共查询到19条相似文献，搜索用时 78 毫秒
1.
闽西晚中生代基性岩脉的地球化学研究 总被引：20，自引：3，他引：17
对闽西三个地区基性岩脉的地球化学研究发现,该区域的基性岩脉为亚碱性岩石系列,具有高 Al、低 Ti、Na2O > K2O的特征;相对富集大离子亲石元素,亏损高强场元素.半村辉绿岩脉和拔里角闪辉长岩脉以 Nb、Ta、Ti负异常为特征,林子坟辉长辉绿岩脉具有 Nb、Ta负异常和 Ti弱正异常.半村和拔里的岩脉稀土元素总量高,明显富集轻稀土元素,(La/Yb)N=6.8～8.4;林子坟的岩脉稀土元素总量相对较低,轻稀土元素弱富集,(La/Yb)N=2.0.结合基性岩脉的地球化学特征和区域构造演化分析,初步认为半村和拔里的基性岩脉来自与俯冲作用有关的富大离子亲石元素流体交代的富集地幔;林子坟基性岩脉是软流圈地幔部分熔融的产物,地壳混染作用是其相对富集大离子亲石元素的原因.结合玄武岩构造环境判别图解可知,半村和拔里岩脉具有的大陆边缘弧的特征并不指示基性岩脉形成的构造环境,而是说明其源区受到俯冲板片派生出来的流体交代作用.半村和拔里岩脉形成于大陆板内拉张带,林子坟岩脉形成于板内裂谷环境.与华南其他地区的基性岩脉对比表明,虽然晚中生代华南地区处于拉张的构造背景下,但是岩脉形成的构造环境与微量元素地球化学特征均有明显的差异,反映了各地区构造环境演变和地幔演化的复杂性. 相似文献
2.
山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义 总被引：10，自引：0，他引：10
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。 相似文献
3.
五台山变质杂岩中的新太古代变质基性岩主要由变质辉长岩、绿泥石片岩及角闪岩组成。根据稀土配分模式可以把它们分为三组:第一组具有平坦的稀土配分型式,稀土总量比较低(29×10-6~52×10-6),显示弱的Eu负异常及无异常(EuN/EuN=0.84~1.02),轻稀土略有亏损到弱富集(LaN/YbN=0.86~1.3),原始地幔标准化图解上具有平坦的分布模式和明显的Zr负异常,稀土和微量元素特征类似于大洋高原拉斑玄武岩,代表了地幔柱形成的高原玄武岩的残余。第二组稀土总量明显高于第一组(34×10-6~116×10-6),具有轻稀土富集的配分型式(LaN/YbN=1.76~4.34),弱的Eu… 相似文献
4.
湘东北中生代基性岩脉岩石地球化学及构造意义 总被引：8，自引：1，他引：8
湘东北中生代发育以辉绿岩类和煌斑岩类为代表的基性岩脉,属陆内拉斑玄武岩系,部分煌斑岩属于碱性系列。岩石富集LREE,δEu负异常不明显,其形成主要受软流圈地幔部分熔融作用制约。煌斑岩类微量元素总体上具有洋岛玄武岩(OIB)岩浆源区特征,富集Nd、P、Cs而K、Rb、Sr、U、Th等富集程度不明显,Ta、Nb略有富集。辉绿岩类表现出Ta、Nb、Ti亏损,但LILE并不富集,反映地壳混染程度的增强。基性岩脉形成于陆内拉张带的构造环境,岩浆活动未受到中生代大洋板块俯冲的影响。基性岩脉在时、空及物质组成上与湘东南玄武质岩石基本一致,属于整个湘东南岩石圈拉张-减薄带的一部分。 相似文献
5.
通过对分布于勉略构造带中段三岔子西侧中堂沟地区的火山岩进行详实的野外地质剖面调查,发现其为一套绿片岩相浅变质火山岩,岩石组合以变安山岩为主,含有少量的变玄武岩和变英安岩,主体为钙碱性系列。岩石地球化学研究表明3类岩石均具有轻稀土富集型稀土配分曲线,并显示弱的Eu负异常;微量元素方面,岩石普遍富集大离子亲石元素Cs、Rb、Ba,亏损高场强元素Nb、Ta,相对亏损P、Ti,不活动微量元素Zr、Hf、Tb、Y等既无明显的相对亏损也无显著的相对富集。在La-La/Nb、Nb-Nb/Th和La/Yb-Sc/Ni等环境判别图解中,变玄武岩和变安山岩样品点均落在岛弧火山岩范围内,并结合其岩石组合特征指示该套火山岩应形成于大陆边缘弧(活动陆缘)环境。其中变玄武岩和变安山岩岩浆起源于楔形地幔的部分熔融,且有陆壳物质的参与;变英安岩的形成则与壳源物质的部分熔融有关。 相似文献
6.
新疆阿尔泰山南缘玛音鄂博断裂南侧变质基性岩的发现及其地质意义 总被引：4，自引：0，他引：4
位于额尔齐斯-玛音鄂博大断裂带南侧的阿热勒托别变质基性岩产于下石炭统姜巴斯套组一套细碎屑沉积岩中.岩石组成以变质玄武岩为主, 它们具有相对高的TiO2、MgO和低SiO2、K2O的特点; 在稀土元素组成上, 显示轻稀土弱富集的配分模式, 无明显Eu异常; 微量元素组成显示大离子亲石元素富集, 并具有明显的正Th异常和弱的Nb负异常、高的Nb含量(> 2×10-6) 以及HFSE基本上和MORB相当的特点; 其Zr/Nb比值落在MORB范围之内, 而Ti/V比值略比MORB高, 表明其为MORB源的亏损地幔在相对较低熔融程度下熔融的产物.其εNd(t) 值为+7.40~+8.35, 略低于MORB, 但高于洋岛以及大陆板内玄武岩.因此该变质基性岩总体上兼有火山弧和洋中脊玄武岩特征, 因而其可能形成于弧后环境, 代表了弧后盆地扩张早期的产物. 相似文献
7.
笔者在云南富宁地区厘定出一套较大面积展布的火山岩，为讨论该火山岩岩石地球化学特征及其构造意义，对该火山岩进行了地质学、岩石学、地球化学分析。结果表明：（1） 该套火山岩是研究区全新发现，结合其地质学特征及邻近地区测年数据，认为其时代可能为晚二叠世；（2）该火山岩主要由灰色致密状玄武岩、灰色（球颗）玄武岩、灰色气孔状玄武岩等基性岩石构成，多具有间粒结构，致密块状构造、气孔状构造，主要由斜长石、辉石组成，局部可见微弱热液蚀变发育；（3）该火山岩属亚碱性系列，SiO2含量处于46.08%~51.80%之间，全碱alk=2.94~5.21，K2O/Na2O=0.03~1.03，钠质多，为基性中-高钾钙碱性玄武岩；（4）该火山岩呈现轻稀土富集、重稀土亏损的弱分异右倾式稀土元素配分特征，δEu=1.02~1.10，呈现Eu正异常，δCe=0.93~0.96，表现Ce负异常。（Rb/Yb）N=1.6~11.4，强不相容元素富集；（Ce/Yb）N=2.03~7.59，（La/Lu）N=2.4~9.93，稀土元素分异明显；微量元素表现为Sr、Ti、Zr、Nb亏损，而P、Th富集特征。Nb/Ta介于11.8~18.5，显示出岩浆源遭受过来自消减板块的影响；（5）火山岩构造判别图显示该火山岩既具有大陆板内环境特征，又具有大洋板内构造背景，是一种叠加的构造环境，这可能是因为该地区大洋演化过程中同时受到了峨眉山玄武岩影响造成的。 相似文献
8.
北祁连乌鞘岭一带出露一套以玄武质岩石为主的双峰式火山岩组合,火山岩岩石类型以变质玄武岩为主,夹少量的流纹岩。玄武质岩石为蚀变玄武岩,属拉斑玄武岩系列,低SiO2、K2O,高Ti,富Na、Th、U等,轻稀土元素亏损—略富集型,无明显Eu异常,微量元素具Nb、Ta负异常。流纹质岩石属钙碱性系列,高SiO2,低K2O,为钠质系列,大离子亲石元素富集,具明显的Nb、P、Ti、Sr负异常和Th、U正异常,轻稀土元素富集,(La/Yb)N为2.98~11.46,Eu负异常明显,δEu介于0.07~0.60之间。结合区域资料分析,乌鞘岭双峰式火山岩可能形成于弧后盆地环境。 相似文献
9.
湘东北中生代基性岩脉岩石地球化学特征 总被引：3，自引：0，他引：3
湘东北基性岩脉以 K2 O/ Na2 O<1,K2 O+Na2 O在 3.0 3～ 5 .5 7之间为特征 ,属陆内拉斑玄武岩系列 ,部分煌斑岩属于碱性系列。岩石富 L REE,δEu负异常不明显 ,其形成主要受软流圈地幔部分熔融作用制约。岩石微量元素总体上具有富集地幔 (EMII型 )洋岛玄武岩 (OIB)特征 ,富集 Nd,P,Cs,而 K,Rb,Sr,U,Th等富集程度不明显 ,Ta,Nb略有富集。湘东北的北部地区基性岩脉虽表现出 Ta,Nb,Ti亏损 ,但 L IL E并不富集 ,可能反映地壳混染程度的增强 ,基性岩脉的特质组成与湘东南玄武岩类岩石基本一致。推测两者应具有同一个地幔源区。依据侵入关系和区域对比 ,认为湘东北基性岩脉的形成是早白垩世以后晚燕山期岩石圈拉张 -减薄作用产物 ,湘东北基性岩脉所处的构造环境应属于整个湘东南岩石圈伸展 -减薄带的一部分。 相似文献
10.
龙脖河铜矿床位于滇中地区红河成矿带南段,矿区火山岩发育、与铜矿化时空密切共生。区内火山岩遭受了不同程度的蚀变或区域变质作用,根据矿物组合可分为变安山岩、变次火山岩和变基性火山岩。三类变火山岩均相对富Na,在地球化学分类图解上样品主要位于碱性玄武岩区域。除个别微量元素外,三类岩石的微量元素含量相近,与各种构造环境玄武岩相比,本区变火山岩富集HFSE(Th、Nb等)、亏损LILE(Sr、Ba等),微量元素配分模式出现明显Th、Nb正异常和Sr、Ba负异常。三类岩石的REE含量范围相互重叠,除Eu异常外,其REE配分模式均为相似的LREE富集型。各种地球化学证据表明,本区三类变火山岩为同源岩浆不同演化阶段的产物,其原始岩浆为大陆板内拉张构造环境交代富集地幔部分熔融的产物,结晶分异作用在岩浆演化过程中具有重要地位。 相似文献
11.
I. M. Gorokhov M. A. Semikhatov M. M. Arakelyants E. A. Fallick N. N. Mel’nikov T. L. Turchenko T. A. Ivanovskaya T. S. Zaitseva E. P. Kutyavin 《Stratigraphy and Geological Correlation》2006,14(3):260-274
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation. 相似文献
12.
Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA 总被引：1，自引：0，他引：1
Joseph L. Domagalski Steven P. Phillips E. Randall Bayless Celia Zamora Carol Kendall Richard A. WildmanJr Janet G. Hering 《Hydrogeology Journal》2008,16(4):675-690
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area. 相似文献
13.
Police, politics, and the right to the city 总被引：1，自引：0，他引：1
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete. 相似文献
14.
扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究 总被引：7，自引：3，他引：4
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。 相似文献
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E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns. 相似文献
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Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean 总被引：2，自引：0，他引：2
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston
situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine
fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and
at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological
(i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates)
controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution
sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were
<20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf
of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is
lost to sediments. 相似文献