen sink, the suboxic
concentrations must be due (as earlier proposed) to the low concentration in the water entering the layer from the south.
That depletion in turn seems due to moderate consumption as the water travels the very long trajectories from its zone of
sea-surface renewal (Lats. 40–50°S). Although large seasonal variations are expected in both throughflow volume transport
and surface productivity (suggesting comparable changes in consumption rate), the volume of the suboxic layer seems big enough
to buffer the oxygen levels there against any very noticeable overall variability. 相似文献
8.
Maik Pertermann Alan G. Whittington Anne M. Hofmeister Frank J. Spera John Zayak 《Contributions to Mineralogy and Petrology》2008,155(6):689-702
Thermal diffusivity (D) was measured using laser-flash analysis from oriented single-crystal low-sanidine (K0.92Na0.08Al0.99Fe3+
0.005Si2.95O8), and three glasses near KAlSi3O8. Viscosity measurements of the three supercooled liquids, in the range 106.8 to 1012.3 Pa s, confirm near-Arrhenian behavior, varying subtly with composition. For crystal and glass, D decreases with T, approaching a constant near 1,000 K: D
sat ∼ 0.65 ± 0.3 mm2 s−1 for bulk crystal and ∼0.53 ± 0.03 mm2 s−1 for the glass. A rapid decrease near 1,400 K is consistent with crossing the glass transition. Melt behavior is approximated
by D = 0.475 ± 0.01 mm2 s−1. Thermal conductivity (k
lat) of glass, calculated using previous heat capacity (C
P) and new density data, increases with T because C
P strongly increases with T. For melt, k
lat reaches a plateau near 1.45 W m−1 K−1, and is always below k
lat of the crystal. Melting of potassium feldspars impedes heat transport, providing positive thermal feedback that may promote
further melting in continental crust. 相似文献
9.
David S. Johnson John W. Fleeger Kari A. Galván E. Barry Moser 《Estuaries and Coasts》2007,30(2):226-237
Coastal systems serve many human uses and as a result are susceptible to anthropogenic activities such as nutrient loading
and overfishing. In soft sediments, infauna frequently serve as key indicators of such activities. To use infauna effectively
as bioindicators, it is important to understand how infaunal abundances and community patterns vary naturally within ecosystems.
We examined the spatial and temporal dynamics of infaunal annelids in four tidal creeks of the Plum Island Estuary, Massachusetts,
USA, from June to October 2003, sampling along a tidal inundation gradient that crossed five distinct habitats from creek
bottoms to the vegetated high marsh platform. Annelids comprised 97% of the total number of macroinfauna. Highest densities
were found in creek wall habitats (33,418–65,535 individuals m−2), and lowest densities (2,421–10,668 individuals m−2) were found inSpartina patens habitats. Five numerically abundant species comprised 87% of the annelid assemblage and three species,Manayunkia aestuarina (Polychaeta),Paranais litoralis (Oligochaeta), andCernosvitoviella immota (Oligochaeta), were broadly distributed across the marsh landscape.Streblospio benedicti (Polychaeta) andFabricia sabella (Polychaeta) were abundant only in mudflat and creek wall habitats, respectively.P. litoralis experienced a summer decline in all habitats, whereasM. aestuarina abundance increased 4–5 fold, in October relative to June in creek wall and tall-formSpartina alterniflora habitats. Hierarchical spatial, analysis revealed that >90% of the variability in annelid abundances was found at the mesospatial
scale (<50 m). Variation among the four creeks, (>1 km) was relatively small. 相似文献
10.
Sulfate reduction rates were measured over the course of a year in the sediments of aJuncus roemerianus marsh located in coastal Alabama. Sulfate reduction rates were typically highest in the surface 0–2 cm and at depths corresponding
to peak belowground biomass of the plants. The highest volume-based sulfate reduction rate measured was 1,350 μmol liter-sediment−1 d−1 in September 1995. Areal sulfate reduction rates (integrated to 20 cm depth) were strongly correlated to sediment temperature
and varied seasonally from 15.2 mmol SO
4
2−
m−2 d−1 in January 1995 to 117 mmol SO
4
2−
m−2 d−1 in late August 1995. Despite high sulfate reduction rates porewater dissolved sulfide concentrations were low (<73 μM), indicating
rapid sulfide oxidation or precipitation. Sulfate depletion data indicated that net oxidation of sediment sulfides occurred
in March through May, following a period of infrequent tidal flooding and during a period of high plant production. Porewater
Fe(II) reached very high levels (maximum of 969 μM; mean for all dates was 160 μM), particularly during periods of high sulfate
reduction. The annual sulfate reduction rate integrated over the upper 20 cm of sediment was 22.0 mol SO
4
2−
m−2 yr−1, which is among the highest rates measured in a wetland ecosystem. Based on literature values of net primary production inJ. roemerianus marshes, we estimate that an amount equivalent to 16% to 90% of the annual belowground production may be remineralized through
sulfate reduction. 相似文献
11.
A diel biogeochemical study was performed to assess the influence that periods of elevated biological activity have on the biogeochemical cycling of macronutrients and redox-sensitive elements in a natural estuarine environment. High-resolution data (15 min sampling) illustrates periodic extreme variations in dissolved oxygen (DO) in the shallow waters of Azevedo Pond, Elkhom Slough, California. During periods of low tidal flushing, DO values can range from highly oxic (>560 μM O2: >250% saturation) during sunny days to suboxic conditions (<5 μM) at night. Nutrient cycling and redox-sensitive trace element biogeochemistry were evaluated in response to the extreme daily DO fluctuations. A diel sampling study was conducted over a 26-h period, where O2 concentrations ranged from 346 μM to sustained non-detectable levels in the night hours. In concert with the DO fluctuations, diel phosphate cycling was on the order of 4 μM in response to tidal flushing events and biological assimilation and regeneration. The IO3 −/I− redox couple quickly responded to suboxic conditions in the water column by a marked increase in I− concentrations and corresponding depletion of IO3 −. The extreme fluctuations of the p∈ in the water column resulted in diel dissolved Mn2+ variations of nearly 5 μM, with observed dissolved Mn removal rates on the order of 1 μM h−1. The elevated biogeochemical cycling of oxygen, nitrogen, phosphorus, iodine, manganese, and iron found in this shallow estuarine environment suggest that tidal restrictions and anthropogenic nutrient enrichments can amplify diel variations and potentially hinder the functional and ecological stability of these systems. These data suggest that accurate chemical monitoring of the health of an estuarine ecosystem must account for the diel variability inherent in these highly productive environments. 相似文献
12.
Quarterly field sampling was conducted to characterize variations in water column and sediment nutrients in a eutrophic southern
California estuary with a history of frequent macroalgal blooms. Water column and sediment nutrient measures demonstrated
that Upper Newport Bay (UNB) is a highly enriched estuary. High nitrate (NO3
−) loads from the river entered the estuary at all sampling times with a rainy season (winter) maximum estimated at 2,419 mol
h−1. This resulted in water NO3
− concentration in the estuary near the river mouth at least one order of magnitude above all other sampling locations during
every seasons; maximum mean water NO3
− concentration was 800 μM during springer 1997. Phosphorus (P)-loading was high year round (5.7–90.4 mol h−1) with no seasonal pattern. Sediment nitrogen (N)-content showed a seasonal pattern with a spring maximum declining through
fall. sediment and water nutrients, as well as percent cover of three dominant macroalgae, varied between the main channel
and tidal creeks. During all seasons, water column NO3
− concentrations were higher in the main channel than in tidal creeks while tidal creeks had higher levels of sediment total
Kjeldhal nitrogen (TKN) and P. During each of the four sampling periods, percent cover ofEntermorpha intestinalis andCeramium spp. was higher in tidal creeks than in the main channel, while percent cover ofUlva expansa was always higher in the main channel. Decreases in sediment N in both creek and channel habitats were concurrent with increases
in macroalgal cover, possibly reflecting use of stored sediment TKN by macroalgae. Our data suggest a shift in primary nutrient
sources for macroalgae in UNB from riverine input during winter and spring to recycling from sediments duirng summer and fall. 相似文献
13.
As a part of the MONTBLEX-90 observational programme, Kytoon and Doppler sodar observations were taken at Kharagpur. These
data are analysed to study the turbulent characteristics of the atmospheric boundary layer in terms of stability, temperature
structure function (C
T
2
) and velocity structure function (C
v
2
).C
T
2
follows aZ
−4/3 law on most of the days, whereas the variation ofC
V
2
is not systematic.C
V
2
andC
T
2
values are found to vary between 10−5−10−1 m4/3s−2 and 10−5−10−2°C2 m−2/3 respectively. 相似文献
14.
Nicholas R. de Sieyes Kevan M. Yamahara Adina Paytan Alexandria B. Boehm 《Estuaries and Coasts》2011,34(2):256-268
Two 14-day experiments conducted in the dry summer (July 2006) and wet winter (March 2007) seasons, respectively, examined
tidal, wave-driven, and seasonal variability of submarine groundwater discharge (SGD) at Stinson Beach, CA, using natural
radium tracers. Tide stage, tide range, breaker height, and season each explained a significant degree of radium variability
in the surf zone. A mass balance of excess radium in the surf zone was used to estimate SGD for each season, confirming larger
discharge rates during the wet season. Our results indicate median groundwater discharge rates of 6 to 8 L min−1 m−1 in July 2006 and 38 to 43 L min−1 m−1 in March 2007. SGD from 200 m of Stinson Beach in March 2007 contributed a flux of phosphate and dissolved inorganic nitrogen
approximately equal to that associated with all local creeks and streams within 6 km of the study site at that time. 相似文献
15.
Heather U. Abello Shawn M. Shellito Leslie H. Taylor Peter A. Jumars 《Estuaries and Coasts》2005,28(4):487-499
Acoustic backscatter from an active sonar system (TAPS-6) over a range of six frequencies between 265 kHz and 3 MHz revealed
characteristics of emergence and reentry events within 1 h of sunset and sunrise, respectively, at a site 10 m deep in the
Damariscotta River estuary, Maine. Emergence traps indicated that the mysid shrimpNeomysis americana was the dominant migrator. Daily fluctuation in irradiance influenced the timing of dusk emergence. Local variability in
irradiance apparently caused populations to emerge occasionally before sunset or to leave the surface after the beginning
of nautical twilight near dawn. Emergence before sunset was marked by slower-than-average ascent, and departure from the surface
after initiation of nautical twilight was marked by faster-than-average descent. This pattern would be expected for populations
avoiding visual predators by concealment in dark water. Mean ascent (0.29 ± 0.03 cm s−1 [±1 SE]) and descent (−0.26 ± 0.02 cm s−1) velocities showed little difference in magnitude, suggesting that a similar mechanism controls both. Ascent initiation times
for the first such event of the night were consistent with a cue based on relative rate of change in light intensity and inconsistent
with either the progress of isolumes or with absolute rate of change in light intensity. 相似文献
16.
Radiocarbon analyses were carried out in the annual bands of a 40 year old coral collected from the Gulf of Kutch (22.6°N,
70°E) in the northern Arabian Sea and in the annual rings of a teak tree from Thane (19°14′N, 73°24′E) near Bombay. These
measurements were made in order to obtain the rates of air-sea exchange of CO2 and the advective mixing of water in the Gulf of Kutch. The Δ14C peak in the Thane tree occurs in the year 1964, with a value of ∼630‰, significantly lower than that of the mean atmospheric
Δ14C of the northern hemisphere (∼ 1000‰). The radiocarbon time series of the coral was modelled considering the supply of carbon
and radiocarbon to the gulf through air-sea exchange and advective water transport from the open Arabian Sea. A reasonable
fit for the coral data was obtained with an air-sea CO2 exchange rate of 11–12 mol m−2 yr−1, and an advective velocity of 28 m yr−1 between the Arabian Sea and the Gulf of Kutch; this was based on a model generated time series for radiocarbon in the Arabian
Sea. The deduced velocity (∼ 28 m yr−1) of the advective transport of water between the gulf and the Arabian Sea is much lower than the surface tidal current velocity
in this region, but can be understood in terms of net fluxes of carbon and radiocarbon to the gulf to match the observed coral
Δ14C time series. 相似文献
17.
J. Magdalena Santana-Casiano M. González-Dávila A. G. González F. J. Millero 《Aquatic Geochemistry》2010,16(3):467-482
Fe(II)-Fe(III) redox behavior has been studied in the presence of catechol under different pH, ionic media, and organic compound
concentrations. Catechol undergoes oxidation in oxic conditions producing semiquinone and quinone and reduces Fe(III) in natural
solutions including seawater (SW). It is a pH-dependent process. Under darkness, the amount of Fe(II) generated is smaller
and is related to less oxidation of catechol. The Fe(II) regeneration is higher at lower pH values both in SW with log k = 1.86 (M−1 s−1) at pH 7.3 and 0.26 (M−1 s−1) at pH 8.0, and in NaCl solutions with log k of 1.54 (M−1 s−1) at pH 7.3 and 0.57 (M−1 s−1) at pH 8.0. At higher pH values, rate constants are higher in NaCl solutions than in SW. This is due to the complexation
of Mg(II) present in the media with the semiquinone that inhibits the formation of a second Fe(II) through the reaction of
this intermediate with other center Fe(Cat)+. 相似文献
18.
E. A. Kalinichenko A. S. Litovchenko A. M. Kalinichenko N. N. Bagmut N. T. Dekhtyaruk 《Physics and Chemistry of Minerals》1997,24(7):520-527
Dehydroxylation of muscovite in the form of small lamellae at 923 <T <1173 K was studied by Electron Spin Resonance (ESR) on Fe3+. The kinetics of the process has been established to be described by the model of continuous nucleation on the large surface
planes of the small plates. Determined by experimental data the rate constant of the process k is shown to be that of dehydroxylation itself. The activation energy obtained by data at T<1100 K is 97.5 KJ·mol−1. The nonlinear dependence of ln(k) on 1/T is explained by the theory of transitions induced by the fluctuative preparation of a potential barrier as a result of thermal
oscillations of ions in the lattice. At high temperatures the potential curve of the hydroxyl's proton is transformed so that
it can overcome the barrier from one potential well to the other (from one hydroxyl site to the adjacent one). Such transformations
of the curve can be caused by the oscillations of large structural clusters (∼1·10−22 kg) with the frequency ∼4.5·1012 s−1.
Received: 3 August 1995 / Accepted: 13 April 1997 相似文献
19.
The experiments of the dissolution kinetics of fluorite were performed in aqueous HCl solutions over the temperature range
of 25–100 °C using a flow-through experimental apparatus. With a constant input of aqueous HCl solution through the reactor,
output concentrations of the dissolved species Ca, F, Cl vary with flow rate, as well as with the surface compositions. Measured
output concentrations of dissolved species and the pH can be used to determine a rate law for fluorite dissolution. Fluorite
dissolution rates are found to be pH dependent. Usually, dissolution rates of fluorite decreases with increasing dissolved
Ca in the output solution at 25 and 100 °C. Dissolution rate can be expressed as
where k is the rate constant and α is the order with respect to the hydrogen ion activity vs. the activity of dissolved Ca. The α was obtained from kinetic experiments. For the fluorite sample passed through 18–35 mesh, α =1.198 at 100 °C and k = 10−0.983, while fluorite dissolved in HCl–H2O solution at pH 2.57 of input solution. Adsorption of a proton and Cl−1onto the fluorite surface, surface cation exchange and the formation of the surface complex Ca(F, Cl)2 and/or (H2x, Ca1−x)(F, Cl)2 control dissolution rates. Investigation of the fluorite surface before and after dissolution by using X-ray photoelectron
spectroscopy (XPS) indicate that surface modifications affect reaction rates. 相似文献
(1a) |
20.
Speciation and phytoavailability of heavy metals in sediments in Nanjing section of Changjiang River 总被引:3,自引:1,他引:2
Heavy metal pollution and their fractionations in the sediments of Changjiang River in Nanjing Reach was monitored for cadmium
(Cd), lead (Pb), zinc (Zn), chromium (Cr), and copper (Cu). Moreover, the biological enrichment of metals by riverine plants
was studied. The results demonstrated there were highly significant variations among different sampling stations for the concentrations
of tested metals. The highest range was for Cu (38.8–120.4 mg kg−1), followed by Cr (74.4–120.0 mg kg−1), Zn (80.9–121.1 mg kg−1), Ni (26.0–55.5 mg kg−1), Pb (15.8–46.7 mg kg−1) and Cd (0.28–0.48 mg kg−1). Cd was the element with highest biological enrichment factor (BEF). The highest BEF of Cd in Erigeron bonariensis reached 3.0, indicating a significant Cd enrichment in this aquatic plant. In addition, 60% of Cd was found in reducible
fraction and exchangeable and acid-soluble fraction, which was consistent with its high mobility. The consistency of Cd fraction
in sediment and suspended particle indicated they came from the same source. Accumulated Cd concentration calculated according
to the release curve showed significant relativity with the total Cd concentration in the sediment. 相似文献