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1.
榍石LA-ICP-MS U-Pb定年技术研究 总被引：3，自引：0，他引：3
榍石具有较高的U含量和封闭温度,是一种重要的适用于U-Pb定年的副矿物。然而,基体效应与普通Pb校正成为制约榍石LA-ICP-MS U-Pb定年发展的主要因素。本文以~(206)Pb/~(238)U为例,采用基体归一化因子(F_(AVG))评估了锆石与榍石U-Pb定年标准的基体效应,结果显示榍石F_(AVG)几乎都大于1.20,而锆石F_(AVG)明显都小于1.20,表明锆石与榍石U-Pb定年标准存在显著的基体效应。以BLR-1榍石标准为外部校准标样,OLT1榍石获得的谐和年龄1014.9±4.8Ma(95%置信水平,n=23,MSWD=0.32)与SHRIMP谐和年龄1017.1±3.6Ma及ID-TIMS谐和年龄1014.6±1.3 Ma在误差范围内一致,同时获得~(206)Pb/~(238)U、~(207) Pb/~(235) U、~(207) Pb/~(206) Pb加权平均年龄在误差范围内与其谐和年龄一致;而以91500锆石为外部校准标样,OLT1榍石获得的~(206)Pb/~(238)U加权平均年龄为891.3±9.5 Ma(n=23,MSWD=5.3),与ID-TIMS测得的谐和年龄相比偏低约12%。经~(207)Pb法校正后,TCB榍石获得的~(206)Pb/~(238) U加权平均年龄1015.6±6.2 Ma(n=16,MSWD=0.84)与ID-TIMS谐和年龄1018.1±1.7Ma在误差范围内一致。本研究表明,采用基体匹配的榍石标准为外部标样,利用LA-ICP-MS对榍石进行U-Pb定年也能获得与ID-TIMS相一致的年龄,精度(2RSE)小于2%。 相似文献
2.
为探讨滇东南瑶山群的原岩年龄以及后期经历的岩浆-变质-构造事件年龄,开展了SHRIMP锆石U-Pb定年研究。结果表明,阴极发光(CL)分析和光学显微分析显示瑶山群的锆石组成比较复杂,可以分为继承锆石、变质锆石、深熔锆石/岩浆锆石等几大类。除少量测点207Pb/206Pb年龄为新元古代外,继承锆石206Pb/238 U表面年龄变化范围集中在235±1.7Ma~261±3.6Ma,加权平均值为250.8±9.8Ma(N=4,MSWD=4.1);深熔/岩浆锆石206Pb/238 U表面年龄显示出~85Ma和~75Ma两个峰值;变质增生锆石206Pb/238 U表面年龄为49~30Ma,且主要集中在32Ma、37Ma和42Ma左右。结合区域地质情况,初步推测:250.8±9.8Ma的继承锆石峰值年龄表明,瑶山群主体的原岩时代可能不早于二叠纪;变质锆石、深熔锆石/岩浆锆石的206Pb/238 U表面年龄可分为~85Ma、~75Ma、~42Ma、~37Ma和~32Ma等5组,可能代表了红河断裂南段自燕山晚期以来5期较强烈构造-岩浆-变质事件的时限。 相似文献
3.
利用长安大学成矿作用及其动力学实验室Agilent 7700X四极杆等离子体质谱(ICP-MS)和Photo Machines Analyte Excite 193nm激光,在激光频率为5Hz,束斑直径为35μm条件下,对91500、GJ-1、Ple?ovice和Qinghu 4个标准锆石进行了原位微区U-Pb同位素和微量元素测定。结果显示,91500标准锆石20个测试点的~(206)Pb/~(238)U年龄范围为1059~1070Ma,~(206)Pb/~(238)U年龄加权平均值为1063.8±6.6Ma;GJ-1标准锆石28个测试点的~(206)Pb/~(238)U年龄范围为601~610Ma,~(206)Pb/~(238)U年龄加权平均值为605.4±3.0Ma;Ple?ovice标准锆石28个测试点的~(206)Pb/~(238)U年龄范围为336~341Ma,~(206)Pb/~(238)U年龄加权平均值为338.8±1.4Ma;Qinghu标准锆石40个测试点的~(206)Pb/~(238)U年龄范围为158~165Ma,~(206)Pb/~(238)U年龄加权平均值为159.9±0.7Ma。上述结果表明,91500、GJ-1、Ple?ovice和Qinghu 4个标准锆石的~(206)Pb/~(238)U年龄都在误差范围内,且年龄加权平均值与前人报道的年龄在误差范围内一致。同时,4个标准锆石的微量元素结果基本落在前人文献报道的范围内。从4个标准锆石的稀土元素球粒陨石标准化曲线可以看出,稀土元素的相对含量较准确。以上结果表明,建立的测试方法实现了对锆石原位微区U-Pb定年及微量元素的同时测定,分析数据结果准确、可靠。 相似文献
4.
在内蒙古大青山地区逆冲推覆构造所截切的英安岩中获得锆石~(207)Pb/~(206)Pb表面年龄加权平均值为1870±19Ma,认为英安岩为华北克拉通古元古代末—新元古代一次裂解事件的产物.同时,据安山岩锆石U-Pb年龄谐和度(102)较好的锆石~(206)Pb/~(238)U表面年龄436±4Ma及英安岩锆石U-Pb年龄谐和度(104)较好的锆石~(206)Pb/~(238)U表面年龄153±2Ma和160±2Ma,表明大青山地区逆冲推覆构造存在构造复活或构造追踪现象。这一认识为大青山地区逆冲推覆构造的研究积累了新的资料,提供了新的研究思路。 相似文献
5.
广西苍梧县宝山矿床位于大瑶山隆起区的东南部,是一个与石英斑岩有关的铜多金属矿床。本文对该矿区内花岗闪长岩、细粒花岗岩和石英斑岩进行了单颗粒锆石LA-ICP-MS U-Pb测年,获得了3件花岗闪长岩的~(206)Pb/~(238)U加权平均年龄分别为433.7±1.2 Ma、435.0±1.2 Ma和449.7±2.3 Ma;1件细粒花岗岩的~(206)Pb/~(238)U加权平均年龄为100.4±0.5 Ma,2件石英斑岩样品的~(206)Pb/~(238)U加权平均年龄分别为95.4±0.7 Ma和92.5±0.5 Ma。本文认为,宝山矿区存在晚奥陶世、早志留世、早白垩世晚期和晚白垩世早期等多期岩浆活动,与成矿有关的石英斑岩锆石U-Pb年龄揭示宝山铜铅锌多金属矿床形成于晚白垩世早期。这些高精度花岗岩锆石U-Pb测年数据为进一步深入研究大瑶山地区的岩浆活动及其成矿作用提供了重要的年代学依据。 相似文献
6.
都龙锡锌矿床锡石和锆石U-Pb年代学：滇东南白垩纪大规模花岗岩成岩-成矿事件 总被引：22，自引：13，他引：22
都龙锡锌矿床是我国最大的锡石硫化物矿床之一。由于缺少可靠的年代学数据,对该矿床的成因尚存在较大争议。本文报道了利用锡石和锆石U-Pb法,首次获得的都龙锡锌矿床及相关的燕山晚期老君山花岗岩的年龄。其中,锡石TIMS法~(206)Pb/~(238)U年龄加权平均值为79.8±3.2Ma(MSWD=3.16),(238)U/~(204)Pb-~(206)Pb/~(204)Pb等时线年龄为82.0±9.6Ma (MSWD=4.81);隐伏花岗岩的锆石SHRIMP法~(206)Pb/~(238)U年龄加权平均值为92.9±1.9Ma(N=10,MSWD=0.71),花岗斑岩的锆石SHRIMP法~(206)Pb/~(238)U年龄加权平均值为86.9±1.4Ma(N=9,MSWD=3.70),表明锡(铜)矿化主要与晚白垩世岩浆热液活动有关。结合个旧、白牛厂两个超大型矿床和相关花岗岩体的年代学资料,指示滇东南地区于白垩纪存在以锡矿化为特色的大规模花岗岩成岩-成矿事件,可能与晚中生代以来华南地块岩石圈伸展有关。 相似文献
7.
东昆仑造山带早中生代幔源岩浆事件及其地质意义 总被引：5，自引：0，他引：5
东昆仑造山带早中生代幔源岩浆底侵不仅为花岗岩类的广泛发育提供了能量和物质基础,也为厘定区域构造环境提供了新的约束。本文对区域上发育的小尖山岩体、拉陵高里沟脑2、3号岩体开展了精确的锆石U-Pb年代学研究,并与区域上镁铁质岩体做了对比。LA-ICP-MS U-Pb定年结果表明,小尖山岩体磁黄铁矿化辉长岩锆石~(206)Pb/~(238)U-~(207)Pb/~(235)U谐和年龄为247.1±1.1Ma,与前人获得的中细粒辉长岩年龄相差20Ma,暗示该岩体为多期岩浆活动的产物。拉陵高里沟脑2号和3号岩体辉长岩锆石~(206)Pb/~(238)U-~(207)Pb/~(235)U谐和年龄分别为(244.9±1.6)Ma和(238.4±4.1)Ma,二者年龄在测试误差范围内一致,为同期岩浆作用的产物。结合区域上已知镁铁质岩体的形成时代及地球化学特征,认为早中生代幔源岩浆形成于后碰撞伸展环境,活动时限为251~221Ma。该期幔源岩浆与地壳物质发生了广泛的物质与能量交换,是今后该区铜镍矿勘查的重要对象之一。 相似文献
8.
为了精确厘定莲花山铜矿的成矿时代,在前人研究的基础上,开展了与成矿关系密切的花岗闪长斑岩锆石U-Pb定年测定。实验结果共获得4组年龄数据,第1组有1个锆石,206Pb/238U年龄为343Ma±2Ma;第2组1个锆石,206Pb/238U年龄为264Ma±2Ma;第3组有1个锆石,206Pb/238U年龄为256Ma±2Ma;第4组有17个锆石,206Pb/238U年龄在240~249Ma之间,206Pb/238U年龄加权平均值为246.4Ma±1.2Ma(N=17)。结合所测锆石的CL图像特征,确定花岗闪长斑岩就位发生在晚二叠世—早三叠世。 相似文献
9.
《西北地质》2015,(4)
阿尔泰山东部诺尔特—阿尔沙特地区晚古生代火山岩十分发育,其中阿尔沙特一带出露一套片理化蚀变流纹岩与含凝灰质英安流纹岩的岩石组合,呈北西—南东向带状展布,前人将其划为石炭系红山嘴组a段,其岩性组合明显区别于红山嘴组b、c段地层,且稳定成规模出露。本次工作笔者对其进行了LA-ICPMS锆石U-Pb测年,获得锆石的~(206)Pb/~(238)U和~(207)Pb/~(235)U谐和年龄为(400.5±4.6)Ma,~(206)Pb/~(238)U年龄加权平均值为(400.4±3.6)Ma,代表岩浆结晶年龄,时代为早泥盆世,较前人认为的石炭纪早。结合区域地质资料分析认为,(400.4±3.6)Ma区内古大洋俯冲已达到顶峰阶段,该火山岩形成于活动大陆边缘构造环境。 相似文献
10.
滇西腾冲地块片麻状花岗岩的锆石U-Pb年龄 总被引：7，自引：1，他引：6
报道了滇西腾冲地块片麻状花岗岩的锆石U-Pb年龄。区域地质和岩相特征表明,片麻状花岗岩为岩浆成因,并经历了后期深熔作用。24颗锆石测得24个年龄数据中,1颗继承锆石的206Pb/238U年龄为537.5±5.6Ma,2颗岩浆锆石的206Pb/238U平均年龄为456Ma,3颗深熔锆石的206Pb/238U平均年龄为117Ma,18颗深熔锆石的Robust (Median) 206Pb/238U年龄为66.2+7/-4Ma。上述结果表明,花岗岩形成于早古生代,而后在白垩纪发生深熔作用,可能是特提斯演化过程中的岩浆响应。 相似文献
11.
This paper evaluates the analytical precision, accuracy and long‐term reliability of the U‐Pb age data obtained using inductively coupled plasma–mass spectrometry (ICP‐MS) with a frequency quintupled Nd‐YAG (λ = 213nm) laser ablation system. The U‐Pb age data for seven standard zircons of various ages, from 28 Ma to 2400 Ma (FCT, SL13, 91500, AS3, FC1, QGNG and PMA7) were obtained with an ablation pit size of 30 μm diameter. For 207Pb/206Pb ratio measurement, the mean isotopic ratio obtained on National Institute of Standards and Technology (NIST) SRM610 over 4 months was 0.9105 ± 0.0014 (n = 280, 95% confidence), which agrees well with the published value of 0.9096. The time‐profile of Pb/U ratios during single spot ablation showed no significant difference in shape from NIST SRM610 and 91500 zircon standards. These results encouraged the use of the glass standard as a calibration standard for the Pb/U ratio determination for zircons with shorter wavelength (λ = 213 nm) laser ablation. But 206Pb/238U and 207Pb/235U ages obtained by this method for seven zircon standards are systematically younger than the published U‐Pb ages obtained by both isotope dilution–thermal ionization mass spectrometry (ID‐TIMS) and sensitive high‐resolution ion‐microprobe (SHRIMP). Greater discrepancies (3–4% younger ages) were found for the 206Pb/238U ages for SL13, AS3 and 91500 zircons. The origin of the differences could be heterogeneity in Pb/U ratio on SRM610 between the different disks, but a matrix effect accuracy either in the ICP ion source or in the ablation‐transport processes of the sample aerosols cannot be neglected. When the 206Pb/238U (= 0.2302) newly defined in the present study is used, the measured 206Pb/238U and 207Pb/235U ages for the seven zircon standards are in good agreement with those from ID‐TIMS and SHRIMP within ±2%. This suggests that SRM610 glass standard is suitable for ICP‐MS with laser ablation sampling (LA‐ICP‐MS) zircon analysis, but it is necessary to determine the correction factor for 206Pb/238U by measuring several zircon standards in individual laboratories. 相似文献
12.
Shuhei Sakata Kentaro Hattori Hideki Iwano Takaomi D. Yokoyama Tohru Danhara Takafumi Hirata 《Geostandards and Geoanalytical Research》2014,38(4):409-420
We have developed new analytical procedures to measure precise and accurate 238U–206Pb and 235U–207Pb ages for young (~ 1 Ma) zircons using laser ablation‐ICP‐mass spectrometry. For young zircons, both careful correction for the background counts and analysis of very small Pb/U ratios (i.e., 206Pb/238U < 0.00016 and 207Pb/235U < 0.0001 for 1 Ma zircons) are highly desired. For the correction of the background, the contribution of the background signal intensities for the analytes, especially for the residual signal intensities for 206Pb and 207Pb, was defined through laser ablation of synthesised zircons (ablation blank) containing negligible Pb. The measured signal intensities for 202Hg, 206Pb and 207Pb signals obtained by the ablation blank were slightly higher than those obtained by data acquisition without laser ablation (gas blank). For the wider dynamic range measurements on Pb/U ratios, an attenuator device for the ion detection system was employed to extend the capability to monitor high‐intensity signals (i.e., > 3 Mcps). Through the attenuator device, the ion currents were reduced to 1/450 of the signal intensity without the attenuator. Because the switching time for the attenuator was shorter than 1 ms, signal intensities for only specific isotopes could be reduced. With attenuation of the 238U signal, counting statistics on 206Pb and 207Pb isotopes could be improved and counting loss on the 238U signal could be minimised. To demonstrate the reliability of this new analytical technique, 238U–206Pb and 235U–207Pb ages for three young zircon samples (collected from Osaka Group Pink Volcanic Ash, Kirigamine and Bishop Tuff) were measured. The data presented here demonstrate clearly that the present technique could become a major analytical tool for in situ U–Pb age determination of young zircons (~ 1 Ma). 相似文献
13.
内蒙古道伦达坝铜钨锡矿床LA-ICP-MS锆石和锡石U-Pb年龄及其地质意义 总被引：6，自引：1，他引：5
道伦达坝矿床位于大兴安岭南段,是一个铜钨锡矿床,其铜、钨、锡储量均达中型。矿体呈脉状,主要产于二叠系砂板岩中的断裂破碎带中,华力西期黑云母花岗岩中的断裂破碎带中亦赋存有矿体。文章选取2件石英-萤石-白云母-电气石-锡石-黑钨矿阶段的矿石样品对其中的进行了LA-ICP-MS U-Pb定年,获得2件样品的~(207)Pb/~(206)Pb-~(238)U/~(206)Pb谐和年龄分别为(134.7±6.6)Ma(MSWD=1.4)和(136.8±7.4)Ma(MSWD=1.7),~(206)Pb/~(207)Pb-~(238)U/~(207)Pb等时线年龄分别为(132±12)Ma(MSWD=0.76)和(135±13)Ma(MSWD=0.9)。锡石定年结果表明,道伦达坝矿床形成于早白垩世。对矿区外围张家营子岩体中的斑状细粒花岗岩进行了LA-ICP-MS锆石U-Pb测年,获得的~(206)Pb/~(238)U加权平均年龄为(135±1)Ma(MSWD=1.3),该岩体的形成年龄与道伦达坝矿床的成矿年龄在误差范围内一致。本次定年结果表明道伦达坝矿床形成于早白垩世,与同期的花岗质岩浆活动有密切的成因联系,该矿床属于与花岗岩有关的岩浆热液脉型矿床。 相似文献
14.
We present the results of a comparative study of several geochronometer minerals (baddeleyite, zircon, apatite, phlogopite and tetraferriphlogopite) and isotopic systems (U-Pb, Th-Pb and Rb-Sr) from phoscorites (magnetite-forsterite-apatite-calcite rocks) and carbonatites of the Kovdor ultramafic-alkaline-carbonatite massif, Kola Peninsula, Russia. Uranium, thorium and their decay products are extremely fractionated by minerals that crystallise from carbonatite and phoscorite magma. We obtain high-precision ages from different chronometers, compare their accuracy, and evaluate the role of geochronological pitfalls of initial radioactive disequilibrium, differential migration of radiogenic isotopes, and inaccurate decay constants.Apatite yielded concordant U-Th-Pb ages between 376 and 380 Ma. The accuracy of the apatite 238U-206Pb ages is, however, compromised by uncertainty in the amount of radiogenic 206Pb produced from initial excess 230Th. The 235U-207Pb ages are relatively imprecise due to large common Pb correction and the uncertainty in the initial Pb isotopic composition. The Th-Pb system yields a more precise age of 376.4 ± 0.6 Ma.Zircon from two carbonatite samples is characterised by moderate to low U contents, high Th contents, and very high Th/U ratios up to 9000. The 206Pb*/238U systems in the zircon are strongly affected by the presence of excess 206Pb*, produced by decay of initial 230Th. The 208Pb*/232Th ages of zircon from both carbonatite samples are uniform and yield a weighted average of 377.52 ± 0.94 Ma.Baddeleyite U-Pb analyses are 3 to 6% normally discordant and have variable 207Pb*/206Pb* apparent ages. Eleven alteration-free baddeleyite fractions from three samples with no evidence for Pb loss yield uniform 206Pb*/238U ages with a weighted average of 378.54±0.23 Ma (378.64 Ma after correction for initial 230Th deficiency), which we consider the best estimate for age of the phoscorite-carbonatite body of the Kovdor massif. The 206Pb*/238U ages of baddeleyite fractions from five other samples spread between 378.5 and 373 Ma, indicating a variable lead loss up to 1.5%. The anomalously old 207Pb/235U and 207Pb/206Pb ages are consistent with the presence of excess radiogenic 207Pb* in the baddeleyite. We interpret this as a result of preferential partitioning of 231Pa to baddeleyite.Fifteen phlogopite and tetraferriphlogopite fractions from five carbonatite and phoscorite samples yielded precise Rb-Sr isochron age of 372.2 ± 1.5 Ma, which is 5 to 7 m.y. younger than our best estimate based on U-Th-Pb age values. This difference is unlikely to be a result of the disturbance or late closure of Rb-Sr system in phlogopite, but rather suggests that the accepted decay constant of 87Rb is too high.Comparative study of multiple geochronometer minerals from the Kovdor massif has revealed an exceptional complexity of isotopic systems. Reliable ages can be understood through systematic analysis of possible sources of distortion. No single geochronometer is sufficiently reliable in these rocks. Th-Pb and Rb-Sr can be a very useful supplement to U-Pb geochronometry, but the routine use of these geochronometers together will require more precise and accurate determination of decay constants for 232Th and 87Rb. 相似文献
15.
T.-L. Knudsen T. Andersen M. J. Whitehouse J. Vestin 《Contributions to Mineralogy and Petrology》1997,130(1):47-58
An ion-microprobe (SIMS) U-Pb zircon dating study on four samples of Precambrian metasediments from the high-grade Bamble
Sector, southern Norway, gives the first information on the timing of discrete crust-forming events in the SW part of the
Baltic Shield. Recent Nd and Pb studies have indicated that the sources of the clastic metasediments in this area have crustal
histories extending back to 1.7 to 2.1 Ga, although there is no record of rocks older than 1.6 Ga in southern Norway. The
analysed metasediments are from a sequence of intercalated, centimetre to 10-metre wide units of quartzites, semi-metapelites,
metapelites and mafic granulites. The zircons can be grouped in two morphological populations: (1) long prismatic; (2) rounded,
often flattened. The BSE images reveal that both populations consist of oscillatory zoned, rounded and corroded cores (detrital
grains of magmatic origin), surrounded by homogeneous rims (metamorphic overgrowths). The detrital zircons have 207Pb/206Pb ages between 1367 and 1939 Ma, with frequency maxima in the range 1.85 to 1.70 Ga and 1.60 to 1.50 Ga. There is no correlation
between crystal habit and age of the zircon. One resorbed, inner zircon core in a detrital grain is strongly discordant and
gives a composite inner core-magmatic outer core 207Pb/206Pb age of 2383 Ma. Two discrete, unzoned zircons have 207Pb/206Pb ages of 1122 and 1133 Ma, representing zircon growth during the Sveconorwegian high-grade metamorphism. Also the μm wide
overgrowths, embayments in the detrital cores and apparent “inner cores” which represent secondary metamorphic zircon growth
in deep embayments in detrital grains, are of Sveconorwegian age. The composite-detrital-metamorphic zircon analyses give
generally discordant 206Pb/238U versus 207Pb/235U ratios and maximum 207Pb/206Pb ages of 1438 Ma. These data demonstrate the existence of a protocrust of 1.7 to 2.0 Ga in the southwestern part of the
Baltic Shield, implying a break in the overall westward younging trend of the Precambrian crust, inferred from the southeastern
part of the Baltic Shield.
Received: 8 April 1997 / Accepted: 14 July 1997 相似文献
16.
Accuracy of Laser Ablation U-Pb Zircon Dating: Results from a Test Using Five Different Reference Zircons 总被引：2，自引：0，他引：2
Urs Klötzli Eva Klötzli Zekeriya Günes Jan Kosler 《Geostandards and Geoanalytical Research》2009,33(1):5-15
Using a state‐of‐the‐art 193 nm‐LA‐MC‐ICP‐MS system and with careful control of analytical procedures, the long term external reproducibility and accuracy of the ages Phanerozoic zircons measured over a period of months using calibrator bracketing for the 206Pb/238U and 207Pb/206Pb ages were ca. 1% (2 RSD) if a single reference zircon was used for the matrix‐matched calibration. When different reference zircons were used for the calibration, suspicious systematic shifts in the obtained ages were observed and thus a reduction in the overall accuracy of the dating method became obvious. Such shifts were within a few percent range of the U‐Pb and Pb/Pb ages and seemed to vary independently of zircon age and composition. A “test of accuracy” experiment was conducted reducing instrumental effects as far as possible by analysing five different reference zircons mounted on a single mount eight times during the same session. An identical protocol was used for all analyses, with unchanged instrument parameters and with ion beam intensities kept as identical as possible. For data reduction, every zircon served consecutively as the reference zircon for calibration, with the others in the batch treated as unknowns. The known reference age and the four calculated ages obtained using the four other RMs for calibration were then compared. Even using such a strict analytical protocol, shifts in 206Pb/238U, 207Pb/235U and 207Pb/206Pb ratios were still present. They varied non‐systematically and ranged from ?4.35% to 3.08% for the investigated age range (1065 Ma to 226 Ma). Assuming the absence of instrumental effects (i.e., memory, dead‐time correction, non‐linearity of ion counters and interdetector calibration, crystallographic orientation, ablation cell geometry and setup, gas flows), the observed shifts were attributed to matrix and/or ablation related effects. It is proposed that non‐spectral matrix effects in the Ar plasma torch resulted in non‐uniform signal enhancement (or depression?) leading to shifts both in elemental and Pb isotopic ratios. Additionally, the ablated particle size distribution could be an important factor controlling plasma conditions and thus mass bias and fractionation. Until such effects are well understood and controlled, it would seem that any LA‐ICP‐MS zircon U‐Pb and 207Pb/206Pb age determination cannot be meaningfully interpreted at below a ca. 3% to 4% (2 RSD) confidence level. 相似文献
17.
Lutz Nasdala Wolfgang Hofmeister Nicholas Norberg James M. Martinson Fernando Corfu Wolfgang Dörr Sandra L. Kamo Allen K. Kennedy Andreas Kronz Peter W. Reiners Dirk Frei Jan Kosler Yusheng Wan Jens Götze Tobias Häger Alfred Kröner John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265
We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 1018 g?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn. 相似文献
18.
Yu. L. Ronkin M. E. Pritchin E. I. Soroka A. Gerdes V. N. Puchkov S. V. Busharina 《Doklady Earth Sciences》2016,469(1):665-669
New results of U–Pb LA ICP–MS dating of zircon from andesite samples cropping out on the western wall of the Saf’yanovka quarry (57°22′58.88″ N, 61°31′50.85″ E) in the synonymous Cu–Zn-bearing massive sulfide deposit of the Urals type are considered. The position of data points of the U–Pb systematics in the 207Pb/235U–206Pb/238U plot determines a cluster practically corresponding to the concordant U–Pb age: 422.8 ± 2.0 Ma. This date indicates for the first time the presence of Pridolian volcanogenic rocks in the East Urals megazone of the Middle Urals. 相似文献
19.
V. N. Golubev I. V. Chernyshev A. V. Chugaev A. V. Eremina A. N. Baranova V. V. Krupskaya 《Geology of Ore Deposits》2013,55(6):399-410
The isotopic (U-Pb, 238U-235U, 234U-238U) and chemical study of whole-rock samples and finegrained fractions of rocks in a vertical section of the terrigenous sequence at the Dybryn uranium deposit in the Khiagda ore field shows that a wide U-Pb isotopic age range (26.9-6.5 Ma) is caused by oxidation and disturbance of the U-Pb isotopic system in combination with protracted uranium ore deposition. The oxidation of rocks resulted in the loss of uranium relative to lead and eventually to an overestimated 206Pb/238U age at sites with a low U content. The 238U/235U ratios in the studied samples are within the range of 137.74–137.88. Samples with a high uranium content are characterized by a decreasing 238U/235U ratio with a decrease in 207Pb/235U and 206Pb/238U ages. A nonequilibrium 234U/238U ratio in most studied samples furnishes evidence for young (<1.5 Ma) transformation of the Miocene uranium ore, which is responsible for uranium migration and its redeposition. 相似文献