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1.
魏家钨矿床位于湘南西部铜山岭地区,是近年来在南岭成矿带西端新发现的一超大型矽卡岩型钨矿床。矿体主要产于祥林铺花岗岩与其围岩的接触带内,其形成与祥林铺花岗岩密切相关。为厘清其成岩成矿时代,本文对魏家钨矿区的花岗斑岩和石英斑岩进行了锆石LA-MC-ICP-MS U-Pb测年。结果显示,矿区花岗斑岩侵位时间为(157.8±0.9)Ma(MSWD=1.06),石英斑岩侵位时间为(158.3±1.4)Ma(MSWD=0.2)。矿区内花岗斑岩与石英斑岩侵位时间在误差范围内一致,表明两者可能是同一岩浆演化至不同阶段的产物,矿区内花岗质岩浆活动与钨多金属成矿作用时限约为158 Ma,为南岭地区中生代"大规模成矿"作用(160~150 Ma)的组成部分。另外,花岗斑岩中捕获有少量加里东期的岩浆锆石(435 Ma),指示该区曾发生加里东期岩浆活动,这与华南地区广泛存在的加里东期构造岩浆活动事件吻合。魏家钨矿成岩成矿时代的厘定对于在南岭成矿带西端寻找晚侏罗世钨矿具有重要的指示意义。 相似文献
2.
鹿鸣钼矿是伊春-延寿成矿带内近年发现的大型斑岩钼矿,矿区主要出露含矿的二长花岗岩、花岗斑岩,不含矿的花岗闪长岩及似斑状花岗闪长岩四种岩性。二长花岗岩与花岗斑岩具有相似的低Sr高Y等地球化学特征,形成于194.8±0.7Ma~184Ma前后的早侏罗世,是斑岩型矿床的赋矿围岩。花岗闪长岩及似斑状花岗闪长岩含有暗色岩包体,主要为高钾钙碱性系列岩石,但以高Sr、低Y及富Na为特征,部分地球化学指标与中国东部埃达克岩极为相似,形成于176.2±2.1Ma并与辉钼矿Re-Os法获得的成矿年龄一致,被认定为斑岩型矿床的成矿母岩。高Sr和低Sr两类花岗岩形成于不同的构造背景,与中生代时期中国东部及其邻区几次重大地质事件密切相关。鹿鸣斑岩型钼矿床与中侏罗世太平洋板块俯冲在高氧逸度条件下熔融形成的埃达克质岩浆高侵位有关。鹿鸣矿区埃达克岩的发现表明中侏罗世太平洋板块已经发生了萎缩与消减,与之相关的岩浆作用及成矿应该具有广泛的区域性,扎实的岩石学工作可为区域更多斑岩型矿床的发现提供线索。 相似文献
3.
河北省四拨子-六拨子钼铜矿区侵入岩 LA-ICP-MS锆石U-Pb定年及成矿意义 总被引：1，自引：0，他引：1
河北省青龙满族自治县四拨子-六拨子钼铜矿位于燕辽成矿带东部,是近年来发现的中型钼铜矿床。矿化多沿层面、裂隙充填、交代,呈脉状赋存于大红峪组的石英砂岩、长石石英砂岩及白云岩夹层和高于庄组的白云岩内,地质特征表明成矿主要与硅化关系密切。文章对矿区6个侵入岩进行了锆石LA-ICP-MS U-Pb年代学研究,结果表明,矿区存在4期岩浆侵入活动:第一期为晚三叠世(211~206 Ma),形成六柱坪和三拨子西沟细粒似斑状二长花岗岩;第二期为早侏罗世早期(196~190 Ma),形成老商家和五拨子花岗斑岩;第三期为早侏罗世晚期(177Ma),形成达子沟细粒似斑状二长花岗岩;第四期为晚侏罗世早期(160 Ma),形成七拨子粗中粒二长花岗岩。矿区辉钼矿的Re-Os加权平均年龄为(194±1)Ma,成矿时代为早侏罗世,与花岗斑岩形成时代一致(196~190 Ma),表明钼铜成矿可能与花岗斑岩岩浆期后热液活动有关。 相似文献
4.
西拉沐伦成矿带中生代花岗岩浆活动与钼成矿作用 总被引：4，自引：0，他引：4
位于华北克拉通北缘的西拉沐伦成矿带内花岗岩浆活动及钼矿化发育,带内主要成矿侵入体岩石类型包括二长花岗岩、斑状花岗岩、花岗斑岩及流纹斑岩,这些岩石属于高钾钙碱性和钾玄岩系列,岩浆源区为古老下地壳和新生地壳。这些侵入体形成于早—中三叠世、晚侏罗世及早白垩世。带内钼矿床包括斑岩型、石英脉型、云英岩型和火山-次火山热液型4种类型,以斑岩型矿床最为发育。带内钼矿床形成时代与相关侵入岩时代一致,也形成于早—中三叠世、晚侏罗世及早白垩世,以早白垩世钼矿床最为发育。3期成岩成矿作用分别形成于华北板块与西伯利亚板块同碰撞至后碰撞构造环境、古太平洋板块向欧亚大陆俯冲的构造环境和中国东部岩石圈减薄构造环境。 相似文献
5.
铜陵地区高钾钙碱性系列侵入岩锆石U-Pb年代学及其地质意义 总被引：6，自引：0，他引：6
铜陵地区高钾钙碱性系列侵入岩主要岩石类型为石英二长闪长(玢)岩、花岗闪长(斑)岩,其次为辉长闪长岩。本文报道该系列侵入岩最新锆石U-Pb定年结果及岩石地球化学数据。结果表明,南洪冲和沙滩脚花岗闪长岩、新桥头花岗闪长斑岩、缪家石英二长闪长玢岩的SHRIMP锆石U-Pb年龄分别为(138.8±1.3)Ma、(144.1±1.2)Ma、(147.2±1.5)Ma和(142.8±1.6)Ma,沙滩脚岩体和缪家岩体的LA-ICPMS锆石U-Pb年龄分别为(144.1±1.5)Ma、(143.2±1.3)Ma,与SHRIMP定年结果一致。一般来说,区内具有斑状结构的岩石,其年龄大于同类无斑状结构的岩石,但狮子山矿田的南洪冲花岗闪长岩年龄比区域上其他的同类岩石偏小,可能反映了区域上此类岩浆具有多次活动的特点。铜陵地区岩浆侵位的大致顺序为花岗闪长斑岩/第一次花岗闪长岩→辉长闪长岩/第一次辉石二长闪长岩→石英二长闪长玢岩/石英二长闪长岩→第二次花岗闪长岩→第二次辉石二长闪长岩。本区高钾钙碱性系列岩浆侵入活动是中国东部晚侏罗-早白垩世期间岩浆事件的组成部分,反映了中国东部区域构造由晚侏罗世的挤压转变为早白垩世的伸展环境。 相似文献
6.
通过岩相学研究和LA-ICP-MS锆石U-Pb测年,对红山子岩体的主要侵入期次和侵入岩形成时代进行了厘定,明确了红山子岩体为复式岩体并探讨了其地质意义。岩相学研究表明,红山子复式岩体由粗粒碱长花岗岩、斑状黑云母花岗岩、细粒黑云母碱长花岗岩和花岗斑岩等组成; LA-ICP-MS锆石U-Pb测年结果显示:粗粒碱长花岗岩的年龄为153. 6±1. 2 Ma,斑状黑云母花岗岩年龄为151. 4±1. 1 Ma,与周边火山盆地赋矿火山岩的年龄一致,属晚侏罗世早期;细粒黑云母碱长花岗岩的年龄为131. 5±1. 8 Ma,花岗斑岩年龄为133. 3±1. 4 Ma,与侵入红山子盆地的花岗斑岩的年龄一致,属早白垩世早期。因此,红山子岩体是由燕山期2个相隔20 Ma的不同期次侵入体组成的复式岩体。研究表明,红山子铀矿床赋存在早白垩世早期花岗斑岩与晚侏罗世火山岩的内、外接触带中,暗示复式岩体早白垩世早期细粒黑云母花岗岩、花岗斑岩与晚侏罗世粗粒碱长花岗岩、斑状黑云母花岗岩的内、外接触带是有利的找矿部位,并得到了铀矿勘查实践的初步证实。 相似文献
7.
西拉沐伦钼矿带半拉山斑岩钼矿床花岗斑岩锆石SHRIMP U-Pb测年及其地质意义 总被引：6，自引：0，他引：6
半拉山斑岩钼矿床是大兴安岭南段中生代西拉沐伦钼矿带中重要的钼矿床之一。矿床产于晚侏罗世火山岩中,矿区发育中生代侵入杂岩,侵入岩主要包括花岗闪长岩、闪长岩及花岗斑岩。矿床形成与侵入杂岩岩浆演化晚期岩浆活动有关。花岗斑岩锆石SHRIMP U-Pb定年表明,与成矿有关的晚期花岗斑岩侵位于(132.1±1.8) Ma。这表明,半拉山钼矿化发生在早白垩世,形成于中国东部岩石圈减薄构造环境。结合已有资料分析,认为大兴安岭南段除铅锌银铁铜等矿床之外,在白垩纪发生过重要的钼矿成矿作用,与白垩纪花岗斑岩有关的钼矿化是今后重要的找矿方向。 相似文献
8.
中甸火山-岩浆弧燕山期热林复式岩体演化
与Ar-Ar 定年及铜钼矿化 总被引：10，自引：0，他引：10
产于中甸印支期火山一岩浆弧北东缘的燕山期热林复式岩体,从早至晚边部到中部划分出主期由细粒似斑状二长花岗岩→中粒似斑状二长花岗岩和边部补充期二长花岗斑岩5个侵入体组成的同源岩浆细粒→中粒→斑状结构演化系列.岩体岩石化学、稀土和微量元素总体反映为同熔型花岗岩特征.在复式岩体Ⅱ号侵入体中粒似斑状二长花岗岩中获黑云母Ar-Ar同位素等时年龄81.7±1.1Ma,坪年龄82.01±0.86 Ma,属燕山晚期侵入体.铜钼矿主要产于晚期侵入体中,边部细粒花岗岩和角岩内带具有细脉状黄铜矿、团块状辉钼矿化;中部发生二长花岗(斑)岩热液蚀变充填交代辉钼矿化--辉钼矿石英细脉、中粗晶浸染状;以及沿裂隙发育岩浆期后含矿热液充填交代辉钼矿化,构成燕山期花岗斑岩铜钼成矿亚系列.成因类型:蚀变花岗斑岩、石英脉型和角岩型3种,指示了燕山期二长花岗斑岩类具有较好的铜钼找矿潜力. 相似文献
9.
江西上饶梨子坑火山盆地潜火山岩地球化学特征、
锆石U-Pb年龄及其与铅锌矿成矿关系 总被引：2，自引：0，他引：2
本文研究了上饶梨子坑火山盆地分布最广的潜火山岩—花岗斑岩和流纹斑岩岩石学、岩石地球化学、稀土微量元素地球化学特征,并开展了锆石U-Pb定年。结果表明,周家矿区花岗斑岩体年龄为164.6±1.0 Ma,相当于晚侏罗世;蔡家坪和橙树坪矿区流纹斑岩的年龄分别为137.0±2.1 Ma、138.8±1.4 Ma,为早白垩世。结合区内潜火山岩的特征及其与铅锌矿在赋存空间、成矿时代、热液蚀变、物质来源等方面的关系,认为梨子坑火山盆地内的晚侏罗世—早白垩世的花岗斑岩和流纹斑岩是本区铅锌矿最重要的成矿母岩和赋矿岩体,这为本区今后的找矿指明了方向。 相似文献
10.
内蒙古鸡冠山钼矿流纹斑岩的成岩年龄及地质意义 总被引：1，自引：0，他引：1
内蒙古鸡冠山钼矿床是近年来发现的一个大型斑岩型钼矿床,位于华北克拉通北缘、西拉沐沦钼矿带的中段,产出于一破火山机构的NW侧。矿床矿石矿物辉钼矿Re-Os同位素等时线法测得成矿年龄为151.1±1.3Ma,为晚侏罗世成矿。本文通过SIMS锆石U-Pb年龄法,测定流纹斑岩成岩年龄为148.5±3.3Ma(U-Pb等时线年龄,2σ,MSWD=2.2),为晚侏罗世成岩。该成岩年龄与成矿年龄在误差范围内一致,说明与流纹斑岩有关的岩浆活动可能形成成矿的母岩浆,成岩与成矿近乎同时发生。 相似文献
11.
The newly discovered Chalukou giant porphyry Mo deposit, located in the northern Great Xing’an Range, is the biggest Mo deposit in northeast China. The Chalukou Mo deposit occurs in an intermediate-acid complex and Jurassic volcano-sedimentary rocks, of which granite porphyry, quartz porphyry, and fine-grained granite are closely associated with Mo mineralization. However, the ages of the igneous rocks and Mo mineralization are poorly constrained. In this paper, we report precise in situ LA-ICP-MS zircon U–Pb dates for the monzogranite, granite porphyry, quartz porphyry, fine grained granite, rhyolite porphyry, diorite porphyry, and andesite porphyry in the Chalukou deposit, corresponding with ages of 162 ± 2 Ma, 149 ± 5 Ma, 148 ± 2 Ma, 148 ± 1 Ma, 137 ± 3 Ma, 133 ± 2 Ma, and 132 ± 2 Ma, respectively. Analyses of six molybdenite samples yielded a Re–Os isochron age of 148 ± 1 Ma. These data indicate that the sequence of the magmatic activity in the Chalukou deposit ranges from Jurassic volcano-sedimentary rocks and monzogranite, through late Jurassic granite porphyry, quartz porphyry, and fine-grained granite, to early Cretaceous rhyolite porphyry, diorite porphyry, and andesite porphyry. The Chalukou porphyry Mo deposit was formed in the late Jurassic, and occurred in a transitional tectonic setting from compression to extension caused by subduction of the Paleo-Pacific oceanic plate. 相似文献
12.
火神庙岩体位于华北陆块南缘栾川矿集区西部,为一杂岩体,该岩体与火神庙钼矿床密切相关.目前,人们对火神庙岩体的研究程度较低,严重制约了对火神庙钼矿床成因的认识.系统开展了年代学、地球化学和Hf同位素组成研究.结果表明,石英闪长岩、二长花岗岩和花岗斑岩的形成年龄分别为150.3±0.6Ma、146.0±0.6Ma和145.1±0.5Ma,为栾川矿集区晚侏罗世第2次大规模岩浆活动的产物.火神庙杂岩体属于I型花岗岩,是不同源区部分熔融形成的岩浆上升就位的结果.石英闪长岩是富集岩石圈地幔部分熔融的产物;二长花岗岩和花岗斑岩是富集岩石圈地幔部分熔融形成的镁铁质岩浆与太华群TTG岩系部分熔融形成的长英质岩浆混合后上升就位的结果. 相似文献
13.
在1:5万区域地质填图的基础上,对浙江临安晚中生代天目山火山盆地内的指南山-东坑火山侵入岩进行锆石U-Pb测年和地球化学分析,探讨火山喷发-侵入作用过程。指南山侵入岩主要由细中粒石英闪长（斑）岩胶结大量安山岩集块角砾组成,东坑侵入岩主要由外部中细粒石英二长岩和内部细粒正长花岗（斑）岩、中粗粒正长花岗岩组成。LA-ICP-MS锆石U-Pb测年显示,指南山细中粒石英闪长岩侵入时代为130.5±1.7 Ma,东坑细粒正长花岗（斑）岩和中粗粒正长花岗岩侵入时代为127.6±1.2 Ma和127.9±1.3 Ma,形成时代为华南中生代早白垩世火山活动的高峰期。岩石属准铝质–过铝质橄榄玄粗岩系列,具有中等-较高SiO2、富碱、高K2O/Na2O、低P2O5、TiO2特征,球粒陨石标准化稀土配分曲线具有弱右倾和强负铕异常的特征,富集K、Rb 、Th、U,弱亏损Sr、Ba等大离子亲石元素,亏损-弱亏损Ti、P、Nb、Ta等高场强元素。天目山-莫干山一带火山盆地中花岗质火山岩与侵入岩具有密切成因关系,其母岩浆可能主要是由幔源岩浆底侵导致江南造山带地壳部分熔融形成的,受到大量富集岩石圈地幔物质混染,并且经历了较高程度的分异结晶演化作用,为华南地区早白垩世早期伸展拉张环境大规模喷发的产物。 相似文献
14.
Two Periods of Skarn Mineralization in the Baizhangyan W–Mo Deposit,Southern Anhui Province,Southeast China: Evidence from Zircon U–Pb and Molybdenite Re–Os and Sulfur Isotope Data 
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下载免费PDF全文 Chunhai Li Yaohui Jiang Guangfu Xing Kunyi Guo Chao Li Minggang Yu Peng Zhao Zheng Wang 《Resource Geology》2015,65(3):193-209
The recently discovered Baizhangyan skarn‐porphyry type W–Mo deposit in southern Anhui Province in SE China occurs near the Middle–Lower Yangtze Valley polymetallic metallogenic belt. The deposit is closely temporally‐spatially associated with the Mesozoic Qingyang granitic complex composed of g ranodiorite, monzonitic g ranite, and alkaline g ranite. Orebodies of the deposit occur as horizons, veins, and lenses within the limestones of Sinian Lantian Formation contacting with buried fine‐grained granite, and diorite dykes. There are two types of W mineralization: major skarn W–Mo mineralization and minor granite‐hosted disseminated Mo mineralization. Among skarn mineralization, mineral assemblages and cross‐cutting relationships within both skarn ores and intrusions reveal two distinct periods of mineralization, i.e. the first W–Au period related to the intrusion of diorite dykes, and the subsequent W–Mo period related to the intrusion of the fine‐grained granite. In this paper, we report new zircon U–Pb and molybdenite Re–Os ages with the aim of constraining the relationships among the monzonitic granite, fine‐grained granite, diorite dykes, and W mineralization. Zircons of the monzonitic granite, the fine‐grained granite, and diorite dykes yield weighted mean U–Pb ages of 129.0 ± 1.2 Ma, 135.34 ± 0.92 Ma and 145.3 ± 1.7 Ma, respectively. Ten molybdenite Re–Os age determinations yield an isochron age of 136.9 ± 4.5 Ma and a weighted mean age of 135.0 ± 1.2 Ma. The molybdenites have δ34S values of 3.6‰–6.6‰ and their Re contents ranging from 7.23 ppm to 15.23 ppm. A second group of two molybdenite samples yield ages of 143.8 ± 2.1 and 146.3 ± 2.0 Ma, containing Re concentrations of 50.5–50.9 ppm, and with δ34S values of 1.6‰–4.8‰. The molybdenites from these two distinct groups of samples contain moderate concentrations of Re (7.23–50.48 ppm), suggesting that metals within the deposit have a mixed crust–mantle provenance. Field observation and new age and isotope data obtained in this study indicate that the first diorite dyke‐related skarn W–Au mineralization took place in the Early Cretaceous peaking at 143.0–146.3 Ma, and was associated with a mixed crust–mantle system. The second fine‐grained granite‐related skarn W–Mo mineralization took place a little later at 135.0–136.9 Ma, and was crust‐dominated. The fine‐grained granite was not formed by fractionation of the Qingyang monzonitic granite. This finding suggests that the first period of skarn W–Au mineralization in the Baizhangyan deposit resulted from interaction between basaltic magmas derived from the upper lithospheric mantle and crustal material at 143.0–146.3 and the subsequent period of W–Mo mineralization derived from the crust at 135.0–136.9 Ma. 相似文献
15.
安徽沙溪斑岩型铜金矿床成岩序列及成岩成矿年代学研究 总被引：10，自引：7，他引：3
沙溪矿床是长江中下游成矿带中典型的斑岩型铜金矿床,位于庐枞盆地北外缘、郯庐断裂内,矿床成岩成矿时代确定对该矿床成因研究及区域成矿规律的认识具有重要意义。在详细野外地质工作的基础上,采集沙溪矿床与成矿有关的主要岩浆岩样品(粗斑闪长玢岩、黑云母石英闪长玢岩、中斑石英闪长玢岩、细斑石英闪长玢岩和闪长玢岩)和与黄铜矿密切共生的辉钼矿,分别利用Cameca、LA-ICP-MS U-Pb和Re-Os同位素定年方法,获得矿床内主要岩浆岩的成岩年龄(130.60±0.97Ma、129.30±1.00Ma、127.10±1.50Ma、129.46±0.97Ma和126.7±2.1Ma)以及成矿年龄(130.0±1.0Ma),并重新厘定了沙溪岩体从早到晚岩浆的侵位序列。通过区域对比,提出长江中下游存在两阶段斑岩型铜金矿化,沙溪矿床为长江中下游成矿带第二阶段形成的斑岩型矿床,沙溪矿床的成岩成矿作用既不同于庐枞盆地,也不同于断隆区第一阶段的斑岩矿床,而是受郯庐断裂和长江断裂动力学演化联合作用的产物。 相似文献
16.
Re–Os and U–Pb Geochronology of Porphyry and Skarn Types Copper Deposits in Jilin Province,NE China 下载免费PDF全文
下载免费PDF全文 Yong Zhang Shu–Wen Xing Quan–Heng Song Yan Wang Zheng–Tao Yu Xiao–Hui Du Yu–Bo Ma Zeng–Jie Zhang 《Resource Geology》2015,65(4):394-404
Jilin Province in NE China lies on the eastern edge of the Xing–Meng Orogenic Belt. Mineral exploration in this area has resulted in the discovery of numerous large, medium, and small sized Cu, Mo, Au, and Co deposits. To better understand the formation and distribution of both the porphyry and skarn types Cu deposits of the region, we examined the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of the mineralization. The Binghugou Cu deposit yields a zircon U–Pb age for quartz diorite of 128.1 ± 1.6 Ma; the Chang'anpu Cu deposit yields a zircon U–Pb age for granite porphyry of 117.0 ± 1.4 Ma; the Ermi Cu deposit yields a zircon U–Pb age for granite porphyry of 96.8 ± 1.1 Ma; the Tongshan Cu deposit yields molybdenite Re–Os model ages of 128.7 to 130.2 Ma, an isochron age of 129.0 ± 1.6 Ma, and a weighted mean model age of 129.2 ± 0.7 Ma; and the Tianhexing Cu deposit yields molybdenite Re–Os model ages of 113.9 to 115.2 Ma, an isochron age of 114.7 ± 1.2 Ma, and a weighted mean model age of 114.7 ± 0.7 Ma. The new ages, combined with existing geochronology data, show that intense porphyry and skarn types Cu mineralization was coeval with Cretaceous magmatism. The geotectonic processes responsible for the genesis of the Cu mineralization were probably related to lithospheric thinning. By analyzing the accumulated molybdenite Re–Os, zircon U–Pb, and Ar–Ar ages for NE China, it is concluded that the Cu deposits formed during multiple events coinciding with periods of magmatic activity. We have identified five phases of mineralization: early Paleozoic (~476 Ma), late Paleozoic (286.5–273.6 Ma), early Mesozoic (~228.7 Ma), Jurassic (194.8–137.1 Ma), and Cretaceous (131.2–96.8 Ma). Although Cu deposits formed during each phase, most of the Cu mineralization occurred during the Cretaceous. 相似文献
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铜陵矿集区舒家店矿区正长花岗岩的年代学和地球化学特征及其指示意义 总被引：3，自引：2，他引：1
舒家店岩体位于长江中下游成矿带中部的铜陵断隆区,与繁昌断凹区(盆地)临近,主要的岩浆岩岩石类型有辉石闪长岩、石英闪长斑岩和花岗闪长岩等。正长花岗岩为舒家店岩体深部新发现的岩石类型,其矿物组合与岩体内其他类型岩石明显不同,其形成的背景存在争议。本文通过对岩体中正长花岗岩的锆石LA-ICP MS精确定年、Hf同位素和地球化学组成分析,研究舒家店岩体正长花岗岩的年代学、岩浆源区等问题。研究显示舒家店岩体为"异源同体"的复式岩体,岩体中的正长花岗岩的侵入时间为126.5±1.6Ma~129.8±2.4Ma,明显晚于早期的辉石闪长岩和石英闪长斑岩(138.2±4.6Ma~143.7±1.7Ma),也明显晚于舒家店斑岩型铜矿床的形成时代。全岩元素地球化学和锆石Hf同位素组成指示舒家店岩体中正长花岗岩为叠加到早期辉石闪长岩及石英闪长斑岩之上的后期岩浆活动的产物,可能与繁昌盆地内花岗岩有相同的源区,为新元古代新生地壳(类似新元古花岗岩)部分熔融的产物,其岩浆源区处于高温低压的环境,相较于辉石闪长岩和石英闪长斑岩起源更浅,指示长江中下游成矿带在145~123Ma地壳处于不断减薄的过程。 相似文献
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The Chalukou deposit is located in the North Great Xing’an Range of the Xing’an-Mongolia Orogen bordering and to the northeast of the North China Craton. The deposit is a high-F-type porphyry Mo deposit hosted by the Chalukou composite igneous body containing small intrusive bodies genetically related to Mo mineralization. The composite igneous body includes pre-mineralization dolerite, monzogranite and syenogranite, syn-mineralization rhyolitic porphyry, granitic porphyry and fine-grained monzogranite, and post-mineralization rhyolitic porphyry, quartz porphyry, dioritic porphyry and andesitic porphyry. Detailed laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb zircon dating of the igneous components of the composite igneous body was carried out to determine the temporal framework for magmatism in the Chalukou region. The new LA-ICP-MS U-Pb ages constraint documented here, together with the published ages, indicate that there was a protracted porphyry Mo ore-forming event of approximately 7 million years between ca. 152 when the ore related rhyolitic porphyry was emplaced and ca.145 Ma when molybdenite ceased being deposited. The dating reveals that the mineralization is a part of relatively long-lived magmatic cycle involving the emplacement of small doleritic stocks at ca. 165 Ma that progressively evolved into extensive granitic intrusions at ca. 164 Ma, and then diminished with the emplacement of mineralization-related porphyries to ca. 152 Ma. The emplacement of barren Early Cretaceous magmatism, represented by volcanic units in the ca. 136 Ma Guanghua Formation and porphyries, followed the mineralized magmatism.The syn-mineralization porphyry units associated with Mo contain zircons assaying ∼15 times higher in U and Th than the pre-mineralization magmatic phases. This indicates that there was a significant enrichment of Mo, U and Th in the magma, and directly associated with ore fluid exsolution. The return to their normal levels in the three elements in the post-mineralization magmatic phases indicates that they were exhausted from the magma chamber in the later phases. A genetic model is proposed for the enormous introduction of ore metals and enrichment at the Chalukou deposit. The protracted and multiphase igneous activity during the long-lived magmatism reflects a multistage enrichment of metal, and may play a crucial role in the formation of a volatile-enriched, fertile and large-volume magma chamber beneath the Chalukou deposit. Such a chamber is envisaged to be required for the formation of porphyry Mo deposits in general. 相似文献
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Xinlu Hu Shuzhen Yao Mouchun He Zhenju Ding Yubao Cui Jun Shen Bin Chen Bopeng Zhu 《Resource Geology》2014,64(2):102-116
The Daheishan porphyry Mo deposit was recently discovered in the northern segment of the Great Xing'an Range, NE China. Three main types of granitoids are identified in this deposit: granodiorite, fine‐grained granite, and porphyritic granite. The orebodies are dominantly hosted within the granodiorite and in the contact zone between the granodiorite and tuff or hornfels, while no mineralization has been found in the fine‐grained granite or the porphyritic granite. We present in situ LA‐ICP‐MS zircon U‐Pb dates for the granodiorite, fine‐grained granite, and porphyritic granite, which yielded 146.9 ± 1.1 Ma (2σ), 146.6 ± 1.7 Ma (2σ), and 149.7 ± 4.2 Ma (2σ), respectively. Their εHf(t) values range from 3.9 to 12.2, associated with young crustal model ages (TDM2) ranging from 524 Ma to 849 Ma, indicating that their parental magmas may have been generated by partial melting of the Neoproterozoic–Cambrian crustal components. The formation of the Daheishan deposit was genetically related to the subduction of the Paleo‐Pacific Plate. 相似文献