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1.
大别山双河超高压榴辉岩中的水:微区红外光谱分析   总被引:7,自引:2,他引:7  
大陆深俯冲板块到一定深度后(约90~110km),几乎没有含水矿物存在,超高压岩石中名义上无水矿物(NAMs)成为俯冲板块中水的主要载体,是示踪超高压变质流体的重要途径.对大别山双河地区超高压榴辉岩中的石榴石和绿辉石进行了详细的微区傅立叶变换红外光谱(MicroFTIR)分析.FTIR结果显示所有石榴石和绿辉石颗粒都含有结构水,以OH的形式存在,其含量范围分别为(30~1860)×10-6和(360~620)×10-6.榴辉岩全岩水含量为(300~750)×10-6,表明即使是在超高压变质作用的温压条件下,榴辉岩也可以至少携带数百10-6的水进入深部地球.对石榴石颗粒内部的多点观察发现,结构水含量的分布出现2种情况:(1)颗粒内部的均一分布;(2)核部水含量高而边部低.石榴石颗粒边部的低水含量可能是抬升过程中由于压力降低引起的H扩散所致,扩散出来的H可能构成了早期退变质流体的重要来源.对于同一样品来说,结构水含量在绿辉石和石榴石之间的比值为0.5~3.5.  相似文献   

2.
一产于大别山北部铙钹寨面理化橄榄岩中的强变形榴辉岩的石榴子石具有退变质环带 ,表现为边部CaO含量下降和MnO含量升高 ,指示Ca和Mn在石榴子石具有较快的扩散速率。该榴辉岩中石榴子石 +绿辉石连线给出的Sm Nd年龄为 187± 5Ma ,显著小于大别山南部超高压榴辉岩及北部榴辉岩的Sm Nd年龄 (分别为 2 2 1± 5~ 2 2 8± 3Ma和 2 10± 6~ 2 14± 6Ma)。这一偏低的Sm Nd年龄可能是由于石榴子石退变质环带引起14 3 Nd/ 14 4 Nd降低所造成的。对该样品石榴子石、绿辉石和石英的δ18O测定表明 ,这些矿物之间的实测分馏值小于它们在 5 0 0~ 90 0℃条件下的平衡分馏值 ,从而证明它们之间存在氧同位素不平衡。榴辉岩中石榴子石的退变质环带也可造成绿辉石与石榴子石之间显著的Nd同位素和氧同位素不平衡现象。  相似文献   

3.
大别山碧溪岭榴辉岩中有三种含水矿物:多硅白云母、角闪石和黑云母,它们分别是超高压(UHP)阶段(即柯石英榴辉岩相阶段)或者石英榴辉岩相阶段、退变质后成合晶阶段和角闪岩相退变质阶段的产物,本文利用离子探针技术对它们进行了氢同位素和硼同位素的分析。三种矿物内部的同位素组成都是均一的,多硅白云母的δD为-105‰±9‰,δ~(11)B为-25.9‰±2.0‰;角闪石的δD为-100‰±9‰,δ~(11)B为-24.4‰±0.9‰;黑云母的δD为-65‰±4‰,δ~(11)B为-19.3‰±1.3‰。多硅白云母和角闪石的氢-硼同位素组成在误差范围内是相同的,而和黑云母则有明显的差别,这表明,从UHP阶段或者石英榴辉岩相阶段到随后的后成合晶阶段,变质流体是内部缓冲的,而在角闪岩相变质阶段,则有了外来流体的加入,这个流体是相对富集D和~(11)B的。碧溪岭榴辉岩矿物相对于其地壳原岩表现出低δ~(11)B的特征,说明俯冲过程中板块经历了强烈的脱硼。  相似文献   

4.
田野  黄建  回迎军  肖益林 《岩石学报》2015,31(7):1818-1840
高压-超高压变质岩中的变质脉能够反映俯冲带变质流体的组成和演化。为了探究大陆俯冲带超临界流体活动及伴随的元素迁移,本文系统地研究了苏鲁造山带南部江苏东海池庄地区的超高压榴辉岩及变质脉。变质脉主要是由石英、石榴石、绿辉石、多硅白云母、蓝晶石、黝帘石、金红石和锆石等矿物组成,与寄主榴辉岩的矿物组成类似。相比于榴辉岩,脉体中的石榴石更加富集重稀土元素(HREE);黝帘石强烈富集轻稀土元素(LREE)。变质脉和榴辉岩中各主要矿物的氧同位素组成在误差范围内一致(石英的δ18O分别为2.42‰和2.79‰;石榴石为-0.30‰和0.010‰;绿辉石为0.25‰和0.071‰),说明变质脉的形成与榴辉岩释放的内部流体有关。综合已有的研究,发现大别-苏鲁造山带不同地区的变质脉和榴辉岩具有极不均一的氧同位素组成,说明在陆壳深俯冲和折返过程中,流体活动有限。利用矿物温压计得到变质脉的峰期变质温压条件为692±65℃和3.6±0.3GPa,脉体中锆石U-Pb定年结果表明锆石的形成时代为218±2.4Ma,指示变质脉形成于深俯冲陆壳折返初期的超高压变质阶段。变质脉中矿物组合和矿物的主微量元素特征说明成脉流体富集Si、Al、Ca、K、LILE、REE和HFSE等元素,表明成脉流体可能是溶解能力极强的超临界流体。  相似文献   

5.
大别山地区榴辉岩全岩的3He/4 He值分布在0 .0 13×10 - 6 ~0 .76 0×10 - 6 之间,平均0 .2 0 0×10 - 6 ,榴辉岩中石榴子石单矿物的3He/4 He值与其全岩的3He/4 He值基本一致。在3He—4 He分布图上榴辉岩的氦同位素数据点远离地幔氦的分布范围,而位于大气氦与地壳氦的过渡部位。采用真空压碎方法对榴辉岩中石榴子石和绿辉石的氦同位素组成进行了分析,也未找到地幔氦的明显踪迹。结合大别—苏鲁地区榴辉岩中极低的δ1 8O值、εNd(0 )值等地球化学特征,提出大别—苏鲁地区超高压变质榴辉岩可能是在地壳中形成的,并未曾俯冲至10 0多千米的地幔深度。榴辉岩的3He/4 He值与围岩类型密切相关,榴辉岩的δ1 8O值与围岩的δ1 8O值同步变化,以及含柯石英大理岩、片麻岩和硬玉石英岩等非基性超高压变质岩和脉状榴辉岩的发现,均证明榴辉岩与其围岩一起经历了超高压变质过程,榴辉岩及其围岩在变质过程中未发生明显的位移,即榴辉岩是原地成因的。  相似文献   

6.
超高压榴辉岩退变质作用对岩石磁化率的影响   总被引:7,自引:2,他引:7  
系统测量了中国大陆科学钻探 (CCSD)主孔 10 0~ 2 0 0 0m超高压榴辉岩的磁化率及其各向异性 ,并进行了相应的岩石学和矿物学分析 .研究结果表明 ,不同退变质程度榴辉岩的磁化率特征具有明显差别 :新鲜 -弱退变质榴辉岩对应超高压榴辉岩相 ,平均体积磁化率κ =1.4× 10 -3 SI ,磁化率各向异性度Pj=1.0 9,磁性载体主要是顺磁性矿物石榴子石和绿辉石 ;中等 -强退变质榴辉岩对应角闪岩相 ,κ =5 .1× 10 -3 SI ,Pj=1.2 0 ,磁性载体主要是退变质所产生的磁铁矿和钛铁矿 -钛磁铁矿 ;完全退变质榴辉岩对应绿帘角闪岩相 -绿片岩相 ,κ =1.3× 10 -3 SI,Pj=1.0 8,磁性载体主要来自顺磁性矿物角闪石、绿帘石、黑云母等 .该研究为超高压变质岩石地区磁异常的解释提供了基础数据和重要的科学约束 ,同时也为大陆深俯冲峰期变质岩石和折返阶段岩石退变质程度提供了磁化率鉴别特征  相似文献   

7.
中国大陆科学钻探工程(CCSD)主孔位于苏鲁超高压变质带南部的东海县毛北村。本文主要研究深度分别为734.21m~737.16m(Ⅰ)和929.67m~932.86m(Ⅱ)两段榴辉岩与片麻岩互层的主孔岩芯,利用激光氟化法和Fourier变换红外光谱技术分别进行矿物的氧同位素组成和结构羟基含量分析。氧同位素分析表明,两段岩芯的榴辉岩中石榴石的δ^18O分别为 1.0‰~ 3.8‰和-4.1‰~-3、3‰,两段岩芯的片麻岩中石榴石的δ^18O均低达-4‰。表明片麻岩和榴辉岩的原岩均在经历超高压变质作用之前一同遭受过古大气降水的高温热液蚀变作用。在第1段岩芯的榴辉岩和片麻岩接触界线附近发现氧同位素交换前锋,指示板块折返过程中靠近片麻岩的榴辉岩与主要来自片麻岩的退变质流体发生流体-岩石交换,且其退变质程度主要受流体的迁移距离控制。红外光谱分析研究表明,所有石榴石都含有以OH形式存在的结构水,其含量的变化范围很大,为50~776ppm;绿辉石中OH含量范围为321~1636ppm;石英中含有以3596cm^-1为特征峰的结构水,但是含量很少。将剖面氧同位素和结构羟基含量的分析结果相结合,我们发现石榴石和绿辉石等矿物的氧同位素组成随着深度的变化与对应矿物的OH含量具有一定的相关性。这证明板块折返过程中的高压退变质作用及其伴生的局部流体活动可能是造成超高压变质矿物之间氧同位素不平衡的主要原因,并且氧同位素不平衡的程度主要受退变质作用发生时的局部水/岩比控制。因此,在深俯冲板块折返过程中,名义上无水矿物中结构水的出溶可以是退变质流体的重要来源。  相似文献   

8.
报道了大别山北部三个榴辉岩样品的矿物 Sm- Nd等时线年龄,它们分别为 (210± 6) Ma或 (214± 6) Ma、 (208± 38) Ma和 (208± 4) Ma。氧同位素研究表明,这些样品中的石榴子石与绿辉石之间处于氧同位素平衡状态,因此,该 Sm- Nd等时线定年结果可靠。本区榴辉岩的高压麻粒岩相退变质阶段的冷却年龄为 210 Ma左右;榴辉岩的钕同位素初始比ε Nd(t)(两个样品一个为- 10左右,另一个为- 2)基本上表现为陆壳岩石特征,可能类似于南部超高压带中的榴辉岩,为印支期扬子陆壳俯冲变质成因。它们的全岩δ 18O值较低,为+ 2.4‰~+ 3.6‰,可能指示其原岩同大别山南部超高压带中榴辉岩一样,在板块俯冲之前,经受过高温地表水热液蚀变。年代学结果表明,大别山北部榴辉岩在 230~ 210 Ma期间经历的是一等温或升温过程,这与大别山南部含柯石英榴辉岩在这一时期的快速冷却过程形成强烈对比,这对理解俯冲陆壳中不同构造岩片折返过程的差异有重要意义。  相似文献   

9.
松多榴辉岩出露于拉萨地块的石英片岩中,主要由较为基性的金红石榴辉岩和较为酸性的石英榴辉岩组成。榴辉岩相矿物组合为石榴子石 绿辉石 绿帘石±多硅白云母±石英±金红石。岩石发生了较强烈的退变质作用,退变质矿物有角闪石、绿帘石、石英、钠长石及绿泥石。石榴子石变斑晶具有生长环带结构,变斑晶和基质石榴子石主要落入C类榴辉岩区,少数石榴子石变斑晶边部和基质石榴子石落入B类榴辉岩区;单斜辉石主要为绿辉石,少数Ⅰ世代和Ⅲ世代为普通辉石;角闪石均为钙质角闪石。根据石榴子石-绿辉石-多硅白云母矿物温压计计算,获得的温压范围为630~777℃和2.58~2.70GPa,峰期变质条件接近于石英-柯石英转变线。榴辉岩的原岩经历了从高绿片岩相、角闪岩相、榴辉岩相、角闪岩相到高绿片岩相的变质过程,这反映了与古特提斯洋闭合有关的俯冲进变质作用和随后的折返退变质作用。  相似文献   

10.
闫伟豪  王勤  李伟强 《地质学报》2022,96(2):500-516
碳酸盐岩和碳酸盐化岩石是俯冲带中碳的主要地质载体。俯冲- 折返的超高压变质岩记录了俯冲隧道中流体- 岩石的相互作用与元素迁移,是研究地球内部元素循环的重要媒介。本文采集了大别造山带罗家岭互层状产出的大理岩和榴辉岩,建立了横跨岩性界面的矿物组成、显微结构和Mg- Fe- C- O同位素剖面。大理岩中主要组成矿物为白云石,其次为方解石、石英、黑云母和绿帘石等。靠近榴辉岩,大理岩中的方解石含量逐渐升高,在大理岩和榴辉岩界面中方解石是主要的碳酸盐矿物。榴辉岩经历了角闪岩相的退变质作用,主要组成矿物为石榴子石、角闪石、石英和云母,含少量方解石和白云石。罗家岭大理岩的δ26Mg(相比于DSM- 3标样)值为-1. 66‰~-1. 51‰。相对于玄武质原岩(δ26Mg=-0. 25‰),罗家岭榴辉岩具有轻Mg同位素组成(δ26Mg=-1. 48‰~-1. 25‰)。大理岩的δ56Fe(相比于IRMM- 14标样)值为-0. 62‰~-0. 56‰,榴辉岩具有较重的Fe同位素组成(δ56Fe=0. 16‰~0. 45‰)。大理岩和榴辉岩中的碳酸盐矿物具有显著的C- O同位素变化(δ13C=-3. 4‰~2. 2‰,δ18O=7. 6‰~14. 3‰),且δ13C与δ18O呈正相关关系。研究结果表明:大理岩和榴辉岩界面的机械混合作用使榴辉岩中含有孤立的碳酸盐矿物,并促进了大理岩和榴辉岩之间的反应,但是机械混合作用影响范围只有几厘米。俯冲带中的流体活动促进了大理岩中白云石分解和元素迁移,使榴辉岩获得大理岩的轻Mg同位素信号,甚至直接携带碳酸盐矿物进入地幔。从大理岩到榴辉岩Fe同位素的扩散迁移可以导致榴辉岩具有较重的Fe同位素组成,而大理岩具有较轻的Fe同位素组成。碳酸盐化榴辉岩是驱动地球深部碳循环和造成地幔Mg同位素不均一性的重要载体。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

13.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

14.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

15.
Well investigated platforms have been selected in each continent, and the history of Cretaceous transgressions and regressions there is concisely reviewed from the available evidence. The factual records have been summarized into a diagram and the timing of the events correlated between distant as well as adjoining areas.On a global scale, major transgressions were stepwise enlarged in space and time from the Neocomian, via Aptian-Albian, to the Late Cretaceous, and the post-Cretaceous regression was very remarkable. Minor cycles of transgression-regression were not always synchronous between different areas. Some of them were, however, nearly synchronous between the areas facing the same ocean.Tectono-eustasy may have been the main cause of the phenomena of transgression-regression, but certain kinds of other tectonic movements which affected even the so-called stable platforms were also responsible for the phenomena. The combined effects of various causes may have been unusual in the Cretaceous, since it was a period of global tectonic activity. The slowing down of this activity followed by readjustments may have been the cause of the global regression at the end of the Cretaceous.  相似文献   

16.
《地学前缘(英文版)》2014,(3):I0001-I0003
正1 AIM AND SCOPE GEOSCIENCE FRONTIERS(GSF) is a bi-monthly international journal that publishes in English high quality original research articles and timely reviews in interdisciplinary fields of Earth and Planetary Sciences.GSF aims to bridge innovative,provocative and challenging concepts and models related to various fields of research including petrology and geochemistry in understanding lithospheric architecture  相似文献   

17.
正1 Introduction In the present paper,MgCl2·6H2O,FeCl3·6H2O,and CeCl3·6H2O were used as raw materials in the precipitationhydrothermal method to synthesize MgF eC e hydrotalcite.The effects of the Fe:Ce molar ratio on the composition,crystal structure,and thermal stability of hydrotalcite are examined.Energy-dispersive X-ray spectroscopy(EDS),X-  相似文献   

18.
正20141430 Chen Ji(Key Laboratory of Petroleum Resources,Chinese Academy of Sciences,Lanzhou 730000,China);Shi Ji’an Sedimentary Facies and Models for the Palaeogene-Neogene Deposits on the Northern Margin of the Qaidam Basin,Qinghai Province(Sedimentary Geology and Tethyan Geology,ISSN1009-3850,CN51-1593/P,33(3),2013,p.16-26,14 illus.,16 refs.)  相似文献   

19.
SEISMIC GEOLOGY     
正20141967An Zhanghui(Lanzhou Base of Institute of Earthquake Prediction,CEA,Lanzhou 730000,China);Du Xuebin Study onthe Geo-Electric Field Variation of Sichuan Lushan MS7.0and Wenchuan MS8.0Earthquake(Chinese Journal of Geophysics,ISSN0001-5733,CN11-2074/P,56(11),  相似文献   

20.
GEOCHEMISTRY     
正20141357 Guo Tao(School of Mathematics and Science,Shijiazhuang University of Economics,Shijiazhuang 050031,China);Hu Jiawen Assessment on the New Pressure-Volume-Temperature(PVT) Data of Supercritical Water(Geological Journal of China Universities,ISSN1006-7493,CN32-1440/P,19(3),2013,p.447-455,9 illus.,3 tables,32 refs.)Key words:supercritical fluids  相似文献   

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