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1.
The temperature (T) evolution of the barium carbonate (BaCO3) structure was studied using Rietveld structure refinements based on synchrotron X-ray diffraction and a powdered synthetic sample. BaCO3 transforms from an orthorhombic, Pmcn, α phase to a trigonal, R3m, β phase at 811°C. The orthorhombic BaCO3 structure is isotypic with aragonite, CaCO3. In trigonal R3m BaCO3, the CO3 group occupies one orientation and shows no rotational disorder. The average <Ba–O> distances increase while the <C–O> distances decrease linearly with T in the orthorhombic phase. After the 811°C phase transition, the <Ba–O> distances increase while C–O distances decrease. There is also a significant volume change of 2.8% at the phase transition.  相似文献   

2.
 Cation tracer diffusion coefficients, DMe *, for Me=Fe, Mn, Co and Ti, were measured using radioactive isotopes in the spinel solid solution (Ti x Fe 1−x )3−δO4 as a function of the oxygen activity. Experiments were performed at different cationic compositions (x=0, 0.1, 0.2 and 0.3) at 1100, 1200, 1300 and 1400 °C. The oxygen activity dependence of all data for DMe * at constant temperature and cationic composition can be described by equations of the type DMe *=D∘ Me[V]. CV·a O2 2/3+DMe[I] ∘·a O2 −2/3·DMe[V] ∘ and DMe[I] ∘ are constants and CV is a factor of the order of unity which decreases with increasing δ. All log DMe * vs. loga O2 curves obtained for different values of x and for different temperatures go through a minimum due to a change in the type of point defects dominating the cation diffusion with oxygen activity. Cation vacancies prevail for the cation diffusion at high oxygen activities while cation interstitials become dominant at low oxygen activities. At constant values of x, DMe[V] ∘ decreases with increasing temperature while DMe[I] ∘ increases.  相似文献   

3.
Load displacement analysis of drilled shafts can be accomplished by utilizing the “t-z” method, which models soil resistance along the length and tip of the drilled shaft as a series of springs. For non-linear soil springs, the governing differential equation that describes the soil-structure interaction may be discretized into a set of algebraic equations based upon finite difference methods. This system of algebraic equations may be solved to determine the load–displacement behavior of the drilled shaft when subjected to compression or pullout. By combining the finite difference method with Monte Carlo simulation techniques, a probabilistic load–displacement analysis can be conducted. The probabilistic analysis is advantageous compared to standard factor of safety design because uncertainties with the shaft–soil interface and tip properties can be independently quantified. This paper presents a reliability analysis of drilled shaft behavior by combining the finite difference technique for analyzing non-linear load–displacement behavior with Monte Carlo simulation method. As a result we develop probabilistic relationships for drilled shaft design for both total stress (undrained) and effective stress (drained) parameters. The results are presented in the form of factor of safety or resistance factors suitable for serviceability design of drilled shafts.  相似文献   

4.
The movie An Inconvenient Truth is a powerful portrayal of global warming and its impacts. The main scientific argument presented in the movie is for the most part consistent with the weight of scientific evidence, but with some of the main points needing updating, correction, or qualification. The detailed argument relies almost entirely on past and current evidence and neglects almost all information that can be gained from computer models, perhaps because such information would be difficult for a lay audience to grasp, believe, or connect with emotionally. This places an undue weight on current events as signs of ongoing climate change: some such events are apparently not related at all to climate change, while for other specific events the role of global warming is difficult or impossible to establish.  相似文献   

5.
We analyzed macroseismic data and considered the effect of extremely long range propagation of sensible shocks during the deep-focus earthquake in the Sea of Okhotsk on May 24, 2013 (Mw = 8.3). In order to explain this effect, we formulated and qualitatively solved the problem of superposition of P-waves over the radial mode 0S0 of the natural oscillations of the Earth during this earthquake. Our results confirmed the possibility of such an interpretation of the observed macroseismic effect and also allowed us to explain the fact of anomalously low decay of seismic disturbances with distance.  相似文献   

6.
 Raman spectra of a single-crystal fragment of hydrous γ-Mg2SiO4, synthesized in a multianvil press, have been measured in a diamond-anvil cell with helium as pressure-transmitting medium to 56.5 GPa at room temperature. All five characteristic spinel Raman modes shift continuously up to the highest pressure, showing no evidence for a major change in the crystal structure despite compression well beyond the stability field of ringwoodite in terms of pressure. At pressures above ∼30 GPa a new mode on the low-frequency site of the two silicate-stretching modes is clearly identifiable, indicating a modification in the spinel structure which is reversible on pressure release. The frequency of the new mode (802 cm−1 extrapolated to 1 bar) suggests the presence of Si–O–Si linkages and/or a partial increase in the coordination of Si. Direct determination of the subtle structural change causing the new Raman mode would require high-pressure, single-crystal synchrotron X-ray diffraction experiments. The Raman modes of hydrous and anhydrous Mg-end-member ringwoodite are nearly identical up to 20 GPa, suggesting that protonation has only minor effect on the lattice dynamics over the entire pressure stability range for ringwoodite in the mantle. Received: 7 December 2001 / Accepted: 16 April 2002  相似文献   

7.
Some thermal infrared anomalies on the earth’s surface are omens of stronger earthquakes, and have a close relationship with the stress fields. Satellite-based remote sensing is an important means of monitoring and researching this phenomenon. The M S 7.3 Yutian earthquake in Xinjiang on March 20, 2008 and the M S 8.0 Wenchuan earthquake in Sichuan on May 12, 2008 both happened in the Qinghai–Tibet Plateau, China, with epicenters more than 2,000 km apart. The two events, however, were a production of an identical stress field in different developing phases. Prior to the M S 7.3 Yutian earthquake, a large-scale abnormal temperature rise not only covered the epicenter of the forthcoming Yutian earthquake, but also arrived at the epicenter of the farther Wenchuan earthquake. The revolving elliptic stress thermal field reflecting earthquake gestation moved from the west to the east of the Wenchuan epicenter at the time of the Yutian event occurrence. The rotation of the calefactive ellipses and belts prior to the two strong events agreed with the stress field, the focal mechanism, and modality and mechanism property of the ruptures in the crustal surface induced by the events. It should be a reflection of the partial mantle uprush and rotation.  相似文献   

8.
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9.
The seasonal variation of foliar δ13C values in Sabina przewalskii Kom. and Sabina chinensis (Lin.) Ant. was measured. The relationships between foliar δ13C values and branch δ13C values as well as environmental factors (monthly total precipitation, monthly average air temperature, monthly average soil temperature, monthly total solar duration, relative humidity, atmospheric pressure, vapor pressure, wind speed and potential evaporation) were investigated. The results showed that the foliar δ13C values were negatively correlated with air pressure, and positively correlated with air temperature, precipitation, vapor pressure, potential evaporation, solar duration, wind speed and soil temperature. No significant relationship between δ13C values and relative humidity was detected. This demonstrates that the foliar δ13C of Sabina is a successful empirical indictor of these meteorological factors within the usual range of C3 whole-leaf δ13C values. Furthermore, the δ13C signature of leaf tissue is similar to that of wood tissue and the responses of δ13C values in S. przewalskii Kom. to environmental factors are also relatively stronger than that of S. chinensis (Lin.) Ant. These results provided strong evidence that it is feasible to extract climatic information from tree-ring δ13C series and S. przewalskii Kom. is a dendroclimatologically promising tree species.  相似文献   

10.
An Inconvenient Truth provides an opportunity to examine the differences between scientific statements and the mixed statements made by politicians. The Gore movie is a powerful example of the latter. There are some inaccuracies and exaggerations in the film, but on the whole it represents mainstream scientific views on global warming. This essay looks into the state of the art of climate change research including its scientific underpinnings. Climate science is in a state of ‘normal science’ as discussed by Kuhn. There is a large body of scientists who are adherents to the paradigm and there does not appear to be any serious alternative at this time.  相似文献   

11.
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12.
The European green crab (Carcinus maenas) is a highly successful marine invader, having established populations in a number of areas outside its natural range in the last 100 years. In South Australia,C. maenas can be abundant on intertidal mud flats, which are used by juveniles of the native blue swimmer crab (Portunus pelagicus) and could have the potential to cause substantial negative effects on this species. The influence of adult blue and green crabs on habitat selection by juvenile blue crabs was tested to determine if they responded to both predators in a similar fashion. The presence of predators did not influence habitat selection by juvenile blue crabs in either laboratory or field experiments, but juvenile behavior in the selected habitat did differ between the two adult species. Many more crabs buried themselves beneath the substrate when adult conspecifics were present than when adult green crabs were present. Burying in the presence of adult green crabs was no more frequent than when predators were absent. It remains to be determined if this makes juvenile blue crabs more vulnerable to predation by green crabs than by adults of their own species, or if the difference in response is because green crabs pose a different or lesser threat.  相似文献   

13.
Quaternary basalts in the Cerro del Fraile area contain two types of mantle xenoliths; coarse-grained (2–5 mm) C-type spinel harzburgites and lherzolites, and fine-grained (0.5–2 mm) intensely metasomatized F-type spinel lherzolites. C-type xenoliths have high Mg in olivine (Fo = 90–91) and a range in Cr# [Cr/ (Cr + Al) = 0.17–0.34] in spinel. Two C-type samples contain websterite veinlets and solidified patches of melt that is now composed of minute quenched grains of plagioclase + Cr-spinel + clinopyroxene + olivine. These patches of quenched melts are formed by decompression melting of pargasitic amphibole. High Ti contents and common occurrence of relic Cr-spinel in the quenched melts indicate that the amphibole is formed from spinel by interaction with the Ti-rich parental magma of the websterite veinlets. The fO2 values of these two C-type xenoliths range from ΔFMQ −0.2 to −0.4, which is consistent with their metasomatism by an asthenospheric mantle-derived melt. The rest of the C-type samples are free of “melt,” but show cryptic metasomatism by slab-derived aqueous fluids, which produced high concentrations of fluid-mobile elements in clinopyroxenes, and higher fO2 ranging from ΔFMQ +0.1 to +0.3. F-type lherzolites are intensely metasomatized to form spinel with low Cr# (∼0.13) and silicate minerals with low MgO, olivine (Fo = ∼84), orthpyroxene [Mg# = Mg/(Mg + ΣFe) = ∼0.86] and clinopyroxene (Mg# = ∼0.88). Patches of “melt” are common in all F-type samples and their compositions are similar to pargasitic amphibole with low TiO2 (<0.56 wt%), Cr2O3 (<0.55 wt%) and MgO (<16.3 wt%). Low Mg# values of silicate minerals, including the amphibole, suggest that the metasomatic agent is most likely a slab melt. This is supported by high ratios of Sr/Y and light rare earth elements (REE)/heavy REE in clinopyroxenes. F-type xenoliths show relatively low fO2 (ΔFMQ −0.9 to −1.1) compared to C-type xenoliths and this is explained by the fusion of organic-rich sediments overlying the slab during the slab melt. Trench-fill sediments in the area are high in organic matter. The fusion of such wet sediments likely produced CH4-rich fluids and reduced melts that mixed with the slab melt. High U and Th in bulk rocks and clinopyroxene in F-type xenoliths support the proposed interpretation.  相似文献   

14.
Fluid inclusions, mineral thermometry and stable isotope data from two types of mineralogically and texturally contrasting pegmatites, barren ones and lithium ones, from the Moldanubian Zone of the Bohemian Massif were studied in order to constrain P–T conditions of their emplacement, subsolidus hydrothermal evolution and to estimate composition of the early exsolved fluid and that of the parental melt. Despite the fact that the lithium pegmatites are abundant throughout the crystalline units of the Bohemian Massif, data similar to this paper have not been published yet. The studied pegmatites are hosted by iron-rich calcic skarn bodies. This specific setting allowed scavenging of calcium, fluorine and some other elements from the host rocks into the pegmatitic melts and post-magmatic fluids. Such contamination process was important namely in the case of barren pegmatites, as can be deduced from the variation in anorthite contents in plagioclase and from the presence of fluorite, hornblende (with F content) or garnet in the contact zones of pegmatite dykes. Fluid inclusions were studied mostly in quartz, but also in fluorite, titanite and apatite. Early aqueous–carbonic and late aqueous fluids were identified in both pegmatite types. The P–T conditions of crystallization as well as the detailed composition of exsolved magmatic fluid, however, particularly differ. The magmatic fluids associated with barren pegmatites correspond to H2O–CO2 low salinity fluids, composition of which evolved from 20 to 23 to <5 mol% CO2, and from 2 to 4–6 mol% NaCl eq. Sudden decrease in the CO2 content of the post-magmatic fluids (<5 mol% CO2) seems to coincide with the enrichment of the fluid in calcium (from the contamination process) and resulted in precipitation of calcites (frequently found as trapped solid phases in fluid inclusions). The fluids associated with lithium pegmatites are more complex (H2O–CO2/N2–H3BO3–NaCl). The CO2 content of early exsolved fluid is 26–20 mol% CO2 and remains the same in the next fluid generation. The main difference between the magmatic and the first post-magmatic fluids is the presence of 7–9 wt% of H3BO3 (identified as daughter mineral sassolite) in the former. The second post-magmatic fluids are again CO2-poor (∼4 mol%) and more saline (∼4 mol% NaCl eq.). The composition of exsolved fluid was further used to constrain volatile composition and content of the parental melts. Finally, P–T conditions of pegmatite crystallization are constrained: 600–640°C and 420–580 MPa for the barren pegmatites and 500–570°C and 310–430 MPa for the lithium pegmatite. While the emplacement of the former occurred in thermal equilibrium with the Moldanubian host rock environment, the emplacement of the later suggests substantial thermal disequilibrium.  相似文献   

15.
The M w 7.8 2015 Gorkha earthquake and its aftershocks significantly impacted the lives and economy of Nepal. The consequences of landslides included fatalities, property losses, blockades of river flow, and damage to infrastructural systems. Co-seismic landslides triggered by this earthquake were significantly widespread and pose a major geodisaster. There were tens of thousands of landslides triggered by the earthquake, majority of which were distributed in between the epicenter of the main shock and the M w 7.3 aftershock. Although 14,670 landslides triggered by this earthquake were identified, only approximately 23% of them were of moderate to large scale with areas greater than 100 m2. Of the moderate- to large-scale landslides identified, just over 90% were triggered by the main shock and smaller aftershocks prior to the major (M w 7.3) aftershock, while nearly 10% were triggered by the ground shaking induced by the major aftershock. Moreover, the number of landslides triggered by the 2015 Gorkha earthquake, specifically by the main shock, was slightly more than the expected number of landslides for the recorded maximum peak ground acceleration (PGA) in comparison to the co-seismic landslides triggered by 26 earthquakes. Over 90% of those moderate- to large-scale landslides were concentrated within the estimated fault rupture surface. Majority of these moderate- to large-scale landslides were disrupted failures with over 96% of which were classified as earth falls. However, the majority of small-scale landslides were rock or boulder falls. The most number of moderate- to large-scale landslides were triggered in the slate, shale, siltstone, phyllite, and schist of the Lesser Himalayan formation followed by an equally significant number in both schist, gneiss, etc. of the Higher Himalayan formation and the phyllite, metasandstone, schist, etc. of the Lesser Himalayan formation. The sizes (i.e., areas) of the landslides were lognormally distributed, with a mode area of 322.0 m2. Slope inclinations of the moderate- to large-scale landslides followed a normal distribution with a mean slope inclination of 32.6° and standard deviation of 13.5°. There exists a strong correlation between the number of landslides and the peak ground acceleration within the study area, specific for different geological formations.  相似文献   

16.
We analyzed historic and current fishery independent data to determine if the abundance of two apex predators, bull sharks (Carcharhinus leucas) and alligator gar (Atractosteus spatula), in Lake Pontchartrain had changed significantly over the last half century. Lake Pontchartrain is an environmentally degraded oligohaline estuary in southeastern Louisiana that has experienced considerable changes in fish assemblage composition over this interval. Using gillnet, beach seine, and trawl data collected during three time periods (1953–1955, 1977–1978, and 1996–2005), we analyzed trends in abundance forC. leucas andA. spatula using generalized linear models with a negative binomial error structure and a log link. Lake Pontchartrain data were divided into four spatial locations (northwest, northeast, southwest, southeast) since each region represents a unique combination of anthropogenic and natural influences that could affect catches. For each species and gear type, we produced log-likelihood profiles for the instantaneous rate of change in relative abundance through time. Raw catches were generally lower for both species in the later surveys.C. leucas were not captured in beach seines since the 1950s andA. spatula were rarely captured in trawls or seines since the 1970s. Likelihood profiles of changes in abundance forC. leucas andA. spatula showed very large declines in both species since 1953.C. leucas declined by 98.6% (95% CI: 73.4–99.9%) in gillnets and became functionally extirpated in beach seines with a decline of 99.9% (95% CI: 23–99.9%). Among all gears,C. leucas declined by the same rate as in gillnets. The decline inA. spatula was also large with a decrease of 98.6% (95% CI: 73.4–99.9%) in beach seines and a decline of 99.2% (95% CI: 54.8–99.9%) in trawls since 1953. Catches ofA. spatula in gillnets did not show a significant change over the study period. The continued decline of these two apex predators could seriously affect efforts to restore this degraded estuarine ecosystem.  相似文献   

17.
Lateral load-deflection behaviour of single piles is often analysed in practice on the basis of methods of load-transfer P–Y curves. The paper is aimed at presenting the results of the interpretation of five full-scale horizontal loading tests of single instrumented piles in two sandy soils, in order to define the parameters of P–Y curves, namely the initial lateral reaction modulus and the lateral soil resistance, in correlation with the pressuremeter test parameters. P–Y curve parameters were found varying as a power of lateral pile/soil stiffness, on the basis of which hyperbolic P–Y curves in sand were proposed. The predictive capabilities of the proposed P–Y curves were assessed by predicting the soil/pile response in full-scale tests as well as in centrifuge tests and a very good agreement was found between the computed deflections and bending moments, and the measured ones. Small-sized database of full-scale pile loading tests in sand was built and a comparative study of some commonly used P–Y curve methods was undertaken. Moreover, it was shown that the load-deflection curves of these test piles may be normalised in a practical form for an approximate evaluation of pile deflection in a preliminary stage of pile design. At last, a parametric study undertaken on the basis of the proposed P–Y curves showed the significant influence of the lateral pile/soil stiffness on the non-linear load-deflection response.  相似文献   

18.
For a common, widespread, and familiar plant,Phragmites australis engenders an enormous level of scientific controversy and emotional conflict. In parts of the world,Phragmites is an important component of healthy ecosystems and an integral (if now minor) contributor to human economies. In other places it is an invading, unfriendly, and ugly weed. To some scientists and environmentalists,Phragmites is an indicator of and key factor in landscape degradation and habitat deterioration. To others, it is a valiant remnant of nature, providing a relatively rich ecology where there might otherwise be only barren and eroding ground. Our review of the literature leads us to conclude thatPhragmites is simply a biological entity. It is not inherently good or bad, since its evolution, biology, and ecology do not give it a value. The controversy overPhragmites, its role in the ecosystem, and the need for and intensity of management efforts are all artifacts of human perspectives. Effective, consistent management decisions (for either control or enhancement ofPhragmites) can only be made on the basis of site-specific scientific findings, a consideration of technologies with their needed level-of-effort, and explicit exposition of the human values driving the management options. We present a simple decision model to illustrate the interaction of these management components forPhragmites in the environment.  相似文献   

19.
Seasonal variation patterns of aboveground and belowground biomass, net primary production, and nutrient accumulation were assessed inAtriplex portulacoides L. andLimoniastrum monopetalum (L.) Boiss. in Castro Marim salt marsh, Portugal. Sampling was conducted for five periods during 2001–2002 (autumn, winter, spring, summer, and autumn). This study indicates that both species have a clear seasonal variation pattern for both aboveground and belowground biomass. Mean live biomass was 2516 g m−2 yr−1 forL. monopetalum and 598 g m−2 yr−1 forA. portulacoides. Peak living biomass, in spring for both species, was three times greater in the former, 3502 g m−2 yr−1, than in the latter, 1077 g m−2 yr−1. For both the Smalley (Groenendijk 1984) and Weigert and Evans (1964) methods, productivity ofL. monopetalum (2917 and 3635 g m−2 yr−1, respectively) was greater than that ofA. portulacoides (1002 and 1615 g m−2 yr−1, respectively). Belowground biomass ofL. monopetalum was 1.7 times greater than that ofA. portulacoides. In spite of this, the root:shoot ratio forA. monopetalum to aerial components. Leaf area index was similar for both species, but specific leaf area ofA. portulacoides was twice that ofL. monopetalum. The greatest nutrient contents were found in leaves. Leaf nitrogen content was maximum in summer for both species (14.6 mg g−1 forA. portulacoides and 15.5 mg g−1 forL. monopetalum). Leaf phosphorus concentration was minimum in summer (1.1 mg g−1 inA. portulacoides and 1.2 mg g−1 inL. monopetalum). Leaf potassium contents inA. portulacoides were around three times greater than inL. monopetalum. Leaf calcium contents inL. monopetalum were three times greater than inA. portulacoides. There was a pronounced seasonal variation of calcium content in the former, while in the latter no clear variation was registered. Both species exhibited a decrease in magnesium leaf contents in the summer period. Mangamese content inL. monopetalum leaves was tenfold that inA. portulacoides. Seasonal patterns of nutrient contents inA. portulacoides andL. monopetalum suggest that availability of these elements was not a limiting factor to biomass production.  相似文献   

20.
The propagation of plane waves in an anisotropic elastic medium possessing monoclinic symmetry is discussed. The expressions for the phase velocity ofqP andqSV waves propagating in the plane of elastic symmetry are obtained in terms of the direction cosines of the propagation vector. It is shown that, in general,qP waves are not longitudinal andqSV waves are not transverse. Pure longitudinal and pure transverse waves can propagate only in certain specific directions. Closed-form expressions for the reflection coefficients ofqP andqSV waves incident at the free surface of a homogeneous monoclinic elastic half-space are obtained. These expressions are used for studying numerically the variation of the reflection coefficients with the angle of incidence. The present analysis corrects some fundamental errors appearing in recent papers on the subject.  相似文献   

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